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The total current inventory of mature fine tailings is estimated to be nearly 850 million m³. Pressure has come to bear on the industry to accelerate its tailings management practices and prevent this inventory from steadily growing. The present paper describes the treatment, management and reclamation of fluid fine tailings. New technologies being evaluated include: i) Thin layered - fines dominated deposits, ii) Deep - fines dominated deposits, iii) Fines enriched sand deposits, and finally iv) water capped disposal in end pit lakes. A brief overview for each of the methods of treatment and disposal for fluid fine tailings is provided.

Aug 1, 2013

By S. Balideh

A good understanding of the behavior of broken rock helps to make more informed decisions regarding slope stability and waste dump issues in mines. The cohesion coefficient of rock has little influence on the strength of broken rock; therefore, a criterion based on friction and cohesion of intact materials does not provide an accurate analysis for the strength of broken rock. This paper illustrates the effective strength of broken rock through a brief literature review about failure of intact rock and rock masses. The complete stress- strain curve and some important points of residual strength of rock are summarized in this paper.

Jun 1, 2012

By T. R. Eger

The Load-Haul-Dump (LHD) vehicle is a trackless, free-steered vehicle used in underground hardrock mining to move large quantities of ore/rock to haulage trucks, ore dump locations, or crushing stations. The purpose of this paper is to show, through case study examples, how principles of human factors can be applied to improve the overall design of the LHD vehicle to enhance line-of-sight (LOS), improve posture and decrease whole-body vibration exposure (WBV). Vehicle modifications (larger cab windows, lower engine profile, smaller buckets, angled radiator profile) can lead to improved line-of-sight. The use of secondary viewing devices, such as cameras, can also improve line-of-sight and allow the operator to adopt a more neutral sitting posture. Seating systems that are suited to the underground mining environment can result in vibration attenuation and less vibration transmitted to the LHD operator. The connection between vehicle design, line-of-sight and driving posture needs to be considered in order to continue to improve the design of the LHD and enable the operator to work in a neutral posture with minimal vibration exposure. Changes leading to improved line-of-sight, vibration reduction, and a neutral sitting posture will lead to fewer LOS related accidents and decreased risk factors for musculoskeletal injury.

Aug 1, 2013

By K. Adham, T. Buchholz

"Significant capacity increases to meet new production demands can often be fulfilled through debottlenecking of an existing production facility, rather than the more expensive option of building new plants and facing new environmental and infrastructure challenges. To achieve that goal, it is important to model and calculate the existing ultimate capacity of each processing plant area, and that of each key equipment sector within the plant areas. This paper describes a methodology of how process modeling tools can be used to simulate the processing steps, how to estimate their existing and ultimate capacities, and how to determine the sweet-spots (minimum cost points) for a plant expansion – leading to a road map of the subsequent debottlenecking project implementation.The debottlenecking technique is presented through a generic work-flow narrative which can be applied to different mineral processing studies, starting with establishment of heat-and-mass balances, drawing a bottleneck diagram, brainstorming capacity increase options, and preparing a cost-capacity curve. Hatch has successfully applied this technique to a number of plant capacity studies, with great benefits to our industrial clients.INTRODUCTIONWith the softening of the metals and minerals prices, and the escalated costs of building new processing plants, it is now economically more viable to improve and debottleneck the existing facilities, rather than build new ones. However, spending new money on old plants requires careful considerations, in order to identify the most economically advantageous incremental steps of improvement and the best potential returns on investment. Process modeling, hand in hand with plant measurements, can identify the best scenarios to balance the three aspects of plant capacity (nameplate, utilization and yield), both at the global and the individual system and subsystem levels."

