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By Gian-P. Lozej, Ross Y. Black, Sami S. Maddah

The Zabirah bauxite is a Cretaceous paleolaterite exposed by postTertiary uplift and erosion of the Phanerozoic sequence. The laterite profile, which is preserved in situ, occupies a prominent angular unconformity over a sequence of sandstones, siltstones and mudstones ranging from Late Triassic to Early Cretaceous in age, and is overlain by a Late Cretaceous terrigenous and carbonate package. The profile is known to be preserved over an area of 250 sq km and at depths below the present surface of up to 80 m. The bauxite layer is hard, compact and predominantly pisolitic, with a variety of subordinate, superimposed textures resulting from post-formation alteration. The bauxite minerals are boehmite and gibbsite. Boehmite generally predominates, and the boehmite:gibbsite ratio averages 2:1, with a marked tendency for the proportion of boehmite to increase down the profile. Kaolinite, a major constituent of the profile, is concentrated in two zones, one above and one below the pisolitic bauxite layer. Iron content is variable and bears a direct relationship to parent-rock lithology. Genesis and preservation of the bauxite are due to the favourable coincidence of a number of geological controls of which the most significant are the local structural and sedimentary regimes, the lithology and chemistry of the parent rocks, and the Cretaceous paleogeography of the region.

Jan 1, 1984

What is your assessment of the current state of the minerals industry? It is no understatement that domestic mining is facing a severe crisis at this time. The sharp decline in commodity prices and demand is putting a great strain on domestic and worldwide mining, causing major declines in profits and market capital of mining companies. This, in turn, has lead to major production cuts, layoffs, shut-downs of operating properties, and the deferral of new and expansion projects. These changes in the minerals industry have played a major role in the health of the economy. Operationally, the industry continues to develop new technologies that are making our work more efficient, more cost effective and more environmentally acceptable and safe. During downturns like this, companies generally pay closer attention to operational efficiencies and process optimization. Historically, new technologies and processes tend to be developed during down markets, and I believe we will see the same thing as companies strive to preserve liquidity and maintain or improve their margins. On the positive side, the drop in commodity prices has resulted in a reduction in operational costs, as the costs for fuel supplies and construction materials have decreased.

Jan 1, 2009

By J. E. Lawver, F. S. Knoll

Introduction Electrostatic separation is the selective sorting of solid species by means of utilizing forces acting on charged or polarized bodies under the influence of an electric field. Electrostatic separation is effected by adjusting those forces acting on particles due to the electric field as well as co-acting forces such as gravity or centrifugal forces so that the different species will have different trajectories at some predetermined time. Electrostatic separations can be broadly defined as being either electrophoretic or dielectrophoretic. Electrophoresis is the separation of charged particles in an electric field, whereas dielectrophoresis is the separation of neutral particles in an electric field1. Examples of an electrophoretic separation can be found with sepa¬rations that use corona charging (ion bombardment), contact charging (triboelectric) and conductive induction. Dielectrophoresis motions are due to the stress and repositioning of charges, i.e. polarization of a neutral particle when exposed to a non-uniform electric field. Separations made using corona discharge devices are often called high-tension, electrodynamic or ion bombardment separations. These are the most prevalent in use today in mineral processing. Dielectrophoretic separation of most minerals is based on differences in dielectric constants of the solid species and usually requires the use of expensive intermediate dielectric fluids. Dielectrophoresis has not been employed for industrial mineral separations, though its effects pose interesting possibilities1, and pilot-plant units developed by the U.S.B.M. are available for testing2. Our discussion will be limited to the three forms of electrophoresis found in commercial practice. Typical Industrial Separations Typical industrial applications of electrostatic separation are: 1. Dry concentration of heavy minerals: ilmenite, rutile, zircon, monazite, xenotime, columbite-tantalite, cassiterite, hematite, scheelite and others. 2. Separation of salts: halite-sylvite, etc. 3. Purifications of foodstuffs such as the removal of impurities and

