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By D. R. Spears, D. A. Stanley

The US Bureau of Mines investigated the fundamental aspects of shear-flocculation using a rapid, in-situ particle size analyzer. Silica was stirred in the presence of an aliphatic amine to determine the effects of collector coverage, stirring speed and solids concentration on the kinetics of shear-flocculation. The results showed that shear flocculation is a two-stage process. In the first stage, which occurs during the first 1-2 min. of the reaction, the mean particle size increases rapidly, and in the second stage, an equilibrium is set up between the rates of floc growth and floc decay. Collector dosage affected the position of the equilibrium by altering the number of surface sites for particle-particle attachment. A minimum stirring speed was necessary for shear flocculation, which was dependent on solids concentration and collector dosage. This stirring speed was the minimum necessary for particles to overcome the electrostatic energy barrier, and that results in keeping the conditioned particles dispersed. Larger particles flocculated more rapidly. At very high stirring speeds, large flocs became unstable, resulting in a narrowed particle size distribution in the slurry.

Jan 1, 1995

By L. G. Austin

Using an instrumented laboratory high-pressure grinding rolls mill, the grinding force, gap dimension, mass flow rate and net mill power were measured for six coals and a crystalline quartz. A technique was developed to estimate the compressive stress-strain curves for compression of the materials in the mill plus the effects of elastic decompression. To reconcile the mill power and grinding pressure results, it was necessary to allow for the energy recovery on decompression. No clear correlation was obtained between the form of the stress-strain curves or the variation of specific mill power factor with the Hardgrove grindability index (HGI), although coals with the lowest and highest HGIs (i.e., 44 and 106) gave results significantly different from the other coals. Feeds below 140 mesh (105 µm) flowed more rapidly than coarser feeds and would not build up high grinding pressures. This indicated shearing and fluidlike properties rather than compression as a locked bed.

Jan 1, 1998

By J. Hanna

The University of Alabama Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of carbonate gangue from sedimentary apatites (francolite) in the pH range of 4-6 without collector conditioning of the pulp. The process, which does not require an apatite depressant, was modified to benepciate a high- MgO siliceous phosphate matrix from south Florida. The modified process includes two flotation stages, one for car- bonate removal and the other for phosphate recovery from the siliceous gangue. The selective flotation separation of the carbonate and phosphate from siliceous constituents of the matrix at various pH levels and collector dosages are discussed. In the carbonate flotation stage, about 70% of the MgO was rejected in the froth. The phosphate flotation stage produced concentrates analyzing about 31% P2O5 0.7% ? 5 MgO, and 4% insol. The overall P2O5 recovery In the two stages was about 85%

Jan 1, 1991

By Kenneth J. Leib, Laurie Wirt, M. Alisa Mast

Chemical-constituent loads were determined for an alpine stream in southwestern Colorado that is affected by natural acid drainage from weathering of hydrothermally-altered rock and from acidic metal-rich discharge from abandoned mines. Base-flow loads were compared to storm-related loads using a tracer-dilution approach. A rainstom occurred during the tracer injection, providing the opportunity to measure metal loads before, during, and after storm runoff. Chemical-constituent loads during the storm increased by 1 to 2 orders of magnitude relative to base-flow conditions. The increase in loads was related to two distinct periods; (1) a flush of higher concentrations that occurred soon after rainfall began, and (2) the peak of storm runoff. The initial flush-having no measurable change in discharge--contained the highest loads of trace metals and dissolved iron. The chemical character of peak runoff was distinctly different, as evidenced by the highest loads of total and dissolved major elements and total iron.

Jan 1, 2000

By L. Piga, G. Belardi, V. Alesse, N. Shehu, J. Freund

The physico-chemical interactions among minerals such as olivine, chromite and serpentine; the most commonly present ions in solution such as Ca and Mg; and flotation reagents such as EDTA and oleic acid were investigated. The study was conducted via release tests, electrophoretic measurements and microflotation of selected minerals coming from the Kukes deposit in Albania. The results were confirmed in beneficiation tests on two ores, one from the Kukes (Kalimash) deposit and the other from the Rizo deposit in Greece. It was demonstrated that, when Na-oleate is used as collector, chromite, olivine and serpentine can be separated at pH 2.5 and/or pH 5.5 when employing ethylenediamine tetraacetate (EDTA) on previously deslimed material. This approach ensures flotation concentrates with a Cr203 content better than 50% with a recovery of more than 75%.