Jan 1, 2016

By A. Diaz, Minera Los Pelambres, C. G. Salinas, G. Leinenweber, F. Diaz, D. Rojas, R. Bernal, O. Jimenez

"Los Pelambres Mine (MLP) is located in the IV Region of Chile, a semi-arid region where water plays a key role in operations as a scarce resource and is vital for the sustainability of human life, animals and ecosystem. The conventional flow meters installed on pipes at MLP can fail to provide an accurate measurement due to corrosion and/or fouling on the inner wall or presence of elements in the water such as acids, salts and suspended solids. Conventional flow measurement methods require the inner diameter to be known, however it is not always possible to assess its real value due to scaling, fouling, corrosion, etc. Here we present a novel methodology to solve these problems, which consists of the measurement of flow by a method that does not require the internal area of the pipes: the fluorescent tracer dilution method. In addition, the fluid velocity can be determined by the transit time of a radioactive tracer method. With the flow rate and velocity, the equivalent area is determined and thus the equivalent internal pipe diameter as well. This methodology was applied in a recirculation pump station, for mineral processing from the El Mauro tailings dam.This work demonstrated adequate correlation between measurements from fluorescent tracers and velocity measurements from radioactive tracers, both of which lead to the assessment of the internal diameter of pipes with scaling. The results of both methods disagree with the data provided by the flowmeter installed on the line due to its miscalibration. This information is useful in validating and correcting the information provided by online flowmeters of all water and solutions transport processes in filled pipes.INTRODUCTIONPresently, the need to optimize water resources is increasingly ever important, due to various reasons such as water scarcity, community empowerment, an increased use of water for mining processes and environmental considerations. Taking into account those main considerations, Los Pelambres Mine decided to focus on water conservation to avoid losses of this vital element. They decided to demonstrate that all of the systems that used water (flow meters, pipes, pumping stations, lagoons, etc) were in good condition and that no evitable loses of this important resource occurred. A plan was proposed to conduct a “hydraulic assessment” of fluid flux and water speed at different points and courses at the mine, with the purpose of obtaining hard data to support, verify and correct the information provided online from specific instrumentation dedicated to those purposes. The final goal was to manage the water resource basin in a sustainable way, based on cross-checked information. The chosen points are representative of the processes present in the mine, such as recirculating water stations at different operating conditions and surface water courses, where the fresh water capture systems operate."

Jan 1, 2016

By W. B. Boggs

Part 1 Originally, the copper produced at the Noranda ?smelter was shipped in the form of blister bars to the Laurel Hill refinery of the Nichols Copper Co., New York. In 1930 a refinery was built at Montreal East for the purpose of refining Noranda copper and copper from the Hudson Bay Mining and Smelting Co., at Flin Flon. After investigation of the probable costs of making anodes at Noranda and at Montreal, it was decided to make them at Noranda rather than to continue to make blister bars there. Fuel is a major item of expense in making anodes: and since less fuel would be required in making anodes from molten copper than in making them from blister bars, a lower anode furnace cost could be expected at Noranda than at Montreal. Further, the expense connected with making blister bars at Noranda would be eliminated. The cost of treating anode and wire bar furnace slags is a serious item in a refinery, and it was found that the cheapest method would be to ship such slags back to Noranda. With the anode furnace at Noranda, much less anode furnace slag would be made at the refinery. Against these savings which would be effected by making anodes at Noranda must be set the high operating cost of an anode furnace at Montreal, using only tank-room scrap and the Flin Flon copper. This furnace would be handling a comparatively small tonnage and would have a high cost per ton. The usual equipment for making anodes from. liquid copper consists of either a stationary reverberatory furnace or a tilting Tacoma-type furnace together with an anode wheel of the Clark or Walker type. The reverberatory type of furnace has been developed from the furnace used in the old Welsh process of smelting and refining copper, while the tilting furnace is a development of the holding furnace, which is essentially a Peirce Smith converter without tuyeres and provided with burners.