Jan 1, 1986

By J. A. Herbst, L. B. Hales, R. Zaragoza

INTRODUCTION The Control Problem The need for automatic control in flotation plants stems from frequent and randomly occurring disturbances to the feed slurry. Typical disturbances occur in the solids feedrate, the slurry percent sol ids, and the mineralogy and flotability of the gangue and valuable minerals. In plants where semi -autogenous grinding mills (SAG) are used, feedrate changes are very large and changes in feed percent solids of 1m or more are common. Mineralogy changes between valuable minerals are common, as are changes in the host gangue rock. As these changes occur, the operator can attempt to compensate for them by making adjustments to the flotation cell levels, the dosage rates of the collectors and frothers, the pH, and in some cases the aeration rate of the cells. This problem is sometimes complicated by the fact that different sections of the flotation plant will be processing different ore types at the same time. Potential Savings with Control Flotation control brings about savings or plant improvements in two areas; the first is in improved metallurgy and the second is in reagent savings. Improved metallurgy includes increases in the average plant recovery and achieves target concentrate grade level s more consistently. Average recovery increases between 1.0 and 5.0 percentage points have been widely reported (Paakkinen, 1979; Sutherland, 1984). Reagent savings of up to 40 percent have also been reported (Hales, 1985). VARIABLES OF IMPORTANCE Control led, Manipulated, and Disturbance Variables The initial step in the analysis of the flotation control problem is identification of important variables which can affect the efficiency of separation. The efficiency of separation is represented by a group of controlled variables which can quantify the performance of a flotation circuit. This group includes variables such as grade, recovery, tonnage through- put, and circulating loads. The efficiency of separation of a flotation circuit may generally be defined by a grade recovery map, where each point on this map re- presents a set of operating conditions (see Figure 1). However, the combination of operating conditions must be set to operate close to the economic optimum. The group of operating variables which are changed in order to achieve desired circuit performance are called manipulated variables and can be classified into two

Jan 1, 1986

By Gy. Deák

The Romanian mining and especially the salt mining industry is going through a restructuring phase; among others it has to respect the European Environment Act. One of the most important deficits of the salt mining industry is the implementation of monitoring systems for geomechanics phenomena, in order to develop an important information database and form a real base for salt mines stability, prediction and prevention measures. Monitoring system solutions, involving discontinuous and continuous measurements of displacement / deformation fields, around underground excavations, are presented and discussed. In addition, a case study for the stability prediction of an experimental salt off-set, located in the Praid salt mine, using DKRControl method, is presented. The two monitoring systems use different tools, namely measuring tapes (to determine distance between markers in T-D station) and ultrasonic transducers (SM-TDA equipment).

Jan 1, 2006

By Larry Powell

Rend Lake is an Army Corps of Engineers reservoir located in Franklin and Jefferson Counties in south-central Illinois. The lake consists of 20,000 acres of water and 19,000 acres of public access land. The site attracts over two million visitors a year and is surrounded by campgrounds and other recreational facilities. The lake overlies the largest tonnage of low sulfur coal in the state. Coal is being removed beneath the lake from five mines operated by three coal companies. Currently high extraction mining operations are approaching low-lying, environmentally sensitive, and high-use recreational areas. Advanced planning to maximize coal extraction and minimize potential effects of subsidence requires the development of procedures to assess the impact of high-extraction mining on the land use of the area. The Bureau of Mines, the Corps of Engineers, and the coal companies have initiated research to assess the following proposed planning steps to ensure the maximum recovery of the coal resources while minimizing impacts to surface land use: 1) Establish a dialogue between the surface and mineral owners; 2) develop a geographic information system to aid in assessing existing land use and potential changes; 3) assess the potential effects of subsidence on drainage, wildlife habitats, and changes in land use prior to mining; 4) coordinate the mining displacements with surface activities to minimize disruption; and 5) develop appropriate mitigation plans before mining occurs.

Jan 1, 1986

By Scott G. Britton

This chapter is concerned with the construction of the dynamic component of belt haulage systems. The dynamic system includes the belt line and tailpiece extension and retraction movements in a production system where mine management is continually placing the belt in the most effective operating position. Correct installation of the belt and tailpiece during an extension is very important for many performance reasons. Two of the most important reasons are to eliminate spillage and safely operate the belt line. This chapter is divided into three major discussions. The first discussion looks at analyzing the parameters of effective belt line construction. This includes a review of the parameters and management tools needed for proper scheduling of a move-up. The second major discussion topic centers on efficient procedures for a belt line extension. Topics such as site preparation, tailpiece breakdown and setup, stringing the belt line and structure, plus operating and maintenance tasks needed after the belt line is installed and running, are covered. The third discussion presents a list of conveyor and conveyor component manufacturers who provide services and products to the coal mining industry. Again, any discussion on underground haulage systems must generalize much of the site specific design approaches to be practical. This text will mention, where applicable, some of the alternatives available to construction engineers in designing belt line systems.

