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By J. Roger Loebenstein

ASARCO Incorporated, the only domestic arsenic producer, terminated copper-smelting operations and the associated recovery of byproduct arsenic trioxide at Tacoma, W A. in 1985. It still shipped small quantities of trioxide from its remaining stocks in 1987. Imports for consumption of arsenic trioxide were slightly higher than in 1986. Domestic Data Coverage.-Shipments of small amounts of arsenic trioxide from remaining stocks by Asarco were reported voluntarily to the Bureau of Mines.

Jan 1, 1989

By Fred Leighton

The Bureau of Mines monitored a rock-burst-prone pillar in a metallic ore vein, up to and through failure, to measure its reactions to increasing loads, as it was mined. Three parameters were monitored: the stress changes at chosen points within the pillar, the displacement characteristics of the drift above the pillar, and the micro-seismic activity in and around the pillar. In descending order of effectiveness, the microseismic technique, vibrating wire stress measurements, and displacement measurements reflected the pillar reactions, and all showed good correlation to one another. A major rock burst in the pillar, which destroyed about 100 feet of drift above the pillar, occurred at the end of this study. This burst was preceded by a large anomaly in the microseismic activity in the failure area.

Jan 1, 1982

By A. N. Styler

As part of its water-jet assisted rock cutting research, the Bureau of Mines has initiated a study into the mechanism of rock fragmentation by water-jet-assisted mechanical tools. The objective of this research is to increase coal extraction efficiency by seeking an improved understanding of the synergistic relationship between mechanical cutters and water jets, enabling the design of more effective cutterheads. Rock chips collected during laboratory traverse speed jet-assisted cutting tests were analyzed with respect to the size distribution of the chips and the forces measured during cutting. As the water-jet pressure was increased, the size distribution of the product became coarser with V-face type cutting tools producing less fine material than conical cutting tools. Fracture mechanics theory accounted for less than 10 pet of the energy consumed during fragmentation of the rock. The energy consumed by processes other than rock breakage decreased with the use of water jets and increasing advance rate.

Jan 1, 1987

Reduce longwall intake contamination by controlling respirable dust generated by the stage loader. Approach Install a water-powered scrubber on the stage loader immediately outby the crusher. Dusty air from the crusher is drawn through the scrubber and a clean air discharge is delivered into the primary face airflow. How It Works The contamination of intake air is a significant dust control problem often overlooked on many longwall faces. This dust source contributes to the full shift dust exposure of all face personnel, and thus can significantly affect compliance with Federal regulations. Several sources contribute to contamination; however, dust generated by the stage loader crusher is the single largest source. The breaking action of the crusher generates a tremendous quantity of dust, which mixes with the primary ventilation airstream and is carried down the entire length of the longwall face. The installation of a water-powered scrubber (see diagram) has proven effective in controlling crusher-generated dust. The scrubber is mounted immediately outby the crusher. A duct is placed over the scrubber intake and attached to a flanged opening over the crusher discharge. In

Jan 1, 1982

By W. W. Adams

"Fatal accidents at coal mines throughout the United States killed 234 employees during January 1924, according to reports from State mine inspectors to the Bureau of Mines of the Department of the Interior, Included in the number of fatalities are 68 deaths caused by two explosions during the month, one explosion occurring in a mine at Johnson City, Ill., and causing 32 deaths, and the other in a mine at Shanktown, Pa., and causing 36 deaths. The fatality rate for the month was 3.94 per million tons, based on a production of 59,435,000 tons of coals In January 1923 the fatality rate was 3.52, based on 206 deaths and an output of 58,458,000 tons.Bituminous mines in all States reported 202 fatal accidents, the production being 51,170,000 tons., and the fatality rate being 3.92, as compared with 3.28 for January last year, For the anthracite mines in Pennsylvania, the reports covered 32 fatalities, which, on the month's output of 7,955,000 tons, indicated a fatality rate of 4.02 per million tons, as against 4.89 for January 1923.As compared with January 1923, the reports for January of the present year indicated lower fatality rates per million tons for all of the main causes of accidents except explosions. For falls of roof and coal, the fatality rate per million tons declined from 1.85 in January 1923 to 1,68 in January 1924; for haulage accidents the rate declined from 0.62 to 0.42; for explosives, from 0.19 to 0.12; for electricity, from 0.12 to 0.07. The rate for explosions increased from 0.21 to 1,31 per million tons. -- Reports of Investigations, Department of the Interior, Bureau of Mines."

