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By H. A. Watson

The introduction and use of synthetic materials in various applications may lead to potential hazards from toxic, gaseous, decomposition products if these materials are subjected to conditions abnormal to their intended use, such as high temperatures or burning from accidental causes. This report covers an investigation of such possible hazards from toxic gases produced by the burning or thermal decomposition of some low-density, expanded, synthetic materials, three of which consisted of polyvinylchloride and one of acrylonitrile. In the production of certain expanded plastic materials, Chemical blowing agents frequently are used to produce a cellular structure. One of these blowing or foaming agents contains azo-bis-isobutyronitrile, which is designated in this report as PN. Information indicates that a product of decomposition of this blowing agent, formed in the blowing operation, is tetra-methyl-succino-nitrile, designated as TSN, Which is significantly toxic. Decomposition of the blowing agent, with release of its azo nitrogen, is represented by the following reaction:

Jan 1, 1951

By H. P. Hermance

The Ely mine, which at one time was the largest producer of copper in the United States, has been idle for the past 30 years. A remarkably continuous ore shoot probably averaging 100 feet wide and 19 feet thick was mined on about a 25° slope for 3,400 feet on the incline. The ore was massive sulfides containing chalcopyrite, pyrrhotite, pyrite, and sphalerite. The estimated production of the Ely mine is 400,000 tons of ore averaging 3.3 percent copper. Because of the critical position of copper during the recent war, a search for extensions and recurrences of parallel ore shoots at the Ely deposit seemed warranted. The Bureau of Mines surveyed selected areas by geophysical methods, diamond-drilled nine holes, and sampled mine dumps during its investigations, which began in 1942 and terminated in 1946. The diamond drilling totaled 5,229 feet. The logs of the holes include chemical analyses of mineralized sections.

Jan 1, 1949

By Franklin D. Slagle

Porosity and bulk-and sand-grain-density values were determined for 2,040 core samples of 30 formations from 47 wells in New York, Ohio, Pennsylvania, and West Virginia, and are compiled for petroleum industry use in well-log evaluation and geologic studies.

Jan 1, 1967

By C. W. Owings

"Ventilation is one of the most important features of coal mining, and if a mine is exceptionally gassy it is often difficult to ventilate it in such a way as to make it safe. The general system of splitting the main air current so that two, three, or more sets of room entries are ventilated by the same current of air does not provide a safe method if non-permissible electrical equipment, such as cable-reel, crab-reel, or trolley locomotives are used on gathering haulage, or if open-type hoist or pump motors are used. The problem has been greatly simplified at the Crucible mine of the Crucible Fuel Co. at Crucible, Pennsylvania.The system is not only applicable to the room-and-pillar method of mining, but it may be adopted for any panel system of mining. There also appears to be a definite application in mechanized mining, where the rapid extraction often results in inadequate attention to ventilation and where the gassiness of the section generally increases because, as compared to hand loading, the methane has less time to drain off. The system to be described should commend itself to coal-mining men.ACKNOWLEDGMENTSThis investigation was made possible through the courtesy of H. J. Nelms, general superintendent. E. M. Marshall, safety inspector, E. G. Sauers, assistant superintendent, and Thomas Mark, mine foreman, assisted in the collection of information."

Sep 1, 1931

By John H. Hild

This is a report on work done and results obtained in a minerals exploration program conducted by the Bureau of Mines on the lead-zinc deposits in the Ross Basin-Lake Como district, San Juan County, Colo., in 1948, 1949, and 1950. Four large veins--the Seven Thirty, Red Rogers, Cashier-Shorts top-Canandaigua, and Queen Anne--and several narrow spur veins were explored at relatively shallow depths with core-drill holes. Thirty-nine holes, totaling 10,491.5 feet, were drilled, and the core samples were assayed at the Bureau of Mines station at Salt Lake City, Utah.

Jan 1, 1959

By J. A. Cavallaro

The heats of formation of anhydrous barium carbonate (witherite), strontium carbonate (strontianite), and lead carbonate (cerussite) were determined by solution calorimetry. The solution mediums were hydrochloric acid for barium and strontium carbonates and perchloric acid for lead carbonate. The heats of formation at 298.15° K are as follows: BaCO3 -297.5 ± 0.8 kcal/mole; SrCO3 -294.6 ± 0.5 kcal/mole; and PbCO3 -168.0 ± 0.3 kcal/mole.

