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By Bert S. Hall

"The purpose of this paper is to review the evidence at hand concerning the earliest centuries of cast iron in Europe, from roughly 1400 A.D. until the second half of the sixteenth century. For the most part it is concerned with the relationship between two technologies which emerged first in China and then later appear in Western lands, gunpowder weapons and iron founding. We should not assume, as I hope to show later in this discussion, that weapons constituted the only product for which the iron founder had any market, but it is clearly true that attempts to produce weapons constituted the most severe technical challenge for the early founder. Firearms appear for the first time in Europe in the 1320s and develop into significant weapons on the field of battle by the end of the century. Theirs is a complex history, subject neither to easy summary treatment nor to simplified models of development. I hope to be able, through the analysis of the evidence concerning cast iron, to show that one important strand in the fabric of gunpowder's history concerns the materials from which cannon could be made. This question is subject to a number of shades of meaning, because ""cannon"" can be made for many purposes under a profusion of different names, and under sharply varying conditions of use. As a result, the question of materials is frequently really a question of competing materials, and involves a complex set of factors, of which production costs and the ultimate safety of the user seem the most important. Judged in this manner cast iron was an important but unsatisfactory metal for weapons purposes until 1543, at which time English founders learned to make iron muzzle-loading cannon which could rival bronze ordnance in most important performance criteria, but which cost much less to produce. With that event, the history of cast iron and the history of weapons entered into the close relationship that persisted until the advent of rifled artillery made of steel in the middle of the nineteenth century."

Jan 1, 1999

By R. Noorani, M. Cai

"Excavation of deep underground openings in highly stressed grounds can generate new fractures near the openings. As a result, rock mass bulking may occur, leading to large wall deformation. A better understanding of brittle rock failure and the associated fracturing process at the laboratory scale is an essential step towards evaluating dilation behavior of rocks. A grain-based model that can capture dilation behavior of rocks under various loading conditions at the laboratory scale can be a useful approach to study rock mass bulking at the field scale. The aim of the paper is to study the dilation behavior of rocks at the laboratory scale employing numerical simulation. A modified grain-based model is used to simulate the macroscopic response of crystalline rocks by considering micro-fractures at the grain scale. Grains generated with the Voronoi tessellation are allowed to fail in tension or in shear using a strain-softening model. Damage is represented by either grain boundary fracture or grain failure, or the combination of the two. As stress increases, the process of damage, fracture initiation and coalescence in rocks can be captured.The grain-based model was calibrated using test data of the Lac du Bonnet granite and a parametric study was conducted. Numerical simulation results showed that the proposed modeling approach is able to capture most of the mechanical properties, fracture pattern, and dilation behavior in both unconfined and confined loading conditions. In an unconfined compression test, interactions of microscopic fractures may lead to macroscopic shear or axial splitting failure depending on the chosen micromechanical parameters. Numerical experimental results show that the dilation behavior of the model is strongly related to the failure mechanism of rocks. Tensile-failure-dominated failure mode generates large dilation due to the formation of new cracks that are sub-parallel to the loading direction. On the other hand, shear-failure-dominated failure mode produces small volume increase. One significant finding from this study is that in order to capture large dilation using grain-based UDEC models, intragranular grain failure should be considered."

Jan 1, 2015

By M. Maldonado, P. Olivares

"A submersible sensor for real-time gas holdup measurement in the collection zone of industrial flotation machines is introduced. The working principle is based on the generation and measurement of a pulp flow using a gas-exclusion cell immersed in the aerated slurry. The gas exclusion cell consists of a variable-area open vertical tube designed to be filled only with pulp by preventing gas bubbles entrance. The higher density of the fluid column within the cell generates a downward flow of pulp; the rate of this flow is proportional to the gas holdup outside the cell. The gas holdup measurement is achieved by tracking the velocity of the pulp flow leaving the gas-exclusion cell, using a magnetic flowmeter. Construction details of a prototype and its testing in two- and three-phases are discussed.INTRODUCTIONFlotation process optimization consists of finding and maintaining operating conditions that maximize flotation performance measured in terms of recovery and grade. The selective separation of mineral particles proceeds in two interactive zones where different and simultaneous phenomena take place: in the collection zone, the valuable particles are separated by collection on the surface of bubbles, while in the froth zone, the bubble-particle aggregates are gathered, drained to remove entrained particles, and taken into the concentrate stream. The cell overall performance, which can be determined from proper stream sampling, is a function of the recoveries in the individual zones. These zone recoveries cannot be independently measured nor calculated from operating variables. Progress in the assessment of these recoveries has been slow because on-line and reliable sensors to measure properties of the drastically different dispersions existing in both zones are not available.In the case of the collection zone, it has been demonstrated that the recovery of hydrophobic particles on the surface of bubbles, considered as a process with first-order kinetics, correlates with the bubble surface area flux (Finch et al., 2000; Hernandez, et al., 2003; Lopez-Saucedo et al., 2012). Bubble surface area flux (bubble area generated per unit time and cell cross-sectional area), is a variable affected by gas flow rate, bubble size distribution, and frother type and concentration. Gas holdup (volumetric fraction of gas dispersed in the slurry) is also affected by the same variables, and as such, carries information on the interacting variables that define the performance of the process. Therefore, a correlation between gas holdup and bubble surface area flux was expected and demonstrated (Finch et al, 2000), and since gas holdup is easier to measure as no bubble size is required, it has the potential to be the basis of a cell control and optimization strategy if a continuous sensor is available."

