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By H. J. Heinen

This report summarizes preliminary research studies by the Bureau of Mines in electrowinning molybdenum directly from pure or impure molybdenum trioxide (MoO3) by fused-bath electrolysis in an open graphite cell without need of a protective inert atmosphere. A formulated electrolyte of the tertiary system containing 41.6 percent sodium pyrophosphate, 16.7 percent sodium tetraborat, 33.3 percent sodium chloride, and 8,4 percent molybdenum trioxide, by weight, electrolyzed at 1,000° C,, gave excellent results. Current density studies were made over a range from 20 to 260 amperes per square decimeter. Current efficiencies of 80 to 90 percent were obtained over the entire range. Yields up to 500 grams of molybdenum per kilowatt-hour were obtained. Higher current densities, however, reduced yields and produced a finer grained metal. The two most important facets in electrowinning molybdenum from MoO3, in an open cell, are temperature and electrode spacing to minimize or eliminate the formation of the suboxide MoO2, the major source of oxygen contamination. At temperatures of 1,000° C. and higher, together with the proper spacing of the electrodes, formation of oxides are practically eliminated. Molybdenum metal electrowon from pure MoO3 was 99.9 percent pure and contained 0,056 percent oxygen and 0,007 percent carbon. This metal, when arc-melted, had a Vickers hardness number of 175 and contained 50 parts per million oxygen and less than 10 parts per million carbon. Molybdenum metal electrowon directly from an impure MoO3 containing 90 percent MoO3 resulted in a metal of 99.8 percent purity.

Jan 1, 1961

By Donald R. Corson

The Bureau of Mines is conducting research on the effects of various established and potential soil-stabilization additives to hydraulic backfill. This initial phase is an evaluation of the effect of inclusion of varying amounts of Portland cement and combinations of cement and a dispersant on the bearing strength of backfill. Results of unconfined compression tests are given for over 200 sample cylinders incorporating a fill material with cement or cement and dispersant. Inclusion of a minor amount of dispersant (0.2 percent by weight) is found to yield a significant increase in strength for 20-to-1 and leaner sand-cement mixes. An apparent optimum concentration of dispersant exists beyond which no further increase in strength is achieved. A dispersant-cement ratio of l.8- to-1 yielded a strength increase of 515 percent over the strength of untreated 40-to-l sand-cement mixes.

Jan 1, 1966

By R. A. Beall

Homogeneous zirconium-alloy ingots have been cast on a production basis by the consumable-electrode arc-melting process at the Northwest Electrodevelopment Experiment Station, Bureau of Mines, Albany, Oreg. This paper describes the various methods used to introduce alloying materials into the ingot and evaluates 1 each method by the degree of homogeneity of resulting ingots, as determined in tests on sections cut from the ingots. As many as 30 or more ingots, each 6 to 10 inches in diameter and weighing 300 to 500 pounds, were melted, using each method; and, as most of them subsequently were fabricated to strip 0.1 inch thick, the test results are considered to be representative of production practice. Ingot homogeneity has been considered more difficult to achieve in arc-melting practice than by methods where the molten metal is poured into molds and the addition can be stirred into the total mass of metal before casting. Owing to the unique requirements of consumable-electrode arc melting the addition can be made only to that part of the total mass of the ingot that is molten at one time. Observation of the flowlines in 500-pound ingots produced at Albany indicates that the molten pool has a maximum depth about equal to the ingot diameter. The weight of metal molten at one time is, therefore, not over 100 pounds. Characteristically, the arc-melting process is conducive to segregation, which can be overcome, at least partly, by adding the alloy constituents almost continuously during casting.

Jan 1, 1956

By D. Harrington

We Americans pride ourselves that ours is the greatest, most advanced and most civilized nation in the world, yet statistics indicate that apparently we have little appreciation for the lives and limbs of the people whose efforts give us whatever greatness we possess. The latest available statistics indicate that the annual accident death rate per 100,000 of population is nearly 80 or far higher than that of any other country in the world except Chile; is more than double the rate in Hungary, Netherlands, Ireland, Belgium, Denmark, Italy, Germany, Norway, Sweden, and Finland; is nearly double that of England, Wales, the Union of South Africa, New Zealand, Japan, Australia, and Scotland; and is 25 to 40 percent greater than Switzerland, France and Canada. To make matters worse, from the viewpoint of mining; the latest available statistics give mining by all adds the worst accident rate of the major industrial occupations in the United States, the accident severity rate for mining in 1935 being listed by the National Safety Council as 10.14, the next highest rate being 4.52 for construction, and the average rate for 30 main industries being 1.58. IMPROVEMENT IN SAFETY RECORDS Offsetting to a slight extent this rather dark picture is the fact that starting about 1930 the mine-accident rate in both coal and metal mining began to fall, reaching an all-time "low" in metal mining in 1932 and in coal mining in 1933. It now appears probable that the year 1936 has again lowered the accident rate in coal mining and this, together with the fact that the years 1933, 1934, 193 5, and 1936 all set much lover accident rates in coal mining than ware achieved for any similar previous period, gives hope that the trend is definitely in the right direction, though from the above figures mine-accident severity has a long, tedious road to travel before it becomes as low as the severity rate of all other major industries in the United States.