Jan 1, 1983

By Yi Luo

Bolting the mine roof is one of the noisiest underground mining operations. The main contribution to the high noise is the drilling of the roof bolt holes, especially in hard rock. A previous research shows that the specific energy consumed in drilling the bolt holes is inversely proportional to the bite depth (i.e., penetration per drill revolution). Less specific energy at a reasonably high bite depth means less energy is wasted in the drilling process to produce heat, bit wear and noise. Therefore, control of drilling operation to achieve a higher bite depth can provide an opportunity to reduce drilling noise from its sources as a proactive noise control approach. In order to explore the feasibility and to develop the proactive technology for reducing drilling noise, drilling tests have been conducted in laboratory settings. The preliminary results show significant reduction in noise dose can be achieved by drilling in medium hard rock at a reasonably high bite depth. This paper presents the findings from the laboratory experimental studies conducted so far.

Jan 1, 2013

By E. I. Jurgens, K. E. Hanney, D. C. Comrie, R. H. Fletcher

Introduction The reclamation of mine/mill tailings areas is undertaken for a variety of objectives including safety, appearance, economical use of lands and forests and long term storage of a future resource. The establishing of criteria for these objectives at any site is a shared task of the government and mining company. Our attention in this paper is directed to uranium mine/ mill tailings as they are handled in the Canadian industry and in the unique Canadian climate. We focus our attention on the state of the art. Uranium is a ubiquitous mineral forming an average of 4 g per tonne of the Earth's crust. Ores are mined at about 500 g per tonne so that the residual content of uranium in tailings is comparable to average background levels. However, as in most mine/mill operations, the ore contains other minerals that become readily mobile after milling operations. Thus the main objective of tailings impoundment is the stability both physically and chemically of the mobile materials. Since the requirements for the operation and construction of tailings areas in Canada have changed considerably over the past decade, there exists a great many mine/mill tailings areas which while considered adequate in their day, would not meet modern criteria. However, most of these installations pose no concern or hazard to the public. The proximity of mine/mill development to inhabited land areas has necessitated more stringent modes of tailings operations and provisions for tailings site reclamation. The more important of these have been: 1) the prevention of dyke failure, with large liquid-solid outflows onto adjoining lands, and 2) the prevention of seepage from the tails of pollutants such as chlorides, sulphides, heavy metals and radionuclides. Uranium mill tailings are discharged as a slurry from the concentrator after the removal of generally only about 1000 g, or less, per tonne of uranium from the as-mined ore. As a consequence, a great volume of low level activity waste is generated. The amount of tailings is expected to grow in quantity in the future even faster than the increase in yellowcake production, as the demand for energy

Jan 1, 1980

By W. Robert Power

Stone is considered by many to be the premium material for beauty and durability in all kinds of construction. Its use dates to the dawn of civilization and only buildings made of stone have survived from ancient times. The use of stone relative to other materials declined from the beginning of the present century reaching a low point in the third quarter, but there has been a resurgence in the use of stone in construction during the past decade, due probably, to new techniques for producing stone, a greater recognition of its beauty and durability, and greater affluence among consumers. The aesthetic appeal of stone is attested to by the many attempts to simulate it in synthetic materials. Today, natural stone is considered by many to be the ultimate in aesthetic appeal, durability, and ease of maintenance. Consumption of dimension stone has increased dramatically during the past decade. The US Bureau of Mines reported that the total value of US consumption in 1978 was $1 13 million and that total imports were valued at $65 million in 1979 (Anon., 1980). In 1989 consumption of domestic dimension stone was valued at $208.3 million and imports at $525 million. This dramatic increase occurred after demand had decreased at an average rate of 2.5% in the two decades prior to 1978 (Anon., 1980). More than half of the imports come from Italy, but production of dimension stone has increased worldwide spectacularly. Meaningful statistics on dimension stone are hard to acquire. The finished piece of stone is a highly value-added product, but stone may be sold as rough blocks, sawed slabs, or finished product. The same piece of stone may therefore be sold and reported three or more times. Furthermore, although the quantity of stone is most commonly reported in tons, stone cladding is more often sold by the surface area and at the same price for different thicknesses. By any measure, however, the production and consumption of dimension stone has increased dramatically during the past decade. A significant indication of the resurgence of stone was the introduction of two new trade publications during the 1980s. Stone World (Tradelink Publishing Co., Inc., Oradell, NJ), introduced in 1984 is published monthly and Dimensional Stone (Dimensional Stone Institute, Inc., Woodland Hills, CA), introduced in 1985 is published monthly. Both magazines provide useful information on new technology, market trends, producing areas and companies, and other information not previously available.

