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By G. W. Murrie, W. P. Diamond, C. M. McCulloch

It is estimated that more than 1 trillion cubic feet of methane is contained within the coals of the Mary Lee group in Jefferson, eastern Tuscaloosa, and southern Walker Counties, Ala. Most of this methane will be encountered by mining. Coals of the Mary Lee group are presently being mined at depths exceeding 1,000 feet and will in the near future be mined at even greater depths, where the problem of methane gas affecting the mining operations will be acute. It is calculated that approximately 90 pct of the methane is at depths greater than 1,000 feet, and over half of the gas is contained within only 12 pct of the study area which is under more than 1,500 feet of over- burden. Degasification in advance of mining will increase mine safety, reduce ventilation expenditures, increase productivity, provide an additional energy source, and make it possible to mine parts of deep coalbeds that probably could not otherwise be mined.

Jan 1, 1976

By Larry J. Nicks

The Bureau of Mines is investigating the catalytic activity of rare-earth compounds to develop a catalyst for the cathode reaction of a hydrogen-oxygen fuel cell. This report presents the results of studies of the catalytic activities of lanthanide oxides for the oxidation of hydrogen at 150° to 250° C. Preliminary activity tests were made with approximately stoichiometric mixtures of hydrogen and oxygen diluted with helium. A series of tests was also run under oxygen-rich conditions in which specific rate constants and activation energies were determined. Variations in rate constants up to 2,000 times were observed for the various lanthanide oxides. The three most active catalysts were oxides of Ce, Pr, and Eu, having specific activities of 6.93 X 10-7, 4.88 X 10-7, and 4.06 X 10-7 moles H2.sec-1.m-2, respectively, at 200° C.

Jan 1, 1973

By Anthony Iannacchione

One of the more pressing engineering problems for deep longwall mines in the Southern Appalachian Basin is to design longwall systems that will eliminate catastrophic coal pillar failure from the working environment. The purpose of this study is to quantify the behavior of a particular size abutment pillar prone to burst or bump. Because the 24.4-111 (80-ft) square abutment study pillar is within the pillar size commonly used in this region, understanding the behavior of this pillar should aid in future efforts to design optimum mining strategies. This research has attempted to construct the pillar stress and roof-to-floor convergence profiles in order to evaluate the ultimate strength, deformation modulus, visco-elastic deformation, and violent failure characteristics of the pillar during longwall mining. This information reflects the overriding influence of the local geologic characteristics on bursts, provides the field measurements needed to verify concurrent modeling studies, and suggest some basic mechanisms associated with the coal pillar bursts discussed in this paper.

By David R. Forshey

This Bureau of Mines report presents a quantitative theoretical analysis of a coupled gasdynamics-heat release system involving the kinetics of water condensation in and behind the rarefaction wave in a shock tube using the method of characteristics. The merger of characteristics to form a shock wave is included.

Jan 1, 1977

By A. E. Raddatz

The Bureau of Mines has determined the electrochemical rate of anodic dissolution of vanadium metal in a VC12-VC13-NaC1 electrolyte at 860' C for the purpose of elucidating the reaction mechanism. Rate measurements were carried out with the help of specially designed equipment capable of continuously recording the weight loss experienced by a cylindrical vanadium anode immersed in the molten salt electrolyte while a constant current is maintained through it. The rate is expressed as a function of current density and VC13 concentration, and the reaction is interpreted in terms of an adsorption mechanism. Multiple regression analysis of the data gave the following rate equation: Rate x 104 (g.cm-2.sec-1) = -0.38 + 2.64 current density (amp-cm-2) + 0.69 log, (mole-percent VC13).

Jan 1, 1974

By W. P. Rumancik, C. P. Lazzara, A. C. Smith

The United States Bureau of Mines (USBM) developed SPONCOM to aid in the assessment of the spontaneous combustion risk of an underground mining operation. A prior knowledge of the spontaneous combustion risk of the coal and factors that increase that risk can be useful in the planning and development of proactive monitoring, ventilation, and prevention plans for the mining operation. Interactive data input screens prompt the user for information about the coal's chemical and physical properties, the geologic and mining conditions encountered in the mining of the coal, and the mining practices employed. During the input process, 'expand' screens provide the user with specific information on each input parameter. This information includes a description of the parameter and its effect on the overall spontaneous combustion risk. The program logic determines the coal's relative spontaneous combustion potential, based on the coal's proximate and ultimate analyses, and heating value. The program then evaluates the impact of the coal properties, geologic and mining conditions, and mining practices on the spontaneous combustion risk of the mining operation. The program output provides details on each factor that increases the risk of spontaneous combustion.

