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By S. Nakamura, K. Fujiwara, S. Hirosawa, S. Tsukamoto, Y. Koshino, Y. Aruga

"In this study, hardness test, differential scanning calorimetry(DSC)and transmission electron micros copy were carried out to investigate the age-hardening behavior of Al-Mg-Si alloy with a Mg+Si concentration of 1.5mass%, and a Mg/Si ratio of 1.0. Pre-aging treatment was conducted for the solution-treated and then water-quenched specimen at 100, 80, 60, 40, 20 (natural aging), 0 and -20°C for 20min or 5h, followed by artificial aging at 170°C for 20min. It was found that when pre-aging time is prolonged from 20min to 5h, the bake-hardening response is deteriorated irrespective of the pre-aging temperature. In particular, the specimens subjected to pre-aging at 20-40°C for 5 h hardly increased the hardness with the subsequent artificial aging. From the results of DSC measurement, it was suggested that as pre-aging temperature is lowered, the amount of solute clusters formed during pre-aging, i.e. Mg-Si clusters and Si-rich clusters, is decreased, but the ratio of Si-rich clusters is increased, resulting in the deteriorated bake-hardening response.INTRODUCTIONIn recent years, Al-Mg-Si alloys have been widely used forautomotive body panels due to their excellent characteristics such as high strength-to-weight ratio and good formability. Their strength is increased not only by artificial aging during paint-bake treatment; i.e. “bake-hardening”, but also when kept at room temperature(RT);i.e. “natural aging”, in association with the suppressed bake-hardening response. Such a “negative effect of two-step aging” has been a serious problem because Al-Mg-Si alloy coils are unavoidably maintained at RT in the manufacturing process of body panels; e.g. shipping and storage. However, it was reported that pre-aging above 70°C before the two-step aging can restore the bake-hardening response, and such an improvement is related to the formation of solute clusters(Sato, 2006; Abidet al., 2010; Takaki et al., 2014; Zandbergen et al., 2015). From the comprehensive analysis by three-dimensional atom probe (Aruga et al., 2014 and 2015), it is believed that Mg-Si clusters formed during pre-aging transform into the strengtheningß"" phase, whereas Si-rich clusters formed during pre-aging act as a detrimental precursor of ß""phase. In this study, it was aimed to investigate the effect of pre-aging conditions, especially pre-aging temperature and time, on the formation of solute clusters during pre-aging, in order to elucidate the mechanism of the age-hardening behavior of an Al-Mg-Si alloy."

Jan 1, 2018

By R. A. Frith

"Belts of Yellowknife Supergroup volcanic and sedimentary strata in the Slave Structural Province are separated by granitoid complexes. The strata and most intrusive rocks are 2.7 and 2.5 Ga old, but rocks around 3.1 Ga have been recognized in some of the complexes and are believed to represent a once-extensive sialic crust. Volcanics were erupted along rifts in this crust and the rifts became sites of crustal foundering and the development of troughs that filled with turbidites of volcanic and granitoid provenance. Present margins of the granitoid complexes may be close to the original margins of deposition of volcanics, with associated mineral deposits, and close to the thickest parts of basins of sedimentation.The Hackett River volcanic belt extends 100 kilometres between Mara River and Back River and is crudely S-shaped, with a northern sector surrounding a core of granitoid basement rocks, a northeasterly facin g central sector and a southerly facing southern sector. Up to 8 kilometres of andesitic volcanics with intercalated felsi c volcanic rocks are preserved within the central sector. The f elsic rocks include thick lenses of volcaniclastics with large, quartz-eye-bearing clasts, but the known metal deposits are not associated with these. Both of the deposit areas, the Hackett River area in the northern domal sector and the 'A itch ' Lake area 40 kilometres to the south in the central sector, are near the tops of relatively thin atypical volcanic sequences above suspected basement rocks. The Yava deposit near 'A itch , Lake overlies a unit of subaerially deposited, welded, andesit ic ash flows and the Hack ett River deposits overlie highly metamorphosed volcaniclastic rocks that include suspected ignimbrites.The deposits are notably argentijerous and lead-rich. They consist of stratigraphically zoned sheet-like bodies of iron sulphides, sphalerite, galena and chalcopyrite underlain by altered rocks containing chalcopyrite stringers. The Yava deposit was formed where hydrothermal fluids exuded through the fractured floor of a flooded caldera basin. The Hackett River deposits may have been formed in a similar setting and it is not inconceivable that all the known deposits in the belt were formed in a single large caldera basin, although there is no independent evidence for the required major fault separation between the Hackett River dome and the 'Aitch' Lake area."