Jan 1, 1994

By R. M. Clowes

Lithoprobe is a collaborative, multidisciplinary research project which is providing new insights into the tectonic evolution of the North American continent through its work within ten study areas across Canada. For the mining industry, such results provide a well-constrained regional framework and better understanding of tectonic processes which lead to the development of ore deposits. In mining camps, seismic reflection methods have proven effective in imaging shallow to moderately dipping litho logic contacts as well as structural features, and in some cases have been used for the direct detection of ore bodies. Here, short case histories are provided for the Abitibi greenstone belt (VMS deposits) in Quebec and the Thompson nickel belt in Manitoba.

Jan 1, 1999

By Tim Cleary, Steve Skelhorn

The 9th Line / 16th Ave tunnels are part of a $700 million expansion of the York Durham Sewage System, north of Toronto. The 15 km of tunnels presented many challenges, including glacial and postglacial deposits, at depths up to 55 m. Due to high hydrostatic heads, the Owner specified EPB tunnelling, however, an alternate was proposed utilising rib and lagging tunnels, combined with a de-watering scheme. State of the art technology was utilised with a new Lovat TBM, incorporating PLC control, soft start water-cooled motors and a head designed to tackle the mixed ground expected. The 9th Line tunnels were completed in 2002. Subsequently the second section of tunnel along 16th Avenue has been awarded to the Joint Venture. This paper presents a case history of the soft ground tunnelling, including design elements, tunnel systems and TBM operations.

Jan 1, 2003

By C. J. Bise

Virtual reality (VR) is a concept in which the human experience of perceiving and interacting with a computer-modeled environment is achieved through the use of sensors and effectors. It is an advanced form of computer graphics. The images are generated based on where the user looks and how the user moves. As personal-computer-based (PC) instruction gains acceptance as an innovative approach to providing safety training, VR can provide a multisensory, rather than merely a multimedia, mode of presentation. New technology continues to be introduced into the mining industry to meet the productivity needs of coal and noncoal producers. There is also an increased need for more innovative training of mine workers. New technology and equipment designs often affect the basic causes of accidents. For example, the development of cabs and canopies for underground coal-mine equipment has reduced the number of accidents related to roof falls and rib rolls. However, safety-training specialists then had to focus on the machines themselves, because the modifications had the potential for causing "pinch-point" accidents. In fact, although the overall physical demands on mine workers have diminished, there has been an escalation in the concerns about trauma from repetitive physical activity. Thus, health-and-safety training specialists have shifted their atten¬tion to the recognition, evaluation and control of workplace hazards (Hancock and Hill, 1995). Recognizing that the spatial relationships of a workplace convey more information about hazards when experienced rather than described, trainers agree that simulation is the method of choice. Unfortunately, until recently, simulation systems were either simple software programs that did not come close to portraying the real experience or were complex hardware systems (such as flight simulators) that did, but at a cost of millions of dollars (Fritz, 1991). However, researchers and training specialists are excited about an emerging approach to work-force education based on virtual reality. VR is also described as cyberspace, immersive simulation, artificial reality, telepresence, virtual environment or virtual world (Meyer and Dunn-Roberts, 1992; Peterson, 1992). It represents a group of concurrent advances in computer and interface technologies. They enable an individual to interact in a multisensory way with a computer-generated environment. To achieve this, a typical VR system incorporates a computer that contains the necessary databases for producing realistic images and audio; a head-mounted display (HMD) or screen for viewing the images; and a three-dimensional controller, joystick or data glove for interacting with the computer-generated environment. If virtual reality is to become an effective tool for the safety training of mine workers, its attributes will have to be measured against other forms of delivery. Accordingly, Carr (1992) listed the following areas in which VR should be considered the method of choice: ? When training mistakes would be costly. ? When the necessary environment cannot be experienced in the real world. ? To build interfaces that are sensible and can be manipulated. ? To make training situations really "real." ?To make perceptible the imperceptible.

