Search Documents

By Ken G. Stowe, Stephen L. Chryssoulis, Christian Bendel, Joe Y. Kim, Ewald Niehuis

"TOF-SIMS (Time-of-flight secondary ion mass spectrometry) was used to detect collectors sorbed onto the surface of mineral particles in concentrate and tailings samples from the Brunswick, Matagami and Kidd Creek concentrators. This technique uses ion beams from either Cs or Ga sources to sputter the particle surface, a method which reduces fractionation of the collector molecule during sampling.In the Brunswick Zn circuit, sphalerite particles lost to the scavenger tails had less amyl xanthate and isobutyl xanthate compared to sphalerite recovered to the Zn final concentrate. Xanthates were detected on the surface of sphalerite particles floating to the CuPb final concentrate.At Matagami, significantly more isopropyl xanthate and isobutyl dithiophosphate were detected on sphalerite recovered to the Zn final concentrate, compared to sphalerite lost in the Zn rougher tails.In the Zn circuit of Kidd Creek, sphalerite lost to the tails had on average ten times less xanthate compared to sphalerite recovered into the Zn final concentrate. Xanthate was also detected on the floated pyrite particles. In addition to isobutyl xanthate, amyl xanthate was also detected on the floated sphalerite and pyrite particles.This preliminary investigation has (a) demonstrated the ability of TOF-SIMS to detect individual collectors on particle surfaces from plant samples and (b) shown that TOF- SIMS is an excellent tool, complimentary to TOF-LIMS, in establishing the surface chemistry of minerals as related to mineral processing."

Jan 1, 1995

By V. I. Lakshmanan

Rare earth elements and yttrium (REEs+Y) are being used in the making of hybrid electric cars, catalytic converters, wind power generators, LEDs, hard disc drives, flat panel displays, and portable electronics. Currently China produces more than 95% of REEs+Y, which has made REEs+Y a critical strategic resource. Process Research ORTECH Inc. (PRO) has developed the innovative mixed-chloride (HCl+MgCl2) solvent extraction processes for recovery of REEs+Y from their ores. The HCl leaching system provides the opportunity to regenerate the acid, while the presence of MgCl2 in the lixiviant enhances the activity of the hydrogen ion by orders of magnitude, making the lixiviant very aggressive and resulting in high recoveries of REEs+Y. Solvent extraction steps are used for separation and purification of REEs+Y from other value metals or impurities including iron, zirconium, hafnium, uranium, thorium, niobium, tantalum and titanium. Direct individual separation of REEs+Y in a mixed chloride system allows avoiding the additional process steps of precipitation and dissolution in HCl. The resulting process has a simplified flow sheet that is closed-loop and environmentally friendly.

Jan 1, 2014

By Louise Laverdure

Outline ?Background ?Issues and considerations ?Why do we need to innovate ?Green Mining Initiative ?Footprint reduction ?Innovation in waste management ?Ecosystem risk management ?Mine closure and rehabilitation ?The Future

May 1, 2011

By Yan Qun, Chen Xiao-ming, Ma Pei-long, Luo Xian-ping, Luo Cai-gui, Feng Bo

The effect of leach promoting reagent LPF on the leaching process of a weathered crust elution-deposited rare earth ore has been investigated and the mechanism is discussed. The result shows that the leach promoting reagent LPF can enhance the leaching extraction of rare earth ore effectively. With the addition of LPF to the lixiviant at a concentration of 0.1%, the leaching extraction increased by more than 8%, the ammonium sulfate concentration could be decreased by 25%, and the leaching liquid/solid ratio reduced by 34%. The mechanism analysis shows that LPF can react with rare earth ions and form soluble coordination compounds, thus reducing the activity of the leached rare earth ions, increasing the concentration difference for ion diffusion, and promoting the rare earth leaching process. These results will hopefully help point to a new approach to making the leaching process of low-grade weathered crust elution-deposited rare earth ore more efficient and with lower lixiviant consumption.

Jan 1, 2014

By P. R. A. Andrews

"The sillimanite group minerals, kyanite, sillimanite and andalusite are identified as alumino-silicate minerals with the common chemical composition AIP3.Si02' so that each possesses similar physical properties. Kyanite is the most abundant mineral and mainly occurs in Quebec, Ontario and British Columbia; sillimanite occurs in Ontario and Manitoba; and andalusite in Nova Scotia. The main use for the sillimanite-group minerals is in refractory applications for the production of refractory bricks and shapes. In refractory applications, the main performance criterion is the relative percentage of mullite formed within the material during firing. This phase gives a greater degree of resistance to creep deformation and slag attack, and improves the ability of the refractory to withstand high temperatures under load. The beneficiation of refractory silicate minerals has been the subject of many investigations at CANMET, and the former Mines Branch. Eighteen kyanite, two sillimanite, and three andalusite evaluation studies were conducted between 1933 and 1987. A review of some of the more important studies is presented, which includes information concerning mineralogy, beneficiation methods and flotation data."

