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By J. Hanna, I. J. Anazia

The Mineral Resources Institute (MRI) has developed a unique process for selective fatty-acid flotation of phosphate minerals from siliceous ores. The process takes advantage of preferential adsorption (over silica surfaces) and high reactivity of fatty-acid collectors toward apatite under slightly acidic conditions (pH 5 - 6.5). The process was successful in upgrading various Florida and North Carolina phosphate samples containing 7.7% to 15.3% P205 and 62.3% to 77.2% siliceous gangue (Insol). The resulting concentrates assayed 28.1 % to 33.1 % P205 and 4.1 % to 9.9% Insol, with high P205 recoveries of 81.8% to 92.2%. Depending on the degree of surface contamination of the silica particles in the flotation feed, one or more cleaning steps, with or without sodium silicate, would be required to achieve higher-grade phosphate concentrates.

Jan 1, 1994

By S. Hicks

This technical note describes an alternative procedure that can be used in linear programming calculations where the compliance limit of lbs SO2/million Btu for the blending coal is subject to change. Dr. Mateer in his technical note titled "Coal blending for sulfur compliance" (ME, September 1994, p. 1103) defined an "excess sulfur" parameter that provides a valid constraint equation for a linear program optimization. The coals used by Dr. Mateer in his examples are shown in Table 1. To create the parameters for the constraint equations to blend to an SO2 content of 1.2 lbs SO2/million Btu, the excess sulfur for Coal A was defined as Sulfur excess% = 0.5 - 0.6*13,000/10,000 = -0.28 This equation was used to create the constraint equation -0.28A + 0.44B + 1.36C[<] 0.0 Another way to create the parameters for the constraint equation is given below. In these equations: •W is the total weight; •A, B and C are the fractional proportions of each potential blend stocks; •Sa, Sb and Sc represent the percent sulfur content of the blend stocks; •Ha, Hb and Hc represent the calorific content of the blend stocks in Btu/lb; and •H and S represent calorific and sulfur contents of the composite blend. The weight of blend to produce one million Btu is [ ]

Jan 1, 1998

By Milton E. Wadsworth

Cost effectiveness in gold and silver leaching has centered mainly on reducing or preventing excessive use of lixiviants. In cyanide leaching practice, the active reactants, cyanide and oxygen, present different problems. The activity of cyanide may be adjusted at cost, but oxygen from air, has a fixed, low activity with an equilibrium concentration of ~7 ppm. Consequently, the use of air in agitation and heap leaching presents distinct kinetic problems. The refractory ores are either high consumers of oxygen or tend to immobilize dissolved precious metal-cyanide complexes. Commercial treatment of refractory ores involves oxidation by pressure leaching, roasting or biooxidation prior to cyanide leaching. Chemical reactions important in preoxidation of refractory sulfide ores by pressure leaching and biooxidation are considered. Major emphasis is given to the role of oxygen in heap leaching of oxidized ores.

Jan 1, 1995

By Robert L. Runkel, Kenneth E. Bencala, Briant A. Kimball

Thousands of abandoned and inactive mines are located in environmentally sensitive mountain watersheds. Cost-effective remediation of mining sites in these watersheds requires knowledge of the most significant sources of metals to surface waters. The significance of a given source not only depends upon the concentrations of a toxic metal, but also on the total mass, or load of metal added to the stream. To determine loads, we combined tracer-injection methods, to provide reliable discharge measurements on a watershed scale, with synoptic sampling, to provide spatially detailed concentration data. The resulting load profiles indicate which sources have the greatest effect on streams, where natural attenuation of metal loads occurs, and where ground-water inflows are located. This is part of the information needed for planning remediation of mine-drainage effects. The approach is illustrated by comparing zinc loading curves from three watersheds affected by mine drainage.

