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By John P. Powell

The increasing demands for petroleum and its products and the steadily increasing cost of discovering and developing new oil fields are factors that emphasize the importance of increasing the recovery of oil from known petroleum reserves. Water flooding is a valuable conservation measure, not only preventing premature abandonment of stripper leases but also reviving interest in many areas previously abandoned. The use of water flooding as a means for recovering additional oil from partly depleted oil-bearing formations was first tried in Oklahoma in 1931. Early water-flooding operations were confined to the area of shallow Bartlesville-sand formations in Nowata and Rogers Counties, where many of the projects were outstandingly successful. The results of these operations stimulated activities in other pools in Oklahoma, and by the end of 1949 water flooding had been tried in 25 of the 49 oil-producing counties in the State (fig. 1). Approximately 33 million barrels of oil, or 1,806 barrels per acre, had been recovered by December 31, 1949, from 18,221 productive acres included in the 162 active and abandoned projects in Oklahoma by injection of approximately 449 million barrels of water.

Jan 1, 1952

IN 1949 the Government Printing Office issued Bureau of Mines Bulletin 468 3 and previously (in 1948) Bulletin 467 4 as part of the program under the Synthetic Liquid Fuels Act of April 5, 1944 (30 U. S. C., 321-325, and amendments). The two bulletins, relating to oil shale and its products, were published to present abstracts of all patents in this field from 1845 to 1945 5 or before the Synthetic Liquid Fuels Act was passed. Also, as part of this program, bulletins were published on patents relating to the pressure hydrogenation of coal e and the Fischer-Tropsch synthesis.7 The Synthetic Liquid Fuels Act was not extended beyond April 1955, but it inspired much increased activity in the field of oil-shale research, and many patent applications were filed. It is the purpose of this bulletin to abstract the patents issued in the United States, the United Kingdom, and Europe from 1946 to 1956, inclusive. A few older patents omitted in the previous bulletins have been included.

Jan 1, 1959

By A. T. Coumbe

The first national survey covering sales of fuel oil by States and principal uses was made in 1926 by E. B. Swanson of the Bureau of Mines (then under the U. S. Department of Commerce) under a cooperative agreement with the American Petroleum Institute. This annual study, covering the market for fuel oil, was made through 1930 with the financial help of the institute bat has since been continued by the Bureau up to the present time. The scope and coverage of the survey have gradually changed over the years as new uses for fuel oil have been found and new products have come into importance resulting in market expansion. Range oil (No. 1 fuel oil or kerosine) came into use for cooking and space-heating daring the depression era in New England, and it was first reported as a total in the 1931 survey. In 1934 the sales were compiled on a State basis. State totals for distillate fuel oil, Diesel fuel, and residual fuel-oil sales were first shown for 1934 and by principal uses and States in 1937. Kerosine deliveries by States and main uses were also released for the first time in 1937.

Jan 1, 1952

By A. R. T. Denues

This investigation was made under a cooperative agreement between the United States Department of the Interior, Bureau of Mines, and the Pittsburgh Testing Laboratory. Funds were supplied by the Chile Exploration Co., whose executive offices are in New York City. The support, cooperation, and services of these agencies made the work possible and are acknowledged gratefully. The writer wishes to express his particular indebtedness to the staff of the Explosives Division of the Bureau of Mines for services and assistance, particularly Dr. Wilbert J. Huff, consulting explosives chemist, J. C. Holtz, J. E. Tiffany, and A. B. Coates; to F. O. Gardner, treasurer of the Pittsburgh Testing Laboratory; to G. B. Holderer, consulting engineer in connection with liquid-oxygen explosives for the Chile Exploration Co.; to the Enos Coal Mining Co. of Oakland City, Ind., particularly to G. H. Utterback of the staff of the mine for providing facilities that made field tests possible; and to full-time assistants J. W. Rothhaar and J. G. P. Weinheimer and to W. S. Hiller, part-time assistant, who were employed under the cooperative agreement.