By M. MacLaughlin, J. Whyatt

A case study is presented that relates statistical descriptions of joint sets to the distribution of local wedge failures along the crest of a catch bench at the Yellowstone Talc Mine. The fracture sets and bench width were mapped by teams of geological engineering students from Montana Tech under the direction of Dr. Mary MacLaughlin. The students analyzed the fracture data, conducted physical property tests, and used a beta version of a NIOSH program “Bwedge” to predict the distribution of surviving bench widths. In the course of this analysis the students developed evidence of software performance issues that, unfortunately, frustrated their analysis. These have now been addressed and a full analysis completed. The analysis confirms the validity of the student mapping program and provides insight into the effects of blasting and excavation practices on the bench. It also provides a tool for exploring the pattern of bench crest failure that would result from variations in both bench geometry and blasting practices.

By R. V. Ramani, C. B. Manula, A. Owili-Eger

MINE PROTOTYPE The prototype chosen for application demonstration is from Kingery (1960). The mine and the ventilation plan is presented in Figure 11. A new coal mine is projected with entrance by slope 1,500 feet long. Nine train entries will be standard for development, five as intake and four as return. One return shaft is planned near the slope bottom. The slope will have an area of 150 square feet and a perimeter of 55 feet. The return shaft will be circular with a diameter of 18 feet and will be 500 feet deep. Two hundred feet of the shaft and 500 feet of the slope will be concrete lined. Will it be possible to operate five units per shift with amount of air at each unit not less than 25,000 cfm? Additionally, a shop at the slope bottom will require 10,000 cfm. The problem is completely worked out using standard ventilation formulas and simple manual calculations in the above reference and is reproduced here in Appendix II for ready reference. APPLICATION In this manual, four different applications of the PSU/MVS are outlined. An article by Stefanko et al (1972), outlines how one can move from a mine map to a network for the generation of computer input. Attention is drawn to Figure 12, which is the network line diagram of the mine ventilation system in Figure 11. Note that every roadway junction has been numbered. The dotted lines represent leakage paths and the letter 'R' on a branch denotes that the split is regulated for the quantity shown. For example, there is a leakage

Jan 1, 1975

By R. V. Ramani, V. T. Burgos, J. A. McClay

Cost Systems Cost systems are organized methods of collecting, allocating, and accumulating resource utility expressed in terms of money. There are two major spheres of cost accumulation: financial accounting and cost accounting. Financial accounting deals primarily with historical costs and provides a means of measuring and recording cost events which have al¬ready taken place. While there are no legal requirements to control the methods of recording and reporting cost data in the United States, the procedures in use are guided by professional organizations such as the American Institute of Certified Public Accountants. The final pro¬ducts of financial accounting practices are the income statement and balance sheet which describe the financial status of the organization under study. Cost or managerial accounting is an expansion of financial ac¬counting procedures, providing more detailed cost breakdowns on present operations with one objective being the projection of present costs into the future. The projection process tends to limit the accuracy of the information; however, to management and project justification per¬sonnel, data on future operations tends to be of greater value. The basic principle behind cost accounting is the cost cycle. As products are developed from raw materials, the value of the work-in¬process increases due to the cost input of the various fabricating ele¬ments. Thus, from the basic input elements of facilities, labor, and raw materials, costs are added to each unit of production as a function of the work performed on that unit.