Jan 1, 2000

By G. Atesok, M. S. Celik, G. Onal, I. Yildirim

A new coarse cleaning device, the Stripa, has been developed for processing of coal in the size range of -100+10 mm. The Stripa is an auotogenous heavy medium separator originally developed for processing of iron ores. Although it has been employed in concentrating ores such as chromite, it has not been applied in coal cleaning. In this study, a pilot plant scale modified Stripa and its counterpart alternative, a diaphragm jig, are compared using subbituminous and lignitic coals. The separation performance of the Stripa and the diaphragm jig has been established in the light of washability properties of the coal samples. Comparison of the performance of the Stripa with that of the jig indicates that the Stripa can be used in coal preparation circuits as an alternative to jigs in the size range of -100+10 mm. Simplicity, low initial investment, and low operating and maintenance costs make the Stripa a plausible candidate for coarse coal cleaning. More importantly, Stripa due to its short residence time, has a superior capacity over jig.

Jan 1, 1995

By J. L. Hendrix, M. Ahmadiantehrani, G. Ramadorai

The concept of hypochlorite treatment prior to cyanidation in the heap leaching of low grade carbonaceous gold ores is discussed. Laboratory column leach tests using a low grade carbonaceous ore were performed to investigate the effects of pH, hypochlorite consumption and concentration, and bed height on total gold extraction. At high pH, hypochlorite stability increases and thus, hypochlorite consumption decreases. At room temperature, total gold extraction is proportional to hypochlorite consumption. However, at some point additional hypochlorite consumption does not increase gold extraction. Gold recoveries of 10% and 80% are achieved at 12 and 167 lb/ton hypochlorite consumption, respectively. Increasing hypochlorite concentration increases the rate of extraction. For a given hypochlorite consumption, gold extraction increased with decreasing ore bed height. Finally, using calcium hypochlorite results in higher gold extraction than using sodium hypochlorite at a fixed hypochlorite consumption.

Jan 1, 1992

By R. J. Sweigard

Many states are considering the need to establish or modify policy relating to the disposal of coal ash. One of the primary concerns is the impact of leachate from the ash disposal sites upon groundwater and nearby bodies of surface water. A detailed site investigation was conducted at a coal ash disposal facility associated with a power generation station. The disposal site is situated alongside a major river. Monitoring wells were installed and soil samples were taken for characterization. Groundwater models were used to simulate migration of leachate from the disposal site toward the river. Such models have the potential to be used to verify regulatory compliance. This paper addresses the validation and adaptability of these models to this case and their usefulness as possible tools to be used in future environmental audits.

Jan 1, 1993

By Gary W. LaChapelle

Cyprus Miami Mining Corp. has a history of overcoming adversity through innovation and adaptation to changing conditions. Requirements to remain profitable in the 1990s include a combination of advanced technology, employee involvement and training, attention to customer satisfaction, environmental awareness and quality management. The Miami property is located in the Globe-Miami area of Arizona, 130 km (80 miles) east of Phoenix and 160 km (100 miles) north of Tucson. The complex is located in a high desert environ¬ment at an elevation of 1065 m (3500 ft). The region receives about 480 mm (19 in.) of precipitation annually. History Mineralization at the Miami property was first discovered in the 1880s, which led to underground mining of copper by the 1890s. In 1911, the Inspiration Consolidated Copper Co. was formed by combining the Inspiration and Live Oak Mines. Full-scale production began in 1915. Block caving methods were used at both mines. Open-pit mining commenced in 1948. Underground mining had ceased by 1954, and all production was obtained from surface operations. Innovation has been the key to Miami&apos;s success. Development of sulfide flotation and the ferric cure process for vat leaching were advanced at Miami. In situ leaching of oxide material, remaining after block caving had removed the sulfide ore, was also used.

Jan 1, 1993

By J. E. Gebhardt, D. A. Rice, P. E. Richardson

An improved understanding of the significant role of electrochemical reactions in sulfide flotation has evolved in the past 20 years, This understanding has been accompanied by a corresponding increase in attempts to control the electrochemical potential of flotation pulps for monitoring and controlling sulfide flotation circuits to improve metallurgical performance. This paper discusses the basic electrochemistry of sulfide flotation and the use of electrochemical potential as a control parameter.