Jan 1, 2016

By Warwick Bullen

A hypothetical economic model has been developed for diamond projects in the Canadian Arctic using data from recent exploration and mining projects. The model reflects economic conditions as it applies to the diamond mining industry in the Canadian Arctic at the present time. The economic model captures pre-production expenditures, production data, and post-production costs. Before- and after-tax cash flows are derived from the data along with the relevant economic criteria. From the corporate perspective, the model provides guidance as to the minimum size and/or in-situ value per tonne requirements of targets being sought in order to ensure economic success and probable exploration and development expenditures. From the government perspective, the model provides an indication of income and mining tax revenues that can be expected from a particular diamond project. The model shows, on average, diamond projects in the Canadian Arctic are expensive to explore for and develop, but are economically robust. They generate great economic return for mining companies and significant amounts of tax revenue for governments. The fact that diamonds can be transported directly from the mine site by air makes them particularly attractive targets for mining companies that operate in the Canadian Arctic.

Apr 1, 2005

By Hani S. Mitri

Overhand cut-and-fill mining of narrow vein orebodies inevitably leads to the creation of horizontal pillars. As the thickness of the overlying crown pillar diminishes, stresses build up in the pillar. More often than not, this situation causes an increased level of seismicity and possible pillar burst. One well-known strategy to reduce the hazard of crown and sill pillar burst in cut-and-fill vein mining is that of destress blasting. The paper first reviews the methods used for the monitoring and assessment of potential pillar burst in narrow vein cut-and-fill mining. The influence of horizontal stress, mine depth and pillar thickness on stress build-up in the crown pillar is examined through a characteristic narrow vein numerical model. The paper then presents, with reference to three mine case studies, the benefits of destress blasting and the factors affecting its success as a ground control technique.

Oct 1, 2001

By Zhen Lei

In Alberta, Canada, heavy industrial projects are constructed using a prefabrication approach: spools and pipes are produced in the factory, and are assembled into modules that are transported to the industrial plants for installation by mobile cranes. Planning the onsite mobile crane operations is critical to the project budget and schedule. However, due to the large magnitude of industrial projects, manual heavy lift planning is tedious, and the results are not particularly responsive to site changes. This paper introduces an integrated mobile crane management system developed by PCL Industrial Management Inc., in collaboration with the University of Alberta, which investigates crane location selection and path checking for field module assembly. The project information is stored in a database, and the proposed system retrieves data, performs the calculations, and records the results back to the database; the calculations involve automatically selecting locations for the mobile crane, considering the crane capacity, lifting range and utilization. Lift paths for modules are checked for feasibility based on selected locations, satisfying the site and crane configuration constraints, and crane walking paths are planned if needed. The designed system is tested in an industrial project to validate the effectiveness of the system.

Aug 1, 2013

By B. Surender Mohan

Mother Earth being a treasure of minerals, it is prime duty of the mankind to preserve this natural source to ensure steady growth of the nation. Utmost care is to be taken to see that these natural resources are explored and exploited scientifically in a sustained manner to ensure that the resource base improves and last longer. In this backdrop, the topic of ?Lignite - its resource and technology options to exploit deep seated deposits? is an apt subject to be deliberated upon in the present context, where the shallow deposits may slowly get dwindled. I shall deliberate upon the resource base of lignite, production profiles of the last five decades, consumption pattern, demand / supply projections, future available technology options to exploit the deep seated deposits, growth trends of the sector etc. in my paper. With the available resource base and future technology options, I can confidentially make a statement that ?lignite will remain as cocontributor along with coal to India?s energy generation and may well maintain its same status in the 21st century too, as it has been in the later part of the twentieth century?.

