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By Hikosaka A, Chiba A

In a fundamental study of the physical chemistry of steelmaking slag, equilibra bet- ween hydrogen-water vapour gas mixtures and liquid slags contained in solid iron crucibles have been measured for four binary slags, FetO-CaO, FetO-Si02, FetO-TiO2 and FetO-Al203 at 14000C. From the data, the activity of iron oxide and the ratio of ferrous and ferric ions (A = Fe3+/Fe2+) were calculated for the slag composition. The best ionic model is found to be that based on regular solution of cations. The oxygen distribution between slag and metal is quantitatively expressed by this model over a wide range of slag composition.

Jan 1, 1980

By Hinchliffe WD, Griffin A

The desorption of gold from activated carbon is promoted by adding organic solvents to aqueous cyanide solutions. At 65-80¦ the elution of gold is fast and is not affected by water quality. The Micron Procedure involves pretreatment of the loaded carbon with NaCN/NaOH followed by elution with methanol vapour and condensate. Carbon is packed into a column above the distillation pot and acts as a fractionating column. Recovery of the methanol condensate leaves a methanol free concentrated gold solution and carbon containing

Jan 1, 1984

By Getliffe RK

It is becoming more and more difficult to operate mineral and metal processes profitably, as operating costs rise, quality demands in-crease, international competition becomes more fierce and Government charges remain at their current levels. Profitability today depends upon efficient operations, which can only be achieved through precise and dependable con-trol of each process unit comprising thetotal plant.Modern process control systems utilise distributed architecture with microprocessor-based controllers, data acquisition devices and VDU operator stations. Honeywell intro-duced this control technology in 1975 with the "Total Distributed Control" System. Now, building on the proven performance and re-liability inherent in TDC hiway modules, Honeywell has extended the TDC system to inte-grate both management information and control by providing distributed processing modules on the new TDC 3000 Local Control Network (LCN).

Jan 1, 1985

By Binns MJ

Gold/silver orebodies of the Golden Plateau deposit, Cracow, Central Queensland, are currently being exploited by the Cracow Mining Venture. A geostatistical block model has been prepared to assist with long term mine planning. The Golden Plateau orebody, of inferred epithermal origin, is a multiply brecciated, silicified fault complex containing irregular, tabular and pipe- like oreshoots. Historically the lode has been stoped and open cut over a strike length of 750 metres at widths of up to 15 metres and to a depth of 250 metres. The Golden Plateau mine produced 1.55 million tonnes of ore at an average grade of 12 g/t Au and 13.5 g/t Ag over a 42 year period. In the preparation of the reserve model much reliance has been placed on recent diamond and reverse circulation drilling (71 holes in total). However a significant volume of data has been derived from historical level assays and underground diamond drilling. Over 3,000 level assays and 50 underground drill holes contributed to the database. Similar lognormal populations were observed for 1 metre composite grades from each major drilling campaign once corrections were made for core loss. Cumulative frequency plots revealed only one outlier which was cut to the population line. The population statistics from the historical level assays showed a significant difference from those derived from the drill hole composites. Level assay populations were cut to local drill hole populations before incorporation into the ore reserve model. The resulting data has yielded interpretable variograms, the parameters of which have been applied to the preparation of a kriged block model of the deposit.

Jan 1, 1987

The difference between a hypothetical and a theoretical approach is considered and the advantages in using a hypothesis is discussed. Virgin horizontal stresses play an important role in stabilising strata which bridge across an excavation, and reduces the tensile stresses which develop in a beam subjected to bending. Simple formulae are deduced for the bridging of a thick massive stratum under such conditions. At shallow depths, tensile failure on the upper side of the beam is the most likely cause of fracture, but below a certain depth this gives place to compressive failure on the underside, with the possible incidence of rock bumps. The presence of strong massive beds delay the onset of subsidence and may restrict the width of the subsidence trough. If the material involved in the caving is strong, this will reduce the final subsidence, especially at shallow depths. The British regulations for the control of aquifers and their dependence on the strain developed at the seabed are discussed. As an alternative, the concept of a disturbance factor is introduced to permit the consider- ation of aquifers at depth, leading to an explanation of the make of water on the first faces to be mined in the Selby Coalfield. 'Elie paper closes with a brief consideration of the different roles played by longwall face supports in the control of readily cavable strata, and the control of strong beds which hold up in the waste.