Jan 1, 1980

By H. Houali

Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items: ? Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists; ? Range of protection (potential of protection along the pipeline); ? Influence of the isolation resistance of the coating on the range of protection; Effect of the aging of the coating and its influence on the current of protection

Jan 1, 2005

By M. Bozorgtabar

Metal Matrix Composites (MMC) have a ductile matrix containing ceramic particles, Due to their improved wear properties, Al?SiC composites have economical applications in many industrial uses where wear is a problem, One of the most serious difficulties in manufacturing Al-SiC composites is obtaining adequate 'wetting' of the particles by the melt. In this research work, a stir casting system was designed for the improved manufacturing Al-SiC composites, The effect of some production variables such as the addition of SiC particles to the aluminum melt on wettability, was also studied. The results showed that the manual addition of particles would not be successful in manufacturing and that a system of adding silicon carbide particles through controlled temperature, atmosphere and improved mixing was needed.

Jan 1, 2005

By M. Pawlik, E. Arinaitwe, V. Ferrera

A series of flocculation tests were performed on dilute quartz suspensions with the use of five polyacrylamide-based flocculants of similar molecular weights but of different degrees of anionicity. The tests were performed as a function of ionic strength and pH. The macromolecular conformation of flocculants in solution was assessed through intrinsic viscosity measurements under the same physicochemical conditions as those of the flocculation tests. It was generally found that the flocculating efficiency of the polyacrylamides correlated with their ability to coil or stretch in solution. Polyacrylamides with the degrees of anionicity on the order of 10-18% showed the highest flocculating efficiency in terms of the settling rates of the flocculated solids and the residual turbidity of the resulting supernatant. At the same time, these most effective flocculants were also found to exhibit the greatest tendency to coil and stretch in solution. This result suggests that the flocculating power of a flocculant is determined not only by its ability to adsorb onto (and bridge) fine particles but also on its ability to conform to the size of the resulting floes.

Jan 1, 2009

By W. T. Irvine

"The H.B. Mine, a zinc-lead operation of the Consolidated Mining and Smelting Company of Canada Limited (Cominco), is in south central British Columbia, on Sheep Creek, a west-flowing branch of the Salmon River. It is 3 miles by road from B.C. highway No. 6, 30 miles south of Nelson, B.C., with an excellent highway connection to the smelter city of Trail, 35 miles from the mine. The nearest permanent settlement is the village of Salmo, 7 miles distant by road. The mine is situated along a belt containing other important zinc-lead deposits, including those of the Canadian Exploration Company, 3 miles to the south, and the Reeves MacDonald mine, 9 miles distant again to the southwest.Deeply oxidized outcrops were located in 1907 on the north side of Sheep Creek valley by two prospectors named Horton and Benson. The property was given the name H.B., after the two discoverers, and there commenced a long and intermittent series of mining operations designed mainly to develop and extract oxidized lead-zinc ore. In 1925 a determined attempt was made by a British syndicate to develop a large tonnage of sulphide ore, but this ended in failure after some 3,000 feet of lateral development had been done. In 1927 Cominco acquired the mine, but it lay idle until 1946 when a geological study was followed by a program of surface drilling which encountered extensive sulphide mineralization. An underground development program revealed more details of the deposit, and sufficient ore was found to warrant construction of a 1,000-ton mill. Mine preparation and mill construction were completed by early 1953, but production was deferred due to low metal prices. The mine was finally brought into production early in 1955."