Jan 1, 1937

By D. M. Soboroff

Etchants containing hexavalent chromium and sulfuric acid are used in a variety of surface-finishing operations. When the resultant spent solutions are discarded, substantial quantities of chromium are lost and pollution prob¬lems are created. To minimize the undesirable environmental effects while improving metal and minerals recycling technology, the Bureau of Mines is conducting research on a method for the economic inplant recycling of these waste etchants. Trivalent chromium, produced when the etchant reacts with a sub¬strate, is oxidized in the anode chamber of a diaphragm cell; other metals, dissolved during the etching operation, are transferred to the catholyte. When waste brass etchants are treated in this manner, all of the trivalent chromium is oxidized and more than 40 percent of the copper and zinc is removed. Similar copper removal and chromium oxidation are achieved with waste printed circuit board etchants and rinse waters from plastic etching operations. The electrical energy needed to regenerate 1 kg sodium dichromate is less than 9 kwhr. Regenerated brass etchants evaluated by two companies equaled or exceeded the performance of fresh etchants.

Jan 1, 1979

By A. B. Hooker

Nineteen of the installations were on rental contracts 1.L."'1der whtch the lamps belong to the lamp company and are rented by t.½em to the mine operatj.nt; company. · The other nine installations had been upon an O\Vnership-rental basis, by which the lamps had become the property of the renter at the end of 5 years. Five of t.11e rentec installations were en a special contract calling for a guaranteed light output. These contr2.cts were based upon certified . initial performance, with the provision that the lamps be replaced whenever periodic tests of fully charged lamps, taken at random from t..h.e charge racks, showed a light output of less than 80 percent of the certified performance.

Jan 1, 1942

By Oliver Bowles

"Properties and Uses.Iceland spar is a name given to a pure crystallized form of calcite (CaCo3) which is sufficiently transparent and free of defects to be used in the manufacture of optical instruments. While the actual requirements are small, the degree of purity and physical perfection demanded renders it somewhat difficult to obtain suitable material.The properties of value in Iceland spar are its transparency combined with double refraction. It is used in the manufacture of polarizing microscopes, saccharimeters, colorimeters and photometers. Its most important use is in the manufacture of Nicol prisms, which constitute an essential part of every polarizing microscope. The principle governing the construction of the Nicol prism is as follows:Ordinary light in passing through a crystal of calcite is resolved into two rays of plane polarized light vibrating in planes at right angles to each other and having different indices of refraction. Thus the two rays follow different paths through the crystal. The prism of Iceland spar is cut diagonally and cemented together again with a transparent cement having an index of refraction intermediate between the two rays passing through the prism. Canada balsam is employed for this purpose. The prism is cut at such an angle that the ray having the greatest index of refraction meets the surface of the balsam at an angle greater than the angle of total reflection, and it is thus deflected to the side of the prism, while the second ray passes through. Thus one of the rays is eliminated and polarized light vibrating in a single plane is obtained."

Apr 1, 1920

By R. L. Grant

The Bureau of Mines applied automatic computational methods to analyze the degree of correlation between sound transmission and atmospheric conditions. Statistical analysis of data collected over a 5-month period indicated that the following weather variables, listed in order of decreasing importance) have a significant effect on the transmission of sound in the atmosphere: 1. Wind velocity and wind direction. Winds in the direction of travel of the sound wave increase the sound intensity and duration. 2. Barometric pressure. High pressures are related to low sound intensities and durations. 3. Atmospheric temperature. High temperatures are related to low sound intensities and durations. Inversion of the atmospheric temperature did not appear to affect sound transmission under the conditions of this study.