Jan 1, 1940

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future. To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951

By Barry Beith

This report details a study which was designed to assess the effect of retroreflective material on detection and form recognition of workers in the mining environment. Further, the study attempted to determine an optimal configuration of retroreflective material with respect to amount and placement on the body to facilitate detection and form recognition. The study involved a one-fifth scale simulation of the perceptual task found in the underground low seam coal mine. Four different configurations of reflective material were presented in various body positions, common to low coal miners, at three different locations in the visual field, i.e., 10, 25, and 45 degrees from focal line-of-sight. All reflective configurations significantly improve detection and form recognition over configuration (cap only) worn by miners. As the amount of reflective material increased, accuracy also tended to increase. Based on the configurations investigated by this study, the Armband configuration (i.e., refectorized armbands, belt, self-rescuer and battery pack) was determined to be optimum. It is recommended that an actual field evaluation be made using the Armband configuration to establish if simulator results are generalizable to the underground mining environment.

Jan 1, 1980

By ALBERT E. HALL, Arno C. Fieldner, Alexander L. Field

As a safeguard against excessive clinker troubles, specifications for the purchase of coal can be drawn to include the "softening" or "fusing" temperature of the ash. The value of such information has been recognized by the Bureau of Mines and has induced the bureau to investigab~ laboratory methods of determining the fUSIbility of coal ash, and the bearing of the results on clinker formation in fuel beds. The bureau realized that the fusibility of a mixture of oxides and silicates snch as is comprised in coal ash ,'aries according to the conditions under which tests are made, and that in the absence of any generally accepted method, no agreement is to be expected among tests made in differ«:-nt laboratories. Indeed, Marks a has recently called attention to differences as great as 3900 C. that were obtained with the same sample of ash by two different laboratories. Therefore if a fusion-temperature clause is to have any place in specifications for coal, a standard m('thod of t('sting should be adopted in order to insure comparable results by different laboratories and to obtain the softening or fusing temperature of the ash unde:'r conditions similar to those of a fuel bed. After a consistent method has been devised for obtaining comparable:' results at different laboratories, there will remain the correlation of these results with those from the burning of coal in furnaces before the value of fusibility tests in coal specifications can hE' finally determined.

Jan 1, 1918

By Jack Smith

New turbine blades designed to resist ash erosion were tested by the Bureau of Mines in a pilot-scale coal-fired gas turbine. After a total of 1,963 hours, the rotor blades were only slightly eroded; and they had an estimated useful life of 20,000 to 30,000 hours. Changes in aerodynamic design of the blades successfully concentrated the ash at the outer casing, but stepped sidewalls for the rotor drum and wear strips at the bases of the rotor blades are still needed to minimize wear at these points. Stepped sidewalls and wear strips did not adequately protect the stator blades. Ash slightly eroded their leading edges, above the inserts, and cut notches into their trailing edges near the bases. Stator blade life was estimated at 5,000 to 7,500 hours. Blade erosion in these tests was less severe than with previous designs, but more efficient combustors and ash separators are required to reduce the amount and size of ash entering the turbine, to achieve acceptable blade life for commercial operation.

