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By R. B. Throndycraft

"1. Belt-Drop Agglomeration Preferred at Heap Leach Operations. The agglomeration method now preferred at heap leach operations utilizes belt-drops along conveyors. Belt-drop agglomeration is being designed into numerous upcoming heap leach operations. It offers substantial capital cost savings over previously favored drum agglomerators. It has such significant operating and maintenance advantages that some drum agglomerators have been retired in favor of belt-drops.The majority of heap leach operations are now built with crushing included in the flowsheet. If crushing is included, belt-drop agglomeration can be added for almost no cost. The agglomeration equipment is simply a few conveyor transfers, designed to provide the tumbling and rolling action which forms the agglomerates. Controlled water sprays are needed at each of these agglomeration transfers. Cement or lime is added as a binder, to stabilize the agglomerates. This reagent is also needed to raise pH to safe operating levels.Addition of the pH control reagent before stacking the ore offers a reagent cost benefit. In the belt-drop mixing technique, the ore is intimately mixed with the lime (or cement). After stacking on the heaps, when the cyanide solution is sprayed onto the high-ph ore, very little cyanide is consumed. Without the pre-addition of lime or cement, the leach solution is sprayed onto neutral ore. The mixture of high-pH leach solution and neutral pH ore causes the solution pH to drop, releasing cyanide gas. This release is minor from a safety viewpoint, much less than dangerous, but the gas release is a costly waste of the cyanide reagent. Pilot-scale comparison tests were made at Pinson. Ore pre-treated with lime or cement showed 30% less cyanide consumption than untreated ore."

Jan 1, 1989

By D. D. Tannant

An experimental and numerical study was conducted on the geomechanical behaviour of oil sands during penetration tests in which a steel wedge with an apex angle of either 20 degrees or 30 degrees was forced into compacted oil sands. The boundary conditions simulated in the laboratory tests are similar to shovel penetration into oil sands. The objective of the laboratory tests was to measure the force required to push a steel wedge into compacted oil sands. A wedge penetration test differs from conventional triaxial tests in that much more shear is generated. The laboratory data was needed to improve calibration of micro-mechanical input parameters for a two-dimensional discrete element model of oil sands constructed with Particle Flow Code (PFC). Initial model calibration was performed with triaxial test data and then a PFC model of the wedge penetration test was constructed. The measured force-displacement behaviour of the steel wedge was compared with PFC modelling results. It was found that different combinations of PFC particle and bond parameters could equally well replicate the laboratory triaxial compression data for bitumen-rich oil sands. When the wedge model was run, it was found that the resulting force required to penetrate the wedge into the oil sands was about four to six times higher than that measured. This clearly indicates that further research is required to improve the predictive capability of PFC models of oil sands.

Jan 1, 2002

By Gregg Hodges, Fred Schoenbrunn, Steve Slottee, Chad McCleary

"In December, 1999 Stillwater Mining Company (SMC) commissioned a new paste /cement backfill plant to supplement the existing sand backfill system for the cut and fill mining operation at it’s Nye, Montana mine. The new plant uses the Baker Process Deep Cone TM Paste Thickener to thicken the total concentrator tailings from 30% solids slurry to a 71% solids paste. This paper describes both general paste formation concepts and the evolution of the SMC paste plant operation from original design criteria, through problem solving and plant modifications, to the operation of the existing plant.Although the original process design was not effective for consistently producing and delivering acceptable paste to the stopes for backfill, SMC was able to make the mechanical and process modifications which allow the plant to now produce and deliver an acceptable product to the stopes. Ongoing test work is targeted at increasing the pumping range of the system, increasing the paste solids concentration from the Deep Cone Paste Thickener and reducing the operating and maintenance costs of the system.INTRODUCTIONThe authors would like to thank both Stillwater Mining Company (SMC) and Baker Process for their assistance in the preparation of this paper. Stillwater Mining Company chose not to participate directly in this paper due to time constraints, but was very helpful in answering questions concerning their approach to problem solving and specific details with regard to engineering criteria.This paper will begin with a general review of the technical and mechanical concepts in paste formation and then focus on the overall design, start-up and problem solving process for the paste backfill operation at SMC’s mine and concentrator near Nye, Montana."

