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By F. P. Haver

The purpose of this investigation was to determine the effect of common impurities, that is, oxygen, nitrogen, carbon, and iron, on the Brinell hardness of electrolytic titanium. On a weight basis, nitrogen had the greatest hardening effect, followed by oxygen, carbon, and iron in order. The hardening effects of oxygen and carbon were almost identical up to a concentration of approximately 0.1 percent by weight. Above this concentration, the relative hardening effect of carbon decreased rapidly, possibly because of its limited solid solubility in a-titanium. Hardness vs. composition curves for both oxygen and nitrogen were essentially straight lines over the range of Brinell hardness numbers (B.h.n.) covered in the investigation. The hardness of titanium was also determined as a function of the percentage of impurity atoms. On this basis, iron in concentrations up to 0.17 atomic percent had a greater hardening effect than either oxygen or carbon. INTRODUCTION Determination of the as-cast hardness of arc-melted titanium is a method of quality control widely used in industry. Numerous studies4/ have been made of the effect of impurities on the hardness obtained by this method. However, most of them have been based on the use of either iodide titanium or commercially pure Kroll sponge (B.h.n. >90), as a starting material.

Jan 1, 1959

By M. Shabbir

A study was made to determine the optimum conditions for precipitation of uranium from mill solutions using hydrogen peroxide. Precipitation tests were made on both synthetic and actual mill solutions. Parameters studied included amount of hydrogen peroxide, initial pH, reaction pH, time, and temperature. Also investigated was the effect of varied amounts of vanadium, molybdenum, and sulfate in the test solution on uranium precipitation and product quality. The optimum conditions for complete precipitation and high product quality were (1) the use of 150 percent of the stoichiometric requirement of hydrogen peroxide, (2) initial pH of 1.0, (3) reaction pH between 3.4 and 5.0, (4) 4 hours reaction time, and (5) ambient reaction temperature. The excess hydrogen peroxide requirement is partially dependent on the amount of impurities present in the feed solution. The hydrogen peroxide process appeared applicable to treatment of the several mill eluate and strip solutions tested. The experimental studies also indicated that the hydrogen peroxide technique gives substantially better product quality than that produced by ammonia precipitation.

Jan 1, 1974

By Van H. Manning

"Under the organic act establishing it, the Bureau of Mines is authorized to conduct investigations designed to improve health and safety conditions in the mineral industry and to promote efficient development and utilization of our mineral resources. The field of the Bureau's activity, therefore, begins with the commercial development of mineral deposits and ends with the production and utilization of the final marketable product.In order to serve more efficiently the various sections of the country, the Bureau has established, in addition to its main offices at Washington, D. C., eleven field experiment stations, three field offices and several mine rescue cars and mina rescue stations. These field branches are so distributed as to cover most of the mining districts of this country, including Alaska. The field service in general deals with specific experimental problems, cooperative work with non-governmental institutions, and mina rescue work, while the Washington office is the administrative head and is responsible for the distribution of general information, the chiefs of the technical and administrative divisions of the Bureau being stationed there.The Bureau is prohibited by law from doing work exclusively for the benefit of any private company or individual. Generally speaking, the Bureau does no assaying, ore testing, or similar service work for the benefit of private companies or individuals. In response to requests for work of this sort a list of assay and ore testing laboratories is supplied. In referring inquiries to com-mercial laboratories or consulting engineers, care is taken to mention several names so as to avoid designating any one establishment or engineer."

Apr 1, 1920

By W. C. Phalan

"Prewar Conditions:Metallic magnesium may be considered a war metal, but a war metal with a future, so far as the industry in the United States is concerned. Its production in the United States prior to 1915, on a commercial scale, was negligible, but imports prior to that year may be taken as a gaze of the demand for the metal. Unfortunately, magnesium was not listed separately by the Department of Commerce prior to the war, among the importations, but was included with other metals, as follows: ""Barium, calcium, magnesium, sodium, and potassium, and alloys of which said metals are the component materials of chief value."" However, the imports of metals enumerated other than magnesium were probably small, so that the importations under the above caption may be considered chiefly metallic magnesium in one form or another and, therefore, is an approximate gage of the demand for the metal in the United States. These imports were as follows:These figures are so close that they give a good idea of the figures for the respective calendar years.Of this prewar use, it has been estimated that about 85 per cent was used annually and in approximately equal quantities in the production of (1) flash-light powder, (2) fire works, (3) aluminum casting work, and (4) nickel and nickel-copper alleys, such as monel metal, etc. The re¬maining 15 per cent was employed for general uses, such as deoxiding brass and other copper alloys in foundry work, and to a small extent in laboratory and research work."