Jan 1, 1997

By John D. Rockaway

This report and accompanying engineering geologic map describe the generalized engineering geology of St. Louis County, Missouri for use in determining the most efficient, economical, and environmentally sound program for land development and urban growth. It includes an evaluation of such factors as the physical and engineering properties of soil and bedrock, surface stability, and subsurface geologic structure. The map and text are designed primarily for property owners, engineers, architects, real estate developers, and city planners involved in land-use planning. The geologic information and engineering interpretation must be considered as a general guide and not as a substitute for a complete on site investigation prior to initiation of any land-use project. The map scale, 1:63,360 (1 inch to a mile) is too small to include the detailed information normally provided on the 7 1/2-minute quadrangle series (1:24,000). The smaller scale is most useful at regional planning levels and was chosen to present information on the more significant engineering factors of the geologic environment for county-wide planning and development. A conventional geologic map deals primarily with the distribution and variation of bedrock formations, and a pedologic map presents information on the soil or natural medium for plant growth. Basic geologic maps and pedological maps are valuable tools that can be of assistance in studying the geologic environment, however, these maps do not provide all the information required for land-use planning. The engineering geologic maps are designed to provide this data. The engineering geologic map is related to both of these basic maps but emphasizes the engineering properties of the rock formations and soils rather than their age or origin. Some of the unit boundaries shown on the county map will closely follow some geologic formation and/or pedologic boundaries; others will transgress these conventional boundaries. Earth materials, bedrock and soil, that have similar engineering characteristics have been mapped as one unit without regard to their geologic or pedologic classifications. This is to assure that geological factors are recognized, adequately interpreted, and presented for use in engineering practice.

Jan 1, 1970

By T. A. McAfoose

As one of the major suppliers of the chestnut Ridge energy center, Rochester and Pittsburgh Coal Company continues the search for more efficient haulage systems. This search is one that is essential in providing coal to the Keystone and Homer City power plants at the most economical cost. These two electrical generating plants located in west central Pennsylvania are part of the energy center which consists of four generating stations. Prior to the time the two stations were put on line, August, 1967 for Keystone and August, 1969 for Homer City, our company made the decision to rely on belt conveyors from the section to the surface to provide for continuous main line haulage. The proximity of these generating stations to proven reserves allow for minimal truck haulage and minemouth setups. With the addition of seven new mines, in the past ten years, revisions have been made on the original setup to interconnect the haulage of several mines to deliver the product by belt to the power plants.

Jan 1, 1979

By G. V. Borquez

For many years drilling and blasting has been considered more of an art than a science. This is still true in some respects, but today scientific approaches to drilling and blasting design must be used to plan an efficient operation which achieves desired fragmentation within constraints. These constraints involve minimizing damage to the wall or nearby permanent structures and avoiding undesirable fragmentation and mine dilution which can adversely affect operation costs. The degree of fragmentation by blasting is the most important single factor in any attempt to optimize the overall cost of the mining operations. The mining cycle begins with the drilling and blasting operations, which result in a given blasted rock size distribution. While this operation represents only about 20% of total mining costs, the efficiency and costs of the subsequent operations are strongly dependent on the fragment distribution obtained.

Jan 1, 1986

By Douglas Ball

An underground storage field is a gas field where man, not nature, has put all or most of the gas. All but one of those in use today are in the pore spaces or "porosity" of sedimentary rocks, the most common being sandstone. The one exception, near Newcastle, England, is a gas storage in a cavern dissolved from rock salt. The tens of millions of barrels of LPG (liguified petroleum gas) now stored in salt caverns mined in shale is liquid storage, not gas storage, and in this paper I recognize the presence of these installations but do not include them in the gas storage category, Since, with the English exception, gas storages are gas fields, they can all be sorted into the categories used to describe gas fields, 95% of them once gas fields anyway, but some of the remaining 5% are the ones having the greatest effects on underground waters.