Jan 1, 2001

By Tony Robles

"A new process is disclosed for the recovery of gold and/or silver values from activated carbon wherein they are adsorbed as cyanide complexes. A unique chemistry allows the new process to use mill process water containing an inexpensive, non-hazardous compound as the eluant. The new process has an elution period of 5 hours at 98°C. The gold in the eluant can be recovered by electrowinning or zinc precipitation. The new elution process is simple, reliable, and provides an eluted carbon that may not require thermal regeneration before reuse. Retrofitting the new process to existing processes such as Zadra, Anglo, and others will not require significant capital expenditures.IntroductionThe efficient and reliable elution process for gold/silver from activated carbon is a very important process in the gold mining industry. The most common techniques for elution of gold cyanide from activated carbon are the Zadra and Anglo procedures.Specialized elution techniques like the Micron and Acetonitrile processes have not been commercialized to significant extent probably due to relatively complex unit operations and expensive reagents.Important functions of the gold recovery circuit are:Efficiently recover gold/silver from the loaded carbon.Carbon is in good condition for reuse for optimum recovery.The pregnant solution is amenable to electrowinning or zinc precipitation to recover gold/silver from the solution.The whole process to be simple and short to reduce gold inventories.Present Elution ProcessesTable 1 shows some carbon elution processes that are available today. The two main elution processes used in the industry are: (1) the Zadra process, in which hot cyanide solution is circulated through an elution column and electrowinning cells; and (2) the Anglo American Research Laboratory (Anglo) process, consisting of a pretreatment step with caustic cyanide solution, followed by elution with deionized water."

Jan 1, 2000

By Ken Wood

"A reliable source of water of an acceptable quality is vital to the success of any mineral processing plant using wet methods. For Cerro Verde, a new 108,000 t/d copper mill in southern Peru, the main source of raw water is the Chili River. The Chili River is heavily contaminated with raw sewage, industrial wastewater and agricultural runoff, and can also receive high sediment loads during the rainy season. The initial water treatment plant could not supply design flows of water due to the exceptionally poor water quality. Problems with treated water quality caused significant difficulties with water consuming equipment, such as the plant cooling systems. This paper details the Cerro Verde water system and changes from design through to start up from a mineral processing perspective.INTRODUCTIONMining, and mineral processing in particular, is a water intensive activity. Improving water system design and practice are key strategic requirements in moving toward a more sustainable mining industry. This case study forms a basis for ongoing research into water use and reuse at mines and mineral process plants, conducted by AJ Gunson, under the supervision of Dr. Bern Klein and Dr. Marcello Veiga at the University of British Columbia. The case study material was gathered through involvement with the design, startup, and redesign of the Cerro Verde water system.Cerro Verde is a low-grade copper porphyry mine, located near the city of Arequipa in southern Peru, at an elevation approaching 2,800 m. In 1972, one of the world’s first copper Solvent Extraction – Electrowinning (SX/EW) facilities was built on the site, processing oxide ore from two main open pits. In 2004, the operator, Sociedad Minera Cerro Verde S.A.A. (SMCV), approved a 108,000 t/d expansion project to process sulfide ore reserves through a new concentrator plant. The plant was designed under extremely tight schedule and capital constraints, with a mandate to intentionally avoid any overdesign."