Jan 1, 1949

By Tong Gao, Jingyu Qin, Xiangfa Liu, Zengqiang Li, Yaoxian Zhang

"The recycling of aluminum materials is a green industry while Al–Si–Fe is a typical scrap aluminum alloy. The key point of recycling Al–Si–Fe alloys is to separate Al and Fe. A method by introducing Al–Si–Fe alloy into Mg melt has been investigated in this work. A separation layer with gathered Fe–rich and Al–poor Fe3Al0.7Si0.3particleswereobtained at the bottom of the cooled ingot, indicating that ß–Al5FeSi phase evolves to Fe3Al0.7Si0.3,and quantities of Al are released to the upper Mg matrix simultaneously. However, the evolution of Al3Fe by adding binary Al–Fe alloy into Mg melt is different. It is supposed that element Si plays an important role in the phase evolution procedure, thus affects the performance of this method.INTRODUCTIONThe rapid development of aeronautic, automotive and aerospace technologies strongly depends on the consumption of materials while sustainable development is the future direction. Aluminum is a recyclable material and Fe is one of the most common impurities. Fe can be introduced into Al alloys by adding low–purity alloying materials and by using unprotected ferrous crucible, tools, or equipment (Belov, Eskin, & Avxentieva, 2005; Lu& Dahle, 2005).For instance, wear–resistant rings are usually inserted into piston head when producing Al–Si pistons and an infiltration procedure by putting the cast iron rings into Al melt before casting is always essential. As a result, both the re–melting of pistons and the reuse of Al melt for infiltrating rings lead to the enrichment of Fe element, which can be even high to5 wt.%(Viala, Peronnet, Barbeau, Bosselet, & Bouix, 2002).It is widely known that coarse ß–Al5FeSi particles will form in high Fe–contained Al–Si–Fe alloys which is harmful for the mechanical properties. In the past decades, several methods to eliminate the harmful effect of ß–Al5FeSi have been investigated which can be widely referred (Munson, 1967; Lee, Kawamura, Inoue, Cho, & Masumoto, 1997; Suárez–Peña& Asensio–Lozano, 2006; Eidhed, 2008).These methods can be divided into two kinds. One is to aggregate and remove the Fe–rich phase through the methods of centrifugation, gravity filtration or magnetic separation. The other way is modifing the morphology of flake–like ß–Al5FeSi by overheating the melt or adding neutralized elements. However, these traditional methods are rarely used due to respective disadvantages, while the commonly used method in industries is using primary aluminum for dilution. However, only less than 30wt.% of scrap Al can be added into primary Al melt for each melting work while it also results in the decrease of product quality simultaneously(Zhang, Liu, & Liu, 2016)."

Jan 1, 2018

By D. A. Akinlade, N. L. Richards, D. C. Murray, W. F. Caley

To investigate the effect of adding Ti to a Ni-Cr-Fe powder metallurgy alloy, a thermodynamic software package was used to predict the phase transformations that occurred during thermal processing. Specifically, the effect of adding 3w/o Ti to a 6w/o Al modified ternary Ni-Cr-Fe alloy (the quaternary) was simulated and the phase transformations that might occur in the material on sintering were obtained using the thermodynamic modeling tool. These predictions were subsequently compared with experimental results obtained by X-ray diffraction and metallography. For comparison, selected compacts were prepared containing only the ternary + 3w/o Ti (no Al). Based upon compressibility curves, the optimum pressure for producing the new Ti compacts was 500 MPa vs 600 MPa for the quaternary composition with Ti. In each case, hardness of the base alloy was enhanced by the Ti addition whereas the residual porosity remained relatively constant at about 19%. Finally, although SEM/EDS failed to confirm the presence of Ti in the gamma prime intermetallic, XRD spectra showed a shift in lattice parameter on addition of Ti, suggesting that the intermetallic was of the form Ni3(Al,Ti).

Jan 1, 2010

By M. Meratian

The in-situ methods have been developed in production of aluminum matrix composites. A commonly adopted in-situ method involves reaction between a metal oxide and aluminum to produce alumina particles or whisker reinforcements. Aluminum-alumina particle composite was fabricated by in-situ method where alumina particles were produced from reduction of copper and silicon oxides by melting and casting aluminum. Aluminum matrix composites reinforced by Copper and Silicon alloying elements and alumina particles have been obtained. The size and shape of alumina particles were studied by scanning electron microscopy (SEM). The size of alumina obtained from mixture of SiO2 and CuO was bigger than the alumina particles obtained from CuO.

