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By Ma Yuxin, Niu Fusheng, Yuan Zhitao, Bai Limei, Han Yuexin

"Using batch flotation experiment, contact angle measurement, particle size analysis, and scanning electron microscope (SEM), the influence and difference of pH value on the flotation rate of talc and chalcopyrite were investigate without collector at the pH range of 3~11. The results showed that, the flotation rate of talc decrease with the increasing of flotation time, while that of chalcopyrite hardly affect by flotation time, besides, the flotation rate of chalcopyrite is much less than that of talc, so the laws of flotation rate of the two minerals are independent of pH value. The flotation test data of two minerals are simulated with first order and multi-rate flotation kinetic model respectively. The simulation results showed that flotation of talc only meet the first order kinetic model, while chalcopyrite’s meet the both. In addition, According to test results of talc and chalcopyrite by the particle size distribution, SEM photographs and the contact angle measurement, the reason why talc did not conform to the first order kinetic model is not because of particle size distribution, but of particle shape. That is to say, because of sheet structure of talc, the contact angle of layers and sections are 74°and 52°respectively. At the same time, the contact angle of layers and sections are different between the particles. So flotation rates between talc particles are difference.INTRODUCTIONPossessing superior self-induced, collector-induced and sulfur-induced floatability, chalcopyrite exhibits good floatability at a wide range of pH values and potentials. Serpentine are regarded as the most difficult selected type in various chalcopyrite ore, and the predominant reason is that it contains talc. Talc, as a nonpolar layered silicate mineral, is one kind of common associated mineral in sulfide ores (Lu, 2010). Concentrate quality and flotation process of chalcopyrite are influenced as a result from the presence of talc. It is because that talc has inherent floatability which makes it readily mixed with the floated mineral and talc is easy to slime causing the slime coating of the valuable mineral (Beattie et al., 2006). Thus in order to improve the flotation effect of chalcopyrite, methods can be introduced from two respects. One method is that fast-floating talc mineral is floated preferentially, and the other is that sulfide mineral is floated prior to talc by depressing the flotation of talc mineral (Beattie et al., 2006), nevertheless, no matter with which the flotation effect of fine-sized chalcopyrite is not positive. Therefore, in order to realize the flotation separation of talc and chalcopyrite, the difference between the inherent floatability of fine-sized chalcopyrite and talc is researched and analyzed in terms of flotation dynamics in the absence of collector and frother."

Jan 1, 2016

By F. Chevarin

The reaction of O2 with the carbon anode is considered as the main parasitic chemical reaction affecting Hall-Heroult process anodes. The current study aims at investigating the influence of the microstructure of baked anode on its overconsumption. Samples were removed from different positions of an industrial anode. Density, porosity, Lc and BET specific surface area were measured. The anode reactivity was evaluated based on the weight losses for the samples resulting from the reaction of anode with air at 550°C after 7h. The essential parameters determined to control the air reactivity are closed porosity, Lc and pores with a pore entrance radius of 1.5, 8.5 and 12 p.m. The knowledge of effects of these parameters allows better understanding of the reactivity of anodes and consequently reduction of their overconsumption in electrolysis bath.

Jan 1, 2011

The rate of liquid copper deoxidation during top blowing of reducing flames has been investigated using a high capacity thermogravimetric unit at 1200 °C. For 1 kg copper samples, it was observed that the rate of deoxidation was proportional to the flow rate of the reducing reagent (H2 or CO). Under similar experimental conditions, it was found that H2 is more effective than CO even though both have similar thermodynamic potential to deoxidize liquid copper. The rate of deoxidation of liquid copper with reducing 0 2/CH4 flames was measured for 0 2/CH4 molar ratios of 1.5 to 2. The deoxidation rate depends on the 0 2/CH4 ratio and decreases as it approaches the stoichiometric ratio (02/CH4 = 2). Estimation of the rate of deoxidation of liquid copper with top blowing flames based on the thermodynamic composition ofH2 and CO in the product gases, agrees well with measured values.