Jan 1, 1986

By Graham J

The successful processing of arsenopyritic ores is difficult and will be facilitated by a better understanding of the mineralogy of gold within arsenopyrite and the type of arsenopyrite in which gold is taken up. Solid solution gold in arsenopyrite is now well documented, and is a significant cause of refractory behaviour in gold processing. Investigations of the crystal structure and stoichiometry of arsenopyrite by X-ray diffraction, electron microprobe analysis and convergent beam electron microscopy have been carried out in order to understand how the gold is incorporated into the structure. Variations in stoichiometry, particularly the As:S ratio, of arsenopyrite leads to variations in structural parameters. These variations result in slight changes in thermal behaviour. The distribution of invisible gold in an arsenopyrite grain is generally non-uniform and synthesised samples contain up to 2 wt per cent gold. A transmission electron microscopy (TEM) technique called ALCHEMI is being used to identify the substitution site. The process of gold agglomeration together with evidence of an ordered breakdown of arsenopyrite to pyrrhotite has been documented with the use of TEM. An arsenopyrite grain containing invisible gold was heated with an electron beam resulting in recrystallisation of arsenopyrite to pyrrhotite with arsenic being expelled. The gold is mostly insoluble in the pyrrhotite lattice and therefore exsolves out and combines with other gold atoms to form droplets at the boundary of the pyrrhotite.

Jan 1, 1992

Exploration risk increases with time, due to a general decrease in prospectivity as the more accessible deposits are found, and be- cause of rising costs and demands due to an improving standard of living. Risk is separated into financial risk, which increases sharply at the development stage, and the risk of failure which is at its peak at the outset of exploration. Risk is also divided into internal and external factors; some of the latter cannot be offset, viz. the systematic overall risk for any enterprise. The recently emergent risk embodied in withdrawal of large areas from exploration access is discussed. An appeal is made for objective multiple land-use policies to be applied so that land remains available at reasonable cost and with appropriate environ- mental safeguard conditions. Risks specific to gold exploration are discussed. As gold now accounts for over 50% of all mineral exploration, and most other metals are depressed, any sharp decline in gold will have grave effects on the ex- ploration industry. Gold exploration will become more difficult and expensive in about five years, after most of the readily accessible deposits in Australia are found. Government's role is important in pro- viding stability and basic data at reasonable cost. Exploration for specific minerals or of particular areas could be stimulated by extending the 150%.tax deductibility of R & D to aspects of exploration of strategic im- portance, particularly in the event of a downturn. Exploration is classic scientific research, at least through to the proving Stages.

Jan 1, 1987

This study begins with the semivario- gram modelling of variables rutile grade and clay content from a beach sand rutile deposit. This is followed by two dimensional block kriging. The deposit was divided into blocks of 30 x 30 x 1.5 m dimensions and the kriged estimate together with the associated kriging variances for each variable within each block were determined. Finally, using the results of the krig- ing program and considering the acceptable limit of clay content together with the cutoff grade for rutile, a method for optimization of mineable thickness and hence the tonnage of ore was applied and the results were dis- Cussed.