Jan 1, 2007

By K. Kawagishi, K. Matsumoto, Y Koizumi, H. Harada

A new burner rig for cyclic and hot corrosion testing of Ni-base superalloys and high-temperature coatings has been developed at the National Institute for Materials Science (NIMS) in Japan. The concepts of the rig design include: use of kerosene as fuel, easy operation for materials research and multi-specimen testing capability per test run. The burner rig consists of six blocks including combustion block, corrosion-solution injection block, furnace block, specimen block, controller block and outdoor facility block. During verification testing, it was confirmed that the rig had accurate specimen temperature control within ±1? from 600 to 1100? and automated easy operation. Cyclic testing of several Ni-base superalloys was conducted. The results from 50 cycle testing indicated that a new NIMS alloy developed for 1700? class gas turbine had higher oxidation resistance than CMSX-4. This new burner rig testing capability at NIMS can be very useful for future oxidation, hot corrosion and coating durability studies.

Jan 1, 2010

By J. Satur

In copper mineral processing, pyrite coexisting with copper sulfide minerals like chalcopyrite is separated by flotation as tailings and its oxidation in tailing dams causes the formation of acid mine drainage. This paper proposes carriermicroencapsulation (CME) as a new method for suppressing pyrite flotability, as well as its oxidation. In this method, an organic carrier combined with Ti is used to form a thin Ti02 layer on pyrite, which gives a hydrophilic property and acts as a protective coating against oxidation. To form the coating, a ground pyrite sample was treated with Ti-catechol complex solution under various conditions. Bubble pick-up experiments and flotation experiments showed that the treatment of pyrite with Ticatechol complex changed the hydrophobic nature of pyrite into hydrophilic even in the presence of xanthate as a flotation collector. Oxidation testing of the CME-treated pyrite by 0.02 kmol m-3 HN03 showed that Fe release was suppressed by the CME treatment with respect to the control. This is assumed to be due to the formation of Ti02 coating on the pyrite surface. The effect of CME treatment on chalcopyrite wettability is also discussed.

Jan 1, 2007

By R. A. Triglavcanin

Delivering dilution water and mixing this water with incoming feed slurry, addition of flocculant, maximising flocculant-slurry interaction to build aggregate size, unabsorbed flocculant percentage, volume average of solids volume fraction, momentum dissipation ratio, dilution recycle ratio, volume average shear, maximum shear rate at exit, aggregate size on exit, uniform discharge profile and more ? all of these need to occur in the right order and in the right proportions within the thickener feedwell, the secret to thickener performance.

May 1, 2009

By Ben Cottrell

In this paper technical drilling is referred to as the process of collecting engineering and metallurgical parameters for subsequent mine design considerations. Throughout the development of a mineral exploration property there are various opportunities to ?piggy-back? technical drilling onto the routine exploration drilling process, helping to reduce future costs and delays associated with re-drilling and missing information. This article is written from the engineers and metallurgists point of view, to outline some best practices for exploration borehole planning and technical data collection requirements.

Aug 1, 2013

By Magdy Ibrahim

Detailed as-built project schedules are necessary to close out construction projects, benchmarking, forecasting, dispute resolution, and improving cost estimates of future projects. Manual procedures for developments of as-built documentation is time consuming, involves numerous interfaces and human interventions. This paper presents computational framework that encompasses automated site data acquisition and generates schedule updates utilizing commercially available project scheduling software. The work is carried out collaboratively with a Hydro Quebec team. The site data is captured employing mobile computing using iPad® type computers and Wi-Fi. The information is directly compiled in a centralized database server. The synchronization tool is a bi-directional application and is used on servers to communicate with iPad® computers deployed onsite. The captured data is stored in Microsoft SQL® relation database that consists of 63 entities. Computer software application has been developed in Microsoft Visual Basic® (vb.net) environment for extracting the collected site data, linking the database to the as planned schedule, and generating the actual, also known as as-built schedule. The development can be utilized in automated progress reporting, evaluating future bids, generating master schedules and a wide range of efficient EVM applications.