Jan 1, 1960

By R. W. Macqueen

Organic matter commonly associated with Mississippi Valley-type (MVT) lead-zinc deposits may be used to assess the burial/thermal history of host rocks and sulfides. Organic matter may also have been involved in the genesis of H2S required to precipitate sulfide ores. Pine Point, Northwest Territories, Canada, provides an example. Located on the south shore of Great Slave Lake, Pine Point is an operating world class deposit which has produced 58 million tons of ore containing 3.0 percent Pb and 6.1 percent Zn from more than 40 Individual orebodies. Well-documented paleokarst features in a Middle Devonian carbonate complex are the main ore hosts. Sphalerite and galena ores are mainly open space fillings, and, from fluid inclusion studies, were deposited from saline fluids at temperatures of up to at least 100°C. Forms of organic matter occurring in the Pine Point barrier-reef complex Include indigenous organic matter, heavy oil and bitumen. Based on numerous geochemical criteria, it is clear that heavy oils and bitumens were derived locally from indigenous organic matter. The geochemical character of the Indigenous organic matter demonstrates that the barrier-reef complex is immature to marginally mature with respect to petroleum generation, and has not been heated above about 60°C maximum. Thus sphalerite with fluid inclusions that yield temperatures up to about 100°C represents former thermal anomalies. Bitumen is of two main forms at Pine Point: widespread soft, tarry material soluble in organic solvents (unaltered bitumen); and hard, brittle, glassy material that is mostly solvent-insoluble, and associated with white sparry dolomite and lead-zinc ores (altered bitumen). There are also partly altered bitumens. Unaltered bitumens have atomic H/C ratios of about 1.4, sulfur contents averaging 7.8 percent, and sulfur isotope ratios 634S) of approximately +4.6 per mil. Altered bitumens have atomic H/C ratios averaging 1.02, sulfur contents averaging 22 percent, and 634S values of about +12.9 per mil. These data and the organic geochemical character of a large suite of bitumen samples analyzed, strongly support the concept that some bitumen has been involved in the thermochemical reduction of sulfate to produce the H2S required to precipitate the ores. Mass-balance calculations indicate that the amount and degree of alteration of bitumen is more than enough to account for the reduced sulfur species deposited as metallic sulfides at Pine Point. MVT deposits, including Pine Point, seem to require the coincidence of available metallic Ions, pre-existing pore space, and a precipitating agent. A close look at organic matter in more MVT settings may outline trends in distribution or alteration which can be used as indicators of past thermal environments and processes of ore deposition.

Jan 1, 2013

By Kent E. McElhattan

The selection of efficiency machinery for an underground mining system is a highly skilled art. Modern techniques of mining, based on sound engineering principles, increase the probability of success. These techniques alone, however, will not guarantee maximum productivity. Human judgement, based on experience with mineral seams and geological conditions, remains the single most important input of the decision-making techniques in selecting high production equipment. The myth of a "Scientific Selection Factor" is absurd. The belief that such a factor exists can waste the time and resources of mining management. Until now, mineral extraction from the original desposit has defied all attempts to systematize the knowledge. Computerized programs are excellent for solving underground transportation and ventilation problems. The variables can be defined by mathe¬matical techniques in this type of problem. By the same, token, "Trial and Error" is not an acceptable method in today's technology-minded world. The candid truth of the matter is that practically nothing is known of the phenomenon of extracting a mineral from the solid. Likewise, local conditions make it nearly impossible to predict accurately the reaction of surrounding strata after the mineral has been removed. The unpredictability of the environment resulting from extracting minerals underground will remain a challenge to mining engineers for many years. In fact, we are barely beyond the trial and error stage at this point in time.

Jan 1, 1969

By John Ralston, Jinming Duan, David R. E. Snoswell, Daniel Fornasiero, Jingwu Yang

The colloidal stability of synthetic silica spheres with clean, methylated and dehydroxylated sur¬faces was studied at different concentrations of dissolved gas and KCl electrolyte at a fixed pH of 4.2. A classic stability ratio/electrolyte concentration analysis shows that hydrophobic, methy¬lated particles undergo faster rates of aggregation with increasing concentrations of dissolved carbon dioxide. Similar data for hydrophilic particles and dehydroxylated particles show no change as a function of dissolved carbon dioxide concentration. Zeta potential data behave simi¬larly, showing a strong influence of dissolved gas only for methylated particles. The results are interpreted in terms of DLVO theory, with the surface-to-surface interaction dominated by the presence of very small protruding bubbles. Direct evidence for the existence of these very small gas bubbles (or "nanobubbles") was obtained using tapping mode atomic force microscopy. Small bubbles do not form on smooth, hydrophilic, or dehydroxylated silicon oxide water sur¬faces immersed in aqueous solutions under known levels of gas supersaturation. Randomly dis¬tributed small bubbles were observed over the whole surface of observation on methylated surfaces of controlled roughness. Bubbles formed on rough, methylated surfaces were larger and less-densely distributed than those on a smooth surface of similar hydrophobicity. The process of bubble coalescence was observed as a function of time. The macroscopic contact angle, measured with respect to the aqueous or gas phase, is very different from the microscopic contact angle detected by TMAFM and appears to be due to the influence of line tension at the pinned three¬phase contact line. The latter has a value of -3 x 10-10 N and acts to stabilize the small bubbles, flattening them and thereby reducing the Laplace pressure.

Jan 1, 2005