Jan 1, 2007

By W. A. Bain

"AbstractProduction from the Excelsior Reservoir has amounted to approximately one million barrels. This production has caused a 'Pressure •drop of 10 p.s.i. from the original pressure of 1,245 p.s.i.g. Volumetric balance calculations indicate that the pool as being produced by a water drive whose strength is •probably unsurpassed in Western Canada. It has also been shown by 'unsteady state' calculations that the reservoir will still be above the saturation pressure of 915 p.s.i.g. at the time of depletion. The average permeability of the producing formation is approximately 1,000 millidarcys and, consequently, well draw-downs are very low. The field is essentially a bottom-water drive and calculations have shown that gravity drainage will greatly assist the recovery of oil. Water flooding data on several cores •have placed the flushing efficiency at •approximately 50 per cent, which indicates a recoverable oil-in-place of 17.7 million stock tank barrels. Calculations and field data indicate that the MER for the early life of this field is probably as high as 8,000 to 10,000 stock tank barrels per day.IntroductionTHE EXCELSIOR NISKU oil reservoir is located about twenty miles northeast of Edmonton. The field was discovered in November, 1949, by Imperial Excelsior N.o.1 well, in Lsd. 13, Sec. 3, Twp. 56, R. 22, W. 4, at a depth of 3,850 feet.Since discovery, development has continued on a 40~acre spacing pattern. At the end of 1951, drilling over approximately 80 per cent of the estimated productive area of 1,680 acres had established 32 we1ls capable •of production. The field •has been fairly well delineated by dry holes on all but the eastern flank ."

Jan 1, 1952

By Guoxiang Chi

This paper consists of two parts: the first part describes the principles and functionality of the BsnMod program, and the second part presents preliminary application of this program to paleo-fluid flow modeling in the Anticosti Basin. The BsnMod program simulates fluid flow and heat transfer during the evolution of sedimentary basins through numerical solution (finite difference method) of three partial differential equations, which describe sediment compaction, fluid continuity, and heat conservation. It can be used to estimate the evolution of fluid overpressure, flow rate, and temperature during the basin history. The program was written in C++, works under Windows environments, and has a user interface allowing inputs in dialogues and outputs in both tabular and graphic forms. The program was applied to the Lower Paleozoic Anticosti Basin in eastern Canada. The basin history consists of a passive margin stage and a foreland basin stage. Preliminary simulation results indicate that no significant fluid overpressures were developed in the passive margin stage and during the early period of the foreland basin stage, but strong overpressures were developed within the foreland basin succession during the middle and late periods of the foreland basin stage. Fluid flow rates were generally slow, and thermal profiles were not significantly disturbed by fluid movement throughout the basin history. Potential source rocks of hydrocarbons were found in the foreland basin succession. The strong overpressures in the foreland basin succession could have been a major driving force for hydrocarbon migration from the source rocks to the underlying potential reservoir rocks.

May 1, 2001

By A. K. Alzo?ubi

Block toppling in natural rock slopes has been under investigation since the 1970?s. De Freitas and Watters (1973) introduced the term ?toppling? to describe the movements of rock slopes by rotation in steeply dipping beds. The Lornex pit case history from British Columbia (Canada) was chosen to study the effect of mining on the stability of toppling rock slopes. A discrete element approach that allows fracturing of intact material was applied successfully to model the composite rock slide-rock topple movement. Three main movement modes were observed in the field and the numerical model; the sliding of the top of the slope exposed normal scarps, the toppling at the middle part of the slope exposed obsequent scarps facing opposite to the slope face, and dilation of the rock caused by fracturing at the toe formed loose material. The development of the rupture surface at the toe of the slope was traced and did not evolve into a continuous rupture surface throughout the slope both in the field and the numerical simulation. Good agreement was achieved between the deformations recorded in the field and the numerical simulation.

Jun 1, 2012

By Young Hyun Paik, Hyung Sup Choi, Yeun Sik Kim

The basic studies on the surface properties and flotation characteristics of ilmenite were made by electrophoretic, adsorption, contact-angle and floatability measurements. The isoelectric point of ilmenite is found to be at pH 5.6. By combining the results of electrokinetic studies and adsorption measurements, a clearer picture of the ilmenite-solution interface was observed. These findings were correlated with the floatability of ilmenite obtained by Hallimond tube tests. The general flotation characteristics of ilmenite are compared with those obtained for magnetite and rutile. It is indicated that the above three minerals, namely, ilmenite, magnetite and rutile, have very similar surface properties and flotation characteristics. Therefore, it is difficult to make an effective separation of these minerals by flotation. However, it is found that sodium orthophosphate acts as a selective depressant for magnetite in anionic flotation. Therefore, close pH control of the pulp in the presence of the phosphate ion enhances the possibility for a successful separation of these minerals.

Jan 1, 1967

By A. J. DeArdo

Linepipe steels have come a long way in the past forty years. In fact, modern, high strength steels for large diameter linepipe applications represent one of the seminal accomplishments in metallurgy of the past half-century. The synergy of advanced steelmaking, alloy design including microalloying, hot rolling, and interrupted accelerated cooling has led to the marvelous steels being used today. The drive for higher performance pipelines has been motivated by the energy sector of our global economy who wanted both higher throughput capacity, i.e., larger diameters and higher pressures, and lower material cost, i.e., relatively thinner gauge wall thicknesses. These requirements led to new steels with higher strengths, better toughness and improved weldability. The goal of this paper is to trace the evolution of linepipe steels from the X60 grades of the small diameter pipelines of the 1960s to the (X80 - X120) grades used in the large diameter pipelines of today. The metallurgical triumphs permitting this success story, e.g., clean steel practices, controlled rolling, microalloying with Nb, and using IAC to obtain low temperature transformation products, will be highlighted and discussed.