Feb 1, 1924

Develop a down-hole replaceable diamond core bit that will reduce overall drilling costs and increase total available drilling time per hole. Approach A one-piece diamond core drill bit of unique geometric shape has been designed, fabricated and field tested. The bit can be withdrawn (or replaced) from the bottom of the well-bore without removing the drill rods from the hole, saving a significant amount of non-productive drilling time. How It Works The replaceable bit system consists of two basic subsystems: the removable core bit, and the equipment necessary to replace the wornout bit without pulling the drill rods out of the hole. The geometric configuration of the bit is that of a one-piece diamond studded cutting element created by "slicing off" two parallel sides of a conventional diamond cone bit. This geometric configuration, along with some minor modifications to the outer core barrel, allows the bit to be rotated in two planes and, with the retraction-insertion tools, raised or lowered through the interior of the drill rods using a conventional wire-line system. For example, to retrieve the bit, a retraction tool is lowered through the drill rods using a conventional wire-line system and at the hole bottom, the tool automatically orients itself within the outer core barrel.

Jan 1, 1981

Lower the respirable dust expo? sure of longwall shearer operators Approach Use improved water sprays on the shearer machine to direct the dusty air toward the face. In laboratory tests and actual mining conditions, the shearer-clearer has proved to be an effective dust control technique. Recent field experience however, has indicated that not enough technical information is available on proper installation of the improved shearer-clearer. This Technology News will provide details of the Improvements made to the shearer-clearer and provide guidelines for installing the system. How It Works The shearer-clearer system consists of several strategically-mounted water sprays and one or more passive barriers. The sprays redirect the airflow around the shearer into both a clean and a contaminated split. The sprays confine the contaminated split or dust cloud to the coal face, allowing the shearer operators to remain in the clean split on the walkway

Jan 1, 1986

By J. A. Organiscak

Two types of airflow splitting methods for improving longwall dust control were investigated by NIOSH's Pittsburgh Research Laboratory. These methods included a translucent mesh barrier and a staged spray barrier system to confine the shearer-generated dust to the coal extraction side of the longwall face while maintaining a cleaner split of airflow on the opposing worker walkway side of the longwall face. The translucent mesh barrier was shown to provide notable dust control effectiveness up to 60 m downstream of the shearer in both the laboratory experiments and a longwall field evaluation, provided the mesh barrier remains relatively parallel to the airflow. The staged spray barrier system showed marginal dust control effectiveness in the laboratory and subsequently was not field tested.

By Charles L. Kimbell

This study is intended to serve three roles. First, it is the second annual edition of this study in a separate volume that represents a global overview and summary to supplement and complement the five regional volumes that now constitute the U.S. Bureau of Mines international, geographically arranged studies. In this regard, it also extends previous works under this title that appeared in the inter-national volume of the Minerals Year-book from the inception of that volume (the 1963 edition) until it was subdivided into six separate volumes in 1989. Following the traditional format of past chapters under this title, the basic statistical presentations herein deal chiefly with 1990, and in a few instances with 1988 or 1989; these latter two only because more recent, comprehensive global statistics simply are not yet available owing to delays in data collection and processing in some countries and continued governmental suppression of data in others. The second role of this study is to provide an update to the coverage of events impacting on the world's mineral industry that have occurred between the end of 1990 and the preparation of this study. Inclusion of this update is almost essential because of the potential effect of some of these events on global mineral industry activities.