Jan 1, 1993

By J. G. Groppo, J. G. Justice, B. K. Parekh

Removal of particulates and/or metal ions from mineral/coal processing waste water is a necessity from the environmental point of view. This paper describes application of a novel AC- electrocoagulation technique to remove the particulates as well as metal ions using AC power. A series of laboratory tests conducted on a stable black water sample obtained from a sub-bitminous coal operation provided a clear supernatant (-10 NTU) from the suspension. The process also shows promise in removal of up to 90 percent of phosphate ions and other metal ions (copper and nickel) from solution. A preliminary economic evaluation of the process will also be included.

Jan 1, 1992

By Hector M. Valenzuela, Juan H. Rojas

This paper presents a strategic plan for automation, plant integration and process management being implemented at the Chuquicamata mining and metallurgical complex of Codelco-Chile. This five-year plan considers different levels of process control and plant integration, which include instrumentation and direct control, process models and supervisory control, plant information integration, and real time process and plant wide management. The conceptual solution developed defines an architecture for the overall system and the projects to be implemented by each production unit, as part of the proposed solution for the division wide process control, plant integration and real time process management. An estimate of the cost benefit relation of the plan is also given.

Jan 1, 1998

By O. A. Paulson, D. D. Runnells, D. P. Dupon, K. J. Bruxvoort

Background groundwater quality is often used to drive remediation programs at sites with waters that have been affected by mining activities. In the past, these levels were sometimes chosen without rigorous statistical and geochemical analysis. A probability-distribution approach was used at the Sweetwater Uranium Project to separate a large set of geochemical data into populations that represent contribu¬tions from different sources. Natural background populations were identified for major ions, metals and radionuclides, and these were submitted to the US Nuclear Regulatory Commis¬sion (NRC) to modify the extent of a corrective-action pro¬gram and to establish control limits for future monitoring.

Jan 1, 2000

By Ralph D. Daley, Kevin E. Redinger

The production of coal/water fuel (CWF), a highly loaded mixture of finely ground coal, water, and chemical additives, presents a unique opportunity for significant ash and sulfur reduction through physical coal cleaning. Froth flotation can be integrated with the staged, wet, fine grinding inherent in the CWF production process. A laboratory scale research program was conducted to demonstrate the feasibility of a flexible, integrated coal cleaning/CWF process flowsheet. Performance of the conceptual flowsheet was examined for two coals of CWF commercial interest, Upper Freeport and Pittsburgh seam coals, from central and southwestern Pennsylvania, respectively. Several multi-stage coal flotation and reverse flotation circuits were evaluated. CWF was produced from the cleaned coal in each case at similar solids loadings and viscosities as observed for the raw coal. However, the ash loading and SO2 emission potential for each CWF had been significantly reduced.

Jan 1, 1988

By M. Leroux, S. R. Rao, J. Kim, V. Gervais, J. A. Finch, G. Labonté, N. Macminn, M. Ounpuu

Collectorless flotation of sulphide minerals from Lyon Lake ore (Mattabi Mines Ltd.) has been studied both in the laboratory and plant. Among the four major minerals chalcopyrite showed the greatest response to collectorless flotation, followed by galena. Flotation of sphalerite and pyrite was minimal. Collectorless flotation was influenced by pulp potential and pH. Experiments using different gas compositions showed collectorless flotation was promoted when the pulp potentials were greater than about 0 mV (SCE). The study of the effect of depressants showed that SO2 at pH < 8.0 depresses both galena and chalcopyrite but at pH 9.5 flotation of chalcopyrite recovers. Use of NaCN preferentially depressed chalcopyrite compared to galena. Preliminary results from plant tests at Mattabi Mines Ltd. confirm that collectorless flotation occurs and that it is preferential for chalcopyrite and to a lesser extent galena. Practical implications of collectorless flotation in plant practice are discussed. A critical factor will be silver recovery.