Jan 1, 1998

By M. Karmis

Surface subsidence has been recognized as an inevitable consequence of underground coal mining for several centuries. The damage resulting from this phenomenon has been witnessed in rural as well as in urban areas and ranges from simple land settlement to severe structural damage to buildings. Subsidence prevention is not feasible, at least under the existing technological and economic constraints of underground coal mining. Using a rational method of subsidence prediction, it has been demonstrated in many coalfields that subsidence control can be successfully practiced in order to reduce and accommodate subsidence within environmentally acceptable levels. This paper presents the development and testing of a subsidence model, based on the zone area method. This technique is a refined development of the influence functions and it is capable of investigating a mining plan of any shape, thus facilitating both longwall and room-and-pillar mining systems. More specifically, this study can be divided into two major efforts: (a) The development of the zone area model. This formulation was designed to accommodate the analysis of an optimum number of zones, over the area of interest, both accurately and efficiently. (b) The testing of the computer techniques with appropriate field measurements. In order to accomplish this, published as well as unpublished information was collected and analyzed according to a regionalized scheme. This procedure minimized differences in subsidence characteristics between the various coalfields and allowed a regional validation of the predictive capabilities of the model.

Jan 1, 1982

By H. Barry Holt, Charles A. Bischoff

On November 15, 1990, President Bush signed the Clean Air Act Amendments of 1990. The new legislation is sweeping in its demands for cuts in smog, acid deposition, toxic air pollutants and ozone-depleting chemicals. The Amendments will siqnificantly alter air quality permitting and compliance and are estimted to cost billions of dollars to implement. This article provides an overview and summary of each of the eleven titles of the Amendments. It also addresses how the Amendments will be implemented.

Jan 1, 1991

By Tzou-Shin Ueng

Rock reinforcement of rock anchors and rock bolts are commonly used for the support of large rock caverns. The rocks at the location of most large underground openings are usually under very high initial stresses prior to excavation. Hence, the stress redistribution caused by excavation will induce considerable rebound deformations of rocks surrounding the caverns. Since the pressures exerted by the reinforcement are generally far below the initial rock stresses, the reinforcement will be stretched along with the rock deformations, and the stresses in the reinforcement increase accordingly. It is not uncommon for the stress in the reinforcement to reach the yield strength, and in some cases the reinforcement may even have failed. Therefore, the increase of stresses caused by the rebound deformations of rocks should be taken into account in addition to the force required to stabilize the caverns. It was found that the measured stress increases of the prestressed tendons after installation were in good agreement with those computed based on the measured rock deformations between surface and the anchoring point of the reinforcement. The rebound rock deformations and the stress increases in the reinforcement can be estimated based on the results of the finite element analysis and experiences in previous field measurements incorporated with considerations of the geologic conditions, rock properties, rock reinforcement and construction procedures.

Jan 1, 1986

By B. (Manas) Das

Rock characterization for geotechnical purposes using the microhardness technique is discussed in this paper. The concept of rock characterization and its steps are logically developed. The geotechnical properties should be functionally tethered to the technological problems for characterization. The overriding geotechnical concern is rock mass stability. The important factors in this respect are rock properties, structural discontinuities, ground water, field stress, temperature and technological factors. The rock properties are the primary factors and the other factors generally affect rock properties. Of the rock properties the strength and elastic properties can form a basis for rock characterization. The microhardness technique can provide these two properties. Study on coal shows that the microhardness impressions can be used for this purpose. On the basis of this study coals of all ranks can be divided into distinct geotechnical groups. The details of these are discussed in this paper.

Jan 1, 1986

By F. C. Schwerer, C. R. McKee, J. C. Seccombe

Production of methane from coal seams requires hydrofracturing, and the length of a hydraulic fracture determines we11 spacing. Since the volume of fluid injected is known, the fracture length is the volume divided by average width and height. If the fracture is contained in the known height of the seam, then fracture width becomes the major factor con- trolling length. Width is proportional to coal compressibility; bulk compressibility is known to be larger than intrinsic compressibility. A method is given here to measure in-situ compressibility (a) from transient pressure testing. Theory linking flow in porous media with rock mechanical properties is reviewed. A consistent derivation of the porous flow equation is given incorporating 3-D deformation and the effective stress parameter "st' linking changes in effective stress and pore pressure. The relations for "st' in terms of a and intrinsic compressibility (ai) are substituted into the field measured porosity-compressibility product (net) and solved for a, the constrained matrix compressibility. In a field example, using 4 wells with an anisotropic analysis, the ratio of major to minor permeability was 17 for the Pratt A seam. a was found to be 6x10-5/psi as opposed to the laboratory value of 1.4x10-6/psi.