Jan 1, 1932

By D. A. Barr

"Most of the lode and placer gold production in the Canadian Cordillera has been derived from mines and placers in the Intermontane and Omineca belts. Gold has been produced from rocks of Precambrian to Eocene age, but the preferred host environment contains Upper Paleozoic to Upper Jurassic eugeosynclinal or arc-type sedimentary and volcanic rocks adjacent to plutonic complexes which have a wide variety in both size and composition. Auriferous quartz lodes occur in fissures and shear zones which are commonly subsidiary to strong fault zones. In common with most vein-type deposits, structural complexities are an essential part of the mine environment.Gold production from the Canadian Cordillera to the end of 1978 totals 35.0 million ounces, of which 47 per cent has been produced from placer mining, principally in the Klondike and Cariboo districts. The balance has been derived from lode gold (80 per cent) and base metal (20 per cent) mines.Gold reserves in producing mines and deposits committed for production as of January 1, 1978 were 87.4 tons, or 21.6 per cent of total Canadian gold reserves contained in all types of deposits. Although more than 100 lode mines have operated in the Canadian Cordillera since the turn of the last century, over 75 per cent of the lode gold produced by 1978 was recovered from five mining camps, namely the Rossland, Hedley, Bridge River, Premier and Barkerville.The average grade of the principal producers in these camps was about 0.45 ounce of gold per ton. Individual camps yielded from 3 to 8 million tons during their operating lives, which varied from 28 to 43 years. The last of these mines ceased operating in 1971.Most of the total lode gold production has been derived from quartz veins, frequently with associated carbonate and ankerite, occupying fractured and faulted zones in Mesozoic volcanic and sedimentary rocks closely associated with a variety of intrusions. A review of the literature suggests that several deposits may have evolved by remobilization of ore constituents from earlier concordant gold-bearing formations. The principal metallic minerals in the deposits are native gold, electrum, tellurides, pyrite, arsenopyrite, pyrrhotite, sphalerite, galena and chalcopyrite.As the mineralogy suggests, many of the Cordilleran lode gold deposits have yielded important co-products or byproducts, including silver, copper, lead, zinc, cadmium and tungsten. Significant by-product gold production has also been derived from porphyry copper, volcanogenic, replacement and pyrometasomatic deposits, particularly in recent years.No major lode gold discovery has been made in the past 67 years, although little exploration activity for gold has taken place during the last 30 years. Several relatively small lode gold and gold replacement deposits have been discovered in recent years, either serendipitously (Chappelle) or on very low initial budgets (Northair and Carolin). Based on well-established precedents, one or more of these may eventually be developed into a large mine.A detailed study of the Canadian Cordillera gold deposits based on recent genetic models could prove rewarding, not only in up-dating information on their origin and depositional characteristics, but in stimulating the search for undiscovered gold deposits, in the Cordillera and other parts of Canada."

Jan 1, 1980

By Roger Lacroix

Presentation outline Project definition Characterization of mine ventilation systems Strategies in place and results Detailed study (2 mines) Other potential energy savings Conclusions Next steps

Feb 1, 2008

By Chuck Crowell

ISO Standards ?Provide Information to Address Commercial and Safety Needs for Standardization: ?Definitions and Terminology ?Test Methods ?Performance Criteria ?Conformity Assessment Process ?Developed by Global Experts ?Promote Global Harmonization

May 1, 2013

By H. R. Wilson

"This paper describes the evolution of the Waste Management Program at the Lupin Mine through the years 1982 - 1988. The program was developed in response to the terms and conditions of the Water Licence issued to the mine in 1981 by the Northwest Territories Water Board. Echo Bay Mines Lupin Mine is located on the western shore of Contwoyto Lake in Canada's Northwest Territories about 80 km. south of the Arctic Circle.The gold mine commenced production in 1982 and the Waste Management Program was based originally on the total containment concept. Due to an expansion of the mill circuitry and increased throughput, it was apparent that the total containment concept would require reevaluation since discharge from the pond would be required within a few years. During the initial years of production, an investigative program was established to determine the most effective means for treating the tailings pond water. This program incorporated both laboratory studies as well as monitoring of the tailings pond contents and environmental conditions as the impoundment area was filling. The program showed that natural degradation phenomena, if properly utilized, are effective in lowering the concentrations of all contaminants to within Licence limits with the exception of arsenic. To ensure compliance with arsenic limits, an iron salt was added to cause arsenic to precipitate from solution in the tailings pond.As a result of our studies, the tailings management system finally implemented at Lupin Mine includes the following components:Tailings pulp retention cells constructed by dyking off one end of the tailings impoundment area.Two tailings ponds in series operated in a sequential decant and fill fashion.An iron salt solution preparation and metering system.A syphon system into which the iron salt solution is injected as the contents of the first pond are decanted into the second pond.A second syphon system for decanting the contents of the second pond to the receiving streamThis paper discusses the findings and conclusions of the waste management investigative program, describes the civil work completed to reach our final operating scenario, describes the sequence of operating the treatment system, reviews performance data, and comments on abandonment and restoration of the tailings impoundment area."