Jan 1, 2005

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By Harold L. Gibson, David H. Watkinson

"Volcanogenic massive sulphide deposits of the Noranda Camp cur throughout the Noranda Shield Volcano but are concentrated and along the margins of the Noranda Cauldron. The deposits are realized along synvolcanic faults that also accommodated subsince and controlled the location of eruptive centres. Deposits within e 3 000 m thick Mine Sequence formed during a period of active volcanism and subsidence coinciding with the onset of two cauldron subsidence cycles. The Noranda Cauldron was a restricted site of 10malously high heat flow and structural permeability that favoured e development of a high-temperature hydrothermal system. Metals may have been derived from leaching of aquifer rocks by convecting a water or directly from a shallow underlying magma chamber, now presented by the Plavrian Pluton, that was at its highest position !thin the crust during cauldron subsidence. The deposits formed rough a combination of sulphide precipitation from exhaled fluid td replacement at and below the seafloor in a manner analogous to ose on the modern seafloor.RESUMESi les dépôts de sulfures massifs volcano gènes du camp minier de ~uyn-Noranda sont présents dans les différentes parties du volcanluclier de Noranda, ils se trouvent concentres toutefois, en plus ·and nombre, sur le pourtour de la caldeira (cauldron) de Noranda. ~s dépôts sont localises le long des failles synvolcaniques qui ont cilite la subsidence et contrôle la position des centres d’éruption.~dépôts situes dans la séquence des mines (3 000 m d’épaisseur) sont formes durant un épisode d' activité volcanique et de subsiden qui coïncide avec l' amorce de deux cycles d' affaissement de la rldera (cauldron) de Noranda. Celle-ci Jut le site exclusif d’unflux : chaleur anormalement élevé et d’une perméabilité d’origine cucturale qui ont favorise le développement d’un système hydrothermal a haute température. Les métaux proviennent soit directement d’une chambre magmatique situee afaible profondeur, so it d’un lessivage des roches de l’aquifère par l’eau de mer circulant par convection. Cette chambre magmatique, représentée maintenant par le pluton de Flavrian, se trouvait à son niveau le plus élevé dans la croute au moment de l’affaissement de la caldeira (cauldron). Les dépôts se sont constitués par un mecanisme combinant remplacement et précipitation de sulfures à partir des fluides exhalatifs, au niveau ou au-dessous du plancher océanique, de la même manière que se forment de nos jours, les dépôts de sulfures massifs au fond des océans."

Jan 1, 1990

By Earl Gebhardt

The planning and design of mining panels in the Potash Corporation of Saskatchewan Inc., Lanigan Division mine Block B involved a number of investigative techniques. The techniques utilized to gain insight into the viability of mining included 2-D and 3-D seismic surveys, longhole drilling, exploration wells, photolineament, magnetic and gravity surveys, and actual room excavation.

Feb 1, 1993

By E. R. Mitchell

When we grow up in an urban environment and choose to become a part of a way of life, it is sometimes difficult to appreciate the cost of this decision in terms of pollution. Explained in this article is our dependence on technology and the amount of pollution that technology produces. Inventories of air pollution on both a personal and a national basis are given so that the reader may judge the magnitude of the problem. In doing so, it is hoped that the reader will understand the need for a responsible attitude toward pollution by everyone and how he can make a personal contribution.

Jan 1, 1971

By J. M. Belland

This paper deals with the geology of the Smallwood mine in relation to its influence on mining and milling operations. Structure within the orebody, and variations in ore grade and material types, will be described and associated with the various drilling, blasting and milling operations. The orientation of planes of weakness, either bedding or jointing planes, and contacts between extremes in material types influence the size of the broken material. Generally speaking, variations in grinding rates and recovery can be associated with stratigraphic sequence and metamorphism.

Jan 1, 1966

By Dennis Z. F. Mraz

"Because rock salt and pot ash formations contain particles capable of elastic deformation, the material has usually been compared with various rheological models containing elastic elements. Extensive laboratory testing of salt and potash samples resulted in various theoretical conclusions based on conditions quite different from those in a deep mine. It is felt that sufficient data have now been collected from underground measurements and observations to demonstrate the inelastic behaviour of salt masses in a deep mine. The conditions in deep salt strata can be defined as near hydrostatic, because the acting pressures are very high compared to the negligible elastic limit of the salt. The pressure field and creep around the single opening is a function of its shape, size and age. The same factors, together with extraction, determine the behaviour of the mining a rea. The application of the correct analytical method in mine design can significantly improve the excavation techniques and predetermine the long-term behaviour of openings."

