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By S. Joshi, E. Asselin

An electrochemical quartz crystal microbalance (EQCM) was used to study the leaching of pure gold in deaerated 1 M Na2S solution. Multiple cyclic voltammograms were measured between -0.76 and 1.242 V (SHE) at 20 mV/sec and 2 mV/sec and the frequency shift of the quartz crystal was simultaneously measured. Both the forward and reverse scans showed oxidation occurred between -0.40 to 0.20V. The frequency shift increased during both the forward and reverse scans in the potential range of -0.40 to -0.06 V indicating electrode mass decreased. Since at -0.40 to 0.20 V oxidation peaks were also observed, part of the oxidation was due to oxidation of gold. Eh-pH diagrams were constructed and showed soluble Au(I)-S(IV) species formed between -0.30 and 0.10 V (SHE). Atomic absorption spectroscopy of the test solutions and the mass change recorded by EQCM both showed about 0.015 mg of gold leached. Since the majority of the frequency shift increase corresponding to gold oxidation occurred at -0.40 to -0.06 V during multiple cyclic voltammogram measurement, the total leaching of gold could be approximated to occur at this potential interval to give a leaching rate of ca. 6.4x10-5 mg/s-cm2.

Jan 1, 2011

By N. W. Xu, M. D. Wei, F. Dai, B. Li

"Chevron notched samples achieve general acceptance for measuring the Mode-I (opening mode) fracture toughness of rocks. The cracked chevron notched semi-circular bending (CCNSCB) sample, which is developed from the International Society of Rock Mechanics suggested the cracked chevron notched Brazilian disc method, has recently received much attention. However, these chevron notched methods have not been fully mastered, some ideal assumptions based by their theories and formulas, such as the straight-through crack assumption (STCA), have not been verified detailedly. Fractures of CCNSCB specimens were numerically simulated considering different heterogeneities, geometrical and mechanical parameters. The results show that, the real fractures of CCNSCB specimens are never satisfied with the STCA. In fact, micro fractures not only occur in the notch tip but also the two chevron edges. Consequently, the crack front features prominently in a shape of parabolic curve, far from being straightthrough. Moreover, curvature of the crack front is only affected by shape of the chevron ligament. Cracks usually start from two sides of the notch tips rather than center of the notch width, and propagate deviating from the postulated fracture routes. These fracture mechanisms induce errors with the measurements, and thus more attentions should be paid to the real fractures of the chevron notched samples for measuring fracture toughness more accurately. INTRODUCTIONWith the increasing requirement of people for resources and energies, frequent rock engineering activities have been conducting, such as underground excavation, oil exploration and deep burial of nuclear waste. Many problems appear in rock fracture. Consequently, there are more and more attentions paid in rock fracture mechanics due to its broad application prospects for solving these engineering problems. Since Mode-I (opening mode) fracture is the most common failure mode in rocks, Mode-I fracture toughness is a primary parameter to predict rock mechanical properties in actual engineering, and thus its accurate values are necessary to the researches of rockburst, rock mass slope stability, rock cutting, hydraulic fracturing, tunneling, et al. Therefore, it is thus significant to evaluate and study relevant methods to obtain the reliable value."

Jan 1, 2015

"The outlook for Eastern Canada is decreasing coal production over the next few years; however, a reappraisal of the long-term requirements and increased prices of coal could lead to a revitalizing of the industry. The market for Western coal is expanding and is expected to exceed 50 million tons per year in the metallurgical and thermal power fields. Western coal reserves are currently estimated at 119 billion tons. Technical developments in Eastern Canada include a shearer and gate-end support system to mechanically cut the stall and brushing at the tail-end of a longwall. In Western Canada, the most modern equipment is used in mining, beneficiating and shipping coal. Results to date on the underground hydraulic experiments exceed expectations. The importance of reclamation is recognized and plans have been made to restore and re-vegetate disturbed areas and mine dumps. In Eastern Canada, experiments were started to determine the feasibility of coal reclamation from mine dumps, including one dump that is on fire. The Mining Research Centre, Mines Branch, continued to conduct research work oriented toward solving Canadian mining problems The Western office of the Centre, opened in 1970, was set up primarily to study problems associated with a resurgent coal industry."