Jan 1, 1966

By R. V. Lundquist, H. Leitch

Sodium aluminate is the principal aluminum compound formed in the sinters prepared by the lime - soda sinter process for recovering aluminum from silicate source materials . The properties and characteristics of this compound were studied to improve the efficiency of the process . Crystalline sodium aluminate was prepared by sintering stoichiometric quantities of soda ash and calcined alumina for 1 hour at 1,250 ° C. The extent of aluminum extraction from sodium aluminate was determined in water and in solutions of NaOH and Na₂ CO3 . Nearly complete extraction of aluminum from sodium aluminate was achieved only in solutions containing free NaOH in excess of that supplied by the salt through hydrolysis . About 42.2 to 68.8 percent of the aluminum was extracted in water or in solutions of Na₂ CO . The precipitation of alumina trihydrate from sodium aluminate solutions was shown to be part of a continuous , reversible reaction according to the equation Al (OH ) A1 (OH )3 + OHThe reverse reaction dissolves alumina trihydrate in NaOH solutions to produce sodium aluminate . Approximate equilibrium concentrations were determined for the reaction at 30° , 50 ° , and 70 ° C. False apparent equilibrium conditions for the dissolution reaction appear when only a small excess of alumina trihydrate is present in the NaOH solutions . A large excess of alumina trihydrate must be present before the true equilibrium point is assured . The engineering significance of the data is summarized , showing controls that should be exercised for a successful and efficient process .

Jan 1, 1964

By P. L. Woolf, J. P. Morris, E. Foerster, G. R. Zellars

Measurements of vapor pressure can be used to determine the thermodynamic activities of the components of metallic solutions . The determination of activity by this method requires accurate values for the vapor pressure of the pure component and for its partial pressure above the alloy solution . This investigation was conducted to measure the vapor pressure of liquid manganese for use in future studies of the activity of manganese in various liquid alloys . In related investigations in the Bureau's Pyrometallurgy Laboratory , vapor pressures of copper , iron and nickel have been measured and activit 4 5 6 have been determined in the iron- copper and iron- nickel systems . Difficulties were experienced with manganese which were not encountered in the previous investigations . Manganese oxidizes readily and greater care was needed to maintain an oxygen- and moisture - free atmosphere in the furnace . In addition , liquid manganese wet the refractories and there was a tendency to foam and splash on introduction of the carrier gas . Because of these difficulties several variations in the experimental procedure were studied . These were first tested with silver which has a vapor pressure of the same order of magnitude as manganese but is relatively inert at high temperatures . Although no significant changes in the original procedure resulted from this work, considerable data were obtained for silver and have been included in this report . Bauer and BBrruunnnneerr7/ have reported the only extensive investigation of the vapor pressure of liquid manganese . However , their results are not consistent with the data obtained by McCabe and Hudson for solid manganese . Measurements of the vapor pressure of silver have been reported by McCabe and Birchenal1,2/ Schadel and Birchenall , 10/ Harteck , 11 / Fischer , 12/ and von Wartenberg.13 / Generally , these investigators conducted their measurements at lower temperatures than were used in this study .

Jul 1, 1960

By K. C. Dean

During the investigation of the occurrence of manganese deposits in western United States, the Bureau of Mines collected 2-ton samples from three oxide manganese ores in the Columbia and Elberta Mining Districts, Tooelo and Juab Counties, Utah. To determine the amenability of these ores to standard ore-dressing methods: of concentration, extensive laboratory tests were made. The Wildcat property, one of those sampled, is 7 miles east of Fairfield, Tooele County, Utah. The ore is described as a replacement deposit and occurs along fracture and bedding planes of shale and limestone. Experimental work was done on a sample taken from a stockpile at the mouth of the shaft. The Wildcat manganese ore is intermediate in grade (25.7 percent manganese) and contains clay as the principal gangue constituent. A high-grade product was obtained with high recovery of Manganese by simple washing.

Jan 1, 1949

By Terry J. Close

The Anaconda Pintlar Wilderness has a significant mineral resource potential. Five deposits have resources totaling about 180,300 tons (163,600 t) containing silver, copper, lead, gold, and zinc. Another 11, not sufficiently exposed to allow resource estimates, may have additional mineral potential. No placer deposits are indicated. There is little potential for the production of sand, gravel, or stone; alternate sources are closer to markets. No oil, gas, uranium, or geothermal energy sources are known to be present.

Jan 1, 1982

By Lloyd Williams

1. Reserves have been estimated for three coal beds in Bledsoe County, Tenn.: Morgan Springs, Lantana, and Sewanee. The Richland and Nelson beds occur in Bledsoe County also, but there was not enough information on them for making an estimate of reserves. 2. Known measured and indicated reserves for all beds, based on a minimum thickness of 14 inches and on 1,800 short tons per acre-foot of coal in place, are estimated at 43 million tons as of January 1, 1954. Of this total, 22 million tons represents coal 28 inches and more thick. Areas in the beds were omitted from the estimate because available data relative to the bed characteristics were insufficient for making an estimate conforming with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves deter-mined by this investigation.