Jan 1, 1993

Improve the effectiveness of face ventilation systems in coal mines by minimizing leakage around line and check curtains. Approach In-mine surveys were conducted to determine current curtain construction techniques, their effectiveness and associated costs. In addition, performance characteristics of extensible curtains were evaluated. A total of 77 conventional curtains in 10 mines was examined for 12 important characteristics. Extensible curtains were erected in a full-scale model and examined for operational difficulties, effects of leakage, and air pressure. Survey Results The underground mine study identified four categories of face brattice construction ranging from simple to complex: 1. Simple suspension of the curtain from roof bolts with the bottom edge lying on floor. 2. Spadding of the curtain to the roof on about 12-inch centers and stabilization of the bottom edge with wood or rock. 3. Use of vertical props and spads with a base board for support on the bottom. 4. Use of vertical props with caps and bottom boards plus horizontal brattice support boards.

Jan 1, 1984

Develop a safer, more effective, and more efficient method to control fires in abandoned coal mines and waste banks. Maintain the costs of this new method at less than or comparable to conventional AMI fire control methods. How It Works Cryogenic extinguishment of subsurface fires is a method of heat transfer. Bureau-designed injection equipment produces a pumpable slurry of liquid nitrogen and solid particles of carbon dioxide. Liquid or gaseous carbon dioxide from a pressurized tank flows to a bell-shaped nozzle where the change in pressure causes the carbon dioxide to form a granular snow. The solid carbon dioxide is mixed with liquid nitrogen. A jet pump is used to move the slurry through the delivery lines and into a simple injection probe. At injection, the nitrogen vaporizes and the carbon dioxide sublimes. This phase change produces a cold gas (-180° C) that, as it expands and moves in all directions, removes heat and also displaces oxygen. This combined process inhibits the combustion process and lowers the temperature below the reignition point. When the liquid nitrogen and solid carbon dioxide are converted to gases, the expanding gas acts like a piston, forcing warm air out of the porous bed, Although smoke and hot gases arc forced from the burning coal, generally there is no significant increase in the odor associated with burning coal.

Jan 1, 1992

Develop new technology to encourage domestic processing of automobile catalytic converters for recovering platinum -group metals. Background Automobile catalytic converters are used to convert pollutants in automobile exhaust into water vapor, carbon dioxide, and nitrogen, About 1 million troy ounces of platinum-group metals arc used each year in the. United Slates to manufacture catalytic converters. It has been estimated that about 60 pct of the used catalytic converters arc being collected. Most of these used catalytic converters were not processed in the United States but were exported to Japan or Europe for processing. In 1991, about 250,000 troy ounces of platinum-group metals were recovered from scrap catalytic converters collected in the United States. Each short ton of decanned catalyst may contain 30 troy ounces of platinum-group metals valued at over $15,000. Development of an economic process for the recovery of platinum-group metals that can be operated on a small or large scale may increase, the percentage of catalytic converters collected and encourage domestic processing to recover a platinum-group metal concentrate. This would significantly decrease the dependence of the United States on imports for these critical and strategic metals.

Jan 1, 1992

Reduce the cost and incidence of low-back pain in underground coal mines through redesign of materials-handling tasks. Background Approximately 25 pct of all injuries in mining involve trauma to the hack. These injuries account for at least 30-40 pct of worker compensation payments made by the industry, are the leading cause of lost work days in mining, and have been estimated to cost the industry $50 million annually. It is clear that the traditional approach to reduce back injuries (i.e., training) has been largely ineffective. Thus, new approaches are necessary to control this problem. This document briefly describes methods that can be used to redesign hazardous materials-handling tasks to reduce the threat of worker injury. Approach A model for redesigning materials-handling tasks is shown in figure 1. The model outlines the sequence of steps that should be followed (and questions that should be asked) when developing new strategies for handling materials in underground coal mines. A critical examination of the current supply-handling system is the first step to developing safer materials-handling procedures. The purpose is to identify hazardous tasks that can be modified to reduce injury risk. Accident analysis (a review of past accident records) and task analy¬sis (usually a videotaped analysis of hazardous jobs or tasks) arc effective methods of distinguishing areas where job redesign is needed.

