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By L. G. Sobral, J. E. Hoffman, T. J. Keefe, A. J. Monhemius, O&apos

The kinetics of electrodeposition of gold from dilute solutions of alkaline KAu(CN)2 at different gold and free cyanide concentrations on a gold rotating disk electrode were investigated by use of a steady-state linear potential scan technique. The design and performance of a laboratory electrowinning cell with a reticulated nickel cathode, operating in the flow-through mode, for the removal of low levels of gold ions from aqueous cyanide media is described. During the batch recirculation of oxygen-free gold cyanide solutions, the gold concentration was reduced from 10 ppm to <0.5 ppm with current efficiencies of up to 80%. The influence of solution flow rate through the cathode and of the pore size of the reticulated nickel foam is discussed. The removal of gold ions from solutions of low ionic strength was also investigated.

Jan 1, 1993

By Richard R. Klimpel

The author was the banquet speaker at the 48th Annual MPD meeting, sponsored by the SME Colorado Minerals Processing Section, May 14-16, 1998, in Colorado Springs, CO. Here are his remarks. It has been an exciting experience to have spent 34 years involved with the process of generating patented technology eventually leading to commercialization. In today&apos;s terminology, this process is called technology transfer. I have had the unusual experience of being involved doing basic research as an inventor while also being responsible for managing new product development and commercialization. In addition, I worked for 31 years before my retirement for a large research-oriented company, The Dow Chemical Co. In 1995, the company spent more than $1 billion dollars on research and development. The last three years of my career have been spent working with a research-oriented university, The University of Florida. And I have worked as a consultant helping several companies to optimize their products and processes. It is on this cumulative experience base that the preparation of this article is based.

Jan 1, 1998

By A. Pratt, G. Deschênes

This paper quantifies the detrimental effects of pyrite and stibnite on gold leaching kinetics. Means to reduce the effect of these minerals by addition of lead nitrate and oxygen are presented. A significant retarding effect was observed when the pyrite concentration was 20%. A pretreatment with lead nitrate reduced the extent of gold surface coating by Ag, Fe and S. Stibnite, at a concentration as low as 20 ppm, significantly affected the gold leaching kinetics through forming a passivating film of Sb(V) oxide possibly Sb2O5. The most practical way to alleviate the effect of stibnite is to leach the materials at a moderate pH with addition of lead nitrate. A low temperature reduced the efficiency of lead nitrate to counteract the effect of stibnite. The increase of dissolved oxygen is not favourable to alleviate the coating of stibnite on gold.

Jan 1, 2004

By Winfield G. Wright, Philip L. Verplanck, Douglas B. Yager, Dana J. Bove, M. Alisa Mast

The upper Animas River watershed is affected by metal-rich drainage from abandoned mines and by natural weathering of mineralized bedrock. To investigate the importance of natural metal sources, surface waters were sampled in a minimally mined but intensely altered area of the watershed. Water chemistry was strongly controlled by the degree of bedrock alteration. Propylitically altered rocks, which contain calcite, produced neutral waters with low metal concentrations, whereas quartz-sericite-pyrite alteration was characterized by acid-sulfate type waters with high metal concentrations. A mass-balance approach was used to estimate natural metal sources, which accounted for 56-905 of the dissolved metal load discharging from the study area

Jan 1, 2000

By Tad S. Golosinsk

Use of computers for hoist evaluation and design dates back to the early 1960&apos;s. Mine hoist production calculations, repetitive in nature, were computerized first. More elaborate modeling of hoist operations followed soon. Typical for this, early period are the models described by Touwen (1973), and by Albert and McIvor (1984). Apart from the simple hoist production calculations, the models were very complex, typically written in Fortran, and often required advanced computing facilities and expertise to run the simulation. The early models were strictly deterministic, with no consideration given to the random nature of hoisting operations. The effects of randomness of the hoisting process on hoist performance were often accounted for by introduction of the deterministic factors, most notably of an "utilization factor" related to the hoist production. The value of the latter was based on observations of actual hoist performance, and could vary in a wide range. For example Harvey (1973) reports values of the "utilization factor" to be between 0.7 and 0.92.