Aug 1, 2013

By Jean-François Dorion

In an underground mine rock reinforcement elements and surface support units are often exposed to conditions that make them susceptible to corrosion. These unfavourable conditions include high relative humidity, the presence of dust and various other particles in the atmosphere, splashing of water and gases from blasting and diesel equipment. The corrosion of support systems is often associated with a loss in capacity that can be a major safety and economic concern in underground mines. A support system is composed of several components such as bolts, mesh, plate, retaining nut, cable ties. Every individual component can deteriorate due to atmospheric or aqueous corrosion and consequently can damage the integrity of the support system. This paper reports the results of a 5-yr study on the loss in capacity of individual support and reinforcement components at selected underground hard rock mines. As part of this investigation corrosion coupons were installed at selected locations at participating mines. A number of these coupons were recovered at regular time intervals and analysed for any signs of corrosion and subsequently tested to quantify any loss in capacity. The testing of the corrosion coupons was complemented by similar tests on recovered mesh and friction bolt specimens from the site. The collected data have provided useful insights on the factors that contribute to the corrosion of support systems. This knowledge can aid in the selection of appropriate support strategies and a reliable assessment of the predicted useful life of a support system and the need for rehabilitation.

Jun 1, 2012

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present investigation flotation was used as a diagnostic to understand the effects of changes to the media during the grinding stage. The observations from flotation for different media are discussed in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. The chemical parameters; pH, redox potential (Eh) and dissolved oxygen (DO) levels were measured. A Base Metal Sulphide (BMS) ore was ground under media of different shapes and compositions to determine the effect of different rod/ball material on the flotation performance of the ore. For a given grind (D80 = 75 µm), media shape had no effect on flotation performance of a BMS ore. Different grinding media had significant effect on slurry chemical properties and flotation performance. Mild steel rods (RMMS) produced the highest solids recovery, nickel and pyrrhotite (Po) recovery, with the highest ethylenediaminetetraacetic acid (EDTA) extractable iron and the lowest DO level. Chrome steel balls and stainless steel rods produced the lowest metal recovery, EDTA extractable iron and the highest DO level. A complementary study was conducted to investigate the effect of using different grinding media compositions, viz, ceramic, forged steel, 15% chrome steel, stainless steel and a mixture of stainless steel and 15% chrome steel (50:50) balls were investigated using a Platinum Group Mineral (PGM), UG2 ore. Grinding products of five different media produced the same solids and water recovery, but the grades and recoveries of Platinum Group Elements (PGE) and chromite were different. Grinding products of ceramic media showed the best flotation performance, with the highest PGE recovery and the lowest Cr2O3 recovery. While grinding products of stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery in the concentrates.

Jan 1, 2016

By K. Huang, L. Pan

"Darcy’s law has been used extensively to model cake filtration. It is a macroscopic model, in which particle size dominates the kinetics and cake moisture. In the present work, a capillary flow model has been developed from first principles to study the effects of microscopic parameters such as capillary radius, boundary layer slip, disjoining pressure, and surface tension that may be important for dewatering ultrafine particles. Laboratory-scale pressure filtration tests show that dewatering kinetics is strongly dependent on capillary radius, which in turn is influenced by surface hydrophobicity, surface charge, and length scales of particles. The model parameters determined from laboratory-scale filtration tests show that use of a hydrophobizing reagent can greatly improve fine particle filtration due to increased slip and decreased capillary pressure. The kinetics of dewatering kaolin clay is fastest at a pH where the layer-structured particles coagulate with a face-to-edge orientation. The capillary flow model developed in the present work may be useful for designing filters and optimizing operating conditions.INTRODUCTIONIn 2014, Canada produced 2.2 million barrels per day of crude oil from the oil sands resources in Alberta, which is expected to grow to 3.2–4.0 million barrels per day by 2030 (CAPP, 2013). One of the challenges to meeting these projections is the tailings management. At present, the industry uses ?77 km2 of the lands to construct tailings ponds. Significant amounts of the tailings disposed to the ponds are silts and clays that are slow to settle and consolidate, creating problems for reclamation. It is, therefore, the objective of the present work to develop a filtration model that may be useful for developing advanced dewatering technologies that can address the tailings management issues.Darcy’s equation is the governing law for filtration. It was derived as an empirical model by H. Darcy in 1856 while he was studying fluid flow in sand filters (Hall, 1956). Since then, many investigators derived it from first principles. It relates superficial fluid velocity to the pressure drop across a porous medium of known permeability. In filtration, the latter can be related empirically to particle size using the Kozney equation (Yoon, 2005)."