Jan 1, 1975

By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By G. L. Oldright, John D. Sullivan

"The present article is the second of a series of papers dealing with the dissolution of copper minerals in various reagents. Work done on the problem has been carried out at the Southwest Experiment Station of the United States Bureau of Mines, in cooperation with the Department of Mining and Metallurgy, University of Arizona. The first paper4 dealt with the dissolution of azurite, malachite, chrysocolla, and tenorite. Preceding articles5 have also dealt with other factors involved in the leaching of copper ores.Cuprite (Cu20) is usually considered as a mineral which is not adaptable to sulphuric acid leaching. Hofman,6 in describing leaching by sulphuric acid, states: ""Cuprite is decomposed into CuO and Cu; and ore carrying cuprite has to be oxidized (weathering, roasting) before treatment."" Greenawalt7 says: ""When acted upon by dilute sulphuric acid, it is partly reduced to metallic copper and partly oxidized into copper sulphate. When heated with strong acid it is entirely oxidized to sulphate."" Work to be described in this article was undertaken to ascertain the conditions whereby all the copper in cuprite could be converted into the soluble sulphate."

Dec 1, 1929

By Daniel N. Tallman

To provide technology for achieving more efficient water filtration systems for the mineral industry, the Bureau of Mines performed demon-stration filtration tests at three iron ore mines and one steel mill. A comparison of equivalently sized magnesium oxide (MgO) and sand filters showed that MgO had a higher capacity and could operate at higher fil-tration rates than sand. In demonstration tests when alum (AlK(S04)2) was the coagulant, suspended solids breakthrough occurred even though the pressure across the filter (head loss) was 7 psig or less. Under these circumstances, the MgO demonstrated 20 to 100 pct greater filtra-tion capacity, defined in terms of the volume of water filtered before breakthrough. When an organic floccu1ant was used at one location, head loss was the run-limiting factor; the filters essentially plugged with-out any solids breakthrough.

Jan 1, 1985

By John Ward Smith

The Bureau of Mines derived equations expressing the theoretical relationship between density of oil-shale rock and its organic content. Effects on theoretical shale density produced by variations in mineral composition and organic matter properties were evaluated. The theoretical relationship was extended to relate oil-shale density to oil yield in both oil weight and volume units by considering the fraction of organic matter converted to oil and the specific gravity of the oil produced. Corollary equations relating organic content by volume to organic content by weight and to oil yield were developed. The general relationships apply to an oil-shale deposit uniform in character. Application of the theoretical relationships to Green River Formation oil shales was demonstrated.

Jan 1, 1969

By C. M. Flynn

The Bureau of Mines prepared and investigated xanthated sawdust adsorbents to determine their effectiveness in removing heavy metal ions from dilute aqueous solutions, mine-drainage waters, and brines. Stripping of the metal values from the metal-laden adsorbent was also investigated. The treated sawdusts had an adsorption capacity of 0.3 to 0.4 meg/g dry adsorbent for Mn, Co, Ni, Cu, Ag, Zn, Cd, Hg, or Pb from feed solutions with pH 5 to 6. The feed solutions tested included mine-drainage waters and geothermal brine. Effluent metal concentrations as low as 0.05 to 0.1 mg/l were obtained at effluent pH values of 6 to 9. The order of affinity of metals for the sawdust adsorbent is Na«Ca~Mg~Mn<Zn<Ni<Cd<Pb~Cu. The presence of Ca, Mg, or Na in concentrations as high as 2 g/l does not seriously impair the heavy-metal adsorption. Metals were desorbed from the metal-laden adsorbent by elution with dilute mineral acids, sodium cyanide, or salts of ethylenediaminetetra-acetic acid.

Jan 1, 1979

By Thomas F. Tomb

The penetration characteristics of a horizontal plate elutriator and of a 10-mm nylon cyclone were evaluated. The test aerosols were polydisperse coal-dust particles ranging from less than 0.3 to 15 micrometers in diameter. Particle densities ranged from 1.3 to 1.4 grams per cubic centimeter. Equivalent Stokes diameters were measured using Coulter counter analytical techniques. Experimental results indicate that the penetration characteristics of the horizontal plate elutriator closely approximate the sampling efficiency curve defining the respirable fraction of the dust cloud recommended and adopted by the Johannesburg Pneumoconiosis Conference in 1959. Penetration characteris-tics of the 10-mm cyclone were evaluated at flow rates of 1.4, 1.5, 2.0, 2.5, and 2.8 liters of air per minute. The data indicate that the penetration curve obtained at 2.0 liters per minute most closely approximates the sampling efficiency curve for respirable dust recommended at a meeting sponsored by the U.S. Atomic Energy Commission in 1961.