Jan 1, 2008

By S. Cossio, J. L. Noyola, R. Espinosa

"Minera Penmont’s La Herradura is a joint venture between Industrias Peñoles, S.A. de C.V. and Newmont Mining Corporation. The mine is located in the northern Mexican state of Sonora. La Herradura consists of an open pit mine with a two-stage crushing plant and heap leaching facility. Gold is recovered from the pregnant solution using the Merrill-Crowe process; production began in July 1998. La Herradura produces about 130 000 oz gold per year and its treatment capacity is approximately 22 000 t/d. Ore mineralization occurs in a shear zone with quartz and native gold. Gold distribution is quite heterogeneous due to coarse visible gold, which in some cases ranges from 100 to 600 microns.Sampling and assaying protocols were established during exploration and prior to start-up of operations, based on nomographs developed from early heterogeneity tests. However, as the coarse gold problem became noticeable, it was necessary to develop new sampling protocols to have an acceptable relative standard deviation to control the fundamental error within ± 15%.An experimental program was developed and conducted on a selected ore block consisting of 195 blastholes; regular ore grade control procedures were applied to both sets of data to evaluate the difference in results between the protocol established prior to start-up of operations (existing) and the new protocol (leaching). In the existing protocol, sub-sampling is done through riffle splitters, and coning and quartering. Fire assaying was used to estimate the gold content on a 50 g sample. In the leaching protocol, a 12 000 g sample of bottle-rolled cyanide was leached, and the leach residue was assayed on a 50 g sample using fire assaying, and a weighted average total gold content was calculated. Currently, a new alternative method is being evaluated, where sub-sampling is done using rotary splitters, and fire assay on a 50 g sample; in this rotary sampling protocol and for comparison purposes, gold assays were also repeated using the leaching protocol.Test results were compared in three groups: < 0.3 g/t (below cut-off), 0.3 to 0.8 g/t, and >0.8 g/t. Overall, results show that the protocol established prior to start-up of operations underestimates the gold assays. Detailed technical results, alternative options, and their implications are discussed in the paper."

Jan 1, 2004

By J. A. Finch

"Gas dispersion in flotation defines the efficiency of the process once the chemistry has been established. There are three measurements, superficial gas velocity, gas holdup, and bubble size, which along with the derived quantity bubble surface area flux, are used to define “gas dispersion.” Sensors for measuring gas dispersion in industrial machines have been developed. This communication describes the working principle of the techniques and illustrates their potential to detect problems and to improve the operation of individual cells, banks and circuits. IntroductionFlotation is the most widely used process to separate minerals and is finding increasing application in other chemical and environmental fields. The process exploits natural and induced hydrophobicity to collect selected particles on the surface of a bubble. Once the process chemistry to control hydrophobicity has been established, the efficiency depends on dispersion of air to generate the necessary bubble surface area. Bubble surface area flux, Sb, the interfacial area generated per unit time and unit area of the machine, is emerging as one of the most useful variables to quantify gas dispersion (Gorain et al., 1997, 1998) although not without its critics (Heiskenan et al., 2001).For a bubble population of mean size db at a superficial gas velocity (or rate) Jg, the bubble surface area flux can be derived from geometric considerations (Finch et al., 1999):"

Jan 1, 2002

By V. Coffin, T. Cienski

"(Figure 1) Reagentized pulp enters into the column at about 1/4 of the distance from the top. Inside the column it meets with a downward flowing stream of water and with an upward flowing mass of air bubbles. Flotation takes place in this counter current system while at the same time fine gangue particles are washed off the froth before it reaches the overflow lip at the top of the column. The main operating features of the column flotation are as follows:a) No moving parts. Solids are kept in suspention not by an agitating action of a propeller but by settling down against the rising air bubbles.b) Wash water. Spray pipes are installed a few inches below the froth surface and deliver required volume of water. The purpose of this water is twofold:(i) it keeps in balance the flow of material through the column and(ii) it washes rising froth in the froth layer as well as removes unwanted fines attached to the bubbles at the lower flotation section. As a result the concentrate produced is of higher purity than in the conventional flotation. Column is characterized by very high up-grading. However, even temporary disruption of wash water supply results in a drastic drop of concentrate grate.c) Flow balance. (Figure 2) For the correct operation volume of the underflow (tail) is larger than that of the feed. The difference is made up by the wash water. This difference called bias is predetermined and ranges from some 4 to 15 USGPM depending on the size of the unit and process requirements."