Jan 1, 1971

By J. Peck, F. Brackebusch, M. Scobie

"A number of alternative strategies exist to improve narrow orebody stope productivity and safety through mechanization. Particular attention is given to one of these: the development of an in-stope mining machine. This paper summarizes those characteristics of vein orebodies in Canadian mines which are considered to govern such mining machine design. It then reviews past and current attempts to develop hardrock mining machines which could potentially be applicable to narrow stope widths.IntroductionSerious interest is mounting to exploit new technology in the development of methods and machinery to stope narrow, hardrock, orebodies. The motives relate not only to the foreseen need to maintain or reduce production costs, but also to considerations of manpower availability, safety, ground control, ore recovery and dilution. This also follows the demonstrated success of technology application in larger metal orebody stoping, where machine development has been seen to lead to improved productivity as well as the future prospects of continuous mining systems and eventual automation, e.g. ITH blasthole drill development and bulk mining. This paper deals in particular with machine design for ore fragmentation in narrow, hardrock orebodies. It is considered that such machine design closely interacts with the over-all stoping method design and that both require consideration in parallel to ensure success in mechanization."

Jan 1, 1990

By Fathi Habashi, Michel Pagé, Farouk T. Awadalla

"Chrysotile asbestos can be dyed with certain dyestuffs to form stable coloured products whose hemolytic and cytotoxicity are greatly reduced. Examples of these dyes are Thiazol Yellow G (a monazo dye) and Trypan Blue (a diazo dye). Other dye stuffs, for example, basic dyes with triphenyl methane structure, Brilliant Yellow (a diazo dye), and Methylene Blue (a thiazine dye) colour asbestos but do not reduce its toxicity. Similarly alizarin, 8-hydroxyquinoline, and representative members of the phthalein group Bromocresol Purple and Phenolphthalein.IntroductionThere is, at present, a controversy regarding the dangers of asbestos fibres, and attempts are being made to render it less toxic. One of these attempts consisted of treating chrysotile asbestos with gaseous phosphorus oxychloride, POCI], at ambient temperature and in absence of moisture. The product had to be heated at 300°C to 500°C to expel exess entrained reagent to get a material containing 0.5070 to 5% phosphate groups and known as Chrysophosphate (Lalancette and Dunnigan, 1982). This product showed decreased toxicity as measured by its hemolytic effect on red blood cells (fable 1). In another approach, Flowers (1983) showed that when chrysotile asbestos was thoroughly mixed with a solution of ferric ammonium sulphate and the slurry was then filtered and dried, the product showed a marked decrease in cytotoxicity.In the present investigation the problem of toxicity was considered from a different point-of-view. Chrysotile asbestos is a hydrated magnesium silicate that can be represented by the structural model shown in Figure 1 from which it can be seen that magnesium hydroxide groups, Mg(OH)2, form a part of the silicate structure. Certain organic reagents that are known to react with magnesium ion in solution to form chelates were reacted with asbestos to find out whether a chelate was also formed on the fibres, and if so , what will be the hemolytic action and cytotoxicity of the product."

Jan 1, 1991

A mathematical model of a decision is represented by the table in Figure 4. The numbers in the matrix are a measure of the effectiveness of each alternate for an objective. In this case, it is the per cent of desired profit that is satisfied by each alternate for each objective. By adding all of the values in a row, we have a measure of which alternative is best for both objectives. However, if you think that alternate 1 is necessarily better than alternate 2, you are wrong. Why? Because the weight of the objectives may not be equal. It could just be that this plant can sell more than it can produce, so that the loss in profit represented by increased sales is more than twice as important as reductions in costs. (See Figure 5). In that case, let us weigh objective 1 as 30 per cent and objective 2 as 70 per cent. It must also be obvious that the sum of all the "objective weights" must equal 100 per cent. Now, by evaluating our alternates according to their weights. we find that alternate 2 is better than alternate

Jan 1, 1964

By G. C. Lipsyy

ALL mineral production? of Can11.da is transported in a mine car at some stage during its extraction. There are as many types and varieties of mine cars as there are of mines. Many of the cars in use were developed in the blacksmith shop. Others were designed by engineers and improved by the mine foremen and the mechanics. Every mine car has the ideas of miner, blacksmith, mechanic, and engineer incorporated in it. Many of these ideas are not generally known. This paper was written to make at least some of this information available to the mining industry. In drawings, tables, and notes, it gives all the important details pertaining to the cars. It .does not recommend any particular type of car for any particular piece of work, nor does it present drawings from which a car can be built. It gives the engineer or master mechanic information on many cars which he can apply to his own particular problems. It is hoped that this information will be of use to mine operators. If a few new ideas are conceived as a result of the paper, the author will feel that the effort of compiling it has been worth while. In order to obtain the data for the preparation of the paper, a questionnaire, copy of which is here reproduced, was sent to all the operating mining companies in Canada. An accompanying letter briefly explained the purpose of the paper and asked for co-operation in furnishing as complete information as possible.