Jan 1, 1973

By James R. Hunter, Sandra K. Zacharias, Ursula M. Franklin

Archaeometallurgical remains can be a valuable source of information about past technological activities and, by inference, the societies that undertook them. Material traces of former metal-producing or metal-working centres can include raw materials, products, or metallurgical installations such as mines, furnaces or forges. Of these remains, the most common is slag, often left undisturbed since its original production. Physical and chemical analyses of archaeological slag and metal can often reveal the processes and materials involved in their formation. Mineral composition and softening temperature of a slag, for instance, can indicate the conditions of the metallurgical operation, such as temperature and atmosphere and, thus, help identify metallurgical processes which took place at a site(1). The present report illustrates the value of such analysis. Metal-working remains from Sainte-Marie among the Hurons, near Midland, Ontario, on the south side of Georgian Bay have been analyzed in order to determine the techniques and processes used by the 17th-century blacksmith who worked at the mission headquarters from 1642 to 1649. Samples were selected from a very large collection of blacksmith refuse which was excavated from the site by archaeologist Kenneth Kidd in 1941-42(2).

Jan 1, 1999

By K. R. Nichol

The author points out that corrosion works 24 hours a day, every day. It is an economic reality that the cost of corrosion is inevitable and that its cost should be incurred in the least expensive way. An economic evaluation technique to properly assess its relative impact is the Discounted Cash Flow Method. Various remedial and corrosion control measures are available and these, when coupled with a planned corrosion control program, help reduce the cost of corrosion.

Jan 1, 1973

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Abstract-Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last five years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the seafloor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radionuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidaland intertidal sediments. For such work the multi-sensor detector probe is towed on the seafloor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS, enables the production of detailed maps of bathymetry, bottom roughness, and seafloor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with seabed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the seafloor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has significant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last ?ve years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the sea?oor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radio nuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidal and intertidal sediments. For such work the multi-sensor detector probe is towed on the sea?oor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS,enables the production of detailed maps of bathymetry, bottom roughness, and sea?oor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with sea-bed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the sea?oor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has signi?cant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997

By J. W. Choung, T. Fu, Z. A. Zhou

An on-line visualization technique and methodology was developed to investigate the role of fine sphalerite (< 10 um) aggregation in flotation. The images of particle aggregates under different operating conditions were recorded and analyzed. The effect of impeller design on particle aggregation was demonstrated. This difference was not mainly due to the energy input into the system, but due to the resultant hydrodynamic conditions created by the impeller and their effect on particle interactions. The recorded image showed that adding fine silica (- 5 um) did not interfere with fine sphalerite aggregation, thereby showing no effect on the sphalerite recovery. Effect of the enlarged aggregate size on increasing flotation recovery was confirmed. Although Malvern Mastersizer produced consistently lower estimates of aggregate size than those by the image analysis, both methods responded to the changes in operating conditions in the similar trend. It was shown from this study that on-line visualization technique is a powerful tool for studying fine particle aggregation and morphology in the context of diagnosis for the flotation separation.

Jan 1, 2004

By Earl Gebhardt

"The planning and design of mining panels in the Potash Corporation of Saskatchewan Inc., Lanigan Division mine Block B involved a number of investigative techniques. The techniques utilized to gain insight into the viability of mining included2-D and 3-D seismic surveys, longhole drilling, exploration wells, photo lineament, magnetic and gravity surveys, and actual room excavation.IntroductionPotash Corporation of Saskatchewan Inc. (PCS) owns and operates four potash mines in the province of Saskatchewan. The Lanigan Division mine is located 110 Ian east of Saskatoon, Saskatchewan, near the town of Lanigan.The Lanigan Mine commenced production in August 1968under the ownership or Alwinsal Potash of Canada Limited. The mine was purchased by PCS in 1977.Lanigan Division&apos;s productive capacity is 3.4 million tonnes of product per year. Ore is extracted from the "" B"" zone or Layer III or the Patience Lake member of the Prairie Evaporite, more than 1000m below surface . The Patience Lake member (approximately 20 m thick) consists of potash interbedded with salt. The average run-of-mine ore grade is 21070 K20 (Fig. I).The mine was initially developed using the room-and-pillar technique. Improvements in mining resulted in the use or extensible conveyors in long panel rooms."

Jan 1, 1993