Jan 1, 1956

By S. M. Shelton, F. D. DeVaney, M. M. Fine

Ferrograde manganese ore or its equivalent is essential to the manufacture of every ton of steel produced ; although it is well -known that there are large deposits of low - grade ore in the United States , the production of substantial amounts of ferrograde material from domestic sources presents a problem that becomes more and more critical as the stockpiled ore is depleted through inability to obtain adequate supplies from foreign sources . Consequently, a program of laboratory and pilot - plant investigations designed to solve the problem of obtaining a domestic supply of manganese has been undertaken by the Metallurgical Division, Bureau of Mines . This paper is one of a new series that will include reports of results obtained in the various investigations conducted under the manganese program . The scope of the program and the organization that was set up to direct and supervise the work were discussed in the foreword of the first paper of this series , Report of Investigations 3606 , Manganese Investigations 1. Concentration of Manganese Ores from the Drum Mountain District, Utah, by S. R. Zimmerley, J. D. Vincent , and C. H. Schack . Other reports will be published as the work progresses .

Feb 1, 1942

By Edward M. Kawenski

Tests were made in the Bureau of Mines Experimental Coal Mine on stop-pings similar to those used in operating coal mines to obtain information on air leakage through the face and the rupture strength of a stopping subjected to a pressure differential. Block stoppings were made from cinder, slag, and gravel aggregates with and without mortared joints and coatings. Sheet stop-pings were uncoated brattice cloth and nylon or brattice cloth and expanded metal-lath coated with asphalt, latex, mortar, or rigid urethane foam. Limited data were obtained on air through stoppings subjected to simulated roof convergence and to shock forces created by the firing of an adjacent charge of explosive. The pressure differential required to rupture stoppings was determined. shows that coating the face of a stopping effectively reduces ail: leakage. Block stoppings, particularly those with mortared joints, are most resistant to pressure and shock forces than are sheet stop-pings. Where ground movement is a factor, sheet stoppings leak less air than block stoppings.

Jan 1, 1965

BIBLIOGRAPHY Allen, C.A, Analyses of Utah Coals, United States Bureau of Mines Technical Paper 345, 1925, pp. 90. Allen, J.E. and E.M. Baldwin, Geology and Coal Resources of the Coos Bay Quadrangle, Oregon, Oregon Department of Geology and Mineral Industries Bulletin 27, 1944, pp. 160. "Aluminum Boom Raises Productivity", Coal Age, Vol. 82, No.6, June, 1977, pp. 103.

Jan 1, 1978

By Henry C. Meeve

This report describes work done in the Creede Mining district, Mineral County, Colo., in 1965-66 as a part of a Bureau of Mines study of the silver production potential of the United States. The ruining history of the district is briefly covered, and representative former and current mining operations are described. Mining and milling costs of the Emperius Mining Company's operation are given in some detail as being representative of the cost of mining typical Creede ore bodies under current technology. An estimate of the silver reserves and resources of the district is presented, subject to many uncertainties stemming from inaccessibility of old workings, lack of mining records, and low level exploration activity, all of which limit the opportunity to accurately evaluate ore potential. The report concludes with an analysis of future silver production trends in the Creede district. An increase of silver production to as much as I million ounces yearly is projected, possibly starting in 1969. As long as ore bodies in the zone of enrichment, in which silver is a major constituent, contribute a substantial part of Creede production, silver price will affect overall production rates appreciably. As the richer are bodies become depleted, an increasing portion of production again will be coming from primary sulfide ores in which silver is a byproduct of lead and zinc. When this occurs, the level of silver production will be governed chiefly by lead and zinc production and prices and can be expected to decline to the 1960-66 level, which amounts to an average of 240,000 ounces per year.

Jan 1, 1968

By James P. Bennett

The U.S. Bureau of Mines investigated the role of imported natural flake graphites in dolomite-carbon refractories used in steelmaking processes and evaluated carbon fibers as a potential substitute. Varying quantities (1.5-30 pct) of natural flake graphite and carbon fibers were added to test samples. The effect of the additions on modulus of rupture (75°-2,750° F), deformation under load (2,750° F), and air-slag-metal resistance (3,000° F) was studied. Carbon purity of natural flake graphite additions did not influence hot strength, deformation under load, or air-slag-metal resistance. When the quantity of 90-pct-carbon graphite addition varied between o and 30 wt pct, hot strength was highest, deformation under load lowest, and air-slag-metal wear the least at 10 wt pct. As test temperature increased from 500° to 2,750° F, the hot strength difference became less. Carbon fiber additions were limited to 1.5 pct in dolomite-carbon brick. At this level, physical properties were generally comparable to those obtained with natural flake graphite, but were below values obtained with 10-pet-f1ake graphite additions. Carbon fibers are not considered a satisfactory substitute for natural flake graphite.