Jan 1, 1995

By Michel Ruel, Ali Soltanzadeh

This paper describes how to make advanced control choices when difficult processes need improvement. The decision-making process involves choosing between a rules-based approach and a model-based approach as well as weighing benefits and drawbacks, complexity and simplicity, investment and results. This paper will present briefly each solution: basic control, advanced regulatory control, model predictive control and expert systems such as fuzzy logic controllers and neural networks. Three examples are presented: ARC (Advanced Regulatory Control) on pH in a comminution circuit, MPC (Model Predictive Control) for combustible management and FLC (Fuzzy Logic Control) on a Semi Autogenous Mill. The article then proposes a decision tree for selecting the most appropriate approach. A table will compare usage, development, commissioning, maintenance and lifecycle costs for each approach. Finally, conclusions and suggestions will summarize the methodology.

Jan 1, 2014

By A. J. Sinclair

Abstract-Exploratory data evaluation is an essential part of every high quality, mineral inventory estimate. Efficient analysis involves a thorough organization of available quantitative data that are the basis of the estimate and perhaps the formation of composite grades. Data organization and evaluation can involve more than 50% of the time necessary to conduct a mineral inventory estimation. The principal purpose of exploratory data evaluation in mineral inventory work is to improve the quality of estimation by providing insight into characteristics of the variables under investigation. Specific aims include: (1) to recognize and eliminate errors; (2) to provide a comprehensive knowledge of the statistical characteristics of all variables of interest for resource/reserve estimation; (3) to document and understand the interrelationships among the variables of interest; (4) to recognize systematic spatial variation of variables such as grade and thickness of mineralized zones; (5) to recognize and define distinctive geological domains that require independent estimation of mineral inventory; (6) to identify and characterize outliers; and (7) to evaluate similarity/dissimilarity of various types of raw data, especially samples of different supports. These aims are not mutually exclusive but they can all have their own impact on resource/reserve estimation. Error must be minimized. Individual variables can have characteristics that lead to different decisions in the course of estimation. Similarly, interrelations of variables might contribute to the ease (or difficulty) with which estimates of several variables can be obtained. Trends can impose the need for two or more domains, each of which might be estimated independent of the others. Outliers, a perennial problem, require detailed evaluations because they impact on reserves much out of proportion to their abundance. Data, of widely different supports, generally must be standardized if all are to be used for purposes of estimation.

Jan 1, 1998

By A. Dunnett, N. J. Turner, J. Koyanagi, M. Ji

The analysis of rare earth element (REE) samples is a necessary part of the metallurgical process for rare-earth bearing ores, providing invaluable information during testing procedures. This requires a fast, multi-element technique, capable of analyzing a variety of matrices for all rare earth elements. X-ray Fluorescence spectrometry and Instrumental Neutron Activation Analysis are typically used for high concentrations of REE, but they have limitations for some process work applications due to an inability to measure all elements, longer analysis times, significant interferences and elevated detection levels. The work reported here uses new approaches with Inductively Coupled Plasma Mass Spectrometry (ICP-MS) in order to achieve high precision and accuracy within acceptable timeframes. A combination of aerosol dilution and Kinetic Energy Discrimination (KED) produce a process solution assay method that is robust enough to deal with changing sample matrices and concentrations, whilst maintaining low reporting limits and precisions of less than 5% Relative Standard Deviation (RSD). For high concentration metallurgical and geological samples, a sodium peroxide fusion digestion procedure was used, followed by ICP-MS analysis using extended dynamic range (EDR) and KED. Using these technologies, it has been demonstrated that the necessary support can be given to metallurgical process work for REE extraction.