Jan 1, 1989

By K. Torigoe, S. Owad, C. Tokoro, Y Tsunazawa

The mechanism of an abrasion process to recover metal values by removing components from printed circuit boards (PCBs) is modeled using a discrete element method (DEM) simulation. To simulate the abrasion process, a model PCB geometry was constructed consisting of bonded particulates. The simulation allowed connections between particles to be broken if the bonding force calculated from DEM exceeded a threshold level. Simulation results were compared with experimental comminution data using an agitation mill with test PCBs on which nine capacitors were surface solder-mounted. Simulation results obtained from the DEM with the anchoring model corresponded to experimental observations.

Jan 1, 2011

By H. Sakurai, M. Kato, F. Tanaka

The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. The conditions in the CL- furnace change its settling efficiency, resulting in high variability of copper losses in slag. Modifications of the operation and maintenance procedures for the CL-furnace have significantly and sustainably reduced the copper losses in Gresik smelter to below 0.7%. A series of flow patterns evaluation in the CL-furnace demonstrated how the chemical reactions and settling conditions of the CL-furnace has been improved by the new operating procedures. Settling mechanisms for the matte droplets in the CL-furnace is also discussed using image analysis of solidified slag. INTRODUCTION The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. Since the top-blowing in the S- furnace agitates the molten bath strongly, matte droplets are dispersed over the slag phase when melts flow out of the S-furnace. Thus, the CL-furnace has an important role to settle and recover matte droplets efficiently. Since many papers have ascribed major part of copper losses to matte droplets suspended in slag (Tanaka 2007; Genevski et al., 2008; Starodub et al., 2016), flow patterns of slag in the CL-furnace can affect greatly on the profitability of smelters which have adopted the Mitsubishi process. PROCESS DESCRIPTION Figure 1 illustrates the Mitsubishi process schematically. The Mitsubishi process is the only system for continuous production of blister copper from copper concentrates and consists of 3 furnaces connected by enclosed launders those ensure the minimum emission of fugitives. In a smelting furnace (S-furnace) copper concentrates are fed with flux, oxygen-enriched air to form a mixture of slag and matte which cascades down to a slag-cleaning furnace (CL-furnace). The CL-furnace settle matte droplets in the mixture on the crucible from which matte is siphoned to a converting furnace (C-furnace), while discharging the cleaned slag (CL-slag). The C-furnace converts matte to blister copper by the top-blowing of oxygen- enriched air.

Jan 1, 2019

By Leiting Yue, Peng Ren, Yu Shen, Zhihong Liu, Haibao Shao, Longgong Xia, Feng Yu