Jan 1, 1986

By W A. Ducker, R-H Yoon, M Mao

Froth flotation relies on an attractive force between a particle and a bubble to selectively extract particles from a mixture. The range and magnitude of this attractive force is an area of ongoing investigation. We describe measurements of the effect of dissolved gases on the long-range attractive surface forces between a silica plate and a glass sphere in aqueous octadecyltrimethylammonium chloride (C18TACl) solutions. The measurements follow on the work of Sakamoto et al (2002) who have concluded that long-range interactions occur in air-equilibrated surfactant solutions but not in degassed solutions. In the present work, we have measured attractive forces that have a much larger in magnitude than the expected van der Waals force in solutions that were degassed by the same procedure used by Sakamoto et al (2002). We find that the forces are most attractive at 5 + 10-6 M C18TACl, which is close to the charge compensation point (ccp) of the glass sphere. At this concentration, the attractive force decays exponentially with distance and the decay length is 34 in air-saturated solution, and 38 nm in degassed solutions. In both air-equilibrated and degassed solution, the force is quite sensitive to the concentration of surfactant. The force is also sensitive to the pH. We note that our degassing procedure increases the pH of the solution from about 5.7 to 6.6 (presumably by removal of dissolved CO2). We find that the forces measured in degassed solution can be reproduced by using a solution that was equilibrated in air, then the pH was increased by addition of NaOH. Therefore, we conclude that the main effect of degassing in our experiments is to raise the pH. We show that the range and magnitude of the attractive force decreases in the presence of salt (NaCl). This suggests an electrostatic mechanism for the attraction. Possible mechanisms for the attractive force are examined, including the mechanisms that rely on a patchy coverage of surfactant on the silica surface.

Jan 1, 2005

By Snowdowne J. B H

Rand Mines, Limited, located in Johannesburg, Republic of South Africa has recently completed feasibility studies which have lead to the initiation of two major coal strip mining ventures. A minicomputer based mine planning system was developed to perform the feasibility studies. The broad approach of this system is to utilise inter.-actively the specialist skills and interpretative abilities of mining engineers and geologists. This paper reports briefly on the outline of the system and at greater length upon certain aspects of its use.

Jan 1, 1977

By Bourne R. W, Smith T

This paper presents initial findings of a project examining novel processes for the treatment of refractory sulphidic gold concentrates. Non-oxidative roasting of such concentrates for 12 hours at 750¦C resulted in the finely disseminated gold agglomerating to form discrete grains. The pyrite and arsenopyrite decomposed to form pyrrhotite, whilst the labile sulphur and arsenic driven off was collected on a condenser as a mixture of elemental sulphur, metallic arsenic and various arseneous sulphide compounds. As a result, the cyanide solubility of the gold contained in sulphidic refractory gold concentrate from the Emperor mine in Fiji improved from 54.5 per cent to 98.4 per cent; from the Fimiston mine in WA (65.2 per cent to 96.6 per cent), from the Windarra mine in WA (69.6 per cent to 91.3 per cent), from the Harbor Lights mine in WA (20.4 per cent to 60.7 per cent), and from the Wiluna mine in WA (12.6 per cent to 28.0 per cent). The non-oxidative roasting conditions have not been optimised for each of these minerals. Subjecting the non-oxidatively roasted minerals to mild oxidative acidic iron sulphate pressure leaching (with typical temperature of 100¦C and typical oxygen overpressure of 500 kPa) to remove iron and so further liberate finely disseminated gold, resulted in the cyanide solubility of the gold exceeding 96 per cent for each of these five concentrate types (including those from Harbor Lights and Wiluna). Thiourea leaching of the sulphur-rich residues under acidic conditions resulted in remarkably high gold extractions being achieved. These novel processing options need to be optimised, and their economic viability established.

Jan 1, 1991

The treatment of nickel ores and concentrates and the subsequent processing to recover separate products of nickel and cobalt is one of the major interests at present in the mining industry. The increasing demand for nickel, and more recently also cobalt, has led to increased exploration for ore sources. Major discoveries have resulted in Canada and Australia. These deposits, as well as others already known, are presently being developed and the process technology tested and evaluated for applicability to the different mineralogical types - mainly sulphide, arsenide and oxide laterites. Concentrates may be treated by either hydro- or pyrometallurgical processes, while the nickel laterites are best suited to hydrometallurgical processing. However, if hydrometallurgy is used, once the ore or concentrate is leached the resultant solutions are then amenable to similar separation technologies for purification and recovery of high purity nickel and cobalt products. Solvent extraction, together with other separation processes such as precipitation, can produce high purity solutions of nickel and cobalt. The final products of these solutions may be nickel and cobalt cathodes, metal powders precipitates or salts, depending on the final process of electrowinning, hydrogen reduction, precipitation, or crystallisation Respectively.