Jan 1, 2014

By S. M. Bulatovic, D. M. Wyslouzil, K. R. Rawlings

"The suitability of a new organic reagent DS20 as a depressant for oxidized and carbonaceous pyritic lead-zinc ore from Nanisivik Mines Ltd. has been evaluated in the laboratory and in the plant.The depressant DS20 is a mixture of Lignosulphonate-Dextrin-Quebracho and was developed specifically for depression of highly oxidized and carbonaceous pyrite.The laboratory test work indicated that the poor metallurgy resulting from the oxidized ore could be improved to normal plant performance by the addition of the DS20 depressant with the existing plant reagents. The laboratory data suggested that lime consumption could be reduced when using DS20.In this paper, the development work and the plant trials with DS20 are described.INTRODUCTIONNanisivik Mines Ltd. treats approximately 2000 tonnes per day of lead-zinc massive sulphide ore, containing currently 1% Pb and 9% Zn. The concentrator operations have been described previously (1,2) and typical metallurgical performance is detailed in Table I.The concentrator flowsheet (Figure No. 1) and the standard reagent scheme (Table No. 2) demonstrate the relative simplicity of treatment of this coarse grained ore.A recently discovered satellite orebody - Area 14 - containing 2% Pb and 12% Zn was brought into production in October 1983. This ore had been oxidized to varying degrees by ground water; the pyrite mineralization was found to be very fast floating and a carbonaceous constituent present in higher than normal proportion also affected flotation. The simple high lime addition could not control the pyrite, and very low grade lead concentrates resulted; zinc metallurgy was also affected by this oxidized condition (Table 3)."

Jan 1, 1986

By Frands Jensen, Erik Eriksson

"Haldor Topsoe’s Wet gas Sulfuric Acid (WSA) technology has been proven in a number of industries converting sulfurous gasses to concentrated sulfuric acid. In the metallurgical sector plants have been delivered handling SO2 gasses from copper, zinc, molybdenum, and lead ore. WSA has high energy efficiency and allows autothermal operation from feed gas strengths as low as 3.0% (volume). Recent variants of the WSA process have been developed that allow very high SO2 conversion efficiencies of over 99.9%. This paper describes the technology, its advantages and industrial achievements.The WSA technology is well suited for production of concentrated sulfuric acid of commercial quality from the sulfur dioxide (SO2) gas that inevitably emerges from the metallurgical processes. Some of the features that make the WSA technology attractive for this application are:- High SO2 conversion rates (up to 99.99%)- High energy efficiency leading to a low autothermal point (~ 3% SO2)- No need for gas cooling and drying to produce concentrated sulfuric acid- No production of waste- Very low cooling water consumptionThis paper describes the WSA process principles and highlights features that make this process attractive for handling SO2 gases."

Jan 1, 2014

By K. Sawada

Along with the expanding demand of copper concentrate in Asian countries, custom-smelters have confronted with difficulties of low TC/RC. Now, Japanese Copper Industry have 2 options; investment in mine development and/or recycling of copper scraps. The strategy of global mining companies is analyzed, and implications for Japanese Copper Industry will be discussed from the viewpoint of sustainability of smelters in Japan.

Jan 1, 2014

By J. Severin

Surface mining operations are increasingly involving the design and development of deeper and larger open pits, often with plans to transition into underground mass mining operations. Experiences at the Palabora Mine in South Africa demonstrate the complex interactions between underground workings and the steep slopes above that may lead to slope movements that potentially pose safety and economic concerns. To properly assess the rock mass response to these interactions for planning of future developments, understanding the controlling influence of geological and geomechanical structures is crucial. Preliminary results are presented from a detailed review of historical slope monitoring data from the Palabora Mine, before and after the initiation of block caving 400-m beneath a 800-m deep pit. This paper demonstrates that a detailed analysis of geology and monitoring data can be used to better understand the kinematic controls of complex rock slope displacements and interactions between open pits and underground mines. This investigative treatment of the monitoring data is important in understanding the failure mechanisms prior to undertaking sophisticated 3-D numerical models.

May 1, 2009

By Y. Hou, E. Arinaitwe, L. Tong

A series of dense medium separation (DMS) tests were performed on four low-grade copper ores from Mount Polley mine in order to determine their amenability to pre-concentration. The tested ores contained disseminated sulphides, mostly chalcopyrite with low copper grades (0.15% - 0.2%) and relatively high iron grades (4.76% - 5.63%). The samples were screened into different size fractions ranging from 9.5 mm to 50.8 mm and DMS tests were performed on each size fraction at various separation densities. The pre-concentration efficiency at different size fractions and separation densities was evaluated in terms of metal upgrading and distribution. Mineralogical tests were also performed on selected DMS sink and float samples in order to understand the influence of mineralogy on the pre-concentration efficiency. The results showed that significant copper upgrading was achieved for intermediate size fractions only at the highest separation density tested. The copper recoveries generally increased with particle size at all separation densities. However, it was impossible to upgrade the copper content in the ores and achieve acceptable recoveries and mass rejections at the same time. Copper recoveries and grades showed a strong correlation with iron recoveries and grades indicating that it is possible to pre-concentrate copper by recovering magnetite and other iron-containing minerals in the ore. Overall, the results suggest that the optimum separation density and pre-concentration efficiency is a function of particle size, and that the ore mineralization properties limit the performance of DMS as a pre-concentration technology for such low-grade disseminated ores.