The Kennecott-Outotec Flash Converting technology has been proven as an advanced and mature process in 5 individual plants during the past 2 decades. High grade copper matte (65–72%) produced in the flash smelting, or other smelting technologies is granulated to 3-5mm granules in a water torrent, and further crushed to fine powder (≈50µm) and dried to contain less than 0.3% H2O. Oxygen enriched air, together with fine copper matte powder and lime flux are injected into the reaction shaft by a matte burner. The copper making and slag making reactions will happen in very short time and distance during the particle falling and settling. However, industrial practice has found negative effects caused by sodium contamination. Na is introduced in the copper matte granulating process, and appears as Na2SO4 on particle surface. When Na content was high, scaling problems in the boiler will be worse, and the processing air will be blocked by the growing accretion around the matte burner, and as-produced blister copper is always high in S and O. In this present study, an industrial matte sample was used in the experimental work. Na was introduced into the matte powder by Na2SO4 solution soaking. The burning behaviour of the doped copper matte powder has been investigated as a function of the impurity concentration and processing temperature. Morphology and composition of these samples explained how Na2SO4 converts and reacts in the oxidizing atmosphere, and how they or their converting species influence the burning behaviour of matte particles. Cross-sections of as-prepared samples were analyzed with SEM-EDS, and the reaction mechanism has been carefully interpreted. Results from the present study can benefit both academic and industrial people. INTRODUCTION "Flash Converting" technology was developed jointly by Kennecott Utah Copper Smelter and Outotec (Finland) OY in 1992. The first industrialization of the technology was in Utah Smelter in 1995. Since 2006, it has been successfully applied in Xiangguang Copper, Tongling Jinguan Copper Branch, Fangchengang Jinchuan Copper, and Ningde Southeast Copper. The technology has also been further developed in those smelters. At present, roughly 2 million tons blister copper is produced annually through the Kennecott-Outotec Flash Converting technology, accounting for more than 10% of global primary copper production. The technology has advantages of high efficiency, high sulfur capture rate, good in environmental issues, mature equipment supporting, high automatic control level, low comprehensive energy consumption and flexible connection with the smelting unit, which make the technology to be one of the best choices in investing a new large-scale copper smelter or updating an old copper project in the world.

Jan 1, 2019

By Jaana Romppanen, Satu Jyrkönen, Tiina Ranki, Peter Björklund, Markku Lahtinen, Kaj Eklund, Päivi Suikkanen

Outotec is continuously developing our existing process equipment and new equipment solutions to enhance the Flash Smelting process. Thanks to the long operating history of the Outotec Flash Smelting process feedback from the numerous operating references are available and is utilized. The general goals for development work are to improve equipment performance, thus realizing savings in Smelter plant operation costs by increasing the process efficiency and online availability. Digitalization also opens new possibilities for the feeding equipment and furnace operation monitoring. These solutions will improve the safety and performance of the smelter, and provide process and equipment related information which has not been available earlier. INTRODUCTION The year 2019 marks the 70th anniversary of Flash Smelting. The technology was operated on industrial scale for the first time at the Outokumpu Harjavalta copper smelter in Finland in 1949. The Flash Smelting technology, is now owned and developed by Outotec Oyj and the first plant, is now owned by Boliden Harjavalta Oy. The two companies have been evolving throughout history by optimizing the process for various feeds and raw-materials, as well as through developing the equipment and operating practices. Even though sustainability was not a hot theme/topic during the first days of Flash Smelting, it has nevertheless been the key principle in guiding the development. This is well proven by the wide adoption of Flash Smelting for the processing of copper and nickel concentrates, mostly due to its ability to fulfil the economic and resource efficiency criteria demanded by its operators. Along with the process technology development, also development of the equipment has taken place over time. Outotec is continuously working on developing our equipment to better suit the changing need of our customers in the continuously changing operational environment. Orebodies are getting more challenging with lower ore grades and more impurities. Achieving high recoveries for all valuable elements becomes more difficult with high slag quantities and with the need to tackle the high impurity concentrations. There is a need for higher capacities in greenfield and brownfield smelters. The role of the Loss-in-Weight Feeder, the Air Slide and Concentrate Burner is to ensure even feed into the reaction shaft of the Flash Smelting Furnace, and to enable controlling the process well, thereby enabling the best performance for the customers smelter. The design of the Flash Smelting Furnace aims for high availability, long campaign and safe operation.

Jan 1, 2019

By J. A. Finch, R. R. Cunningham

The amount of foam volume generated in relation to the gas flowrate has long been used to define the foaminess of a solution and to characterize surfactants. The vessel geometry and gas flowrate range can affect the foam volume results. A fixed area column was tested alongside a variable area conical vessel with two surfactants. It was found that the fixed area vessel will cause foam volume to expand or contract which masks the effect of the surfactant. The conical vessel showed two regimes of foam volume production dependant on gas flowrate. The low gas flowrate regime revealed the physiochemical nature of the surfactant while a high gas flowrate revealed kinematic properties. Foaming properties of a surfactant is best determined with a variable area vessel at low gas flowrate.