Jan 1, 2016

By Kaiwen Xia, Bibhu Mohanty, Per Svedensten, Sheng Huang

"The mechanics of crushing and grinding operations in mining and excavation processes has been investigated in a laboratory simulation study. It employs a multi-particle bedded rock target, which is subjected to multiple impacts. The impact set-up consists of a Hopkinson pressure bar and a Piston-holder system. The apparatus, employing a 38 mm diameter pressure bar, was used to apply varying but calibrated dynamic loading force on the rock particles. The energy consumed by the sample during fragmentation was determined by considering the energy carried by the incident wave and the reflected wave. The Pistonholder system is used to hold rock samples and to recycle fragments after each test for particle size analysis, for single as well as multiple impacts. The feed size selected was in the range of 9.5 to 12.7 mm for all rock samples, and the impact velocity was set at 14 m/s. Two strong granitic rocks and a relatively weak limestone were the target rocks. The resulting particle size distribution after each set of impacts, ranging from single to 10 consecutive impacts, were analyzed, and various size distribution functions (i.e. Rosin- Rammler, Swebrec, Grady and Gilvarry functions) were fitted to compare their suitability in predicting the fragment size distribution for each rock type. INTRODUCTIONCrushers are widely used in the mining industry all over the world. Understanding fragmentation behaviour of rock under crushing process is fundamental to improved productivity and efficiency in mining operations. This is particularly so as all subsequent size reduction processes such as crushing and grinding are far more energy intensive than the initial blasting process employed in breaking of in situ rock. A considerable body of experimental studies exists on the behaviour of rock crushers for specific rock types in order to aid in the design of various types of crushers. However, these studies are mainly site specific, that is, the results are largely empirical, and the fundamentals of fracture process that lead to size reduction have not been dealt with adequately. Most such studies have attempted to link the input parameters, such as feed size and crusher parameters, with output particle size, and global energy expended in the process. However the physical mechanism of crushing process is still not well understood. First of all, the energy consumed by the rock sample is hard to calculate during standard crushing or grinding tests; secondly, multi-particle test is hard to perform in the laboratory due to irregular shape of the subject rock sample. In This paper, describes a laboratory crushing apparatus for multi-particle rock samples, with sufficient control of the energy expended in the process, with a view to relate creation of new fracture surfaces in the size reduction process."

Jan 1, 2015

"The technical report form provides the headings to be used and content required when a completing a technical report to be filed in accordance with NI 43-101. The technical report is meant to be a summary of the scientific and technical information on the mineral property. The Instrument (NI 43-101) requires that technical reports be filed with Canadian provincial or territorial securities regulators to support certain disclosure of mineral exploration, development and production activities and results in order to permit the public and analysts to have access to information that will assist them in making investment decisions and recommendations. FORM 43-101F1 TECHNICAL REPORT INSTRUCTIONS (1) The objective of the technical report is to provide a summary of scientific and technical information concerning mineral exploration, development and production activities on a mineral property that is material to an issuer.This Form sets out specific requirements for the preparation and contents of a technical report. (2) Terms used in this Form that are defined or interpreted in National Instrument 43-101 Standards of Disclosure for Mineral Projects (the “Instrument”) will bear that definition or interpretation. In addition, a general definitioninstrument has been adopted as National Instrument 14-101 Definitions that contains definitions of certain terms used in more than one national instrument. Readers of this Form should review both these national instruments for defined terms.(3) The qualified person preparing the technical report must use all of the headings of the items in this Formandmay create sub-headings. If unique or infrequently used technical terms are required, clear and concise explanations must be included. (4) No disclosure need be given in respect of inapplicable items and, unless otherwise required by this Form,negative answers to itemsmay be omitted. Disclosure included under one heading is not required to berepeated under another heading. (5) The technical report is not required to include the information required in Items 6 through 11 of this Form tothe extent that the required information has been previously filed in a technical report for the property being reported on, the previous technical report is referred to in the technical report and there has not been any material change in the information. (6) The technical report for development properties and production properties may summarize the information required in the items of this Form, except for Item 25, provided that the summary includes the materialinformation necessary to understand the project at its current stage of development or production. (7) The technical report may only contain disclaimers that are in accordancewith section 6.4 of the Instrument and Item 5 of this Form."