Jan 1, 2014

By Ken McClure, Alex Day

Located North of Williams Lake British Columbia, Gibraltar Mine is the fourth largest open pit Copper mine in North America. Gibraltar commenced Copper concentrate production in 1972 with a mill throughput rate of 30,000 tons per day. A series of expansion projects, including installation of a second SAG mill with variable speed drives in 2013, has increased mill throughput to 85,000 tons per day. Over the past 24 months, Gibraltar Mine in partnership with Spartan Controls has executed several advanced process control programming projects culminating in the implementation of a Continuous Speed Controller (CSC) for the most recently installed SAG mill. This paper covers development and results for the SAG mill speed controller. INTRODUCTION In January 2016, the price of Copper fell below $2.00 USD per pound, the lowest price in 7 years. Gibraltar Mine faced a significant challenge; how to maximize profit in an environment where capital spending was not an option. An opportunity was quickly identified to improve performance through increased automation and advanced control of the grinding processes. Beginning in March 2016, Gibraltar Mine partnered with Spartan Controls to introduce Advanced Process Control (APC) to the grinding circuits. The collaboration between metallurgical and process control engineering disciplines proved to be effective for achieving gains in throughput, reliability and productivity for the mill process. The Gibraltar milling facilities include 2 grinding-flotation plants for concentration of chalcopyrite ore with throughput rates of 58,000 tons per day (Concentrator 1) and 38,000 tons per day (Concentrator 2). Each of the two concentrators has a 34’ diameter SAG mill powered by 2 GE 4800 kW synchronous electric motors. For SAG 1 (in concentrator 1), power is transmitted through 2 Eaton Airflex clutches. For SAG 2 (in concentrator 2), the motors are driven by 2 TMEIC Variable Frequency Drives (VFDs). All programming is done using DeltaV, which Gibraltar uses as its Distributed Control System (DCS) and Human Machine Interface (HMI).

Jan 1, 2019

By Z. Liang, Z. Q. Liu, X. F. Li, H. L. Zhang

"Dynamic characteristics of frozen soil is important for the safe, effective and rapid construction in cold regions and artificially frozen engineering. In this paper, dynamic characteristics of frozen clay with various low temperature and different strain rate were studied by using Split Hopkinson Pressure Bar (SHPB) test and numerical simulation test. Variation of dynamical parameters and dynamic stress-strain curves of frozen clay were obtained and analyzed. The results of these test show that: Frozen clay exhibits temperature effect and strain rate effect that the failure type tends from plastic failure to brittle failure with the increase of strain rate or decrease of temperature; Under impact loading, frozen clay exhibits three typical dynamic stress-strain curves as strain rate increases, and the maximum strain of frozen clay only linear increases with strain rate.INTRODUCTIONArtificial freezing technology has been widely used in the construction of underground engineering, such as the coal mine shaft, the deep foundation pit, the urban metro and subsea tunnel, etc. Research on dynamic mechanical behavior of artificial frozen soil will provide supports for these artificially frozen engineering (Xu et al. 1998; Ma 2009). However, the dynamic mechanical research on frozen soil is mainly carried out at low frequencies or small amplitudes of the waves, behavior of frozen soil under impact loads or high strain rate loads has not been made clear."

Jan 1, 2015

By G. J. Desroches, E. Ozberk, M. J. Collins, B. D. Krysa, I. M. Masters

The zinc refinery of Hudson Bay Mining and Smelting Co., Ltd. went through a major modernization in 1993, when the roaster and the calcine and fume leach circuits were replaced by a new Sherritt zinc pressure leach plant. The HBMS plant, in Flin Ron, Manitoba, represents the first commercial application of the Sherritt two-stage zinc pressure leach process, with /00% of the zinc concentrate feed processed in autoclaves. The process design of the new plant required definition of the deportments of elements such as antimony, arsenic, chlorine, cobalt, fluorine, germanium, magnesium, manganese, selenium, tellurium and thallium. This paper describes the deportment of these elements in the commercial zinc plant during the first nine months of pressure leach operation, and compares these results with operations prior to the introduction of pressure leaching, and with the results of tests carried out in the She"itt laboratory during the process development phase.