Jan 1, 1967

By Brinton C. Brown

This paper describes the methods and equipment developed at the Bureau's Experimental Oil-Shale mine near Rifle, Colo., for placing men in position to scale loose rock from the walls, pillars, and roofs of high stopes or rooms. The equipment developed at Rifle has application not only in oil-shale mining but in most of the country's underground limestone mines and in the exploitation of other mineral deposits mined in high stopes by room-and-pillar methods. Equipment in use at Rifle includes: 1. A boom-type scaling rig with a self-leveling platform constructed on a small "cat"-mounted crane. Men working from the platform on this machine can efficiently scale mine walls and roofs 27 feet above the floor. 2. A conventional fork-lift truck modified to provide a remotely controlled working platform from which men can scale to heights 27 feet above the mine floor. The platform on this unit is larger than on the boom-type rig and allows the men to inspect larger areas of the mine wall from a single setting of the machine. 3. A third rig, consisting essentially of a platform mounted on a tele-scoping tower, designed and built to elevate men 65 feet above the mine floor. Versatility of this machine permits men to work from the platform at heights of 5 to 65 feet. In the operating position, the unit requires a minimum clearance of 25 feet. In the nonoperating position the tower of the machine folds to an over-all height of 15 feet 10 inches to permit travel through haulageways. 4. An industrial gun, lightweight scaling bars, and mechanical scalers, which have been tried for removing loose rock from the mine walls with varying degrees of success.

Jan 1, 1950

By WM. H. RINKENBACH, C. A. Taylor

No complete work on explosives, their constitution and analysis, has hitherto been published. Several books that contain chapte.r;s on analysis do not cover the matter thoroughly. Methods tha;t, manu~ facturers, testing stations, and other . agencies have developed to meet their own requirements have not been made public. The Bureau of Mines has issued four publications 1 - cov:eri:ng special phases of the subject. This bulletin. is not inte.nded to replace those reports, but rather to cover present methods employed 'in the , industry and to include all classes of explosives and the materials used in their manufacture. No sharp distinctions can be drawn between classes of explosives. . Surplus military explosives, for example, may be used for blasting, just as blasting explosives, under some conditions, may be employed for military purposes. Moreover, one class gradually merges into another because of similarity in composition. Explosives are here grouped as dynamites, black powders, propellants, detonators, and primers. Some materials are used in practically all these groups ; others in only one. To discuss all the materials that have been or that may be used and the methods for their identification and quantitative determination is not feasible, but the methods described will probably suggest ways of examining new mixtures.

Jan 1, 1923

By James Westfield

This report covers the calendar year 1953 and has been prepared and submitted in accordance with the provisions of Sec. 106(a) and Sec. 212(c) of the Federal Coal Mine Safety Act (66 Stat. 692; 30 U.S.C. Secs. 451-483). During this first full calendar year of operations under the Federal Coal Mine Safety Act, the coal-mining industry of the United States attained the best injury records in its history - improving the former best records (made in 1952) by 91 fatal and 10,020 nonfatal injuries. Whereas, the mandatory provisions of the act were intended and designed to prevent major mine disasters, apparently the effects have reached beyond the scope thereof in reducing mine accidents generally.

Jan 1, 1954

By Scott W. Hazen

This Bureau of Mines report presents the results of a study and statistical analysis of part of the initial exploration churn-drill sampling and some of the subsequent underground diamond-drill-core sampling in the North are body at the San Manuel copper mine, Arizona. These data were derived from regular exploration and mine sampling, not from special samples obtained solely for statistical analysis. The study was conducted as part of the Bureau's continuing program on sampling-methods research. The major objective of the study was to investigate the feasibility of using the techniques of statistical analysis in evaluating sample and assay data and computing grade and tonnage of Ore from porphyry-type copper deposits. It was recognized that using existing data acquired over a period of several years by different methods would introduce problems and limitations for precise comparisons. However, it was expected that the study would provide some general conclusions and certainly a number of preliminary conclusions on the nature of the mineral characteristics and their effect on sampling procedures, the requirements for sampling deposits of this type, and the comparative results of churn-and diamond-drill sampling in the same area of the deposit. All of this information would be essential for future sampling-methods research for computing grade and tonnage of ore.