Jan 1, 2003

By W. G. Robinson

"MINING is one of Canada's most important industries and exploration is the life-blood of this dynamic and exciting business. The health and growth of the mining industry of tomorrow depends on the effort and thought that go into exploration today. The Members of the Geology Division of the C.I.M. are directly concerned with exploration, and it is fitting that this Division should periodically sponsor reviews of the thoughts and practices of the exploration com-munity. Accordingly, we have invited seven leading authorities to contribute papers dealing with specialized aspects of this field.Exploration is a science, or art if you will, that is constantly changing in keeping with our expanding knowledge of geology and technology. It started with the old-time prospectors who searched the wilds for exposures of ore, and made finds that developed into some of our most important mining camps. As more discoveries were made, they were able to relate certain types of deposits with particular geological conditions, laying the foundation for modern concepts of economic geology. The mapping by the early field parties lacked detail and usually served to outline the ""greenstone"" areas considered favourable for prospecting. More de-tailed studies through the years by government and company geologists led to new thoughts on the origin, emplacement and geological control of orebodies. The continuing diversity of opinion on these subjects indicates a need for further research, but each year sees an increase in our reserves of factual information."

Jan 1, 1967

By Chas. L. Emery

"The laws of rock mechanics apply equally well to all rock structures, and open pits are not exceptions. The concepts and some arguments about the emphasis to be placed on various aspects of open-pit design are discussed in this article.RocksROCK can be described as a granular material consisting of grains and glue. The grains may be fragments of other rocks or polycrystalline aggregates. The glue may be ferruginous, calcareous, argillaceous, siliceous or other material connecting the grains. In a crystal intergrowth, the outer layers of the crystals in contact with each other may be considered to act as a glue. Water may be a glue in clay or a grain in a crystal structure. Air and other fluids or gases are grains if they occupy spaces in a granular mass. Such grains are functional either chemically or mechanically or both."

Jan 1, 1966

By David S. Wong

With air emission limits for total particulates continually tightening, management of `potroom dust' or airborne particulates from aluminium smelting potrooms is of increasing importance. To better understand how settled and airborne particulates are generated within a potroom, methodologies have been developed to sample and analyse the compositional signature of dust, in relation to its sources. During a smelter case study, these methods allowed tracking of mineralogical phases in dust across a range of potroom locations, showing that the mechanisms of dust generation do vary spatially and vertically in a potroom. Such methodologies may also be applicable to other metallurgical industries.

Jan 1, 2011

By K. Hanumantha Rao, A. Javadi

Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Boliden concentrator in Sweden but with the addition of i) collector and depressant, ii) Na2S reductant and iii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid. H2O2 is also found to be a better oxidant in chalcopyrite-galena flotation separation than the commonly used K2Cr2O7.

Jan 1, 2016

By R. H. Watson

A paper read by J. A. H. Church before the Northern Alberta Branch last February described a method of working thick inclined coal-seams from the dip upwards, with the view to preventing fire risk by using water for the stowage of waste workings, and extinguishing a conflagration should such break out, was favorably received; but there was some doubt as to the cost of such a method, as it involves a retreating system, which might prove too expensive for practical adoption. Let us consider a typical leasehold such as we are familiar with in the Rocky Mountains. The leasehold is crossed at one end by a mountain river, which is cut by the outcrop of a seam of coal, 30 feet in thickness, pitching as shown on the drawing herewith, which also shows the general line of the outcrop in elevation through the leasehold, which is two and a half miles long and contains 1,500 acres. The average lift is about 600 feet above river level and drilling has proved that the coalseam can be tapped at a depth of 1,500 feet, 2,000 feet down the pitch from the outcrop in the river, all as shown in the illustration, which is typical enough of our mountain conditions to serve the purposes of comparison of methods. We take up the leasehold and invest $30,000 to pay for drilling and prospecting; $30,000 more for the price of the lease to locator or holder, and say $100,000 to pay for a railway spur (it might cost twice this sum, but we are only comparing two methods in the same location) and "now we are ready to consider equipment and the cost of development.