Jan 1, 1945

By Claudia Gasparrini

"Factors affecting the extraction of gold are of a mineralogical nature. Knowledge of the mineralogy of the ore or metallurgical product to be treated, if appropriately combined with the metallurgical test work, may improve gold recoveries. .This paper outlines the mineralogical techniques f or the study of gold ores and metallurgical products and describes the gold mineralogy in relation to its metallurgy. An effective plan for studying refractory and other difficult ores, combining metallurgical test work, chemical analysis and mineralogy and capable of giving positive results over relatively short periods of time, is suggested.IntroductionFactors affecting gold recoveries are of a mineralogical nature and include (i) the gold-bearing minerals, (ii) their grain size and, particularly where the grain size is very fine (10 microns in diameter and less), (iii) their host minerals and (iv) the association these form with the gold-bearing minerals.Mineralogical studies of gold ores and metallurgical products containing gold in economic amounts (today down to 1/10 of one ounce per tonne or 2.84 ppm) are difficult and time consuming. Mostly because of such reason, metallurgical testing (test work) is usually done simply by trial and error without understanding the causes for failure or success.Mineralogical studies, if appropriately conducted and combined with the test work, provide an efficient mean s of improving recoveries through the understanding of gold losses derived from the use of the wrong technique for separation. The information they provide is therefore the first step in the development of recovery techniques, for those ores where the test work alone failed to produce positive results."

Jan 1, 1983

By J. A. Folinsbee, Andre Robitaille, Tony Y. Chong

"Conventional crushing and grinding is followed by gravity concentration to recover free milling gold. Refractory gold, finely disseminated within the pyrite and arsenopyrite matrix, is recovered by flotation followed by pressure oxidation, cyanidation, and cementation. Non-refractory gold is recovered by cyanidation/CIP processing.A comprehensive test program aimed at improving flotation recovery was initiated in June 1995. Plant testing indicated that flotation tails value could be significantly reduced using mechanical flotation cells. Based on these test results, a flotation circuit that incorporates one of the three existing flotation columns followed by mechanical scavenging and cleaning was developed. Detailed engineering was completed in September 1996. Construction started in February 1997 and was completed in 3 months at a cost of $3.2 million. An on-stream X-ray analyzer was installed to provide real-time arsenic and iron analyses and inferred sulphur value on some of the flotation streams.The new flotation circuit proved to be an instant success. Flotation tails values were reduced by 27%. Final tails solids and solution was reduced from 0.035 to 0 023, and 0.0014 to 0.0006 oz/ton Au, respectively. Based on a mill throughput of 1,620 stpd this decrease in tails value will result in an increased gold production of 7,500 ounces per year. The payback for the project is estimated to be around one year.This paper describes the evolution of the project from bench scale testing to commissioning. Also, the operational and economic impacts on down stream processing are highlighted"

Jan 1, 1998

By Louise Corriveau, Bronwyn Azar, Valerie A. Jackson, Luke Ootes, Jeff Harris

We use the results of new bedrock mapping, combined with geochemical point data and airborne radiometric data (in particular equivalent uranium concentrations) to help determine which geological units in the Paleoproterozoic Great Bear magmatic zone (GBmz) contain elevated uranium. The data collectively indicate that the highest primary uranium concentrations are in equigranular granites and subvolcanic/volcanic porphyries. Notably, these rocks host the majority of known uranium-bearing deposits and/or prospects in the GBmz. We speculate that the uranium in these deposits/prospects was derived from nearby, uranium-enriched rocks and was mobilized by much younger, circulating hydrothermal fluids. Sedimentary rocks of the Thelon and Dismal Lakes groups unconformably overlie the GBmz and are known to host unconformity-type and sandstone-hosted uranium prospects. Most likely, the uraniumenriched rocks of the GBmz acted as a uranium donor to these overlying sedimentary basins. The method of investigation employed in this study may be applicable to other ‘granitic’ terrains in order to identify regions with favourable rocks for uranium exploration.

