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By A. W. Deurbrouck

Four samples of Pittsburgh-bed coal, of various size consist and ash content were dewatered in a pilot-size vacuum-disk filter partially enclosed with a steam jacket. Steam fed at 2.5 to 12.5 pounds per minute reduced the moisture content of the filter cakes from 2.8 to 13.8 percentage points more than normal vacuum dewatering. Approximately 1.5 pounds of steam was required to remove 1 pound of water.

Jan 1, 1966

By L. B. Pankratz

Enthalpies were determined for synthetic chalcopyrite (CuFeS2) between 298° and 1,050° K and for synthetic bornite (Cu5FeS4) between 298° and 1,100° K by copper-block drop calorimetry. Two transitions were found for each compound. The lower transitions were both crystal transformations from tetragonal (low-temperature form) to cubic (high-temperature form). The chalcopyrite transformation occurred at 830' K with a heat of transformation of 2,405 cal/mole; the bornite transformation was at 485° K with a heat of 1,430 cal/mole. The other transitions were of the second order and were presumed to be magnetic in character. The second-order transitions for chalcopyrite occurred at 930° K, and the one for bornite at 540° K. Enthalpy increments, entropy increments, and heat capacities are tabulated at even temperatures above 298.15° K. Equations of enthalpy are also given.

Jan 1, 1970

By C. Ortuglio

The effect of cracking by increasing the free space above the charge on the composition and yields of the volatile products from carbonization of Pittsburgh-bed coal and one industrially used blend from Eastern United States and one from Western United States was investigated with the BM-AGA carbonization apparatus. Increasing the free space above the charge from 1 inch to 3 inches, to 6 inches, and to 9 inches resulted in lower tar yields and increased gas and light oil yields. Anthracene and naphthalene yields were increased; quinoline and benzene insoluble fractions of both the tar and pitch increased considerably with increased free space, although the carbon content of the tars and pitches increased only slightly. Increased cracking, occasioned by the increase in free space, resulted in a decrease in the yields of tar acids, tar bases, neutral oils, olefins, aromatics, and paraffins and naphthenes. Gas composition was relatively constant; hydrogen and methane tended to increase and ethane decrease. Results of the investigation are being used to design a unit to upgrade the volatile products of carbonization by cracking the hot products as they leave the carbonization chamber.

Jan 1, 1970

By Jeffrey Shawn Peterson

In past years, the U.S. Bureau of Mines has been involved in safety research that could ultimately re-late the conditions of spark testing and actual use by estimating the simple ignition probability of a circuit in question. A major problem in estimating this probability is that results show a significant variability, even though gas mixtures and electrical parameters may be closely controlled. Some researchers have suggested that the ambient environmental conditions of the testing may influence the results. A series of tests were conducted using a spark test apparatus to simulate a failing electrical circuit. By independently adjusting the temperature, pressure, or relative humidity of the combustible gas mixture, multiple test environments were examined. At each ignition, a computer re-corded the temperature, pressure, and relative humidity of the gas immediately prior to the explosion. These data were then used to establish the effect of the test environment on the ignition probability and to create a mathematical model of the test environment's synergistic effects. The analysis indicated that these effects were not as significant as previously expected. No general algorithm was found that could be used to predict these effects across the range of circuits tested.

Jan 1, 2010

By L. Kaufman

Fifteen boride composites were synthesized by hot pressing and evaluated by physical and incendivity testing as non-sparking tool materials. The incendivity tests, conducted at the U. S. Bureau of Mines, Albany Research Center, compared the boride compo-sites with standard cobalt-bonded tungsten carbide material used for coal cutter bits. Two titanium diboride composites and two zirconium diboride composites out-performed cobalt-bonded tungsten carbide in wear resistance and reduced tendency to cause ignitions. However, three of these candidates exhibited undesirable chipping. The remaining candidate, a TiB2-(Ni, Cu) composite, did not chip, nor did it cause ignitions at levels where cobalt-bonded tungsten carbide tools caused ignitions in the incendivity tests. Thus, this material appears to be a logical candidate for further development.

Jan 1, 1973

By E. C. Tarpley, H. M. Cooper, R. F. Abernethy

The standard method of employing preliminary air-drying to determine the moisture in coal has been criticized with respect to the loss of heating value from excessive air-drying. By this method, the coal is air-dried at approximately 10-15° above room temperature with the loss in weight being less than 0.1 percent per hour, and then the residual moisture at 105°C is determined. The total moisture is calculated from these two values.