Jan 1, 1963

By G. W. Jones

In a previous report results were given and a method outlined whereby from a knowledge of the composition of the natural gas and of the inflammability limits of the individual constituents composing the natural gas, the limits of inflammability of natural gas and air mixtures could be closely calculated. This method is based on the application of Le Chatelier's law as modified by Coward, Carpenter and Payman, to apply to a mixture of any number of combustible gases. This law must not be used indiscriminately, because many exceptions have been found. For example, when ethylene, acetylene, hydrogen sulphide, or chlorinated hydrocarbons are present the law may not hold. For a discussion of the rally exceptions which have been found, reference should be made to a report by Coward and Jones. Before this method can be used the inflammable limits of the individual constituents must be known. Also, the composition of the complex combustible mixture, and representative mixtures besides, must be tested both experimentally and by calculation to prove whether Le Chatelier's law may be applied.

Jan 1, 1933

By W. R. K. Wu

Studies are reported on the structure of coal and coke with the graphical , statistical densimetric method based on the relation between the molecular volume per carbon atom ( M / C ) and the atomic hydrogen - carbon ratio ( H / C ) . Previous work , mostly from chemical and physical investigations , is critically reviewed . Difficulties in evaluating the ring increment are demonstrated for coal and coke for the statistical densimetric method based on the additivity of atomic volumes of constituent elements . A new diagram is presented for the graphical method . Methods are introduced for correcting M /C and H/C for the presence of minor constituents in coal and coke . With the graphical method , the fractions of aromatic carbon atoms in the total carbon atoms are estimated for a coal , a resin , and 5 petrographic components ; the types of condensed structure in the fundamental units of molecules are discussed for these substances , 28 coals , and 6 " average " cokes at 500 ° to 1,000 ° C. It is also shown that the number of rings in the fundamental units of coal generally increases with increasing rank and that of coke , with increasing carbonization temperature .

Jul 1, 1960

By D. I. Bleiwas

Bureau of Mines personnel evaluated the potential availability of nickel from 151 deposits in 18 market economy countries and selected 126 for detailed analyses. An evaluation was made of tonnage-cost relationships indicating the quantity of nickel available at various total costs of production expressed in dollars per pound nickel, including a 15-pct rate of return on the invested capital. The 126 deposits studied contain approximately 73 million metric tons (t) of nickel. An estimated 52 million t is available from laterite deposits, of which less than 2 pct could be produced at $3.50/lb Ni, about equal to the average published price of nickel in 1981. Approximately 21 million t of nickel is available from sulfide deposits, of which about 10.0 million t can be produced at $3.50/lb. Sensitivity studies performed for both laterite deposits and sulfide deposits indicate that the total cost of nickel from laterites is most sensitive to increases in energy costs, and that sulfides are most sensitive to increases in labor costs; sulfides are also sensitive to changes in byproduct revenues. In 1983 the Nickel Mountain mine in Oregon was the only U.S. producer, though development continued on the Gasquet property in California. Of the total 5.1 million t of recoverable nickel in the United States, about 20 pct is available at or below $3.50/lb.

Jan 1, 1984

By G. D. Coe

Float-and-sink tests indicate what results are obtainable by gravity separation and rare therefore an invaluable adjunct to most coal-cleaning processes. However, it is difficult to make a direct interpretation of float-and-sink data on coal, and several systems for interpreting them have been proposed. Of these, that developed and used extensively by Bird3/, Yancey4/, and Gandrud5/ is considered by the author to be the most satisfactory. It makes use of four interrelated curves (hereafter referred to as be "washability curves"). These curves were explained by Bird in a paper6/ published in 1923, but his explanation has been regarded by some as not sufficiently