Jan 1, 1996

By A Tomsett, R Kidd, Z Casley

Bivariate recoverable resource estimation aims at predicting the recovered metal for a secondary variable when a cut-off is applied to a primary variable. The choice of a consistent geostatistical model is advisable to allow a robust estimation from exploration data of the primary and secondary metal recovery functions on a generic selection block (selective mining unit û SMU) within large panels. Ore processing decisions at Lihir Gold LimitedÆs Lihir Gold Mine are based on the gold and sulfur estimates of SMUs from production (grade control) data. The predictive model from exploration data at Lihir is based on the estimation of a recoverable resource for gold by Uniform Conditioning (UC), with an estimate of the sulfur grade being provided by Ordinary Kriging of panels. While univariate UC is adapted to the diffusive nature of the gold mineralisation (Ladolam orebody) at Lihir, the independent estimation of sulfur, through ordinary kriging, fails to capture the potential spatial correlation that exists between gold and sulfur mineralisation. This paper presents a practical implementation of bivariate UC, which better represents in the resource model the spatial correlation between gold and sulfur. Incremental economic gains through improved definition of material categories and scheduling are investigated, and the particular impact on the process of geological interpretation and domaining is emphasised.

Jan 1, 2009

By Fraser C. J

The township of Yalloum was established in 1921 to provide accommodation for the work force on the sites of the power station and open cut which were to become the basis of Victoria's electricity industry.A company town, Yallourn flourished, and in its heyday in the 1950s the township had a population in excess of 5500 residents.However the town was sited over a valuable coal field. In the 1960s, studies conducted by the State Electricity Commission indicated that excavation of this coal as a continuing development of Yalloum Open Cut was the optimum choice to meet the growing energy needs of Victoria. Operation in what became known as the Township Field commenced in 1979 and the completion of the overburden stripping was successfully achieved on target in 1991.

Jan 1, 1992

By Fuller P. G

The purpose and current practice of cable trusses in underground coal mines is briefly outlined and details of various cable truss designs are presented. The main part of the paper describes the in-situ performance of cable trusses installed as secondary supports in gateroads and recovery roads of longwall coalfaces. The performance analysis is based on the results of in-situ monitoring carried out at a number of sites at two underground coal mines within Australia. Truss performance has been assessed as load developed in relation to roof convergence, face position and time. Additionally, the influence of strata conditions, installation pattern/density, roadway layout and geometry have been taken into account. An analytical model has been developed to predict truss loads. The principal variables are listed and the basis of the model is described. Based upon behaviour observed in the field the model has been progressively upgraded and validated against measured performance. Guidelines on truss performance and factors which influence it are presented and the implications of these to the use of cable trusses is discussed. Possible methods for improving truss performance in certain strata conditions are outlined and some comments are made on the value of cable trussing compared to cable bolting in these Situations.

Jan 1, 1992

A brief descri;tioki is given of nuclear power reactors and their fuels. These fuels are made from a variety of uranium compounds such as uranium dioxide, and uranium carbide as well as uranium metal and its alloys. The various processes used to produce some of these compounds from yellow cake are outlined. Using the natural uranium, heavy water reactor by way of illustration, fabrication of fuel elements is dis- cussed and the characteristics of U02 powder required for this partic- ular fabrication are indicated. The flowsheets and equipment presently in use overseas for production of this type of U02 powder are described. Possible areas where improvements might be made to this conventional process are enumerated and some details are then given of the programme of work which has commenced at the A.A.E.C. Research Establishment to gain experience in the general field of nuclear grade UO20