May 1, 1920

By Harry R. Nicholls

Preliminary tests on presplitting rock in the presence of an in situ static stress field were undertaken to study the influence of a horizontal static stress field on the creation of a vertical presplit fracture plane. These tests indicated that it is easier to fracture the rock parallel to the in situ maximum compressive stress than in other directions. Instrumented shots indicate that the interaction of stress waves generated by the detonating charges is probably responsible for starting tensile fractures between shotholes and that expanding gases may propagate these initial cracks by a wedging action. The hole spacing for presplitting appears to be equal to the half wavelength of the stress wave. However, wider hole spacing appears feasible if the initial fracture is started by closer hole spacing.

Jan 1, 1966

By T. I. Weston

This is one of a series of papers being prepared for and published by the United States Bureau of Mines, describing mining and milling methods and costs at crushed-stone plants throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total production costs. It is recognized' tat publication of total production costs might in many instances cause embarrassment to individual producers, as well as to the industry as a whole. However, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no mis-understanding of the scope of the cost tabulations shall ensue. ACKNOWLEDGMENTS The author wishes to acknowledge the assistance-of F. W. Horton, mining engineer, United States Bureau of Mines, in the preparation of this paper.

Jan 1, 1933

By Edward W. Parsons

The explosive-anchored rockbolt was field tested in six mines where rock conditions varied from incompetent shale or mudstone through fairly soft sand-stone to firm sandy shales. The purpose of the testing was to document, under a wide variety of conditions and in comparison to other rockbolt anchors, the quality of the anchorage produced by the explosive-anchored bolt. In addition, the length, strength, and design of the explosive charge necessary to produce positive anchorage up to the yield strength of the weakest component of the bolt were determined. A l4-inch length beaded explosive charge was found to be suitable, in general, in relatively weak strata, and the length can be reduced in more competent strata. Of the 127 explosive?-anchored bolts tested, 118 bolts produced an evaluated anchorage in excess of 17,000 pounds. Only 4 of 43 expansion-shell bolts and 4 of 14 wedge bolts produced anchorage this good. In preliminary tests, properly coupled explosive-anchored bolts did not ignite an explosive gas mixture. Some minor phases included in the investigation were as follows: (1) effect of explosive-anchored rockbolt on surrounding rock; (2) effect of time on anchored bolts based on torque tests; (3) effect of submersion in water on rockbolt anchorage; (4) pull tests to higher loads; and (5) ignition tests.

Jan 1, 1965

By Thomas M. Barczak

The transverse loading requirement for stoppings as specified in the current Code of Federal Regulations is 39 psf. This measure is based on physical testing of a freestanding wall in accordance with ASTM E 72 specifications, where the dominant parameter is the tensile strength of the sealant. A new protocol based on arching has been developed to determine the true transverse load capacity of stoppings. Arching is achieved by the restraint of the stopping against the mine roof and floor, whereby compressive forces are developed within the wall. A laboratory procedure using the NIOSH Mine Roof Simulator (MRS) to simulate rigid-arching of stoppings was developed and verified through full-scale in-mine tests. Using this protocol, a systematic study of the design parameters that affect arching capability in block stoppings was conducted. The study included a theoretical assessment of arching and development of design formulations that can accurately define the transverse load capacity of various stopping constructions under various loading conditions. This approach should lead to a safer mine environment by matching the transverse load capabilities of the stopping design to the requirements in the mine to ensure proper ventilation control is maintained.