Jan 1, 1967

By W. E. Wallace, C. A. Hill, M. J. Keane

"Diesel exhaust particulate material from exhaust pipe scrapings of two trucks, diluted automobile diesel exhaust particulate material collected on filters, and two oil shale ores were prepared for the Ames mutagenrcity assay by dichloromethane OOP ex¬traction, by dispersion into 0.85% saline, or by dispersion into dipalmitoyl lecithin (DPL) emulsion in saline. Salmonella typhimunum TA98 was used to detect frameshift mutagens in the samples. Samples of diesel soot gave positive mutagenic responses with both DCM extraction and DPL dispersion, with the DPL dispersion giving higher results in some cases. The results suggest that possible mutagens associated with inhaled particles may be dispersed or solubilized into the phospholipid component of pulmonary surfactant and become active in such a phase.INTRODUCTIONThe Ames Salmonella/microsome assay (Ames et al., 1975) has been shown to be a useful test for detecting genotoxic properties of various agents. Hundreds of specific chemicals have been screened (McCann et al., 1975), and the test has been applied for many types of environmental samples. Airborne mutagenic agents, for example, have been found in urban air (Chrisp and Fisher, 1980; Hughes et al., 1980; Ro· senkranz et al., 1978), in diesel engine exhausts (Huisingh et al., 1978), and in the by-products of coal combustion processes (Chrisp et al., 1978).Samples of airborne particles are typically collected on membrane filters, and undergo a rigorous extraction procedure with organic solvents and/or ultrasonic agitation (Clark and Hobbs, 1980). Often extracts are transferred to another solvent that is compatible with the assay system. These extraction procedures, while efficient from an analytical perspective, are not physiologically plausible. The questions that present themselves are whether a demonstrated mutagen can be taken up in vivo and whether the process is quantitatively or qualitatively different from the above laboratory procedure (Wallace et al., 1984).When a particle of respirable size is inhaled to the alveolar region of the lung, its first physiological contact is with pulmonary surfactant that lines the inner surfaces of the alveoli. This surfactant is an aqueous fluid containing proteins, phospholipids, and other components (R. J. King, 1982). The principal phospholipid constituent is L·alpha-phosphatidylcholine, beta,gamma-dipalmitoyl, or dipalmitoyl lecithin (OPL) (l. C. King et al., 1981)."

Jan 1, 1989

By C. J. Cohen, L. A. Dahners

"SUMMARYA method has been developed for surveying, drill holes without lowering into the hole any surveying equipment other than an etch tube. The orientation of the rods at the collar of the hole is maintained as the etch tube is lowered. The attitude of the etch ellipse in depth with respect to the rod orientation at the collar can then be observed. This relationship permits the bearing of the hole in depth to he calculated. The rod orientation is maintained during the lowering by means of a pair of alinement clamps. One clamp is fastened to the top of each rod as the rod is coupled and is removed when the alinement has been transferred to the other clamp at the top of the next succeeding rod. A particular advantage of this survey technique is that surveys can be readily made in magnetic country rock.PRINCIPLE OF THE TECHNIQUEAn axial lamina of the column of drill roes is the lamina in which one fiber would be the centerline of the rods. In the new survey technique, the rods are fed into the hole in such a manner that the axial lamina of each successive rod maintains its position at the collar of the hole. In depth, as the rods bend in following the drill hole, the axial laminae also bend. The lamina that was originally vertical will, in general, be tilted away from the vertical. The trace of this lamina is marked on the glass etch tube before the tube is lowered in the hole. The axial lamina that becomes vertical at the survey station is recognized as that axial lamina which contains the long axis of the etch ellipse. The angle between the lamina originally vertical and the lamina vertical at the survey station is thus measurable. When the vertical axial lamina at one survey station has been determined by the etch ellipse at that station, angle R between this lamina and the vertical axial lamina at the next survey station becomes measurable also. By moans of angle R, and dip angles D1 and D2 at the two stations, the change in bearing (z) of the drill hole between the two stations can be calculated."

Aug 1, 1944

The principal activities of the Bureau of Mines Pittsburgh Mining and Safety Research Center during fiscal year 1971 (July 1, 1970, to June 30, 1971) are reviewed in part 1 of this paper. Part 2 summarizes publications during fiscal year 1971.