Jan 1, 1981

By A. Y. Senchenko, Y. V. Kulikov

"Different methods aiming at specific energy calculation and design of AG/SAG circuits are used in mining. They include JK DWT/SMC test, SAGDesign test and CWi/RWi/BWi tests. The simplest methods with no secret equations and giving energy required for grinding in kWh/t were proposed by F.?. Bond and J.H. Starkey. D.J. Barratt proposed to use results of CWi/RWi/BWi tests for AG/SAG mill sizing. The present paper gives an alternative for forecast of specific AG/SAG energy. The principle is similar to the theory proposed earlier and consists in cumulative AG/SAG energy calculation using indices of rod and ball grinding (RWi+BWi) without impact crushing index (CWi). Then total energy is divided between two grinding stages using special formulas based on extensive statistical information. The forecast indices of AG/SAG and ball grinding are similar to the SAGDesign testing results. Hereinafter the predicted indices are used for mill sizing of the whole grinding circuit. The method considered in the paper enables prediction of AG/SAG energy based on the test results according to Bond method. The proposed method version was not widely published earlier. The aim of the work was to elaborate cost-effective, reliable and accessible way to determine specific AG/SAG energy. At this stage of method development, it is recommended to use it only for works at preliminary Geometallurgy stage (Scoping, Pre-Feasibility). At design stage the obtained data should be confirmed by appropriate testing using alternative JK DWT/SMC and SAGDesign methods.INTRODUCTIONAppropriate crushing and grinding testing is required to design efficient comminution circuits. It is obviously important to obtain accurate information about ore hardness properties since the main energy consumption at the plant is associated with comminution processes. Moreover, it is required to apply the processes that make it possible to minimize operating costs and efficiently use capacity of the installed equipment installed.When studying ore hardness properties, it is required to take into account that breakage of the material is performed using different equipment. That is why accurate selection of the equipment and the circuit calculation without relevant testworks is impossible. Ideally, the testworks should provide answers to the following questions: determination of ore hardness properties, determination of specific energy consumption for comminution as well as obtaining of sufficient amount of statistically significant results from the tests. The results from crushability and grindability testworks in the first place provide assessment of ore hardness properties and in addition correlate with throughput of the respective equipment. The data obtained can be used for modeling of comminution circuits at the stage of the technology development"

Jan 1, 2016

By Dave Price

"Canada is scheduled to become the 4th highest diamond revenue producing country in the world by year 2004 with the already operating Ekati Mine and the anticipated operation of the Jericho Mine in 2002 and the Diavik Mine in 2003.This paper provides an overview of worldwide diamond production statistics and a brief introduction to a diamond processing plant. The dense medium separation (DMS) extraction process is presented and this process is discussed in more detail with respect to the extraction of diamonds in terms of feed preparation, dense medium, dense medium cyclones, ferrosilicon recovery and dense medium cyclone operating efficiencies.INTRODUCTIONThe Ekati Diamond Mine in the Northwest Territories started commercial production of diamonds in the 4* quarter of 1998. At full production, the mine is anticipated to produce annually some 3 million carats of diamonds. The Jericho Mine in Nunavut Territory and the Diavik Mine in the Northwest Territories are anticipated to come into production in the 1'' quarter of 2002 and 1st half of 2003 respectively. The combined annual diamond production of these three mines will total approximately 10.34 million carats by 2004, making Canada the 4~ highest diamond revenue producing country in the world.A diamond processing plant initially utilizes crushing, scrubbing and screening in the beneficiation process to liberate diamonds from kimberlite ore and size the product for further treatment through DMS. Alluvial diamond operations do not require initial crushing and scrubbing but incorporate a feed preparation and sometimes a recrush facility with the DMS plant. The heavy sink product from the DMS, which contains diamonds, is further upgraded through x-ray separation and high intensity magnetic separation prior to producing the final diamond product.DMS is a relatively simple separating principle. A mixture of particles of different density is immersed in a dense fluid, so that particles having a density lower than that of the fluid will float while those of heavier density will sink. The translation of the float-sink principle from a laboratory method to continuous industrial practice offers the prospect of very precise mineral separations based on density differences alone."