Jan 1, 2009

By A. A. Lavrinenko, N. I. Gluhova, L. M. Sarkisova, D. V. Makarov

"The investigated sulfide Cu-Ni ores are characterized by low PGE contents and emulgated impregnations of pentlandite and palladium minerals in the main ore-forming mineral pyrrhotite, which hinders their selective separation, requiring a collective flotation of sulfides to concentrate, and hydrometallurgical processing. As revealed by studies of floatability of Pt-Cu-Ni ore in a mixture of butyl xanthate and chelating phosphorus containing reagents, the most effective additive is Aerophine 3416 (a phosphinates mixture) manufactured by Cytec. Using collective flotation with a butyl xanthate – Aerophine 3416 composite in the ratio of 1:3 has afforded to enhance the Pt, Pd, and Ni recovery by 13.6 %, 9.2 %, and 9.4 %, respectively. The optimal ratios of Aerophine 3416 to butyl collector for the collective flotation are the following: 1:1 for Pt and Pd and 3:1 for Ni. The effect of these reagents on the electrode potential and surface hydrophobicity of pyrrhotite, pentlandite, and platinum black has been investigated. The extraction UV spectrophotometry experiments demonstrate that DIBDTPI exists on the pyrrhotite surface mainly in the form of disulfide in weak acid medium and in the form of compounds with Fe on the mineral surface in minute amounts. There appears some disulfide and few amount of (DIBDTPI)2Ni on the surface after interaction of DIBDTPI and pentlanditeINTRODUCTIONXanthates are widely used in flotation of copper-nickel ores containing platinum group metals (PGM) as sulfides collectors which can concentrate the most part of PGM connected with the sulfides. Though xanthates are hardly efficient for flotation of free PGM, the latter are floated more slowly compared to the sulfides of base metals. The reasons for poor floatation of free (mineral) forms of PGM are under-researched, however the key accepted reasons are: fine disseminations of free PGM, insufficient interaction with xanthate and negative influence of blue copperas and sulfur-containing ions which are sulfides oxidation products (Penberthy et al. 1999; Shackleton et al., 2007). That’s why an additional collector, normally dialkyldithiophosphates, is used during flotation of PGM-containing copper-nickel ores. A reagent DP-4 is used for recovery of PGM at Norilsk mining and metallurgical plant. The reagent represents a slightly-soluble organic calcium sulfonate which is given to flotation pulp in the form of water emulsion of 5% - solution in automotive diesel oil."

Jan 1, 2016

By Patrice Nadeau, Yuejun Zhang, Dan Chen, Liming Huang, Claude Gagnon

"The traditional Denver flotation cell is generally suitable to process material ranging approximately from 5 µm to 300 µm. For floating over 300 µm material, its efficiency is significantly getting lower mainly due to the difficulty to suspend coarse particles uniformly, which decreases the chances of particles to attach to bubbles and increases the chances of detachment.RTFT (Rio Tinto Fer et Titane) owns one of the world’s largest hemo-ilmenite deposits. Considering the whole processing technology, the ore is only crushed to -1180 µm. The crushed ore contains about 0.32% S and most of the sulfur is removed by rotary kilns in the ore preparation plant. In order to achieve a similar S reduction, without emitting SO2 into the air, an alternative technology by flotation was pursued.Laboratory and pilot scale-up tests showed that traditional Denver flotation cell could perfectly remove the sulfur from the material sizing 0-300 µm. For the coarser particle sizes, two different models of equipment were tested to improve flotation efficiency: HF (HydroFloat Separator) from Eriez and CLF from BGRIMM (Beijing General Research Institute of Mining and Metallurgy), China. The D6” HF, which is a device that combines flotation and gravity separation, demonstrated its ability to recover those very coarse particles. As compared to the Denver flotation cell, the modified 25 L CLF coarse particle flotation cell achieved better results at higher pulp solids percentage and with a shorter flowsheet."