Feb 1, 1948

By G. W. Birge, D. E. Wolfson, J. H. Lynch

This report by the Federal Bureau of Mines describes the carbonizing properties of coals from the principal beds in Boone County , W. Va . Results are given for samples of coals from No. 5 Block , Stockton - Lewiston , Coalburg , Winifrede , Chilton , Hernshaw , Cedar Grove , Alma , and No. 2 Gas beds . Boone County coals rank as high -volatile A bituminous . Eighteen of the 21 samples tested contained from 3.3 to 7.9 percent ash and 16 of the samples contained from 0.6 to 0.9 percent sulfur . Two samples from the Alma and No. 2 Gas beds , the lowest stratigraphically of the seams tested in Boone County , contained from 1.4 to 2.7 percent sulfur . Most Boone County coals yield

Jul 1, 1960

By George W. Healy

The direct retorting of zinc sulfide concentrates in the presence of lime and carbon was examined on a laboratory scale with ten-gram charges of loose mix or fifteen-gram ones of pellets. A slow stream of nitrogen swept through the furnace tube over the boat of reactants, carrying with it the zinc vapor, which condensed on a rolled-up steel sheet near the exit, permitting weight of zinc produced to be obtained after completion of a run. Variables explored were percent of theoretical reagents, temperature, and time. During the runs gas samples were analysed periodically, and the content of CO2, CO and nitrogen were obtained. The quantities of the carbon gases could be calculated because the nitogen flow rate was measured. The gases were also examined for sulfur species, but neither COS nor SO2 could be detected at maximum sensitivity. Zinc recovery increased with excess carbon and lime and with temperature. It ranged from 77% at a ten percent deficiency to 90% at a ten percent excess at 1100°C. Going to 1200°C and theoretical reagents gave 93% recovery. Increasing time from 200 minutes to 300 minutes increased zinc yield by up to 10%. Results from sphalerite and a commercial concentrate from AMAX gave generally similar results. The reaction rate of zinc sulfide as sphalerite and of calcined sphalerite indicated that the latter reacted almost twice as fast, and recovery of zinc was five percent higher. Though the retorting step using sulfide, lime, and carbon proved to be non-polluting, it was feared that on storage the calcium sulfide in the residues would decompose, giving off noxious gases. Consequently the stabilization of the residues by oxidation was essayed. Because of the presence of unreacted zinc sulfide, the first product of oxidation was S02. Reaction of CaS to CaSO4 was incomplete, going from 20% at 800°C to 90% at 1200°C. Thus the non-polluting nature of the process as a whole is in doubt, and its economics are likely to be unfavorable compared to the traditional way of calcining the concentrates, followed by retorting of the oxide with carbon.

Jan 1, 1982

By Stanton L. Tainter

When the disruption of gold mining stopped the usual source of siliceous flux needed by copper smelters , sandstone copper deposits in northern Arizona offered possibilities as a source of the flux during the war emergency . The Federal Geological Survey , while making a comprehensive survey of sandstone copper deposits , investigated the Warm Springs mining district in northcentral Coconino County in August 1943. A month later , J. H. Hedges , chief of the Tucson Division , Mining Branch , Bureau of Mines , examined the operations in connection with an application for an access road . Both investigations concluded that the district , as an emergency source of copper-bearing siliceous flux , had considerable merit , provided high prices for copper continued in effect . Early in 1944 , V. M. Ryan and S. B. Atherley requested assistance from the Bureau in exploring various deposits on their property . The Bureau / drilled 152 holes , aggregating 3,756 feet , on the Petoskey and Mackin groups of claims . This report is based upon churn drilling done under contract from October 7 to November 25 , 1944 .

Feb 1, 1947

By J. M. Mutmansky, S. Padmanabhan

"The subject of quartz occurrences in respirable coal mine dusts has been of increasing concern in recent years. The primary impetus for this concern has been provided by better measurement technology that has detected an increased number of mines with high quartz content in their respirable dusts. This paper presents the results of statistical analyses of quartz levels in multi-stage impactor samples from eighteen different coal mining sections located in Pennsylvania, West Virginia, Ohio, Illinois, Kentucky, Colorado and Ucah. The quartz and kaolinite determinations were then determined by combining impactor stage loadings to provide larger dust masses and applying the infrared spectrometry procedure outlined in Bureau of Mines/MSHA Method P7.The results will be presented using two categories of data collected during two separate phases of the research:(l) quartz concentration data from mines where quartz was known to be present in relatively high concentrations, and(2) quartz concentration data from mines chosen at random.The aspects of the occurrence of quartz in coal mine airborne dusts that will be reported include the size dependence of the quartz content, quartz variations with location in the mining section, and variations due to mining region. The results of the study show a strong pattern of size dependence of the quartz content in mines for which high quartz concentrations exist. A similar, though less pronounced, pattern exists in mines chosen at random. Quartz levels appear to have a varying relationship to section location and strong geographical patterns do not appear to exist in the data collected. Kaolinite content was found to be similar to that of quartz with patterns that are somewhat more consistent."