Jan 1, 2000

By F. M. Makarinsky

"SynopsisThe Kanichee open pit mine and milling complex is situated approximately four air miles north-west of Ternagami, Northern Ontario, in Strathy Township. Mining and milling production commenced in January 1974.Milling throughput currently is at a rated capacity of 500 tons per day, seven days per week. A bulk nickel-copper sulphide concentrate is produced, and is trucked daily to the smelter at Falconbridge Nickel Mines Limited, Falconbridge, Ontario, some 120 road miles from Kanichee. Concentrate grades produced are in the order of 4.0% Ni and 8.0% Cu, with corresponding recoveries of 68-70% nickel and 86-90% copper. Stage additions of 100% guar-gurn solution reagent to the flotation cells for depression of talcose minerals, proved to be the major break-through for optimizing metallurgical performance.2. HistoryThe present Kanichee Mining property is known to old-timers in the Temagami area as the former Cuniptau Mine. Several attempts were made in the mid '30's and 40's to extract the ore at a profit, but each effort resulted in failure.In 1933-36, Cuniptau Mines Development Co. Limited, later called Cuniptau Mines Limited, sank a 245-foot vertical shaft and completed 2,200 feet of lateral work on the 100-140 and the 225 foot levels. Fifteen tons of ore were sent for testwork to the Mines Branch, Ottawa, Ontario.Cuniptau Mines Limited, in 1936, milled some 3,000 tons, and the resulting concentrate was put through a pilot smelter situated on the present mine site. Metallurgically, the smelting results were not encouraging, primarily due to the high melting point of the talcose minerals in the concentrate. From the period 1937-48, minor exploration work was done by Ontario Mining Corporation, Ontario Nickel Mines Limited, and Trebor Mines Limited. During the period 1948-49, 128 diamond drill holes, totalling 40,900 feet were evaluated by Trebor Mines Limited. In 1961, the name was changed to Ajax Minerals Limited, during 1968, five diamond drill holes were sunk, totalling 1,700 feet. Since that period the property has remained idle."

Jan 1, 1975

By A. R. Barnes, N. O. Lotter

Recoverable economic copper sulphide minerals such as chalcopyrite, bornite, chalcocite and covellite often occur together in varying proportions in the major copper-bearing ores, and have individual flotation requirements and characteristics. Pyrite also occurs in these ores to varying extents as the sulphide gangue, and is problematic because of its natural tendency to float quickly and easily. In a bulk sulphide float, selectivity against pyrite is desirable, particularly if it does not host other paymetals such as gold or silver. At the same time it is a requirement to float all of the copper sulphides despite their electrochemical differences. The electrochemistry and semiconductor properties of these minerals are reviewed, together with implications for flotation with and without collector addition. Mixed collector systems for the improved flotation of these sulphides are proposed as a solution. The use of xanthate and dithiophosphate in the collector suite allows the co-existence of dixanthogen and free dithiophosphate radical because the latter has a higher redox potential requirement than xanthate to oxidise to the dithiolate. Because some of these minerals require dixanthogen, and others, free thiolate, to generate surface hydrophobicity, a bulk flotation of all the species becomes possible in the overlapping area of Eh and pH between the two dithiolate equilibrium lines on the Pourbaix diagram. The arsenic-signature copper minerals are added to the study, since many copper operations encounter arsenic as a penalty element in the saleable concentrate. It is shown that the addition of arsenic to the copper and iron sulphides alters the semiconductor and electrochemistry properties, and in turn, its flotation characteristics. The degree of mineral association and liberation between these minerals can be a complicating factor due to textural associations, and should also be considered in the process as a next step.

Jan 1, 2016

By D. J. Kemp

The 20th century saw changes in the mining and metallurgical industry not only technically but also in social and environmental expectations. As projects continue to become larger their visibility raises concerns among many groups. For mining companies, transparency, openness, and early engagement of all parties are fundamental to assure success. An equally important task is to anticipate the standards that will be required to meet society’s expectations in the 21st century.

Jan 1, 2005

By Karl Nienhaus

The BGMR has developed a method for an online-analysis during drilling processes in cooperation with Fraunhofer Institute for Laser Technology in Aachen and various industrial partners. This allows for efficient utilization of deposits, maximum recovery of desired minerals and frequent and costefficient updates of deposit models. The used method, namely laser-induced breakdown spectroscopy (LIBS), was implemented into a compact demonstrator in order to analyze drill dust and loosened material within mining environments and directly on drill rigs. The consequently developed OFURanalyzer (OFUR ? online-analysis of mineral deposits) provides possibilities for exploration and visualization of deposit models in real-time and thus creates an opportunity for innovative applications, such as contactless, continuous quality control of minerals throughout the extraction process. A major challenge in the execution of this project was the necessity to develop a laser system that could withstand rough mining environments dominated by dust, shocks, vibration and therefore would be suited to operate under such conditions.

