Search Documents

By C. R. McClung

"Molybdenum, in the form of molybdenite, is a common byproduct of many copper mining and concentrating operations. Contrary to most copper sulfide minerals where recovery is principally liberation controlled, the recovery of molybdenite is much more complex with fully liberated particles commonly lost to tailings. It is this complexity that facilitated the necessity for a geometallurgical investigation of molybdenite from the Bingham Canyon deposit. The aim of this investigation was to determine the effect mineralogy and/or mineralogical attributes (i.e. morphology, angularity, liberation, size) have on the recovery of molybdenite in the processing circuit. A set of samples was collected from the ores and products produced by Rio Tinto Kennecott’s Copperton Concentrator. All samples were analyzed using normal polarized reflective light, Mineral Liberation Analyzer (MLA) and X-ray diffractometery (XRD) techniques. The results of this investigation revealed the presence of two distinctly different types of molybdenite, which have been identified as the two polytypes of molybdenite, i.e. hexagonal (2H) and rhombohedral (3R). The 2H polytype occurs as textbook-shaped particles in quartz-molybdenite veins that are located in the core of the Bingham Canyon deposit. The 3R polytype occurs as disseminated, “ball”-shaped particles with a dull or frosted appearance along the margins of the mineralized intrusive body or central core. Concerning their metallurgical behavior each type exhibits unique metallurgical properties that are consistent with those reported in the published literature. For instance, the 2H polytype is easily ground and kinetically “faster” floating with surface attributes that are amenable to higher rates of recovery. This commonly results in the production of a high quality molybdenum concentrate under normal operating conditions common to most copper concentration operations. In contrast, the 3R polytype is difficult to grind and kinetically “slower” floating with surface attributes that less amenable to recovery under normal operating conditions. Therefore, in deposits with higher concentrations of the 3R polytype, modifications to the normal operating parameters may be necessary to improve the recovery of molybdenum. Finally, a preliminary investigation into the metal budget of porphyry Cu and Mo deposits indicates that a positive correlation may exist between the total economic metal budget and the polytype content. For example, higher concentrations of the 3R polytype appear to be more prevalent in Au-enriched porphyries versus Mo-enriched porphyries. This observation may also serve to help explain why it is easier to obtain high rates of recovery in Mo ± W-rich deposits, which contain little to none of the 3R-polytype. Consequently, the potential for the metal budget of a porphyry deposit to be used as an indication of the molybdenite polytype present, as well as its impact on the economics (exploration) and/or on the processing circuit (plant design) could exist. In conclusion, this investigation highlights the necessity of understanding the mineralogical properties or characteristics of molybdenite and/or other economic mineral(s), as these can and will have a direct impact upon the performance and plant optimization."

Jan 1, 2016

By K. Darcovich

The wettabilities of agglomerates made from coals of several different ranks were measured by the adhesion technique. Oil levels from 0 to 10% by weight were used. As was expected, it was found that higher-rank coals are more easily oil-wetted and that the surface properties of the agglomerates correlate with agglomeration recovery and ash removal data.

Jan 1, 1992

By L. L. Chasko, D. W. Alexander

Researchers from the National Institute for Occupational Safety and Health’s Office of Mine Safety and Health Research conducted an assessment of the effects that ground control mesh might have on rock and float coal dust distribution in a coal mine. The increased use of mesh to control roof and rib spall introduces additional elevated surfaces on which rock or coal dust can collect. It is possible to increase the potential for dust explosion propagation if any float coal dust is not adequately inerted. In addition, the mesh may interfere with the collection of representative dust samples when using the pan-and-brush sampling method developed by the U.S. Bureau of Mines and used by the Mine Safety and Health Administration for band sampling. This study estimates the additional coal or rock dust that could accumulate on mesh and develops a means to collect representative dust samples from meshed entries.

Jan 1, 2014

By Charles Kocsis, Pedro Nascimento, W. Patrick Arnott, Samuel J. Taylor

Respirable crystalline silica (RCS) is an inhalation health hazard for mining and industrial work environments and must be monitored. We provide theoretical analysis of real-time measurements for determining RCS mass concentration without the use of filters by using photoacoustic spectroscopy. The suspended dust in the mine air can be continuously sampled by the photoacoustic instrument. A tunable quantum cascade laser is the light source, allowing for determination of interferences such as kaolinite, coal dust, and water vapor. The most useful spectral region is found to be between 11 and 13 μm. Absorption by water vapor, and, to a lesser extent, carbon dioxide, in this spectral region has gaps that allow for quantification of the aforementioned dust species as well as a convenient check on the calibration of the instrument. This work brings photoacoustic measurement of aerosol to the mid infrared range where spectrally dependent light absorption can be used to quantify dust composition and mass concentration.