Jan 1, 1974

By R. R. Sayers

There is probably no industry , trade , or art in which mercury is used but what has produced some cases of mercury poisoning . This is true of the mining and smelting of mercury , where the hazard has long been recognized . When the ore contains free mercury or the more soluble salts , and when the workings are underground and are poorly ventilated , cases occur , but there are a far greater number of cases among the employees about the reduction works . 3 In 1863 William V. Wells visited the mines at Almaden , * Spain , which were worked by convicts . He reported that the men at the furnaces suffered severely , being able to work only about one week out of four , when it was necessary to transfer them to places where the exposure was less . He states that "pale cadaverous faces and leaden eyes are consequences of even these short periods . " Mercury , like lead , when absorbed in small amounts at intervals , as daily, over an extended period of time will result in symptoms of poisoning . This is due to the fact that the mercury is eliminated from the body more slowly than it is absorbed . The frequency and severity of cases of mercury poisoning are far less with modern methods of mining and recovery of the metal than formerly . However , further reduction is possible and much can be done by both the workmen and the operators by following the proper precautionary measures , some of which are described in this chapter .

May 1, 1922

By T. G. Mayhew, A. A. Bergeron, R. J. Mahany

This report describes an operational communications system which provides remote intra-terrestrial wireless transmission of environmental information. Design and modification specifications of requisite equipment are included along with a detailed description of system operation

Jan 9, 1976

By E. C. Tarpley

The Federal Bureau of Mines has studied solvent extraction as a means of concentrating the mineral components in coal. Solubilities of a number of American coals were determined using abietic acid as a solvent. The effect of rank on solubility was investigated, and maximum solubility was found with coals of intermediate rank. Vitrinite is the most soluble petrographic component; fusinite, micrinitc, and exinite are nearly insoluble. Spore exines also have a low solubility. Abietic acid is a hydrogen donor and reduces pyrite to ferrous sulfide. Mild hydrogenation of high-molecular-weight fragments of the coal structure to those of lower molecular-weight probably contributes to the solvent action. Even where solubility of the coal substance exceeds 90 percent, contamination of the mineral matter with coal makes identification of the mineral components difficult. Further separation might be possible by the application of float and sink techniques to the residue. INTRODUCTION Work n the solvent extraction of coal is conducted to recover commercially useful products and to characterize coal;. and obtain information on their structure. Some coals, particularly those of low rank, contain waxes, resins, and humic acids which can be removed by solvent extraction and find varied industrial uses. In World War II, solvent extraction of coal was conducted on a commercial scale in Germany to obtain a low-ash feed material for hydrogenation and to produce electrodes carbon for the aluminum industry.4 5/

Jan 1, 1960

By Lawrence W. Scott

This report presents several systems for continuously monitoring the quality of air in underground mines that are being developed by the Bureau of Mines. Underground stations measure methane, carbon monoxide and nitrogen dioxide concentrations, air velocity, and air temperature. This information is transmitted over a single telephone pair to central stations located on the surface. The central stations display alarms and the data is selectably displayed on digital panel meters.

Jan 1, 1977

By L. M. Chan, D. H. Carlson, J. B. Johnson

"Abstract — Concentrations of tailpipe pollutants from diesel-powered. underground mine vehicles change over time due to engine wear and the need for maintenance. Since this deterioration in pollutant emissions may adversely affect the air quality in an underground mine, it should be monitored and controlled. This paper presents decision criteria concerning when to service a mine vehicle diesel engine. These criteria, based on mine air and tailpipe concentration measurements, are designed to maintain the tailpipe concentrations within limits that assure satisfactory mine air quality.Application of the deterioration criteria to mine vehicle emissions involves:establishing, for each pollutant, the allowable deterioration factor, anddetermining the deterioration factor, from the mine air and tailpipe diesel pollutant measurements, and the mine air threshold limit values (TLVs).If the deterioration factor is greater than or equal to the allowable deterioration factor the vehicle is removed from service for maintenance.An analysis applying the criteria to measurements made in an underground coal mine is presented. The tailpipe pollutant concentration data were collected using the Emissions Mea-surement Apparatus (EMA) developed by Michigan Techno-logical University. Since the TLV for diesel particulate matter (DPM) has not yet been established assumed mine air DPMTLVs of 15 and 1.0 mg/m3 were used in the analysis. For all of the diesel haulage vehicles included in the analysis. DPM was found to be the critical pollutant (the one most in need of control). For an assumed mine air DPM TLV of 15 mg/m3 none of the diesel haulage vehicles would he removed from service. However reducing the DPM TLV to 1.0 mg/m3 would make it necessary to remove two of the three vehicles tested from service."