Jan 1, 1989

By Lijun Xu, Ragula Bhaskar

The transport of dust particles from a turbulent air stream on to the surface of a mine entry is mainly due to the effect of diffusion, sedimentation and inertial impaction. While the literature in aerosol science contains many references on particle deposition, most studies apply to smooth surfaces in small, short tubes. The deposition data from those experiments may not be applicable to deposition in mine airways that have large areas of rough surfaces and extend several thousand meters. This paper describes the mechanisms of mine dust transportation and deposition, specifically, by estimating the turbulent deposition velocity for coal dust in mine airways. Data from in-mine experiments on ambient dust concentration and dust deposition along a straight entry were used. A statistical model for dimensionless turbulent deposition velocity was developed, and compared with the models developed by other researchers. The model shows that the distance from the dust source is an important factor in the turbulent deposition of mine dust.

Jan 1, 1995

By R. Vance, C. Cho, N. Mardi, Z. Qian, K. Prisbrey

One problem with the application of neural networks to the multivariable control of mineral and extractive processes is determining whether and how to use them. The objective of this investigation was to compare neural network control to more conventional strategies and to determine if there are any advantages in using neural network control in terms of set-point tracking, rise time, settling time, disturbance rejection and other criteria. The procedure involved developing neural network controllers using both historical plant data and simulation models. Various control patterns were tried, including both inverse and direct neural network plant models. These were compared to state space controllers that are, by nature, linear. For grinding and leaching circuits, a nonlinear neural network-based model predictive control strategy was superior to a state space-based linear quadratic gaussian controller. The investigation pointed out the importance of incorporating state space into neural networks by making them recurrent, i.e., feeding certain output state variables into input nodes in the neural network. It was concluded that neural network controllers can have better disturbance rejection, set-point tracking, rise time, settling time and lower set-point overshoot, and it was also concluded that neural network controllers can be more reliable and easy to implement in complex, multivariable plants.

Jan 1, 1998

By M. W. Rutland, E. Manev, R. J. Pugh

Data collected from several different fundamental surface chemical techniques were compared to study the interfacial interactions in the dodecylaminelmica flotation system. In the present study, the method used was the microinterferometric free foam film technique of Scheludko (1967) in which the stability, thickness and interfacial potentials at the air/dodecylamine solution interface were determined. These results were compared to previously published data, obtained from surface force measurements (Rutland et al. 1992), in which the interaction and hydrophobic adhesion (pull-off force) between molecularly smooth mica sheets in the amine solution had been reported. Also equilibrium contact angle measurements were used for comparison. The data was collected over a range of pH values and related to the batch flotation response of mica in dodecylamine solution. It was found that maximum flotation occurred at pH 8, but this did not correlate with the minimum in double layer interaction potential. However, it appeared to correspond with a tightly packed collector monolayer giving maximum hydrophobicity to the mica surface. Finally, from the extended DLVO theory, it was shown that heterocoagulation between the bubble and the mica could only occur, providing there was a very long range hydrophobic interaction force to counterbalance the repulsive van der Waals and electrostatic forces.

Jan 1, 1995

By J. K. Ahlness

The US Bureau of Mines investigated technologies for determining the integrity of in situ leach mining wells. A self-contained trailer-mounted well integrity testing system (WITS) was designed and built to enable rapid testing of well casings for leaks as required by environmental regulations. The WITS utilizes two inflatable packers to seal off the entire casing length or any portion thereof. Water pressure is built between the packers to the desired test pressure, and the presence or absence of casing leaks is determined by monitoring the pressure drop between the packers. A winch and steel cable are used to run the packers in and out of the well. The WITS underwent an industry field test at the Irigaray in situ uranium leaching mine near Buffalo, WY. A total of 37 wells with an average depth of 69 m (225 ft) were tested at an average rate of four wells per eight-hour shift with a two-person operating crew. This represents a 75% time savings and an 83% labor savings compared to the rigid-pipe method previously used at the mine, with which a three-person crew tested an average of one well per shift.