Jan 1, 2016

By G. Morin, S. Amira, F. Chiesa, B. Duchesne

"The effect of heat treatment on the stress corrosion cracking (SCC) resistance of A206 aluminum alloy was studied using the breaking load test according to ASTM G139 standard. This method uses the residual strength measurement from tensile test specimens previously stressed axially while exposed to the 3.5% NaCl alternate immersion test according to ASTM G44 standard. The residual strength after exposure is used as a measure of SCC degradation. The performed heat treatments were conventional natural aging T4 and artificial over-aging T7 tempers in addition to artificial aging T6 temper added for purpose of comparison. These tests showed that A206-T4 has a good resistance to SCC at pre-loads up to 100 MPa while A206-T7 was prone to SCC for pre-loads of 0 and 50 MPa, and showed total loss of ductility for pre-load of 100 MPa. Both A206-T4 and A206-T7 pre-loaded at 150 MPa showed poor resistance to SCC. A206-T6 showed the worst susceptibility to SCC as it lost all mechanical resistance at the end of the alternate exposure to 3.5% NaCl solution, even without any applied pre-load. Metallographic analyses showed that the resistance of A206 alloy to SCC is mainly affected by the transition from pitting to intergranular corrosion attack. The initiation and the propagation of intergranular corrosion attack might be assisted by high stress concentrations in the pits, particularly for pre-loads higher than 100 MPa. The transition from pitting to intergranular corrosion can also be promoted by hydrogen evolution from growing pits, which supports crack propagation by hydrogen embrittlement.INTRODUCTIONA206 aluminum-copper casting alloy offers ones of the best mechanical properties among the aluminum foundry alloys. This alloy belongs to the 206 alloy family developed in 1970s as an alternative to the highly resistant and ductile but more expensive Ag containing 201 alloy (Tiryakioglu, 2009). A206 showed also good low cycle fatigue strength (Sigworth, 2002). These properties made A206 alloy a strong candidate for some vehicles lightweighting applications. In spite of its interesting properties cited above, A206 alloy was rarely used in critical applications due to its tendency for hot tearing and stress corrosion cracking (SCC). Studies of A206 hot tearing behavior showed that this tendency can be reduced by improving castability and by grain refinement (Sigworth, 2002). The optimisation of the casting design can also prevent the tendency toward hot tearing. The SCC of aluminum-copper alloys arises from their susceptibility to localised corrosion, especially in chloride containing media. The localised corrosion in Al-Cu alloys is caused mainly by their heterogeneous microstructure, where the presence of many phases leads to the formation of micro-galvanic coupling with the matrix. However, most of the studies aimed at investigate the SCC of Al-Cu alloys concerned the wrought ones, especially the AA2024 alloy tempered in the T3 (or derivative) condition and few studies concerned the 206 and cast alloys in general (Alexopoulos, 2009 and 2016; Campestrini, 2000; Vogt, 1998; Talamantes-Silva, 2008; Zhang, 2003). Jean et al. (Jean, 2009) studied the effect of heat treatment on SCC behavior of B206 alloy using alternate immersion technique and grain boundary attack method and did not find direct correlation between the two methods. Another study showed that aging of 206 alloy may make a casting susceptible to SCC (Sigworth, 2002). However, these studies did not provide detailed information about the mechanisms of SCC of 206 alloy, as well as the effect of the stress intensity. The present work investigates the effect heat treatments and the stress intensity on the morphology of the corrosion attack and the SCC behavior A206 aluminum alloy. This study uses the breaking load test according to ASTM G139. This test utilizes direct tensile specimens and was developed to give a more quantitative measure of the SCC performance of resistant aluminum"