Jan 1, 1995

By X. Cao, X. -G. Chen, K. Liu

Due to the detrimental effect of platelet iron-rich intermetallics on mechanical properties (particularly ductility) in cast alloys, it has been essential to transform these phases into Chinese script morphology. In the present work, the effects of Mn and/or Si addition and cooling rate on the phase transformation of the iron-rich intermetallics in 206 cast alloys with different Fe contents ranging from 0.15 % to 0.5 % were systematically investigated. The results obtained showed that platelet ß-Fe and Al3(FeMn), Chinese script a-Fe, Alm(FeMn) and Al6(FeMn) can be observed in the 206 cast alloys, depending on the Fe, Mn and Si contents as well as the cooling rate. It was found that the addition of either Mn or Si favors the formation of Chinese script iron-rich intermetallics but inhibits the precipitation of the platelet phases. In addition, the combined addition of both Mn and Si has a synergistic effect on the phase transformation. Furthermore, there exists a critical cooling rate to effectively suppress the formation of platelet iron-rich intermetallics for a given alloy. The threshold cooling rate decreases with increasing Fe, Mn and Si contents. Casting process maps are established to correlate the intermetallics precipitated with alloy chemistry and cooling rate for 206 cast alloys containing various Fe levels.

Jan 1, 2014

The control of carbon concentration in a counter current carbon absorption circuit is critical to optimise gold recovery. MINTEK has developed a carbon movement controller to address this potentially problematic area in gold extraction. This controller reduces operator interaction by automating carbon movement. Elution schedules are entered into the control system, which then moves the carbon through the circuit into the first adsorption tank until enough carbon is available for elution. This is done while maintaining the specified carbon profile within the circuit. MINTEK has also developed an online-carbonconcentration- meter to measure carbon concentration in pulp. The meter uses an ultrasonic measurement technique. Long term testing has shown the measurement to be robust and require minimal maintenance. Results from a gold mine in South Africa’s well known Witwatersrand gold producing area has shown a decrease in soluble gold loss between 30 - 50% when the controller was used.

Jan 1, 2014

By A. Kishimoto, Yoshida Honmachi, T. Uda, Y. Taninouchi

Recycling of e-scrap is often performed by utilizing a pyrometallurgical Cu smelting process. Several valuable metals, including precious metals, can be efficiently recovered through the Cu smelting process. However, recovery of Sn is quite difficult because it is distributed in slag during the smelting process. Sn is used as solder and plating in electronic devices, and its recycling will be more important in the future. In light of this background, a pretreatment process that can extract Sn directly and selectively from e-scrap was developed in this study. The proposed Sn extraction process involves alkaline leaching using iodate ions, IO 3, as an oxidizing agent. We conducted leaching experiments for Sn, Sn-Ag-Cu alloy solder, and Cu, and the effective dissolution of Sn was confirmed. In principle, the electrodeposition of Sn from the leach solution and regeneration of IO3 are possible by a subsequent electrolysis process. The results obtained in this study suggest that the proposed leaching process can be an effective and useful pretreatment for Cu-smelting-based e-scrap recycling. INTRODUCTION Electronic scrap (e-scrap), including waste printed circuit boards (PCBs), is one of the fastest growing waste treatment streams in the global urban environment. E-scrap contains numerous valuable metallic elements, including Cu, Sn, and precious metals, in rich quantity. Furthermore, some metals and other materials contained in e- scrap are hazardous to human health and the environment when they are not properly managed. The recycling of e- scrap is therefore a major concern in terms of resource supply and waste treatment, and it has been performed by many companies using a variety of methods.

Jan 1, 2019

Accurately modeling and predicting long term mill throughput is one of the challenges facing metallurgists, geologists and mine engineers in their quest to consistently deliver accurate life of mine business plans. Batu Hijau has systematically improved long and short term mill throughput predictions since feasibility and commissioning in 1999. This has been achieved through a combination of ongoing improvement to the geology ore hardness and grade characterisation model, drill and blast optimisation and, by application of these data to model mill throughput. Batu Hijau has demonstrated the ability to consistently estimate long term mill throughput within ±2% accuracy. Aside from reliably predicting expected production rates with the existing plant configuration, this predictive ability provides a solid foundation for identifying operating and design criteria for short term grinding circuit optimisation and future expansions. This paper discusses ongoing throughput prediction model development at Batu Hijau based on geo-metallurgical characterisation. Also discussed are tools used for day to day production performance management. This includes on line "Mine to Mill" variable monitoring to improve operations parameter ecision making and performance assessment.

Nov 1, 2011