Jan 1, 1970

By M. D. Schlesinger

Mercury exists in coal in minute quantities, but the large tonnages of coal consumed could represent relatively large amounts of mercury entering the environment. Limits have now been placed on the emission of mercury, and it is important that reliable analytical methods be available to the chemist. The Bureau of Mines has evaluated analytical techniques used by a number of laboratories; most used vapor phase atomic absorption as the final detection method. Neutron activation was used by some of the laboratories. All of the methods described could be applied, but they require careful manipulation to prevent loss or mercury contamination. In the samples analyzed the mercury content ranged between 0.05±0.01 and 0.4l±0.06 part per million.

Jan 1, 1972

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

Mine ventilation can be broadly defined as the branch of mining engineering primarily concerned with the controlled flow of air through mine airways to maintain an acceptable atmospheric environment wherever men work or travel underground. Martinson (1976) has defined three elements of mine ventilation, 1) an engineering element concerned with establishing quality control (removal of dust and gases), quantity control (regula¬tion of air direction and magnitude) and climatic conditioning (temperature-humidity control), 2) a biological element in which an understanding of biological response is used in assessing the mine environment, and 3) a philosophical element requiring judgements as to the degree of risk or worker discomfort that is socially acceptable. Most texts on ventilation, such as Hartman (1961), limit themselves to a discussion of the engineering element. Although also limiting his text to engineering control, Weeks (1928) thoughtfully addresses the other elements in the preface of his book where he states: "Life is brief and happiness elusive under the best of conditions; so beside the commercial aspect must be placed the humanitarian. Is it not reasonable that the operator should give his men a chance to spend their working hours in a comfortable environment, with the danger of sudden death or disability reduced as much as possible?" The statutory requirements of ventilation are, in most countries, established on the basis of biological response as determined by basic research or are dictated by social awareness, often touched off by major disasters, resulting in demands on regulatory bodies for more stringent requirements. To a limited extent, the philosophical and biological elements of ventilation are intertwined in that social awareness may

Jan 1, 1977

Design a high-production coal mining machine with inherent low dust generation and low frictional ignition potential. Approach Constant depth linear cutting (CDLC) provides a longterm solution to excessive dust generation from shearers and continuous mining machines through new design of the rotary drum culling system. Problems with rotary drum systems, which must be eliminated to control the dust generation at the source, include the effect of a con¬stantly varying depth of cut using fixed bit spacing, secondary fragmentation of already broken coal and, frictional heating of bits and entrainment of dust by fanning action due to high drum rotational speed, Each bit on a rotary drum enters the coal face at zero depth of cut, goes to some maximum depth at the horizontal centerline during sump, and exits at zero depth.

Jan 1, 1989

Protect rescue workers fighting fires or mine personnel temporarily working in hot environments from heat stress. Approach A specially designed ice-cooled vest is worn while working in hot environments where cooling the mine air is not possible. How It Works The vest holds a total of 44 individual ice cells in packets that are firmly held near the wearer&apos;s skin. These ice cells remove heat from the wearer, reducing heat stress and increasing comfort. The locations of the ice cells and packets are shown in the diagram. The vest is constructed in three layers with the outer layer being aluminzed fiberglass cloth. Its aluminized surface reflects radiated heat, and its fiberglass cloth provides fire resistance and strength.

Jan 1, 1979

Provide a means for reliable in situ stress change measurements in soft, friable geologic materials under high stress. Background Effective mine design requires a knowledge of changes in rock stress generated by a mining operation. In situ stress measurement can provide a means of obtaining this knowledge from an active mine for the ultimate purpose of design verification and analysis. The Bureau of Mines has designed and tested a device for measuring changes in rock stress-the borehole platened flatjack (BPF). It has found application in investigating stress anomalies due to geologic structures, stress concentrations from multiple seam interaction, and stress abutments from pillar retreat and longwall mining.

Jan 1, 1990