Jan 1, 1992

To more rapidly and economically prepare solutions for chemical analysis, of a wide range of ores, slags, minerals, and metals. Approach A Simple pressure-dissolution system was devised using an inexpensive, heavy wall plastic bottle containing a sample in an acid medium. Using the technique, a complex silicate sample can be dissolved in less than 1 hour. How It Works A weighed portion of a sample, ground to minus 100-mesh, is placed into a polycarbonate or polysulfone plastic bottle. A mixture of hydrochloric acid, nitric acid, and hydrofluoric acid then is added. The bottle threads are wrapped with a layer of Teflon tape to prevent leakage, and the bottle cap is screwed on tightly. The sealed bottle is placed in a balling water bath. In the hot water, the plastic bottle acts as a pressure vessel to contain the pressure generated inside it. This technique should only be used by trained experienced people who are familiar with the hazards of hot acids under pressure. After being cooled in cold water, the resulting solution is brought to the final volume by adding 1.5 weight-percent boric acid solution to the bottle. The cap is replaced, and the bottle and solution is reheated. Precipitated fluorides, as well as any residue, are dissolved by the fluoride-boric acid reaction. The resulting clear solution then is suitable for spectro-photometric examination or other analysis.

Jan 1, 1980

By Edward Thomas

"HISTORYThe origin of roof bolting as a means of roof support is obscure. During the past 23 years a method was developed by the. St. Joseph Lead Co: at its mines in southeastern Missouri, ranging from occasional use of single bolts with small bearing plates to systematic networks of bolts utilizing continuous bearing plates. Officials of this company are not certain which of its employees suggested their use. Many instances of occasional use of roof bolts have come to light during the past few years in widely separated mining districts, such as in West Virginia, Alabama, Illinois, Colorado, and Wyoming bituminous coal mines, and in Pennsylvania anthracite, Lake Superior iron, and Colorado lead-zinc mines. A few of the known installations have boon in place as long as 40 years.These installations usually were made to supplement wooden timbering in mine openings whore space was constricted, although it had been reported that roof bolting was started as a systematic moans of roof support in at least three instances but was abandoned because the cost of installation was excessive. The extra expense above that of conventional timbering could not be recaptured through economies resulting from increased efficiency, such as would be gained through mechanized mining.Roof bolting was first mentioned in mining literature in an article by W. W. Weige 3/ in Engineering and Mining Journal of May 1943, in which he described the use of bolts with 4-inch channel bearing plates in mines of the St. Joseph Load Co."

Sep 1, 1950

Identity the difficulties of establishing vegetation on mining-related wastes resulting from adverse chemical, physical, and biological properties; describe the ecological and soil factors affecting the relationship between mycorrhizal fungi (soil microorganisms) and plants; and evaluate the feasibility of establishing vegetation on mine waste by introducing mycorrhizae. Problems in Revegetation Successfully using vegetation to stabilize a situ disturbed by mining-related activities depends on knowing the chemical, physical, and biological characteristics of the site prior to, or at the time of, stabilization. The primary objectives of mine land reclamation are to minimize environmental degradation and to facilitate the re-establishment of a functional plant-soil system. Mining disturbances can significantly alter the physical, chem¬ical, and biological characteristic of a site, thus affecting plant establishment, survival, and growth. The physical disturbance caused by the removal and replacement of soil and overburden, together with the waste material from ore processing, affect the chemical, physical, and biological process within the disturbed soil or waste. Additionally, variability in soil properties results from differences in climate, topography, vegetation, and parent material of the site.