Jan 1, 2005

By W. M. Myers

"The continued expansion of modern industry broadens the markets for minerals and their product. With these increasing demands new uses are being found for minerals that heretofore were considered as possessing no commercial possibilities. This tendency is reflected in the nonmetallic field in a constantly increasing demand for minerals formerly considered to be of scientific interest only, Furthermore, nonmetallic minerals of established commercial importance are used in new ways in various products, and this tends to expand the markets for these minerals. Some recent outstanding developments in applications of minerals are given in the following pages.The Andalusite GroupAmong the minerals that until recently were considered of scientific interest only, may be listed those of the andalusite group. This group is composed of the three minerals, andalusite, cyanite (or kyunite), and sillmanite, which are all forms of the compound Al2SiO5 (A1203, S1O2), and are therefore identical in chemical composition, but differ in physical properties,"

Mar 1, 1924

By F. D. Everett

Thermoelectric and metal alloying applications have changed the status of tellurium from oversupply to under supply . In a search for new sources of this element in Arizona , Colorado , New Mexico , Utah , and neighboring states , the Bureau of Mines analyzed more than 200 samples and obtained the results of tellurium determinations by private companies on more than 500 samples from a wide variety of mineral - bearing deposits . The About 40 minerals containing tellurium have been reported , mainly tellu- rides of gold , silver , bismuth , mercury , lead , copper , iron , and nickel . minerals usually occur in small quantities and identification in ores is extremely difficult . Samples containing more than 0.1 percent tellurium were taken from the Hilltop and Memphis properties in Dona Ana County , N. Mex . , and the Silver King property in White Pine County , Nev . , where development was chiefly for base metals . The Lone Pine mine in Catron County , N. Mex . , and the Bambolla mine near Moctezuma , Sonora , Mexico are potential sources of native tellurium occurring in small but high- grade pods . Much of the production of tellurium has come as a byproduct of electro- lytic refining of copper and lead- zinc ores in Arizona , Colorado , New Mexico , and Utah . Base -metal ore deposits will continue to be the most important pri- mary source of tellurium , although the concentration in ores is nearly always less than 10 parts per million . Any significant increase in output of tellu- rium probably will be related to production and improved efficiency in smelt- ing and refining base - metal ores .

Jan 1, 1964

By E. P. Youngman

By a decree of March 14, 1929,5 the President of the Faitian Repub- lic, considering it to be necessary, until the mining legislation of the Republic shall have been revised, to put into effect the mining law of Decem- Der 4, 1860 (relative to mines, diggings, and quarries), by the authority given in article 55 of the Constitution, declared the law of February 14, 1919, to be abrogated and the provisions of the earlier mining law (December 4, 1050) again to be valid. No concessions were granted under the law of 1919. All citations in this paper, unless otherwise designated, refer to the law of 1930.

Jun 1, 1932

By L. B. Pankratz

Heat contents, measured above 298.15° K, and derived entropy increments are presented in tabular and equation form for the two crystalline forms of zinc sulfide (sphalerite and wurtzite) and for four solid solutions of iron and zinc sulfides having the compositions Zno.,,6Fe0.302S, Zno.750Fe0.250S, Zno.650Fe0.3505, and Zno.498Feo.502S.

Jan 1, 1965

By R. Hogg, T. F. Dumm

"Abstract - With increasing interest in the physical cleaning of fine coal, there is a need for extension of the sink float analysis procedure to finer sizes. Problems arise, however, in ensuring complete dispersion of the particles in the heavy liquids. A procedure has been developed in which surfactants are used as dispersing agents, and solids concentration is minimized (using a simple formula to estimate the minimum weight needed for statistical reliability). Using centrifuges to increase separation rates and subsieve particle size analysis of the specific gravity fractions, a complete size specific gravity distribution can be obtained. Analyses have been performed on coal samples as fine as -10 µm.IntroductionTraditional gravity separation techniques such as jigging, heavy media and water-only cyclones, shaking tables, etc., have been used to remove impurities from coal ranging in size from about 15.cm (6 ln.) to about 150 µm (100 mesh). The coal washabilty or float-and sink technique ls a well-established procedure for determining the optimum extent to which a coal can be cleaned by such physical separation methods. Because of the desire to recover even finer coal fractions by gravity separation techniques, there is a need to extend the coal washabillty analysis into the ultrafine range. The purpose of this paper ls to describe some of the significant factors that influence fine particle specific gravity separation. Washability analyses have been performed on three ultrafine ( <10 µm) coal samples representing three general mining districts in Pennsylvania. Results of these analyses indicate that the washabillty technique can be successfully applied to ultrafine particles when proper care ls taken."