Jan 1, 1938

By Peter N. Gabby

A mineral purvey of 40,000 acres of the 42,213-acre Little Humboldt River Wilderness Study Area was conducted by the U.S. Bureau of Mines in 1985 at the request of the U.S. Bureau of Land Management. There are no identified mineral resources but anomalous gold, silver, mercury, and arsenic concentrations were found. The study area is located in Elko County, NV, in the Owyhee Upland geomorphic subprovince. It is underlain by mid- to late-Miocene-age rhyolite, basalt, tuff, vitric ash, and tuffaceous siltstone. On the south side and partly within the study area, a mining company recently (January 1986) located 125 contiguous claims over an area of hydrothermally-altered volcanic rocks that have anomalous surface concentrations of gold, mercury, arsenic, and silver. Anomalous gold-silver concentrations in altered rocks were encountered at several other widely scattered localities in the study area. These elevated metal concentrations and associated hydrothermal alteration indicate gold resources may be present in the study area. A 20-ft-thick bed of diatomaceous earth, which contains 60 to 85 percent diatoms, crops out 0.3 mi north of the study area. Elsewhere, three samples of altered volcanic tuff taken within the study area contain from 46 to 70 percent zeolite (clinoptilolite). The diatomaceous earth and zeolite sampled are not of sufficient quality to compete with materials presently being marketed. There has been no mineral production from the study area, but a caved adit, about 25 ft long, and six prospect pits were found.

Jan 1, 1987

By Joan Weinberg

The real gross national product (GNP) expanded by 2.3% during the second quarter, down from the anomalous 4.4% growth rate in the previous 3 months. If the expansion continues through October, it will have lasted 5 yr and become the second longest in 40 yr.2 As in the first quarter, improvement in U.S. exports played a role in the continuing--albeit slow--growth. More than 2 yr of declines in the dollar relative to currencies of other industrial countries have contributed to a slight reduction in the trade deficit in real (volume) terms, as real net exports of goods and services rose $1.9 billion (table 1). Exports grew a strong 12.1% while imports, which had fallen the previous two quarters, rose 7.4%. Manufactured goods and petroleum products accounted for most of the second quarter import increase. The American Petroleum Institute estimates that the volume of crude oil and refined products imports in the first half of 1987 surpassed those in the same period last year by 7.5%, reflecting falling domestic production and higher than expected demand. Expenditure on durable goods--those that last at least 3 yr-by both consumers and producers also contributed to the second quarter expansion. Personal consumption of durable goods rose 9.0%, after having fallen the two previous quarters. Motor vehicle purchases accounted for most of the second quarter increase and the first quarter decrease. Sales of automobiles surged in the last quarter of 1986, as consumers rushed to capture the sales tax deduction that was eliminated on January 1. Sales fell in the first quarter of 1987, but have now moved closer to the trend line exhibited in the first three quarters of 1986. Automobiles accounted for half the 0.8% July gain in retail sales, and two-thirds of the 1.4% June gain. Producers durable equipment purchases also rose this quarter, accounting for the increase in nonresidential fixed investment.

Jan 1, 1987

By D. A. Reynolds

The Bureau of Mines-American Gas Association survey of the carbonizing properties of American coals was begun in 1929, and has been continued almost without interruption since that time. Upwards of 100 coals have been carbonized at low, medium, and high temperatures in this survey, and about 200 additional coals have been carbonized at high temperatures only. All survey coals were blended with coal of different rank for carbonization at one high temperature (900° C,). During the past few years, 12-high-volatile A coals were blended with Pocahontas No 3 coal from Kimball, McDowell County, W. Va., and in this report the physical properties of the cokes from these high-volatile coals and their blends are compared.

Jan 1, 1949

By V. F. Parry

[Approximatel~r 7-1/2 illion tOlls of subb1tnminous coals are mined an-nuall in Colorado, Wyo~ing, and Montana, of which 50 percent probably reaches dome ,-tic conswno:os. r:L'he moi s t'_re of the se subbi t1.Uninous coal sis high, averae;:t.:ug about 25 :!,)ercent \-Then they are :nined. T'ne coals are non-caking d ~~ack to a vari ble degree when exposed to nornal atmospheric conditions. ~hey a~e gpod domestic fuels, are considered to be smokeless in most furn~ces, and have been used. f, r f!1an: y ars in hand-fired domestic furnaces in hich tnc practice i~ to e~ploy large lureps for efficient com-]

Jan 1, 1941