Jan 1, 1989

By R. D. Brown

There are techniques for separating aluminum alloys from mixed scrap, but there are no efficient ways to separate wrought aluminum from cast aluminum. This Bureau of Mines report describes a novel technique for separating mixed aluminum alloy scrap into cast and wrought aluminum alloy fractions. The technique, which uses conventional heating, fragmentizing, and screening equipment, exploits differences in the mechanical properties of cast and wrought aluminum alloys at elevated temperatures. The cast alloys become brittle at high temperatures owing to intergranular melting of regions of eutectic composition. This melting begins to occur as the solidus temperature for each alloy is reached. Solidus temperatures for casting alloys generally range from 520° to 580° C, but are above 600° C for most wrought alloys. Thus, the casting alloys are easily fragmented while the wrought alloys remain ductile in the proper temperature range. Starting with a mixture containing approximately 80 pct cast and 20 pct wrought alloys, fractions of 100 pct cast and 98 pct wrought have been produced.

Jan 1, 1985

By Lewis V. Wade

This report provides background information concerning a mine roof simulator currently being considered by the Bureau of Mines. The simulator is a mechanical device with the ability to simulate the forces and displacements associated with mine roof over an area 20 by 20 feet. The topics covered in the report include a conceptual description of the system, definition of system capabilities, discussion of how such capabilities were decided upon, description of available control modes, and a comparison between the mine roof simulator facility and similar facilities existing elsewhere.

Jan 1, 1974

By R. J. Seibel

A statistical comparison of the dust exposures of coal miners with identical occupations in Pittsburgh, Pocahontas, Freeport, and Kittanning seams was conducted. Results indicated that, in some cases, identical occupations have different dust exposures in different seams. For example, the continuous miner operator in the Pittsburgh and Pocahontas seams is exposed to more dust than the same man in the Kittanning seam, but the Kittanning seam has more dust along the haulage roads than the other seams. Also, average dust exposures for similar occupations in continuous and conventional mining operations are similar.

Jan 1, 1974

By A. E. Isaacson

The U.S. Bureau of Mines determined the effect of common sulfide minerals on the corrosion rates of various types of ferrous alloy grinding media. Data obtained from this study will aid in determining the contribution of any electrochemical reactions between sulfide minerals and grinding media to the total grinding media consumption. Common sulfide minerals used in this study were chalcopyrite, galena, and sphalerite. In the presence of oxygen, chalcopyrite was found to increase the corrosion rate, galena was found to decrease the corrosion rate, and the effect of sphalerite was dependent upon the type of grinding media. Possible electrochemical reactions of these minerals in the presence of grinding media are suggested.

Jan 1, 1989

By Sabri Ergun, Robert W. Smith, Victor H. Tiensuu

Factual geometries are considered for X- ray scattering studies of weakly absorbing materials by both reflection and transmission methods . These studies are usually made on slab specimens to obtain adequate scattered intensities ; however , the intensities are appreciably influenced by absorption of the X-rays in passing through the specimens . Conventional equations derived to account for this absorption are based on idealized geometries , but for polycrystalline carbons the use of idealized geometries leads to several percent error in the corrections to be made . Use of factual geometries substantially reduces this error .

Jan 1, 1964

By A. T. Coumbe, I. F. Avery

The Bureau of Mines has completed a survey of petroleum pipe - lines by direct correspondence with the oil companies and the use of the records of the Interstate Commerce Commission in order to cover both interstate and intrastate systems . The review shows that crude petroleum and product pipe -lines in the United States had a total length of 152,814 miles on January 1 , 1950 , an increase of 25,463 miles since May 1 , 1941 , the time of the last previous survey . The expansion in pipe -line systems was due largely to new trunk-line construction , as the mileage built to carry refined products increased by 11,880 miles , and those intended for crude -oil transportation gained 6,193 miles . Trunk lines represented 60 percent of all pipe -line mileage on January 1 , 1950 , compared with 58 percent in 1941 . The average diameter of trunk -lines for crude oil , as calculated on the various sizes and weighted according to their respective lengths , increased to 9.8 inches on January 1 , 1950 , compared with 8.4 inches on May 1 , 1941. The mileage for lines up to 8 inches used in crude trunklines has decreased since the 1941 survey , while those of larger sizes have increased . The extensive use of large- diameter oil pipe -lines has developed since the construction of two major lines from Texas to the East Coast at government expense as a World War II emergency measure . The successful operation of these lines proved their economic advantages over smallerdiameter lines as well as their effectiveness in moving unprecedented volumes of oil during the period when tanker movements were restricted by submarine action in the Atlantic Ocean . The 24-inch diameter " Big Inch " line carries over 300,000 barrels daily of crude oil , and the 20 -inch " Little Big Inch " carried over 230,000 barrels daily of gasoline and light fuel oils to destinations where they were urgently needed . Hence , Although these lines were sold and converted to natural -gas service in December 1946 , after fulfilling their wartime mission , their record proved to the industry that significantly lower operating and investment costs per barrel -mile of oil moved could be achieved than were possible with the comparatively small lines in general use up to that time . the several major oil pipe -line projects that have been constructed since the late war are of large diameter pipe . To assure supplies and market outlets of sufficient magnitude to support such lines and provide adequate flexibility , ownership is often shared by several large companies whose transport needs are served in common . The principal recent expansion in facilities has been from supply points in Southwestern States toward markets in the North and East and to Gulf tidewater .