Jul 31, 2022

By D. M. Carris

Since the Buffalo Creek incident in February, 1972, Federal and state environmental agencies have had the pressure on the coal industry in the Appalachian area to close the coal processing plant water circuits. In an attempt to comply with this requirement, Eastern .Associated Coal Corp. decided to install a vacuum disc filter system at its Kopperston plant to eliminate the tailings pond and reduce the amount of plant make-up water. It was recognized at the time that the plant static thickener tailings would be a very difficult slurry to dewater because of its unusually high clay content. The following is a case history of the Kopperston installation and the refinements Eastern has made in its vacuum disc filter operation to increase efficiency.

Jan 1, 1979

By John S. Cummings

Although there are many geologic situations which might be discussed at a session such as this, as I considered the problem, it became apparent to me that I should discuss a situation which has been of concern to me, and should be of concern to the geologic community. As a result, the questions which I will pose, and the criticisms, have not been arrived at quickly or easily, but have accumulated through time, to the point where I feel discussion is necessary. Very briefly let me say that my criticism of geologic mapping, of conclusions reached, and objectives or lack of such, results from my association with many areas where such studies have been completed, and resultingly my inability to comprehend the system of evidence or logic which supports extensive age-formational designations. The heart of the problem is that many conclusions resulting in geologic designations are based on weak or non-existent evidence, and such should be catagorized as hypotheses. Although the geologic community as a group does not approve or disapprove of such designations, it is evident that many or most of such designations attain a "status", and arc accepted as more or less valid statements. As will be shown, the amount of specific lithologic data provided in some quadrangle mapping projects is exceedingly slim. However, of concern herein is that the type of information presented at any stage is sufficient to warrant conclusions drawn. To see the magnitude of the problem, it is probably necessary to review some basic fundamentals upon which our geologic systems are established. The United States Geological Survey has defined a "formation" as the broad unit of geologic mapping consisting of a large and persistent stratum of one kind of rock. Obviously such a designation allows that a formation could be considered "time variant" in a horizontal as well as in a vertical context. However, other definitions enable a formation to mean units

Jan 1, 1972

By R. DasGupta

The dissolution behavior of gold in ammoniacal solutions at 75°C has been investigated. The variables investigated include concentration of lixiviants, pH of the solution and various oxidants. The anodic dissolution of gold was studied in the absence of oxidants using the potentiodynamic polarization technique. The cathodic reaction of oxidants was studied on a platinum electrode. Tafel polarization tests were also performed to determine the dissolution rate. The overall dissolution of gold in ammoniacal solutions was examined using a mixed potential theory. A comparative study on the role of cupric am mine, oxygen, hydrogen peroxide, sodium hypochlorite as oxidants for the dissolution of gold in ammoniacal solutions has been carried out.

Jan 1, 1996

By Ali Ahmadi, Andreas Rausch, Angela Binder, Stefan von der Mark, Dhananjeyan Jeyaraj, Jana Thomas, Nils Nöther, Stefan Wittek, Thomas Ulrich, Eleni Gerolymatou, Mario Kolling, Helmut Mischo, Michael D. Martin, Tugba Sen, Jens-André Paffenholz, Erik Farys, Oliver Langefeld, Wilfried Ließmann

This paper outlines the MOVIE project, which is dedicated to the development of a digital twin for an underground laboratory at the research and education mine “Forschungs- und Lehrbergwerk Reiche Zeche” in Freiberg (Germany). Data from induced rock deformations and temperature fluctuations is collected using fiber-optic sensors. The objective of the project is to establish a virtual laboratory for real-time analysis of the interactions between geology, geomechanics, geometry and ventilation. This will be achieved by integrating models from these disciplines with artificial intelligence, creating a sophisticated hybrid model. The insights gained will enhance safety and efficiency in mining through improved digital planning options, ultimately contributing to more effective resource management and operational decision-making in different mining environments.