Jan 1, 1988

By M. J. Ferrante

Relative enthalpies of high-purity disodium hexatitanate (Na2Ti6013) were measured at the Bureau of Mines to provide new thermodynamic data needed to advance the technology of materials. Measurements from 298.15 to 1,478 K were made by drop calorimetry with a copper block. Tabulated values are listed for the standard relative enthalpy, heat capacity, en-tropy, and Gibbs energy function between 298.15 and 1,500 K. Enthalpy data are also given in equation form and are combined with thermodynamic data from the literature to derive values of standard enthalpies of formation, Gibbs energies of formation, and logarithms of the equilibrium constants of formation. Similar calculations were made for the reaction of Na20 with Ti02.

Jan 1, 1986

By R. R. Lowery

The Bureau of Mines developed hypereutectic aluminum-silicon alloys which 11.7.d better mechanical properties than the unmodified hypereutectic alloy. A commercial aluminum-20 weight-percent silicon LIr alloy was selected as a ary base for improvement. The primary silicon. grains were reduced from ASTM 4-5 to ASTM 8.5 by the use of phosphorus and phosphorus compounds. The remaining eutectic matrix was refined by sodium metal additions of 0.2 weight-percent. Solid solution strengthening of the alpha aluminum was obtained by adding 2 percent copper and 0.5 percent magnesium. Also, 1 percent nickel was added to harden the alloy. Optimum thermal treatment consisted of a solution treatment for 10 hour:, at 480° C with hot water quench, followed by aging for 6 hours at 175° C. The final alloy exhibited a Rockwell B hardness of 75 ±2 in the heat-treated condition. The ultimate tensile strength was 39,5O0 psi with no recordable elongation. The coefficient of linear thermal expansion was 20.4 x 10-6 per °C in the temperature range 20° to 300° C. No wear resistance data were collected.

Jan 1, 1966

By J. T. Dunham

Zirconium has possible use in industry where severe corrosion conditions are encountered because it resists attack from a variety of corrosive environments. However, very little experimental testing has been done to evaluate the corrosion behavior of zirconium when simultaneously subjected to high tensile stresses and exposed to corrosive environments. This investigation was initiated for an evaluation test, but was limited to environments consisting of ferric chloride solutions which were known to attack zirconium and were shown to promote stress-corrosion cracking in preliminary tests. Tests for cracking susceptibility were conducted by the Bureau of Mines to show the effect of stress, solution concentration, air aeration of solution, and the method of mechanical processing. Tensile stress was applied to the specimens by a constant-load method which proved more reliable than a constant-strain method.

Jan 1, 1961

By G. M. Kintz

From 1895 to 1932, inclusive, 1,0163/ men were killed in and about New Mexico coal mines. Of these, 473 (approximately 47 percent) were killed in the 17 explosions listed in this paper. The second largest explosion of record in the United States, in so far as fatalities are concerned, occurred in New Mexico. The data in this circular were taken from publications of the United States Bureau of Mines and published annual reports of the State inspector of coal mines of New Mexico. The tables included are complete only with regard to major disasters. The Bureau of Mines considers as a major disaster one in which 5 or more men are killed. A few minor disasters are included, however.