Jan 1, 2013

By B. Qiu

The large surface ground movements induced by underground mining could threaten the safety of the pipelines laid across the subsidence-prone area. Existing analytical methods for the stress analysis of buried pipeline over mine subsidence area were based on the assumption of ?thin? pipeline, which limited their applicability. This paper presents the improved model with the capability to determine the stress distribution of the ?thick? pipeline. The pipe-soil interaction in this model was also updated to adapt various pipe soil contact conditions. In addition, the time-dependent effects of dynamic subsidence effects were also added to the model. A case of protecting a long section of a buried large-diameter pipeline over two longwall panels in a shallow mine is shown. The stress distribution along the pipeline is determined and the overstressed sections are identified. A partial uncovering plan was developed based on the predicted stress and complicated terrain at the site.

Aug 1, 2013

By J. W. Bawden, J. Nantel

"The mine operator has two prime objectives when he operates a mine: (l) the mine must be safe, and (2) the mine must operate with the lowest possible costs. The operator constantly faces a dilemma; if he is over cautious with regard to safety, his costs may be very high, and if he is over-zealous in trying to reduce costs, the safety of his operation may be jeopardized.Modern bulk mining methods rely heavily on high productivity non-entry stoping techniques (e.g. open stoping, VCR, etc.). Such techniques have the advantage of removing the operator from the active and sometimes dangerous mining face and ofminimizing costly development. On the other hand, this generally results in a certain loss of flexibility in following irregular ore-waste contacts. If stopes are opened too large and/or are inadequately supported, severe dilution with resulting escalating costs usually results. If initial access drift support is inadequate for latter mine induced stresses high rehabilitation costs may also be incurred.Optimization of stope dimensions should logically occur as part of a general mine rock engineering program, within the over-all mine planning context. The same program should help highlight those areas where drift rehabilitation may be a problem.Whenever successful mining is performed, rock engineering is being applied, either by design or by chance. The cost implications of planned practical rock engineering as an integral part of mine planning and design can be very significant to the ultimate mining ""bottom line"". At Noranda Minerals Inc. allowable stope dimensions are derived using a combination of numerical stress analysis and empirical design techniques. This paper discusses the use of the above techniques and their limitations as tools for rock mechanics based stope dimension optimization. The potential cost implications of such design efforts within the general mine planning context are also addressed."

Jan 1, 1989

The comminution circuit at Tarkwa Gold Mine was commissioned as a Single Stage SAG mill operated in closed circuit with hydrocyclones designed to process 4Mtpa. The circuit was later expanded by adding a secondary ball mill in closed circuit with hydrocyclones with a view to treat 12Mtpa. The change in the circuit configuration and assigning the low aspect ratio SAG mill for primary grinding application makes the Tarkwa experience unique in terms the optimisation strategy and operating philosophy. This paper reports the findings from a series of surveys performed on this plant. The surveys reported include data obtained when the SAG mill was operated as a single stage mill in closed circuit with hydrocyclones and also SABC mode under two different feed conditions. The differences in operating philosophy between the initial single stage SAG circuit and the current SAG/Ball mill circuit are discussed.

Jan 1, 2012

By J. B. Mawdsley

Introduction The writer was instructed to visit the Chibougamau region during the field season of 1927 and report on the mineral discoveries that had been made there since 1911. lt was deemed advisable to obtain detailed information regarding the rocks underlying the area in the vicinity of these recent discoveries. Accordingly an area 60 square miles in extent was mapped. The outcrops were studied along the water courses and along bush traverses spaced at half-mile intervals between these water courses. The completion of the rest of the summer's programme allowed only three weeks for this work. lt is from this small, mapped area, and this necessarily cursory survey, that the material for this paper was obtained. Location And Means Of Access The name Chibougamau district is applied loosely to an ill-defined area of about 1,000 square miles lying mostly north and west of Chibougamau lake in the Province of Quebec. The lake is approximately half way between lake St. John and James bay. It lies 150 miles north of the Canadian National railway and 40 miles south of Mistassini?lake.