Mar 1, 1992

By Raymond M. Stateham

Climatic conditions are compared with roof fall occurrence from April 1, 1972, to December 31, 1975, by the Bureau of Mines. These comparisons indicate that humidity has a strong influence on roof fall occurrence rates. Cubic regression techniques are used to develop best fit curves. Statistical analysis of these curves indicate that both are sinusoidal and exhibit positive correlation with each other. The sine waves have a period of 1 year with maximum and minimum inflection points in August and February.

Jan 1, 1978

By H. J. Heinen

The Bureau of Milts studied repetitive batch electrowinning of molybdenum from molybdic oxide ) to determine the effects upon the electrolyte life, purity of metal product , and overall cell performance. The electrolyte consisted of 54.0 weight-percent sodium tetraborate (Na2B407), 23.6 weight-percent sodium chloride (NaC1), 14.9 weight-percent sodium fluoride (NaF), and 7.5 weight-percent Mo03. The feed materials were pure and technical-grade Mo03. Electrolysis was conducted at l,000° C in a graphite cell in an atmosphere of air and carbon oxides. Electrolyte degradation did not occur during repetitive winning of molybdenum from pure Mo03 in an 8-day (5,400-ampere-hour) period of operation. Electrowon metal contained <0.1 percent total impurities. The electrode configuration is a key factor in the direct conversion of technical-grade Mo03 to metal by repetitive cyclic electrolysis. The best configuration found was a cathodic crucible and a central anode. Metal purity of 99.8 percent and a current efficiency of 91 percent were maintained until the combined impurity buildup the electrolyte reached 4.7 percent silicon, l.0 percent aluminum, and 0.6 percent iron. One pound of molybdenum was produced per 1.5 pounds of solvent salts employed. About 25 percent of the initial NaCl and NaF contents of the electrolyte were lost owing to volatilization and crucible penetration.

Jan 1, 1966

By D. Harrington

Advocates of health and safety in mining have found themselves confronted in recent years with what might appear to be contradictory procedures with regard to dust occurrence in mines and what appear to be suitable methods or measures to give the mines and mine workers a maximum measure of protection against dust. A concerted and relatively effective drive has been made to introduce rock dust into bituminous and lignitic coal mines to prevent or limit explosion and fire disasters, while an equally determined effort has been and is now being made to curb rock dust or to eliminate it from air in metal mines to prevent or at least limit the occurrence of miners&apos; consumption and other diseases. Both procedures are logical even though the efforts appear to be of an opposing nature. While rock dusting has not been applied in coal mines nearly as universally or as effectively as could and should be done, nevertheless a careful analysis of the record of the past 10 years indicates that the amount of rock dusting that has been done has resulted in the saving of a minimum? of 200 lives annually certainly no small achievement. Largely but by no means wholly due to the use of rock dusting, the number of fatalities from explosions and fires in our coal mines in the last 4 years haw been reduced more than 75 percent as compared with the 4-year period 1911-15, the first years of the existence of the United States Bureau of Mines, which was brought into existence in 1910 largely to try to do something about reducing the disgracefully high fatality occurrence from explosion disasters in our coal mines. Hence, rock dusting has been given at least a. trial and has proved its effectiveness definitely.

Jan 1, 1937

By Wm. W. Odell

A study of certain gas making and fuel problems peculiar to the gas industry of California has been made by the Bureau of Mines. The work was done at the request of, and in cooperation with The California Gas Research Council 2, for the purpose of obtaining basic information on the gas-making fuels available to California, and their applicability to the present and future needs of the gas industry in that State. The data obtained have been applied in outlining a construction program, and indicate the possibilities in efficiently utilizing fuels in making gas by other than the oil-gas process. This paper presents an outline of the study and a summary of the principal results obtained, with some of the more important conclusions and recommendations based on this data. Gas is produced in California by processes which are both unique and different from those common to other parts of the United States. The bulk of the manufactured gas is made in and distributed from two main districts which are centers of population - namely, the Los Angeles district and the San Francisco Bay district. The gas manufactured in the Bay district is, almost exclusively oil-gas, whereas that produced in the southern part of the State, where natural gas is available, is mostly mixed natural gas and reformed-gas, but oil-gas is the chief product when the supply of natural gas is inadequate. Practically all of the gas companies are equipped with oil-gas generating apparatus, and anticipate using it in the future. As the continued use of the oil-gas process to the exclusion of all other processes, depends upon a continued supply of oil at a low cost, and the prospect of obtaining such low-priced oil in the future is somewhat uncertain, the questions have arisen: What will the future gas-making process or processes be? When will it be necessary to make plans for the installation of different gas generating equipment, and what will that equipment comprise?

Jan 1, 1926