Jan 1, 1934

By A. Wahab Khair, N. P. Reddy

"INTRODUCTION The continuous mining machines which were introduced in the 1950's now account for more than half the production of coal from underground mines. Unfortunately, these continuous miners which were designed for increased productivity have also increased the concentration of respirable dust in mines. Inhalation of this respirable dust by miners causes the Coal Worker's Pneumoconiosis (CWP). Concern for CWP increased in the United States following a 1963-65 survey that showed definite x-ray evidence of CWP in 9.8 percent of working miners and in 18.2 percent of nonworking miners in the Appalachian bituminous coal region (Breslin and Niewiadomski, 1982).One of the major objectives of the Federal Coal Mine Health and Safety Act of 1969 was the prevention of CUP. This law initially limited the daily average exposure of coal miners to 3 mg/m3 of respirable dust. However, following the results of a probabilistic model developed by Jacobsen, et. al. in 1971, the limit was reduced to a mass concentration of 2 mg/m3 unless quartz content exceeds 5 percent, a rare occurrence in mines. Based on x-ray categorization prior to death it is believed that the mass concentration in the respirable fraction is a parameter of primary interest for hygenic evaluation of dust exposure. Morgan, Burgess and Jacobson (1973) suggested that the quantity of inhaled dust, although influential is not the only aspect of exposure which is significant in producing CWP. Miners working in higher rank coal (anthracite) mines are more susceptible to CWP (Morgan, Burgess and Jacobson, 1973). This also confirms the findings of the British (Bennett, Dick and Kaplan, 1979 and Hurley, et. al., 1979) and Germany (Reisner and Rubock, 1977). Based on the cytotoxicological evidence Reisner and Rubock (1979) suggested that when coal properties are similar, increasing quartz and mineral content increases toxicity. David, Ottery and Le Roux (1975) examined that as the severity of the CWP increased the retention of the coal dust content in the pulmonary region remained the same, while that of quartz content increased significantly. Leiteritz, Baur and Bruckman (1971) studied the various components of coal dust and showed that coal particles comprised a smaller fraction of the mass of fine dust than did particles of quartz and minerals. It is ironic that quartz and mineral matter both comprise smaller fractions of the higher rank coal dust (Dodgson, et. al., 1971 and Dwiggins, 1981). Results of a recent research revealed that quartz or any other mineral examined had no strong or consistent effect on the incidence or progress of CWP (Attfield, 1984) while Dodgson, et. al., (1971) concluded that high exposures to minerals such as illite, kaolinite and mica will retard the progress of CWP. Size and shape characteristics are believed to be important in the relationship between mineral particles and health effects (Shedd, Virta and Wylie, 1982)."

Mar 1, 1989

Major activities of the Bureau of Mines Explosives Research Center during fiscal year 1965 (July 1, 1964, to June 30, 1965) are reviewed briefly. Part 1 summarizes significant accomplishments of the projects that were active during the report period. Part 2 presents short abstracts of the publications that appeared in the Bureau series and in other media during fiscal year 1965. Publications issued after June 30, 1965 are noted where pertinent in footnotes but are not abstracted. ACKNOWLEDGMENTS The Bureau of Mines gratefully acknowledges the support given through cooperative agreements by the following organizations to investigations con¬ducted by the Explosives Research Center during fiscal year 1965: Dow Chemical Company Manufacturing Chemists&apos; Association Monsanto Chemical Company The Sulphur Institute

Jan 1, 1966

By James S. Grichar

Interest in mergers in the nonfuel mineral industry developed when 5 were listed among the 50 highest valued mergers in the United States in 1981. This report presents a Bureau of Mines study of trends in merger activity from 1960 to 1979 and explores motives for mergers in the nonfuel mining and mineral industry. The objective was to determine precedent for or a trend toward the 1981 acceleration in merger activity and to examine certain financial motives for non fuel mineral mergers. Data indicate that the relative value of non fuel mineral mergers has grown since 1972 although the number of mergers has remained proportionate to historical trends for all mergers. Since 1974, the assets acquired in "large," nonfuel mineral firm mergers, those of $10 million or more, have comprised at least 93 pct of assets acquired. More nonfuel mineral firm mergers involved mineral companies as the acquiring firm than vice versa but mining and minerals firms acquired were of higher value than nonmining firms. A major motivation for mergers involving large mineral firms was the acquisition of assets at less than replacement costs. Univariate statistical testing, a methodology chosen for its applicability to the data, confirms this hypothesis while rejecting other financial motives. The remainder of the work is devoted to a discussion of suggested areas for future study.

Jan 1, 1984