Oct 1, 2009

By M. Helinski

In the authors? experience inappropriate water management in hydraulic fill masses has been the root cause of most barricade failures. Inappropriate water management can lead to high water pressures, reduced effective stresses and increased barricade stresses (Kuganathan 2002). In addition the high hydraulic conductivity and non-plastic nature of most hydraulic fills makes susceptibility to piping failure (Cowling et al. 1987) a high possibility in many hydraulic backfills where a static water head is available. In order to avert both of these failure mechanisms it is essential to control the elevation of the phreatic surface within the fill mass. This is usually achieved through campaigned filling and resting periods. The duration of filling and resting periods are often estimated using some form of stope drainage simulator. Due to the random nature of many characteristics that influence the fill mass hydraulic conductivity, simulation of hydraulic fill drainage can be difficult. The high consequences of inaccurate phreatic surface estimates combined with the high variability in drainage properties often results in operators taking a conservative approach to this modelling. This conservative approach can lead to significant delays in the filling cycle which can have a major impact on the productivity of many hydraulic fill operations and can often results in an unnecessary movement towards capital intensive paste fill systems. This paper presents a water management technique which combines a simplified drainage model with in-situ monitoring to provide a rational approach to water management. With an accurate drainage model filling operations can be carried out at optimum efficiency without compromising safety. The implementation of this strategy has lead to a significant increase in filling rates at a number of Australian filling operations. A brief case study from one of these sites has been presented.

May 1, 2007

By Arthur D. FitzGerald

EDC established an Environmental Review Framework in 1999. Throughout the early fall of 2001, the Corporation held public consultations across Canada to strengthen that framework, leading to a public release on November 15, 2001 of a report summarising the results of these consultations. Following this, the Corporation implemented strengthened environmental review requirements in the form of its Environmental Review Directive, in compliance with legislated amendments to Canada?s Export Development Act that went into effect on December 21, 2001. Over the past few years, there has been a global trend towards an increase in the social and environmental requirements of multilateral/bilateral financial institutions and export credit agencies. More recently, this activity has focussed on capturing institutions that have not yet adopted similar requirements and, more specifically, on developing a convergence of the requirements from institution to institution. This paper describes EDC?s new ERD and some of the initiatives that have taken place or are in process that are moving international financial institutions toward converging their environmental and social requirements for projects in the private sector.

May 1, 2002

By L. T. Loe, A. S. Norsk, Mo i. Rana

High production rate and good stability demand the optimization of all phases of electric pig iron smelting. This is important with respect to slag chemistry, which to a large extent regulates the process temperature in electric smelting. Controlled basicity and slag volume. and a satisfactory screen analysis of the reduction material and sinter, are of the utmost importance for smooth furnace operation. Large variations in slag volume and in B/ A and C/Fe ratio will have an influence on the furnace resistance and thus the specific energy development in the furnace, which lead to variable reduction of SiO.. The result will be variable hot -metal quality and un-stable furnace operation.