Dec 1, 1950

By W. L. Eaton

This report is the second in a series concerning the Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region; a catalog of the microfilmed maps of mines in the Wyoming Basin of the Northern anthracite field is presented. The first report I.C. 8274, published in 1965, was a catalog of microfilmed maps of mines in the Eastern Middle anthracite field. Additional catalogs will be published as the microfilming of significant mining areas is completed.

Jan 1, 1968

By Robert L. Grayson, Syd S. Peng

"An airborne dust study was undertaken at a Southwestern Pennsylvania underground bituminous coal mine by the Pennsylvania Department of Mines and Mineral Industries in 1964 for the purpose of making recommendations and requirements regarding compliance with health and safety aspects of The Bituminous Coal Mining Laws of Pennsylvania, approved by the legislature on July 17, 1961. The study was designed to accurately represent the airborne dust conditions of the subject mine. Sampling by midget impinger of specific worker locations throughout the mine was accomplished. Sample analyses yielded dust concentrations to mppcf, particle size determinations in cumulative per cent less than specified cut-off diameters, and determinations of free silica percentages in total dust samples. The data from this study is further analyzed, and the results are presented.INTRODUCTIONThe Bituminous Coal Mining Laws of Pennsylvania, enacted in 1961, prompted a study of respirable coal mine dust by the Department of Mines and Minerals Industry in 1964. In recognition of their obligation for ensuring the health and safety of bituminous coal miners, the department set out to characterize the airborne dust of mines throughout the commonwealth. The purpose of the studies was to make recommendations and requirements for compliance with the law and for control of airborne coal mine dust in Pennsylvania mines.One such study was undertaken at an underground bituminous coal mine operating in the Pittsburgh Seam in Southwestern Pennsylvania. The study was desig11ed to sample specific worker locations throughout the mine site and characterize the respirable dust relative to each of them. A midget impinger was used to gather respirable range dust samples during an 8-hour shift. Continuous miner operator, roof bolter, stoper bolter, loading machine operator, shuttle car operator, gathering motorman, mainline motorman, and rotary dumper jobs were sampled underground. In addition, barge mover, coal sampler, fine coal operator, heavy media operator, and boiler room attendant occupations were sampled on the surface. The surface sampling was over a 71-hour shift because of UMWA contract provisions."

Jan 1, 1988

By L. B. Pankratz

The Bureau of Mines conducted heat-content measurements above 298.15° K for dehydrated analcite (NaAISi2O6) to 1,000°K, kaliophilite (KA1Si04) to 1,800° K, and leucite (KAlSi206) to 1,800° K. Heat content and entropy increments were tabulated, and the heat content data, were given in equation form. A first order transition was noted for kaliophilite near 810° K with a heat absorption of 160 cal/mole. Leucite had a second order transition which became complete near 955° K. In this transition a crystal change occurred from tetragonal (low-temperature form) to cubic (high-temperature form).

Jan 1, 1968

By B. W. Gandrud, G. T. Bator

The recent introduction of small coal jigs in Alabama to meet the needs of truck - mine operators for cheap and economical cleaning equipment marks another step in Alabama's pioneering record in the mechanical cleaning and preparation of coal . During the past 4 or 5 years a number of these small jigs , with capacity of 5 to 10 tons per hour , have been installed at Alabama truck mines and at a few truck mines in Illinois , Tennessee , and Pennsylvania . Most of the installations have been at mines that specialize in the production of domestic , stoker coal . This report describes three models of small jigs and includes performance data obtained recently on one of the models by the Bureau of Mines, United States Department of the Interior , in cooperation with the University of Alabama, Tuscaloosa , Ala . , for the purpose of comparing it with fullsize jigs on a performance basis . With literally hundreds of truck mines now in operation throughout the country , it has been assumed in preparing this report that there is widespread interest in the availability of small - scale inexpensive preparation equipment for use at such mines in the production of steam and domestic coal and in some instances coal for manufacture of coke . Practically none of the coal from Alabama truck mines is scld to coke - oven plants ; but in some sections of the country truck mines supply a considerable amount of coking coal, and the use of small, inexpensive washers at some of them might be very advantageous during the present war emergency from the standpoint of increasing pig - iron production through improvements in coke quality .

Aug 1, 1943