Feb 1, 2025

By David S. Cahn

For many years the green and dry compressive strengths' of pellets have been, considered as possible criteria of pellet performance during induration. Although widely quoted throughout the industry, little attention has been given to standardizing the unfired pellet compressive strength test or to determining the characteristics of the test. The purpose-of this study was to compare the constant deformation rate test with that using a constant loading rate in addition, the dependence of these tests on such pellet properties as size, weight, and method of balling was to be investigated.

Jan 1, 1967

By W. C. Dailey

The Groveland Mine. Concentrator and Pellet Plant are located in Dickinson County in the Upper Peninsula of Michigan. The construction of the Groveland Mine in 1959 was the first United States operation for the Hanna Mining Company in mining and beneficiating low grade iron formations. (1) The plant produced concentrates at 675,000 lt/yr. (746,600 mt/yr.) which was used as sinter feed in the steel industry from 1959 to 1963. Upon completion of a pelletizing plant in April, 1963 production increased to 1.6 million lt/yr (1.77 million mt/yr) of pellets. After the plant expansion, mill capacity increased to 2.2 million 1t/yr (2.43 million mt/yr.), producing 2.0 million It/yr (2.23. million mt/yr.) of pellets assaying 63.0% iron and 7.0% silica. (1) Prior to April, 1971 the concentrator operated with a flowsheet consisting of spirals and a petroleum sultonate iron notation circuit. This was presented in a paper by R. R. Smith and E. E. Sougstad, "Flotation at the Groveland Mine" in the 50th Anniversary Volume entitled "Froth Flotation". The ore body at the Groveland Mine consists basically of two types of iron formation (34% total iron, 20% magnetic iron head), the most abundant of which is a bedded magnetite-chert-silicate rock. This is intermingled to varying degrees with non-bedded to poorly bedded hematite-clastic quartz-chert rock. (1) In developing the Groveland flowsheet, Humphrey spirals were used because of their ability to produce a coarse size concentrate at a low cost. Tests run in the lab and pilot plant on the Groveland ore showed a. spiral weight recovery in the 27 to 33% range. (2) However as the ore body was opened up, it became evident that the most abundant ore type did not liberate at the coarse size fraction needed for spirals. Plant recoveries for the first five years operating the spirals only averaged from 10 to 15% weight recovery. In 1971 the weight recovery on the spirals had dropped to a low of 5%. To increase iron recovery and at the same time increase plant capacity with the least effect on the present operations the mill flaw-sheet proceeded from a spiral-notation circuit to an all flotation circuit to a magnetic separator-flotation circuit. During this changeover the concentrate grade also had to be improved to meet market demands. To do this the following changes evolved

Jan 1, 1978

By G. Deschênes

Silver minerals are known to have slow leaching rates and low overall extraction and require a high concentration of cyanide and a long retention time to maximize leach extraction. Their response to cyanidation is considered mild to moderately refractory, largely due to complex mineralogical compositions. New research on improving the dissolution of silver minerals in cyanide was performed using high-purity minerals, as well as a high-grade ore sample from the Kupol property, owned 75% by Kinross Gold. The high-purity silver minerals studied in the leach investigations included acanthite, stephanite and pyrargyrite, which were also the predominant silver minerals in the Kupol ore sample. Dissolution of silver from acanthite produced only 37% extraction in 48 hours of leaching with 500 ppm NaCN. Analysis of the leached acanthite surface showed appreciable formation of polysulfide species, which can interfere with silver leaching. Adding lead nitrate into a pretreatment stage increased the acanthite silver extraction to 86.2%. No polysulfide species were formed with the addition of lead nitrate from the surface analysis. Cyanidation of stephanite and pyrargyrite produced very low dissolutions of silver, only 12.6% and 10.4%, respectively, in the absence of lead nitrate. Silver extraction from stephanite improved to 98% by adding lead nitrate directly to the leaching stage, whereas pyrargyrite required a pretreatment with lead nitrate to extract 83.2% Ag. With the addition of lead nitrate, the mineral surfaces had a PbO species and minor amounts of Pb(OH)2 and antimony was oxidized on the stephanite and pyrargyrite surfaces during leaching. There was a much greater concentration of Sb(V) on stephanite relative to pyrargyrite. Therefore, lead forms a redox couple on silver mineral grains and favors the oxidation of silver minerals. The high-grade Kupol sample assayed 22.6 g/t Au and 359.3 g/t Ag following treatment by gravity separation. Gold and silver extractions from the Kupol sample were 94.5% and 82.9%, respectively, using 500 ppm NaCN and 250 g/t lead nitrate. The findings to improve the extraction of silver from the ore sample with lead nitrate addition were congruent with those to improve the extraction of silver from the individual high purity minerals. Pretreatment did not, however, improve gold or silver extraction significantly with the ore sample.