Jan 1, 1988

By Bruce Johnson

This paper is not written to "break new ground" in computer applications; it is just a treatment of how an operating metal mine utilizes a mainframe computer for planning, analyzing, and reporting on the ventilation and cooling systems. The Unisys mainframe computer at the mine site is used in programs that analyze the ventilation network, keep records on various ventilation installations, calculate the results of measurements and produce reports on ventilation conditions in the working places and on the main air distribution, and plan and analyze the cooling system. All the programs are interactive to terminals. There are a series of data files that are generated by some programs which may be used by other programs. Most of these programs have been developed in-house. The computer is also used as a word processor via a vendor-supplied text editing program to produce memos, letters, and to keep up-to-date lists of equipment used.

Jan 1, 1989

By D. F. McCarthy

INTRODUCTION Mined underground chambers specifically designed for the purpose of storing liquefied petroleum gas (LPG) at ambient temperatures have been in use for over thirty years. The first caverns were developed by Warren Petroleum of Tulsa, Oklahoma, in 1948, for its plants in Texas. The basic concept of an LPG-storage cavern is to create a space in an impervious formation at a depth sufficiently below the water table so that if any movement of fluid occurs the ground water will enter rather than the gas escape from the cavern. In the past, the primary reason for LPG storage underground has been its attractive cost advantages over steel storage on the surface. At current prices the cost of storing 7.949 ML (50,000 barrels) would be equivalent, whether stored on the surface or underground; whereas 79.494 ML (500,000 barrels) of storage underground costs only one-fifth of surface storage. It is usually uneconomical to excavate less than 79.494 cu m (50,000 barrels) of storage space. The fixed costs - engineering, mainshaft and ventilation shaft - are a substantial part of the total cost, whereas the incremental costs for excavating additional storage are relatively low. Recent concern over the hazards posed by the handling and storage of LPG and liquefied natural gas (LNG) has led to a new interest in the underground storage of these gases. Underground storage offers the following advantages: safety, security, low initial cost, low maintenance cost, operating, cost, minimum land require-

Jan 1, 1981

By Hal McVey

Introduction The role of marketing in the minerals and mining industry takes on different degrees of importance depending on the commodity, but nowhere are sales and marketing more important than in industrial minerals. This article compares industrial minerals marketing with the marketing of other mining and mineral products. Marketing in Mining Some broad generalizations on the marketing of industrial minerals in relation to other mineral products can be made without getting bogged down with exceptions to generalizations. Two totally different areas of mineral production are crude oil and natural gas, and metals, including ores and concentrates. Although these commodities are the basis for two completely different industries, they share two things in common from a marketing standpoint: • Their value per unit volume is usually high enough so that they can be transported great distances. • Their specifications are readily definable and, therefore, the quality of a standard product from a production run can be communicated by stating certain chemical and physical features. This permits sales to be consummated by telephone, telex, and letter, without the need to pretest the products under use conditions. In regard to the first item, industrial minerals, as opposed to oil, gas, and metals, are in most instances site specific. Location of the point of production in relation to the point of use is of paramount importance based on a generally lower unit to volume value. This means that transportation is a major factor, with the cost of getting the mineral to market commonly exceeding its f.o.b. value. Coal marketing has many characteristics in common with industrial minerals. Coal sales can es-

Jan 11, 1983

By Gill G. Geesey, Michael R. Hankins, Paul L. Wichlacz, Anita Gianotto, John G. Jolley, Randy B. Wright