Jan 1, 1928

By Alan Reed

"Afton Mines Ltd. (N.P.L.) operates an 8500-tpd open-pit copper-gold mine near Kamloops, R.C. The pit is currently 480 feet deep and will reach an ultimate depth of 800 feet. The east, south and west walls of the pit are composed of Triassic andesites (Nicola Volcanic Formation) and contemporaneous sub-volcanic intrusions of micro-syenite, microdiorite, diorite and picrite-basalt (Iron Mask Pluton). The north wall of the pit consists of Tertiary sandstones, shales and mudstones (Tranquille formation) and dacitic dykes, sills, flows and tuff s (Kamloops Volcanic Formation).The Afton copper-gold orebody (30 million tons of open-pit ore with a grade of 1.0 per cent copper, 0.016 oz/ton gold and 0.12 oz/ton silver) occurs within the Triassic Iron Mask Pluton adjacent to its faulted contact with Tertiary rocks. The Triassic-Tertiary contact is a complex fault system dipping 65 degrees southward and causing the Triassic rocks to overlie the Tertiary rocks. The detailed trace of this contact is very intricate due to the mutual interference of three principal fault systems.The dominant geological structures in both Triassic and Tertiary rocks are faults striking WNW and dipping 65 degrees southward, i.e. sub-parallel to the orebody (strike faults). Cross faults and oblique faults are abundant and highly significant in some sectors of the pit. The Tertiary sedimentary rocks show an early series of northwesterly plunging folds deformed by a later series of northeasterly striking folds. Major lithological and structural boundaries divide the pit into 8 structural domain s within which the pitwall slope stability is controlled by the local geological structures and lithology.Assay data from production blasthole samples and exploration diamond drillhole samples show a log-normal frequency distribution, with a fairly low relative variance. Variograms computed from production blasthole samples show good continuity with elliptical horizontal zones of influence which are truncated by the major faults that bound the ore zone."

Jan 1, 1983

By G. F. Raymond, W. P. Armstrong

"At the time of this study, the Valley mine was producing 23 000 tonnes of ore per day from a large, low-grade porphyry copper orebody. Sulphide mineralization, principally bornite and chalcopyrite, occurs in a stock work of quartz veins in one phase of the Guichon Creek batholith. The property was explored from 1967 to 1982, and was placed in production in 1983.Using a three-parameter lognormal approximation developed by G.F. Raymond at Similkam een and Mount Isa Mines, a geo- statistical conditional probability ore reserve was estimated prior to mining. Comparisons with blasthole kriging and milled ore for the first 17 months of production showed close agreements at all cut-offs between conditional probability estimates and mineable ore. This was not true of either kriging or polygon estimates. An important part of this work was identifying and correcting for bias in both exploration and blasthole samples.IntroductionCominco's Valley lake deposit is a large, low-grade, porphyry copper orebody in the Highland Valley of British Columbia. Total indicated plus inferred ore reserves are 700 M tonnes at ore grade of 0.47070 Cu. At the time of writing, ore milling is at a rate of 23 000 tI d through the old Bethlehem mill. Mining is in 10m horizontal benches using 9.8 m3 shovels and 90 tonne trucks. Since this paper was written, Valley and nearby Lomex have been combined into Highland Valley Copper with a combined oreproduction of about 120 000 tI d.Copper mineralization, principally bornite and chalcopyrite, is regularly distributed throughout the deposit as disseminated low-grade within a granodiorite host rock, and as higher grade veinlets within a stock work of near-vertical quartz veins generally 10 cm or less in width. It is likely that problems with sample variability and sample bias are mainly related to mineralization within quartz veining. Valley geology has been described in detail by Allen and Richardson and by Osatenko and Jones (2). The exploration sampling program and identification of diamond-drill sample bias have been discussed by Armstrong and Newman'»."