Jan 1, 2016

By China University of Mining and Technology, P. Zhang, C. Zhou, C. Duan

"Recovering pyrite from the gangue with high sulfur content is of great significance for both economic development and environment protection in China. Due to the global water shortage and high cost in wet separation processes, it is urgent to explore more efficient energy and water conservation method in mineral processing field. This study has proposed an innovative method based on density difference for fine pyrite enrichment by vibration fluidized bed. In this study, the total sulfur content (TSC) of the gangue sample is 19.18%, and the pyrite is disseminated with fine granularity in the gangue which should be crushed for dissociation. The combination and dissociation experiment of -6mm gangue shows that the dominant density of -6+3mm, -3+1mm and -1+0.5mm comminuted material is +2.9g/cm3. Based on the analysis of characteristic, the effects of various factors on the separation performance were experimental studied. The results show that gas velocity, vibration intensity and bed height all have the significant effects. With the increases of superficial gas velocity, vibration intensity and bed height, the separation performance all presents a decreasing tendency. Additionally, the TSC of -6+3mm, -3+1mm and -1+0.5mm materials are respectively up to 37.94% , 35.43% and 30.61% at the optimum conditions, which are the 1.72?1.90 and 2.29 times as much as the TSC of raw material, respectively. This study demonstrates the vibrated fluidized bed can recovery pyrite from the gangue effectively.INTRODUCTIONWith the increasing mining and separation of coal, the yield of gangue has a further growth tendency, which has become one of the largest reserves of industrial waste (Querol et al., 2008). However, many harmful elements, such as S?NOx and Hg, is existed in the gangue leading the serious damage to the soil and environment (Hao, Yun, Zhanyuan, Sen, & Song, 2013). In addition, the economic would be suffered from the loss resulting in the occupied of arable land caused by the accumulation of gangue (Yeheyis, Shang, & Yanful, 2009; Zhou, Liu, Yan, Fang, & Wang, 2012). Therefore, the government has put forward the policies of ""green mining"" in China (Xing & Gao, 2009; R. Zhang, Ai, Zhou, Ju, & Zhang, 2015; Zheng, Du, Li, Qiu, & Yang, 2015). Among different research areas of coal utilization, extracting the useful minerals has become one of hot topics (Ledin & Pedersen, 1996; P. Patra & Natarajan, 2003; Partha Patra & Natarajan, 2004). At present, many researchers has devoted to the desulfurization of coal all over the world. As result, the sulfur element, which is mainly existed in the presence of pyrite, would transferred in the tailings, namely the gangue. Meanwhile, the pyrite is important raw materials to produce rubber, paper, textile and match. Consequently, recovering the pyrite from the gangue is not only suitable to the requirement of ""green mining"", but it could turn the waste into the treasure having the important significance."

Jan 1, 2016

By Andreas Zielonka

To meet the increasing demands of the quality and long term stability of technical systems also the applied materials have to full fill higher standards. This is of special importance where the function of a whole system depends on the reliability of the used materials for example for connector systems in automotive, computer and other electronic equipment?s. In most cases for connector systems electro deposited top layers are applied. To improve the quality of the applied layers new electro deposited systems are developed. One important field of research are the development of composite materials as dispersion coatings and multilayer systems. Multilayers are systems with a high number of single inter-layers of different metals or alloys with the wide chance of the alloy composition. As gold is one of the most important contact material for high quality connector systems it is used as basis for the development of multilayer systems. For the electrodeposition of multilayers two different methods can be applied, the single and the dual plating process. As in the dual plating process two different electrolytes are used, the single plating process allows the formation of multilayers from one electrolyte. In the presented research results cobalt and nickel are used besides gold for the formation of the multilayers. The properties of the layers can be influenced in a wide range by the change of electrolyte composition and the process parameters as current density, current waveform, temperature, hydro-dynamic conditions at the electrode surface and by the number and thickness of the inter layers of the deposited materials. The paper describes the fundamentals of the electro deposition of multilayer systems. For the investigation of the properties of the multilayers different techniques are applied. One of the most important parameter are the thickness of the total layer and of the applied sublayers. The thickness of the sublayers can be varied between a few nanometers up to micrometers. The wear resistance, the contact resistance and the plug-in forces are measured as these parameters are important for the technical application of such layers. For the description of the structure composition and surface properties the sample where also investigated by scanning electron microscopy (SEM), energy dispersive x-ray-analyses (EDX) and glow discharge optical spectroscopy (GDOS). The paper shows that the deposition of gold based multilayers is possible and that the properties of such systems can be varied in a wide range what opens new fields of applications of such materials.

Oct 1, 2003