Jan 1, 1993

Reduce shaft sinking costs and workers exposure to mechanical hazards, drill dust, blast dangers, and fumes. Approach Replace drilling and blasting by using a large, cab-mounted impact breaker suspended from the bottom work deck of the galloway. How It Works The pneumatically actuated impact breaker is positioned by an articulated boom con-trolled from an operators cab. The breaker delivers 2,000 ft-lb blows that fragment the rock at the shaft bottom. Mucking is accomplished by a backhoe bucket on an articulated boom mounted on the cab. See photograph. The mucked material can be removed either by dumping into a previously drilled borehole or by being lifted out in a muck bucket as shown in the drawing. Positioning of the breaker, rotating the cab around its vertical axis, and moving the cab support frame around the perimeter of the shaft are all controlled by one joystick. Separate controls position the mucker boom, which can be swung horizontally through a 180° degree arc towards either side of the cab. Because the cab can be rotated to any position around its vertical axis, and can also be moved in a horizontal circle around the shaft, virtually any position on the bottom of the shaft can be reached by the breaker and mucker.

Jan 1, 1981

By I. D. Shah

Thermal decomposition of copper (II) sulfate (CUS04) and copper (II) oxy-sulfate (CuO?CUS04) are important steps in the overall oxidative roasting of covellite (CuS) and chalcocite (Cu2S). Nonisothermal thermogravimetric techniques were used to investigate the decomposition reactions in flowing Na and air. Thermal decomposition of CUS04 and CuO?CUS04 followed "linear" kinetics with an apparent activation energy of 55±2 and 66±3 kcal per mole decomposed, respectively. These apparent activation energies comply with those previously reported when isothermal kinetic techniques were used. The addition of oxygen decreased the rate of decomposition, while small amounts of iron which were admixed with CuO?CUS04 did not have a significant effect. Neither oxygen nor iron had any appreciable effect on the apparent activation energy of the decomposition reaction.

Jan 1, 1972

By P. A. Bloom

Arsenic-containing flue dusts are currently being stockpiled by several nonferrous smelters in the United States. These stockpiles are a source of environmental concern since the dusts can be transported by wind and contain water-soluble arsenic. The stockpiles also represent an alternate source of metals. To provide a quality environment, the Bureau of Mines investigated a process to make environmentally acceptable the discard of arsenic obtained from the treatment of arsenical flue dust. The process includes (1) leaching arsenic from a lead smelter copper dross flue dust, (2) fixing arsenic as an insoluble compound, and (3) recovering other metal values. Overall results of acid-leaching tests on lead-smelter flue dusts showed that H2S04 dissolved 80 to 90 percent of the As, Zn, and Cd, and up to 86 percent of the In. Pb, Ag, and Au remain in the residue, which can be recycled to the smelter. Indium was recovered from the strong acid leach solution by solvent extraction; arsenic was fixed in a stable form by precipitation with Fe2(S04)3 and CaO or CaC03.

Jan 1, 1982

By B. W. Madsen

As part of a program to maintain an adequate supply of minerals and metals to meet national economic and strategic needs, the Bureau of Mines conducted research to determine the diffusion coefficients for ferric ions in synthetic copper leach solutions. Determination of ferric ion diffusion coefficients in typical dump leach solutions is necessary for predicting leaching rates of copper from large-scale leaching operations and for optimizing concentrations of ferric iron in solutions to maximize leaching efficiency. Derivative chronopotentiometry, an electroanalytical technique, was used to determine ferric ion diffusion coefficients. The diffusion coefficient decreased dramatically with increasing concentration of iron in solution. An empirical model was used to relate the ferric ion diffusion coefficient to the total amount of sulfate in solution. Measuring the diffusion coefficient dependence on temperature yielded an activation energy of 5.5 kcal/mole of ferric ion. Activity coefficients of ferric ions as a function of concentration were calculated from diffusion coefficient data.

Jan 1, 1981