Thin films of copper [2.0 nm on germanium internal reflection elements (IREs) and 3.4 nm on germanium discs] were exposed to 10% gum arabic (aqueous solution) , 2% alginic acid (aqueous solution), 1% bacterial culture supernatant (BCS, simulated seawater solution) and 0.5% Pseudomonas atlantica exopolymer (simulated seawater solution). The IRES were monitored in situ, in real time using fourier transform infrared/cylindrical internal reflection/attenuated total reflection spectroscopy as a function of time at ambient conditions. The discs were characterized (pre- and post-exposure) by X-ray photoelectron and Auger electron spectroscopies. Ancillary graphite furnace atomic absorption spectroscopy was used to monitor the removal process of the copper thin film from the germanium substrates. Results indicate that Cu was oxidized by gum arabic, alginic acid and BCS. Furthermore, Cu was removed from the Cu/Ge interface by all four polymers. The Cu was found associated with the polymer solutions.

Jan 1, 1989

By K. L. Whitehead, R. A. Jankowski, N. I. Jayaraman

Most continuous miner sections utilizing flooded-bed scrubbers also use blowing face ventilation. Blowing ventilation, however, interferes with dust capture and minimizes scrubber effectiveness. To enhance the efficiency of the scrubber system and reduce dust concentrations, the Bureau of Mines tested various combinations of operating parameters. Experiments for system efficiency took place in a full- scale model mine at 3.05 m roof height. In general, higher values for scrubber and face airflows resulted in lower dust concentrations. In addition, optimum dust controls would include a face ventilation to scrubber airflow ratio of one. When the airflow ratio was either less than or greater than one, the dust levels in the return and at the operator locations increased. No single dust control technique was the most effective one at all locations due to mutual interaction among techniques.

Jan 1, 1992

By L. John Minnick

Current developments in using lime and limestone slurries to remove sulfur oxide gases from the stacks of coal- and oil-burning furnaces have established an important need for treatment systems which include adequate disposal of resulting waste materials. The paper briefly outlines the classes of scrubbers which are using lime and limestone and describes the characteristics of the by-product material being produced. Some discussion is also included relating to methods of disposal of the scrubber underflow. Since coal-burning plants also produce fly ash as a waste material, one system developed by the author&apos;s company combines this material with the sulfur oxide by-products. The mixture is processed in a manner which converts the waste products into usable materials with acceptable structural and environmental properties. Recent interest in protection of ground waters from heavy-metal leachates has made the fly ash-sulfur oxide system an acceptable means of disposal, because the conversion products have very low permeability and adequately encapsulate soluble salts within the hardened mass. Although only limited information is available on the types and chemical requirements of limestone used in these processes, a few guidelines are presented to indicate the range of materials that can be used with good results.

Jan 1, 1974

By R. D. Miller, D. W. Steeples

Application of shallow, seismic reflection to problems associated with mineral exploration, mine planning, abandoned-mine detection and environmental evaluation has been successful in many geologic settings. The increased dynamic range of recording equipment and the decreased cost of processing hardware and software have made shallow, seismic reflection a cost-effective means of imaging geologic targets significant to mining operations. Seismic data possess sufficient resolution in many areas to detect faulting with displacement of less than 3 m (10 ft) in coal seams as thin as 2 m (6.5 ft) at depths of 200 m (655 ft). Subsurface voids associated with abandoned mines at depths of less than 20 m (65 ft) can he detected and mapped. Seismic reflection has been successful mapping disturbed subsurface associated with dissolution mining of salt. Complex geologic features associated with deposition of various hydrothermal minerals have been mapped with high-resolution seismic reflection at depths from 80 m (260 ft) to more than 300 m (985 ft). Faults in sulfur-hearing cap rock over salt domes have been accurately located, allowing improved efficiency of the dissolution mining process. Shallow, high-resolution seismic reflection has the potential to enhance the economics and safety of mine operations.