Jan 1, 1988

By G. H. Gale, M. A. F. Fedikow, L. B. Dabek

Abstract-Rare earth element (REE) data are reported for ores, sulfide-bearing rocks and host rocks from massive sulfide deposits and barren sulfide facies iron formations in Proterozoic volcanic rocks of the Flin Flon-Snow Lake area, Manitoba. Some of the rare earth elements (e.g., Eu), are selectively leached in zones of intense alteration and redeposited together with the sulfides and silicates in the uppermost parts of the alteration zones and at the rock-water interface. Chondrite normalized REE profiles of layered sulfide ores and exhalites proximal to the deposits typically have positive europium anomalies and are enriched in light REE. In contrast, barren sulfide facies iron formations exhibit negative or ‘normal’ Eu profiles. REE data are useful to explorationists in determining the presence of ‘off-hole’ metal-bearing sulfide zones, in distinguishing metal-poor sulfidic layers related to ‘economic’ hydrothermal activity from barren sulfide facies iron formation and in some instances as a means of establishing ‘ore-equivalent’ strata.

Jan 1, 1997

By G. W. Adams

Foreword While the literature on radium is voluminous, there is no single publication available from Canadian sources which attempts to cover at all fully the world radium industry. The comparatively recent developments in the Wilberforce area, and the consequent arousal of public interest in radium, seemed to call for the publication of such a paper which would be intelligible to the layman. To satisfy this apparent need, the writers submit this paper which contains material derived from various sources, and for which the writers make no claim of originality. Direct references are made throughout the paper to sources of information.

Jan 1, 1931

By D. C. Carter

"The Nova Scotia Department of Mines and Energy located a drillhole at Riverside Corner, Hants County, Nova Scotia, to examine the stratigraphy, structure and potash potential of the Kennetcook River gravity low. This evaporite-related gravity anomaly is one of the largest virtually unexplored gravity anomalies in Nova Scotia. The drillhole intersected a structurally complex sequence o flower Windsor Group ('B' Subzone) evaporites. Downhole geophysical wireline logs were used, in conjunction with detailed lithological descriptions, to interpret the structure and stratigraphy of the sequence. Similar application of total gamma ray, density, caliper and neutron-neutron log responses allows stratigraphic correlation of Windsor Group carbonate marker units separated by up to 35 km in Cape Breton. This work confirms the value of downhole geophysical logs as a tool in the exploration of evaporite deposits regardless of the presence or absence of high quality core. INTRODUCTIONThe exploration methodology for evaporite (specifically salt/potash) deposits in eastern Canada (and worldwide) is relatively simple: identify a negative gravity anomaly within a favourable geological setting, Windsor/Cordroy Group sediments in eastern Canada, and drill it (Anderle, 1980). Although this is an obvious oversimplification of the necessary expertise in the planning and complet ion of an exploration program, those familiar with potash exploration drilling can attest to the risks and expense, in terms of time and problems , associated with the location and drilling of diamond-drill wildcat holes. Potash exploration programs in eastern Canada, their results and inherent difficulties, have been documented by Anderle et al. (1979), Cooper (1981), Dekker (1982), Carter and Boehner (1986), Carter (1988) and Carter and Anderle (in prep .).Downhole geophysical wireline logs have become an important tool in the stratigraphic and structural interpretation of evaporite sequences in eastern Canada and, in many cases, represent the only information recovered or the only information available due to the drilling method (rotary) and/or the long term instability of evaporite cores. This paper documents examples of downhole geophysical log responses which, combined with detailed lithological examination of drill core, or in the absence of core, are used in the interpretation of the complex lithology and structure of a deformed evaporite deposit. Geological and geophysical data from the Nova Scotia Department of Mines and Energy (NSDME) Riverside Corner 85-1 drillhole are presented here as a partial case history and prime example of the use of this method to interpret the complex structure of an evaporite deposit. Drilling of NSDME Riverside Comer 85-1 was conducted in late 1985and early 1986by the Department (Carter and Boehner, 1986) under a program to assess the potash potential of selected areas of the province as part of the Canada-Nova Scotia Mineral Development Agreement 1985-89. A reinterpretation of a portion of the available data from two exploration drilling projects on Cape Breton Island in the Canso-Bras d'Or area is also presented (see inset, Fig. I). Several drillholes have intersected the Windsor Group evaporite sequence in these areas and the available geophysical logs are a valuable tool in the interpretation of the structure of the deposits. However, no attempt has been made to present or discuss the detailed geological investigation and comparison of these two deposits. They are presented here as an example of the reinterpretation of existing data and their application to stratigraphic correlation and structural interpretation of complex evaporite deposits. Further work is necessary to document the stratigraphic and structural correlation of these two areas."

Jan 1, 1989

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013