Aug 1, 2013

By S. Esfahani, M. Barati, K. Danaei

"Substituting Portland cement with slag cement is one of the most economically attractive uses of slags. For this application, high cooling rates are required to form an amorphous structure. However, this is counteracted by the need to use small coolant flowrate to allow recovery of slag thermal energy as high quality heat to the coolant fluid. Therefore, a relationship between cooling rate of slag and its structure is essential to recover the heat effectively while making an amorphous slag.A modified Single Hot Thermocouple Technique (SHTT) was employed to investigate the crystallization behavior of slags by plotting their TTT (Time-Temperature, Transformation) diagrams. Seven different slag compositions containing CaO, SiO2, Al2O3, MgO were prepared at varying basicity (CaO/SiO2 =0.5-1.4).The results indicate that with increasing basicity, the TTT curves of glassy to crystalline transformation shift to the left which means higher crystallization tendency. This agrees with the fact that with the increase of basicity, the Si-O bonds are weakened, which in turn facilitates the re-ordering and crystallization of the silicate structure."

Jan 1, 2014

By Vlad Ruzicka

"Uranium deposits in the Rabbit Lake-Collins Bay area are associated with the sub-Athabasca unconformity which separates crystalline Archean or Aphebian basement rocks from Helikian clastic sedimentary rocks of the Athabasca Group. The basement rocks are a part of Wollaston lithostructural domain.Most of the high grade deposits, such as Collins Bay ‘A’ and 'B' Zones and Eagle Point are associated with altered rocks of the basal unit of the Wollaston Group. Some deposits, such as Raven and Horseshoe are confined to the uppermost unit of this Group. The Rabbit Lake deposit occurs in the middle, meta-arkose unit of the sequence. Locations of some deposits (Rabbit Lake, Collins Bay ‘A’ and 'B' Zones) are also controlled by thrust faults, such as Rabbit Lake Fault and Collins Bay Fault.The deposits contain either monometallic (uranium) mineralization (Rabbit Lake, Raven, Horseshoe) or polymetallic (mainly uranium-nickel) assemblages (Collins Bay “A’ and 'B' Zones).IntroductionThe Athabasca Basin region, a part of the Churchill Geological Province of the Canadian Shield, is composed of Archean and Aphebian crystalline basement and younger, Helikian, unmetamorphosed supracrustal rocks. The Rabbit Lake-Collins Bay area is situated at the eastern margin of the Athabasca Basin region, which hosts a substantial proportion of Canadian uranium resources.The crystalline basement complex was subdivided by Lewry and Sibbald (1979) into lithostructural domains and these domains were grouped into major crustal units designated, from northwest to southeast, as Western Craton, Cree Lake Mobile Zone, consisting of Wollaston, Mudjatic and Virgin River domains, and Rottenstone Complex (Fig. 1)."

Jan 1, 1986

By H. C. Cooke

"This paper has reference in a general way to the region extending from the north shore of lake Buron to the northern limit of the elliptical-shaped area generally known as the Sudbury Basin, and more especially to the district lying south of the Basin (Fig. 3). Attention is concentrated mainly on the structure of the district and, as space does not permit of much geological description, it is assumed that the reader has some knowledge of the general geology. The accompanying table outlines the sequence of the rock formations according to the most recent available information; for further details the interested reader may consult the publications of the various authors mentioned in the paper.STRUCTURE OF THE SEDIMENTARY ROCKS SOUTH OF THE SUDBURY IRRUPTIVEThe rocks south of the Sudbury irruptive, excluding certain intrusives, are, in order from north to south:(1) A band of basic lavas.(2) A band of well-bedded greywackes and quartzites, long termed the McKim greywacke.(3) The Copper Cliff formation, with McKim greywacke' both to the north and south.(4) The Ramsay Lake conglomerate.(5) A thick quartzite formation.All these rocks strike approximately east-northeast, dip steeply south, and generally face south, though there are local exceptions."