Jan 1, 1968

By D J. Fray

In this work, a fused salt electrochemical process was investigated experimentally for production of metals and alloys directly from respective solid oxides by electro-deoxidation. Direct electrochemical reduction of the oxides was carried out in molten CaCl2-based chlorides in an electrolytic cell, incorporating an oxygen-evolving inert anode, over the temperature range of 850 - 950¦C. The technical viability of the process was demonstrated by the electro-deoxidation of pure oxides and oxide mixtures including NiO, Nb2O5, Nb2O5/TiO2 and Nb2O5/SnO2 to produce nickel metal, niobium metal, NbTi alloys and the intermetallic compound, Nb3Sn. Compared to the conventional metallurgical processes for producing these metals and alloys, this new electrochemical process appears to be much less energy intensive, with lower costs and no direct greenhouse gas emissions from the electrolytic reduction process. The present electrolytic reduction process has the potential to be scaled up for the green extraction of a number of non-ferrous base metals and processing of many advanced alloys.

Jan 1, 2006

The application of modern sciences prior to nineteenseventies have resulted in the placing of Continental Drift theory into broader concept of Plate Tectonics. The concept is applied to explain the Cenozoic Tectonics of North Sumatera.Oceanic crust flooring the Indian Ocean is moving northeasterly and being obliquely subducted at a Benioff zone along the western margin of Asian Plate, marked by the Sunda Trench in the west coast of Sumatera. This phenomenon was generated since late Mesozoic, continued during Cenozoic era up to present day, resulted an exellent example of arc-trench system which can be traced along SW - NE transect of North Sumatera.The oblique-subducting plate of Indian Ocean beneath Asian Plate, together with spreading of Andaman seafloor beginning in Pliocen epoch, have led to the origin of Sumateran Fault System; the System extends throughout the length of Sumatera island. In the region under review it comprises almost contiguous set of broadly SE-trending. Evidences for transcurent-dextral displacement have been observed.

Jan 1, 1990

By Jones BH

Discovery of the Vera-Nancy deposit in late-1995 followed 12 years of active exploration in and around the Pajingo Epithermal System, an andesite hosted veinfield covering an area of 150 square kilometres at the northern end of the Devono-Carboniferous Drummond Basin in North Queensland. Early exploration targeted open-pittable resources in the numerous auriferous veins and it was not until 1994 that exploration focus shifted to drilling to depths below about 100 metres from surface, which resulted in the Vera-Nancy discovery. That deeper drilling process is still at a very early stage of coverage of the epithermal system as a whole and substantial potential exists for additional discoveries.Drill-out of Vera-Nancy has to-date established a gold resource in excess of 1.4 million ounces. Mine development is proceeding via a twin decline system with first stoped production scheduled for August 1997.

Jan 1, 1997

By Schmincke H-U

The Pleistocene basanite-tephrite Rothenberg cone complex was built by an alter- nation of strombolian and phreatomagmatic phases of explosive eruption. Two main centres, on a one km long NNE-trending fissure, were active during its construction. The strombolian deposits from three discrete facies corresponding to the crater-fill and inner wall and outer wall environments on the cone. The outer wall facies consists of an alternation of 1. 'normal' coarse-grained, relatively well- sorted lapilli and bomb beds, and 2. finer-grained poorly-sorted lapilli beds. Evidence suggests that the former was pro- duced by open-vent lava fountaining, with balanced magma supply and discharge rates, and the latter are the products of eruptions during partial blockage of the vent, by collapse of wall-rock, and formation of a degassed crust on the magma. The resulting explosions there- fore ejected a mixture of fresh actively ves- iculating magma, older partially degassed lava and material recycled from the wall of the cones. The phreatomagmatic deposits are an alternation of moderately-sorted fall beds and thinner ash-rich pyroclastic surge and rain-flushed units. The clast populations are much more diverse than strombolian ones, including abundant wall rock fragments from 0-100 m depth. The juvenile (magmatic) particles range from highly vesicular scoria to dense 'bread-crusted' clasts, and contain abundant small wall rock inclusions. The phreatomagmatic phases are products of explosive interaction of small batches of magma with shallow groundwater. Vesiculation of this magma played a small but significant role throughout the fragmentation.

Jan 1, 1987