Jan 1, 1989

By A. J. Neale, B. C. Flintoff

A relatively inexpensive and reliable method of using liquid phase tracers to aid in the solution of material balance problems is introduced. The method is of value in situations where one is required to calculate a material balance around a process that has the operating appearance of a "blender" or "splitter" with respect to the available slurry sample data. The paper briefly reviews material balance development and tracer applications in mineral processing, introduces the problem to he addressed, and provides both theoretical and industrial evidence establishing the potential of the method.

Jan 1, 1987

By M. S. J. Leary, M. J. McPherson, O&apos

This paper introduces a computer simulation that extends the use of microcomputer systems for mine ventilation planning. The program was developed as part of an ongoing study to produce a simulation model that would determine the optimum duties of a main fan and a booster fan without requiring the trial-and-error runs that are necessary with currently available programs. To use the new program, the user specifies the location of one main fan and one booster fan, and the minimum required airflows in any number of working places. The computer determines the fan duties that will maintain the required airflows at the lowest operating costs without causing undesired recirculation. The methodology of the program and an example showing how it can be applied are presented.

Jan 1, 1990

By A. Unal

Coal resource characterization usually calls for estimating more than one variable over a block or node simultaneously. Within the realm of geostatistics, each variable has been evaluated independently from the others assuming a lack of significant correlation. Research conducted with coal seams, however, has shown that the variables of immediate interest, such as seam thickness, ash, sulfur content, and density depict some correlation schemes in distinct zones, if not throughout the entire area. The above findings have two immediate consequences : (1) correlation analyses provide guidelines to determine the geologically distinct zones, and (2) where possible, cokriging should be used instead of kriging. This will maximize data utilization decreasing the frequently criticized high estimation errors. The cokriging formulation will also provide more accurate estimates for under sampled variables using better-sampled ones. This is a common case with coal with regard to the non-cored reconnaissance drill holes for which only very few variables were recorded. A case study illustrates the improvements that may be obtained by taking advantage of the intervariable correlations.

Jan 1, 1986

By J. P. Savely

This paper describes the development of a trim blast design to improve the stability of a final pit wall. Description is given of the effects of rock characteristics, rock type, and pit plans on the blast design. Currently, six benches have been mined with trim blasting. A more stable final wall has resulted and the successful program has reduced mining costs over an extended time period. Low-cost blast monitoring and field observation were used to determine peak particle velocity and blast damage. Using criteria developed from this relationship, trim blasts were designed and evaluated.

Jan 1, 1987

By Naum S. Malts, Victor M. Sizyakov, Nikolai S. Shmorgunenko

A method has been developed in the USSR for processing the low-grade high-silica raw material by sintering the aluminacontaining mixes, which is widely used both as a principal process and in combination with the Bayer process. The process parameters were obtained on the basis of a study of interaction and equilibrium states of the individual profiles of a multi-component system Na20-A1203-Fe203-CaO-Si02 at the sintering temperatures. The compositions and melting temperatures of eutectics of the individual profiles are given. It is shown that the most easily meltable mix is one having a red mud as the main component. The variations are given of the sinter physical characteristics and recovery of the useful components with the sintering temperature. Considerations are given on selection of a sinter leaching flowsheet and directions are shown for improving a series method of processing the low-grade raw material.

Jan 1, 1984

By James W. Evans

It appears that all extractive processes involve, at one or more points, fluids (gases or liquids) and that the flow of the fluid is an essential part of the functioning of the process. Usually that flow is turbulent and the turbulent flow frequently determines the rates of mass and heat transfer as well as other important phenomena such as bubble/droplet breakup and coalescence, particle suspension, etc. Over the past decade many attempts have been made to model turbulent flows in metallurgical unit operations. The present paper summarizes some of that work. Amongst the operations considered are agitated leaching, ladle metallurgy, electrowinning/refin- ing, induction furnaces, Hall cells and electro- magnetic casting. Where possible, comparisons are made between model predictions and experimental results.

Jan 1, 1990