Jan 1, 1954

By F. Cheuk, E. Krause, V. G. Papangelakis, G. A. Moldoveanu, S. Abendschein

Systematic studies have been conducted at the University of Toronto in order to evaluate lanthanide extraction from clay minerals from different geographical regions. It was found that rare earth elements (REE) are easily recovered into an aqueous solution via an ion exchange mechanism by leaching with electrolyte solutions containing monovalent cations under ambient conditions. In this study we assessed extraction levels of individual REEs as a function of initial clay composition and leaching conditions. It was found that, in spite of variations in clay origin, all clays consistently reached peak REE extraction levels with fast kinetics. However, terminal extractions were clay-specific. The feasibility of using seawater as a leaching solution and potential synergies with ammonium sulphate as a lixiviant was also investigated. Seawater was found to be inferior to using ammonium sulphate, and provided no observable synergy in leaching performance when used together. The aqueous phase trapped in leached clays was shown to contain significant amounts of REE, as demonstrated in clay washing tests. Techniques to improve the REE concentration in leachate through process variations were investigated. However, it was found that most techniques capable of increasing REE concentrations in the resultant leachate also resulted in reduced REE extraction.

Jan 1, 2014

By D. Saramak, Z. Naziemiec

"Chalcedonite is an unique rock due to the relatively small area of its occurrence. It also possesses multi-raw-material features therefore it should be given a special protection aiming at its complete and optimal utilization. It is the natural sedimentary rock and the only mine in Poland, located in Inowlodz, where the opencast mining from “Teofilow” deposit is carried out.Chalcedonite mainly consists of cryptocrystalline and microcrystalline chalcedony together with small amounts of autogenous and detrital quartz. The chalcedony itself is a fairy common mineral and many forms of its occurrence is known, some of them are semi-precious minerals. Among the most popular ones following can be found: agate, bloodstone, onyx, carnelian, chrysoprase. Many countries own chalcedony deposits: Australia, Brazil, India, Canada, Namibia Russia, South Africa. However chalcedony in its pure form does not occur in the mentioned chalcedonite rock. The pores, which take usually from 5% to 25% of volume and have sizes smaller than 0.5 mm, are the characteristic feature of all chalcedonite forms. The paper presents some crucial problems of its processing together with most significant directions of its applications. New method of chalcedonite enrichment based on densimetric separation (patented in Poland) is presented. Results of investigation show that the obtained products can increase quality of concrete and filter grits."

Jan 1, 2016

By Sadan Kelebek, Gerhard W. Heinrich, Peter F. Wells, Peter J. Whittaker

"Based on plant mineralogical data & circuit modelling, a pilot plant campaign was conducted at Strathcona Mill to identify options for improving the performance and operating flexibility of the copper-nickel separation circuits. Emphasis was given to options for combined treatment of the two feed streams (primary nickel ore rougher concentrate and copper ore circuit concentrate) to obtain more flexibility in the use of existing column flotation capacities. The pilot test results demonstrated that circuits which incorporated preconcentration prior to column flotation gave the best metallurgical results. Maximum column carrying rates were also related to the preconcentration. Predictions that increased circulating loads from the column scavengers would improve copper-nickel separation performance were confirmed.IntroductionThe copper-nickel separation circuits at Falconbridge's Strathcona Mill produce a high grade (>30% Cu) copper concentrate most of which is treated at the Falconbridge Kidd Creek smelter near Timmins. The remaining nickel concentrate which still contains approximately 20% of the feed copper is combined with other lower grade nickel/copper concentrates and shipped to the Falconbridge nickel smelter. The separation is required because of the limited capacity for copper processing in and downstream from the nickel smelter. Since no nickel is recovered at present in the Kidd smelter, the challenge is to minimize the nickel content of the copper concentrate.At present there are two independent separation circuits treating the rougher concentrates from the copper and nickel circuits as shown in Figure I. The minerals treated are mainly chalcopyrite and pentlandite but there is up to 25% of the copper present as cubanite in the copper ore. The circuits were kept separate because the flotation rates and froth characteristics were very different, probably because of the presence of cubanite and the large difference in the concentrate grades feeding the circuits."

Jan 1, 1995