Jan 1, 1986

By M. A. Ackerson, R. E. Griffin, W. H. Pomroy

Two automated fire detection system configurations have been used successfully in underground mines: the pneumatic "tube bundle" approach and the electronic telemetry approach. The electronic telemetry approach is more widely used, owing to its greater speed, flexibility, and capacity to both monitor other underground conditions, and remotely control underground equipment. However, depending on specific mine conditions and layouts, pneumatic detection, or a combined pneumatic/telemetered system may offer significant advantages over the telemetered approach alone. This paper describes research by the U.S. Bureau of Mines to design and in- mine test a rapid response pneumatic fire detection system tailored to the unique requirements of multilevel metal mines. The relative merits of pneumatic detection are discussed in the context of typical multilevel mine layouts and environments. A Bureau developed proto- type system is described with emphasis on design features which counter commonly perceived and/or experienced pneumatic detection system operating problems. Finally, the results of a 3-yr in-mine performance evaluation of the prototype hardware are discussed. Included are descriptions of system layout and coverage, response time, tube leakage, sample dilution, elimination of accumulated water from sample lines, and system maintenance and reliability.

Jan 1, 1989

By F. Forbes

For many years, the Machinery Division of Dravo Corporation has been designing and constructing bins and hunkers as part of overall plant facilities. We have designed bins to handle a variety of materials including coal, coke, iron ores and concentrates, sintered and pelletized ores, calcined and raw limestone, bentonite, alloys for BOF shops, and even cast iron chips from machining operations. We, along with everyone else in this business, have had our bin problems. The bins either plug, rathole, segregate, wear out, flood the discharge device, or overload it. Surprisingly, sometimes they have worked. As engineers, it has long concerned us that something as important as bin design should be so imprecise and that it has been so conspicuously avoided in research and in literature. In past years, rule-of-thumb design criteria had been to keep the sides of the bins as steep as possible and the outlets of the bin as large as possible. This criteria led to the design of bins with 600 to 700 side slopes and table feeders which were very large. Unfortunately, this meant trying to fit tall, skinny bins into a layout where minimum building height was required for obvious economic reasons. Like everyone else in the industry, we found that this design procedure was expensive and ineffective.

Jan 1, 1968

By Gerald H. Luttrell, Rick Q. Honaker

A coal preparation plant incorporates a variety of solid-solid separation processes that operate in relatively independent parallel circuits. Studies have shown that total plant performance can be optimized by selecting circuit cutpoints that maximize total clean coal yield irrespective of the performance of individual circuits. Although the optimum cutpoints can be determined using simulation programs, these mathematical routines require detailed washability data and empirical partition information that is not often available to plant operators. In addition, routine fluctuations in the washability characteristics of the plant feed make this approach impractical to implement in industrial facilities. As an alternative, practical optimization criteria can be developed for plant operators through a fundamental understanding of scientific principles involved in coal cleaning operations. This article provides an overview of the most important optimization criteria and presents several industrial case studies that illustrate the financial benefits of this practical approach m plant optimization.

Jan 1, 2005

During 1997-2001, an EC funded project investigated the environmental consequences of the use of industrial waste and sewage sludge based artificial top soils (ATS) in rehabilitating large coalmine waste dumps in the Saar region of Germany. Both the laboratory leaching tests and field lysimeter data analysis carried out by the research partners have shown that the amount of dissolved heavy metals in the leachate was low, and generally below the regulatory limits. However, the dissolved amount of nutrients, especially mineral nitrogen, was found to be relatively high. The hydrological properties of waste rocks and ATS mixtures were established through history matching of the laboratory column tests and the field measurements. 1D column models and 3D field models were used to numerically simulate pollutant transport at the ATS rehabilitated waste dumps. This paper presents the findings of the numerical modelling research carried out for the characterisation of hydrological and pollutant transport properties of rehabilitated coalmine waste dumps in the Saar coalfield.

Jan 1, 2003

By M. C. Williams

The dynamic behavior of batch mill, CSTR mill, and a closed grinding network consisting of a mill, sump, and cyclone was analyzed using the dynamic population balance model (PBM). The dynamic solution of the PBM of a batch, CSTR and a closed grinding network consisting of a mill, sump, and cyclone forms the basis of the dynamic analysis presented here. Two numerical dynamic solution approaches were used. These are: 1) providing additional constraints on breakage selection functions or 2) performing the Arbiter-Bhrany (or other) normalization of the selection functions. Actual experimental anthracite batch grinding data was used to obtain the functionality of the batch dynamic mill selection and breakage functions for a real physical system. The Levenberg-Marquardt algorithm for systems of constrained non-linear equations is used to solve the batch dynamic PBM grinding equations to obtain the grinding selection and breakage rate functions. The mill, sump and hydrocyclone were modeled as a CSTR operating at various retention times. Batch dynamic PBM data was used to provide the mill kinetic and breakage selection function data. Different dynamic solutions were obtained depending on the numerical approach used. Each solution approach to a dynamic PBM with transport, while giving the same prediction for a single batch grinding time, gives different solutions or predictions for mill composition for other grinding times. This fact makes dynamic nodal analysis and control problematic. The fact that the constraint solution approach gives a solution may suggest that normalization for closed networks is not necessary. Differences in solutions to the PBM cannot be excused away by inaccuracies in the data used to model the grinding phenomenon.