Jan 1, 2011

By John Hanna

Over the years the coal industry in Alabama has generated about 150 million tons of fine waste coal, increasing at a rate of 2 million tons/year, during mining and cleaning operations. Reclamation of the fine-size wastes containing 20-60% by weight clean coal provides, free of charge, mined and crushed feedstocks for coal recovery and eliminates a major source of acid water pollution. Tests were made on the impounded wastes and current plant discharges to recover the coal fraction by sizing, gravity and flotation techniques. Gravity separation of the plus 100 mesh material produced commercial grade coal averaging 8.2% ash, 0.8% sulfur and 13,350 Btu/lb. However, the coal recovery was relatively low at 50-65%. Froth flotation using mechanical and froth column methods gave similar coal products at much higher coal recovery of 87-93%. The coal produced analyzed 10% ash and 1.1% sulfur.

Jan 1, 1991

By Karl C. Dean

To assist in the reduction of environmental degradation resulting from milling operations, the Bureau of Mines has developed, and successfully demonstrated, chemical, vegetative, and combined chemical-vegetative procedures for stabilizing milling wastes under varying environmental conditions. Costs of achieving reclamation using these stabilization procedures are compared with those of other physical and vegetative approaches. The Bureau's chemical-vegetative procedure for establishing vegetation directly on fine-sized wastes compares favorably with other stabilization processes that have been used.

Jan 1, 1972

By D. McElhinney, K. Mohamed, T. Batchler, T. Matthews

Steel props are a type of standing support utilized in coal mines to support mine roof. In addition to the vertical roof loading, sometimes the steel props are subjected to lateral loading of spalled ribs. To enhance the safety of mine workers, the performance characteristics of the steel prop was studied under different scenarios of vertical and lateral loadings. Quik Stik props were used for use in this study. A uniaxial compression loading test was conducted for the Quik Stik prop assembly (inner and outer tubes, ball bearings, collar) to investigate the loading mechanism of the prop. Rupture tests were conducted for the inner and outer steel tubes of the Quik Stik props to estimate the yielding strength of the steel tubes. Nine Quik Stik props of 8-ft high were tested using the Mine Roof Simulator (MRS) at the National Institute for Occupational Safety and Health (NIOSH) Pittsburgh research facility. Three props were tested under vertical loading to measure the vertical loading capacity of the props. Six props were tested under lateral loadings with low and high roof-to-floor convergences to measure the lateral loading capacity and the retained vertical loading capacity of the props during lateral loading. Vertical loading tests showed that the tested props could be classified as yieldable supports with a stable load capacity of about 110 kips to 140 kips. Lateral loading tests showed that the vertical load capacities of the tested props were diminished because of applying lateral loads, and the props behaved as nonyielding supports with a maximum lateral load capacity of about 8.5 kips to 9.5 kips at stable lateral displacement up to 3 inches.

Feb 1, 2023

By Rebecca Boakye, Zohreh Kazemi Motlagh, Virginia T. McLemore

The most significant uranium (U) deposits in New Mexico are sandstone-hosted deposits in the Morrison Formation (Westwater Canyon Member), where >169,500 short tons of U3O8 were produced from 1950 to 2002. In addition, >9076 pounds of vanadium (V, a critical mineral) and some molybdenum (Mo) were produced from these deposits. These and other U deposits (limestone-hosted, U-veins) in New Mexico also contain critical minerals. Critical minerals are mineral resources that are essential to our economy and whose supply may be disrupted; many critical minerals are 100% imported into the U.S. Some sandstonehosted, limestone-hosted, and U-vein deposits are elevated in heavy rare earth elements. One sandstone-hosted sample contained 0.3 ppm Re (critical mineral), 659 ppm Se and 408 ppm Mo. The arsenide five-element vein deposits in the Black Hawk district are mineralogically and texturally complex, low- to moderate-temperature, hydrothermal, structurally-controlled, Ag-Co-Ni-Bi-As bearing carbonate vein systems with local minor elements. Mineralized samples from Black Hawk contain up to 9970 ppm Ag, 8540 ppm As, 5690 ppm Co, 72,400 ppm Ni, 57 ppm Bi, 165 ppm Sb, and 32,600 ppm U.