Jan 1, 1989

By Robert W. Smith

[In a certain application it was necessary to compute the incomplete beta function, ß(1/2, p, q), for a certain set of values of p and q. Since the set of p and q values was much more finely spaced than those in any published tables, the authors have decided to make their results available in this report. In connection with this application, the function ß(1/2, p, q) was needed at various points in the p, q plane at intervals of 0.05, 0.05 p = 2q < 10.00. Fletcher, Miller, and Rosenhead3/ state that the only tables available in the desired range are those of Pearson.4/ However, the interval used by Pearson was not small enough for the present application. For this reason, it was decided to calculate the function ß(1/2, p, q) for p = q = 0.05 (0.05) 10.00. This table is published because of the fundamental importance in mathematical analysis of the incomplete beta function.]

Jan 1, 1953

By D. W. Butner

As a part of the Bureau of Mines program for the discovery and development of critical and essential mineral deposits, the Darwin district, Inyo County, Calif., was chosen for investigation as a possible source of, tungsten ore. Two properties were active in the district at the time. One was producing tungsten concentrate and the other was preparing to produce tungsten concentrate as a byproduct in the milling of lead-zinc ore. The objective of the project set up by the Bureau was to investigate promising areas and to sample, thoroughly those which preliminary inspection indicated contained tungsten ore. Work was begun November 17) 1941, and completed January 19, 1942. In the course of the project, 18 localities were inspected and 9 were sampled. The following pages brief the history, note the location, and outline the physical features and geology of the district. The work performed by the Bureau of Mines is described and supplemented with assay maps.

Jan 1, 1949

By N. C. Dunham

"The Bureau of Mines exploratory work on the Bear Lodge, Wyo., fluorite property wider the strategic minerals Program was completed in November 1944. Exploration consisted of surface trenching, shaft sinking, and drifting at shallow depth. Doak C. Cox of the Federal Geological Survey visited the area during the latter part of 1944 and napped the Bear Lodge property.The Bear Lodge property is situated in the Black Hilts National Forest in eastern Crook County, Wyo., 6 miles north of the community of Sundance (fig. 1). Sundance is 29 miles northwest of Upton, Wyo., a station on the Chicago, Burlington, & Quincy Railroad and 43 miles southwest of a siding on the Chicago & Northwestern Railroad, 3 miles south of Belle Fourche, S. Dak. U. S. Highway 14 passes through Sundance in an east-west direction. Sundance may be reached from the south over U. S. Highway 85 and Wyoming State Highway 585.The Bear Lodge property i a situated in the Boer Lodge Mountains in secs. 15, 22, and 23, T. 52 N., R. 63W., 6th P.M.The topography in the vicinity of the fluorite deposits consists essentially of rounded hills which slope gently to the valley floors. Near the north end of the Property the terrain steepens locally, and the canyon walls are Precipitous along the courses of several streams. There is an adequate supply of water and native timber for mining purposes. The average elevation near the deposits is 5,700 feet.The climate of the region is relatively moderate. The summers are usually warm, with frequent rainstorms. Temperatures often fall below zero during the winter months. Snowfalls are moderate to heavy.Fluorite occurrences in the Bear Lodge area have been known since 1914; however, fluorite was not discovered on the Bear Lodge property until 1943, when prospectors working on a nearby manganese deposit found fluorite mineralization in the limestone. No production has been recorded from the property."

Apr 1, 1946

By Richard H. Spencer

Since the passage of the Coal Mine Health and Safety Act of 1969, the Bureau of Mines has made many advances in mine communications. These efforts have resulted in the following developments and demonstrations: Surface-to-surface electromagnetic transmission of baseband voice signals through overburdens as deep as 600 feet. This transmission was achieved with equipment from the Interim Mine Rescue and Survival System Program, and demonstrated that baseband voice communications could be obtained through these overburdens in the absence of mine-generated noise; that is, when the mine power system was shut off, However, during mine operational conditions, the mine-generated noise proved to be so large that effective baseband voice communications to the desired depths could not be effected.

Jan 1, 1975