Jan 1, 1995

By J. E. Gebhardt, S. Chander

Significant advances have occurred in the use of electrochemical techniques for sulfide mineral flotation research. The techniques have been used singly or jointly with other characterization methods. When used in combination with other methods, the electrochemical methods provide a means to control the state of oxidation of the surface. Various analytical methods are employed for characterization. The methods that have been used include wetting, x-ray photoelectron and fourier transform infrared spectroscopies. The electrochemical methods include voltammetry and transient electrochemical techniques of galvanostatic polarization and AC impedance spectroscopy. The challenge for the future lies in the utilization of this knowledge in plant operations so as to increase the overall efficiency of flotation separations.

Jan 1, 1989

By Mulong Yu, Yosry A. Attia

Beneficiation of high magnesium Florida phosphates requires ultrafine grinding to liberate the dolomite (the main source of magnesium), and a separation process capable of dealing with ultrafine sizes such as selective flocculation. The objective of this study was to investigate the feasibility of separating dolomite from apatite ultrafines by selective flocculation. To achieve this objective, selective polymeric reagents to either dolomite or apatite must be first designed and synthesized. This challenging task was accomplished by carefully selecting complexing/chelating agents which are selective to either the Ca or Mg ionic sites on the minerals, and incorporating these reagents into the structure of long chain water soluble polymers to obtain either selective flocculants (with high molecular weight, MW, polymers), or selective dispersants (with low MW polymers) to either the dolomite or the apatite particles. Synthesis and testing of these polymers on individual and mixed mineral slurries, and on a sample of natural high magnesium phosphate ore, have been attempted and the results are described in the paper. The preliminary results showed encouraging signs for the feasibility of selective flocculation separation of dolomite from apatite.

Jan 1, 1993

By Jose M. Milian, Raphael F. Matson

An intensive study was started in 1968 to determine the most economical process for winning nickel and cobalt from an extensive de- posit of complex, low grade nickel-cobalt ore (1.6% Ni, 0.10% CO) designated "the Greenvale ore." In 1974 the commercial plant at Yabulu, in Queensland, Australia, began processing the ore. In the interim, a great deal of laboratory and pilot-plant effort was applied to develop technical, process and commercial design data to demonstrate to potential financial backers and customers that a full-scale plant was feasible. The laboratory test work, pilot plant facilities and pro- gram are briefly reviewed in this paper.

Jan 1, 1979

By A. Peppas

Perlite is a naturally occurring siliceous rock, which can be expanded from four to twenty times its original volume when heated at a temperature close to its softening point. The expanded perlite is characterized by increased sound and thermal insulating properties. However, the conventionally expanded perlite products have high porosity and low mechanical properties that limit the range of their applications in the construction and chemical industry. The present work aims at the development of new closed porous microcellular material from perlite with enhanced mechanical and physical properties to be applied in new applications, like joint compounds, functional fillers for special paint types, special blasters and mortars, artificial marble. For the production of these new materials a vertical electrically heated furnace with six different heating zones and controlled gradient temperature profile was used. The effect of major process parameters, like temperature and air flow, on the quality of the produced materials was studied using Greek perlite from Milos Island. The quality of the new products was evaluated in terms of their bulk density, compression strength, water and oil absorption, surface area and pore volume. The experimental results show that the produced materials are characterised by improved mechanical and physical properties compared to the conventionally expanded perlite products.

Jan 1, 2006

By Steven H. Brown

Ore bodies which were once uneconomical to mine by conventional methods such as tunneling or open pits, have become attractive due to the development of nonconventional techniques, involving considerably less capital expenditure. Technologies such as uranium solution mining or in-situ leaching, have enabled commercial scale mining and milling of relatively small ore pockets of lower grade, and may make a significant contribution to overall U.S. uranium supplies during the next 20 years. Commercial size solution mining production facilities have operated since late 1975. Solution mining involves the pumping of ground water, fortified with oxidizing and complexing agents into an ore body, leaching and solubilizing the uranium in-situ, and then pumping the solutions to the surface where they are fed to a processing plant. Processing involves ion exchange, precipitation, calcining, and packaging operations. This paper presents an overview of the solution mining process and the health physics monitoring programs developed over the last four years at several production facilities as a result of the radiological character of these processes. Although many radiological aspects of the process are similar to that of conventional mills, conventional-type tailings as such are not generated. Some special monitoring considerations are presented which are required due to the manner in which radon gas is evolved in the process and the unique aspects of controlling solution flow patterns underground. An overview of the major aspects of the health physics compliance and monitoring programs that have been developed are discussed.

Jan 1, 1981