Jan 1, 1996

By G. Bräuner

The methods of burst control treated in the authors&apos; very informative paper have been applied in the Ruhr Coalfield, Germany, for more than 20 years and have proved to be highly effective. It might be interesting here to mention a few experiences: • The symptoms of critical stresses when drilling with small diameters ("test drilling") are essentially the same as described. However, we consider the situation safe if these symptoms occur beyond a certain distance ahead of the face. • That safety distance equals three times the seam thickness plus the daily advance. It is the total seam thickness that counts, not merely the mined portion. • Critical stresses within the safety distance are dissolved by so-called destressing measures: drilling with heavier equip¬ment, blasting, or water infusion. • To avoid bump initiation, the destressing operations should begin at the sides of the stressed zone rather than in the middle. • As to water injection, there are two different principles. If the situation is critical already, high pressures are applied for hydraulic fracturing. If the stresses still allow to drill deep holes, the fluid pressure is kept low and acts for a longer time. This is to make the coal break successively instead of violently - a long-term precaution. • When the stresses are very high, destressing is the most appropriate means. We mostly drill with 95 mm-diam (3.7 in. - diam). The techniques in detail are somewhat complex and sub¬ject to modifications. But the general idea is to accomplish burst prevention by controlling the potential burst situations.

Jan 1, 1989

By S. K. Kawatra

With the increasing importance being placed upon modernizing the coal industry as a result of recent developments in the international energy balance, computer control has been and is being instituted in many coal cleaning plants. Control techniques that are well established in many base metal industries have been adapted to coal washing. Essential to any control scheme is an accurate measure of the parameter which is to be controlled. A sensor is required that will provide information both quickly and precisely. In fine coal circuits, the critical parameter that must be measured and controlled is the per- cent ash contained in the clean coal product and tailings. Measuring the ash content of these slurry lines on a continuous basis enables the operating conditions in the circuit to be adjusted so as to obtain optimum separation efficiencies at all times. An on-line ash monitor has been developed and tested at Michigan Technological University which is capable of making percent ash and percent solids determinations instantaneously. Two radioisotopes are employed in this system to generate signals that can be related to the density and the ash content of the slurry. Such data provide a means to execute a short term control strategy.

Jan 1, 1982

By Jean-Claude Bianchini, Paul Bauernfeind, Erwin Gartung

Introduction The city of Nuremberg, located in Bavaria in the Federal Republic of Germany, started building a subway in 1967. The construction operations began in a southern suburb, where no complications were encountered in the design and execution of the job. As the first subway line approached the downtown area of the city, the civil engineering challenges increased rapidly. Tunnels had to be excavated next to, or below precious historical buildings, and the work of the responsible engineers was closely watched by the public, who were very anxious about any damage to the existing beautiful old houses and churches. The job has been handled successfully to date in cooperation with the owner-designer, the geotechnical consultant and the contractors, who jointly went through a process of systematic learning and gathering of experience, and who developed a modern tunneling technique specifically tailored to the natural properties of the encountered ground conditions and the requirements of the city of Nuremberg. The application of scientific methods has been an important part of this development. Research into the geotechnical properties of the predominantly encountered soft Keuper sandstone, studies of the geomechanical performance of grout reinforced sand sections and finite element analyses of various tunnel problems for the prediction of displacements, for the assessment of stability, or

Jan 1, 1979

By H. Sevim

In long-term open pit production planning, a series of nested and maximum-value pits is usually generated first. These pits are then considered as possible pushbacks over a number of planning periods. To determine the best pushback in each planning period, the pits are evaluated for their technical and economical feasibilities under certain production constraints. Parameterization is a commonly used technique to generate a series of pits. In almost all cases, however, some of the consecutive pits generated by this technique are too far apart from each other. This is called the "gap" problem. It may make the entire pit series useless for production planning purposes. A new pit gener¬ating algorithm has been developed to overcome the gap problem. Through this algorithm, a series of nested maxi¬mum-value pits can be generated with a controllable size increment. The logic of the algorithm is illustrated through a small hypothetical case. Its capability of generating maximum-value pits that are as optimal as those generated by parameterization and its advantages over parameteriza¬tion are presented through an actual gold deposit case.

Jan 1, 1996