Jan 1, 1924

By W. J. Mcgaughey, M. A. Vallée

"Abstract -The application of geophysical technology to resource delineation aims to improve the quality of resource/reserve estimates by integrating high-resolution survey methods, geophysical modeling and inversion with three-dimensional representations of geological and mineral deposit data. The use of geophysics can cost-effectively improve a geological interpretation based only on geological and sampling data. Success depends upon the ability to use geological visualization and modeling software, first to develop a three-dimensional geological model and then to modify it interactively by integrating geophysical data with the geological and sampling data.The high resolution required for mineral delineation geophysics results in a focus on borehole seismic and high-frequency electromagnetic methods. Borehole wireline logging is used to develop an understanding of the relationship between physical properties and geological description. Data from core samples and borehole wireline logs allow the construction of a three-dimensional physical property distribution, consistent with the existing geological interpretation. The three-dimensional physical property distribution is used for both geophysical forward modeling (to compare to field data) and as a starting model in iterative inversions.Advanced visualization techniques allow the simultaneous viewing of the three-dimensional physical property model, the geological information and data from which it is derived, and the geological interpretation and the geophysical results. Geophysical results may be simulated responses from a forward model or the output from a numerical inversion in the form of an updated physical property distribution. Iterative refinement of the geological interpretation is required to ensure consistency with the geological and geophysical data. The key to success with this approach is that all relevant geological, geophysical, and rock property data reside in a common, visual model of the earth.Examples from massive sulfide deposits illustrate the benefits obtained by the integration of geophysical and geological data."

Jan 1, 1998

By József L. Margitfalvi

Different Au/MgO catalysts modified with Mn, and Fe were prepared by precipitation-deposition. The catalysts were characterized by XRD, FTIR, Temperature Programmed Reduction (TPR) and CO chemisorption and were tested in CO oxidation in the temperature range of 243-523 K. The catalytic tests using both Temperature Programmed Oxidation (TPO) technique and time on stream (TOS) experiments revealed the high activity of catalysts prepared. In TPO experiments the modification by Mn significantly increased the activity above 300 K, however in the subambient temperature range the activity decreased considerably. Catalysts modified by iron did not show any decrease in the activity below 300 K, while the activity at high temperature increased significantly. Catalysts modified by Mn, Fe showed higher activity, selectivity and stability in preferential CO oxidation, carried out in the presence of hydrogen than the unmodified Au/MgO catalysts. Results of in situ FTIR spectroscopy on both the base Au/MgO and the iron modified catalyst unambiguously revealed the formation of ionic gold in the presence of CO/O2 mixture. The formation of this species was strongly hindered in catalyst modified by manganese. Results obtained strongly support the need for the formation of "metal ion - metal nanocluster" ensemble sites. These sites are involved in the activation of the CO molecule prior to its reaction with atomic oxygen. It is suggested that at subambient temperature these ensemble sites contain mainly ionic forms of gold, while at higher temperature iron or manganese ions are involved in CO activation.

Oct 1, 2003

By Richard J. Haslinger, C. Mark Rebagliati, James L. Oliver

Abstract - Exploration at the Specogna gold deposit has identified a geological resource of 65.0 Mt grading 1.63 g/t Au, which equates to 3 million ounces of contained gold. This resource is hosted in a low-sulfidation epithermal deposit of Miocene age that is localized along the northwesterlytrending Sandspit fault. The fault has juxtaposed Late Cretaceous mudstone of the Haida Formation to the west, with Late Tertiary coarse clastic sediments and lesser andesitic volcanic rocks of the Skonun Formation to the east. A plagioclase porphyritic dacite dike intrudes the Haida mudstone and Skonun sediments along the fault. Gold mineralization, in hydrothermal breccias, veins and stockworks developed mainly in Skonun sediments and dacite. These are formed in an 800 m long zone that roughly parallels the Sandspit fault. The gold zone is funnel-shaped in cross-section, approximately 300 m wide at surface, 220 m above sea level, and narrows to approximately 50 m, at sea level. The deposit lies within an elongate zone of moderate to intense hydrothermal alteration that, at surface, extends over a known area of approximately 2 km2. Its western extent is bounded by the Sandspit fault. There is an asymmetric alteration zonation, with a core of silicic-potassic (adularia) and smectite-illite clay alteration that is bounded to the east by argillic alteration. Similar zoning defined by the distribution of metals reflects the position of the main feeder conduit. Mineralization of altered wallrock is dominated by 1% to 4% auriferous pyrite and marcasite. Gold and silver occur as electrum; individual silver minerals have not been identified. Other sulfides are rare, and are identified only microscopically. The mineral suite is typical of low-sulfidation epithermal systems. Gold occurs in early, multi-phase, variably bladed and banded quartz veins and breccias, which are cut by barren, single phase, drusy quartz veins.

Jan 1, 1998