Jan 1, 1970

By Tapiwanashe Chenje, David Hewitt, Peter Radziszewski

"Steel media wear is a major cost component in mineral processing. In the case of existing operating mill, steel media wear prediction can be used to help compare the performance of steel media from different suppliers before completing marked ball tests. It can also be used to investigate how ores from different site of a given mine affect steel media wear. In the case of Greenfield cases, steel media wear prediction can be used to estimate the cost of steel media for a given feasibility study.This paper presents a wear testing and prediction methodology that ties together abrasion wear and corrosion wear testing results through the use of a simplified discrete element charge motion model. The experimentation dimension to this methodology takes samples for steel media, mine site ore and water to determine abrasive and corrosive wear parameters of a given media, ore, water set.The test methodology development is illustrated along with a comparison of wear predictions with observed wear rates in some operating mills. A case study is included that illustrates how this methodology was used to estimate steel media wear performance. The paper closes with a discussion on the use of parts of the experimental methodology to investigate other abrasive wear conditions such as liner wear, paste backfill piping and ore breakage as well as avenues for future test development.INTRODUCTIONThe cost of comminution processes represents a significant part of the overall costs of a mining operation. Grinding media/liner wear alone accounts for 15-25% of the total operating cost. The annual steel grinding media consumption is approximately 2.5 mtpa or 0.3% of total world steel production [Smorgon Steel Group, 2005]. Using an estimated grinding media cost of about US$0.75/kg [Halbe and Smolik, 2002], gives a media cost of over US$1.875 billion per annum. Mining continues to shift towards exploitation of lower grade ores as the higher grades get depleted. These low-grade ores require finer grinding for the liberation of the value minerals, and hence it can be assumed that grinding media consumption will also continue to rise.The Bond abrasion test, dating back to 1963, [Weiss, 1985] is still used to estimate the total mill media wear. This is a purely empirical test based on the ore. From Bond abrasion index tests, it is possible to determine a wear rate using the following function:"

Jan 1, 2009

By S. Nagamatsu

Alumina supported gold catalyst prepared by spray reaction method (spr) provides gold particle with about 20 nm of diameter. The gold particle size is larger than conventional gold catalysts. However, the spr catalyst shows higher catalytic activity for NO-CO reaction. In the present paper, we have discussed the local structures of spr-Au/Al2O3 catalyst by using Au L3-edge XANES spectra. In order to investigate the local structures of Au-sites, multiple scattering approach to XANES analysis was applied. Calculated Au L3-edge XANES spectra for fcc-Au and Au2O3 were in good agreement with the observed spectra. XANES spectra for spr-Au/Al2O3 were characterized by 4 types of Au sites (bulk, interface, surface and peripheral). In this case, almost all gold sites (> 90 %) are bulk site. The other sites are less than 10 % of gold particle. However, the experimental and the calculated results of Au L3-edge XANES spectra for spr-Au/Al2O3 require about 30 % of gold oxide or hydroxide. Bulk of Al2O3 contains a certain number of gold nano-particles, which was incorporated in the bulk Al2O3 support. In the interface area, gold oxide forms a few layers. This result was also supported by DV-Xa electronic structure calculations. The comparison of the catalytic activities of the spray catalysts and the impregnation catalyst for the NO-CO reactions imply synergy effects between gold nano-particles and alumina support.

Oct 1, 2003

By Tano Balbin, Valery Astakhov, Juha Timperi, Lauri Koresaar

"Online elemental analysis is the basis of optimal flotation control in mineral concentrator plants. Traditionally XRF analyzers have been used as the online analysis method. However, online XRF analyzers struggle to measure elements below calcium in atomic number (Z=20). For many processes lighter element assays would be beneficial to improve control of grade and recovery. Processes where elements below Ca are required include P, Mg and Si in phosphate concentrators, Si, Mg and Al in iron concentrators, and S and C in gold concentrators. Laser-Induced Breakdown Spectroscopy (LIBS) based elemental analysis can readily be applied to these processes. LIBS is based on generating plasma in the slurry sample by a high energy laser and analysis of the plasma by optical emission spectroscopy. Capabilities of a new Courier® 8 analyzer based in LIBS technology are demonstrated for elemental analysis starting from lithium (Z=3). Results of a plant installation in a sulfide gold concentrator provide a good agreement with the analyzer and laboratory assays.IntroductionEffective process control can be regarded as one of the fastest paying investments for a mineral processing plant. Process optimization in flotation circuits requires constant feedback of the process state. If only manual laboratory samples are available, this optimization becomes difficult due to the long delay between taking the sample and acquiring the laboratory result. If the element grades are available in online basis, the operator or automatic process control system can make corrective actions in real time.Online X-Ray Fluorescence (XRF) analyzers have been in use at concentrators for decades. The XRF analyzers can provide a fast, accurate and precise analysis from slurry streams. However, the drawback of XRF analyzers is their lack of capability to measure elements below Ca (Z=20) in atomic number. The low energy X-rays of the low atomic number elements get absorbed by water in the sample, protective window of the analyzer, or air between the sample and spectrometer."

Jan 1, 2017