Feb 22, 2026

Dravo Corporation was founded in 1891 and has long been recognized as a major domestic engineering and construction firm headquartered in Pittsburgh. In 1977, Dravo had revenue of $852.2 million with international business activities contributing $248 million; quite a different picture than envisioned at the turn of the century. Engineering and construction activities still dominate Dravo's most recent history and will do so for the immediate future. However, fluctuations in capital spending by large industrial sectors of our economy during the late sixties were affecting Dravo's planning for continued growth along its traditional lines of business. Diversification was a possible solution to smooth out the upward trend in corporate earnings. One large result of these continuing efforts was the formation of Dravo Lime Company, a vertically integrated, proprietary chemical supplier for the air pollution control market. Briefly retracing the seventies, the passage of the Federal "Clean Air Act" in 1970 supplied the impetus for Dravo Lime Company. This law promulgated limits on the emissions of sulfur dioxide (SO2) from large stationary sources that would affect local air quality. The major industry that felt the brunt of this regulation was the electric utility industry, especially those generating electricity with coal-fired boilers. The law hastened the development of a new industry, flue gas desulfurization (FGD), and is composed of three major segments: (1) the electric utility, (2) the FGD equipment suppliers (the scrubbing modules), and (3) the scrubbing chemical suppliers. Dravo's experience suggested the equipment end of the business but market analysis indicated that our long range corporate goals could be better attained by investigating the chemical processes involved in the removal of the SO, gas. The result being Dravo Lime Company. This paper will briefly describe the Thiosorbic lime scrubbing process and review our innovative mine and calcining facility.

Jan 1, 1978

By William I. Weisman

Natural sodium sulfate is obtained from both brines and solid deposits. The brines almost always contain other salts with sodium chloride predominating. They may be obtained from surface occurrences, such as Great Salt Lake or from shallow subterranean deposits. Althought many sodium sulfate minerals are known to exist, only three are of commercial significance. These are thenardite, the anhydrous salt; mirabilite, the decahydrate; and glauberite, the double salt of sodium and calcium sulfate. The reader is referred to Weisman (1983) for details on mineralogy and geology of sodium sulfate minerals. Sodium sulfate deposits, either in the form of brine or solid minerals, are found in many parts of the world. Natural sources, by far, provide the primary supply of commercial grades in Canada, Mexico, Spain, and probably in the U.S.S.R., Chile, Argentina, and Turkey. In the United States, production of natural material and synthetic (including by-product) are about equal in volume and have been for many years.

Jan 1, 1984

By J. H. Howard

The purposes of this report are to summarize the findings of the Committee on the Challenges of Modern Society Non-electrical Project (a working committee of the North Atlantic Treaty Organization) and also, thereby, to provide an introduction and review of the current situation regarding non-electrical applications to those who are interested in the subject.

Jan 1, 1975

Silver bearing bulk sulfide concentrates from several Peruvian mines were autoclaved in a 19 liter (five gallon) laboratory autoclave in Lima, Peru. Cyanidation of autoclaved concentrates following a hot lime jarosite destruction step extracted over 98 percent of the silver and over 95 percent of the gold. Autoclave operating parameters such as time, temperature, pulp density and autoclaved solids recycle were investigated and reaction rates determined. The problems of excessive heat generation, silver solubility during autoclaving, and formation of pellets containing unreacted sulfides were addressed. The data presented will be used to design a continuous autoclave pilot plant to pro-vide reliable scale up data for a 50 -100 ton per day facility.

Jan 1, 1992

By Katarína Gáborová, Marcela Achimovičová, María Florencia Márquez‑Zavalía, Jaroslav Briančin, Oľga Šestinová, Pavel Škácha

In this paper, the structure, morphology, chemical composition and leaching of naumannite ( Ag2Se) were studied. Mechanical activation of Ag2Se in a planetary ball mill resulted in increasing its specific surface area. The influence of milling time on the particle size was studied by particle size distribution analysis and scanning electron microscopy. The leaching kinetics of non-activated and mechanically activated samples in 3.5–7.9 mol/L HNO3 solutions were examined. Subsequently, the effect of leaching temperature in the range of 25–50°C on the recovery of silver from mechanically activated naumannite was documented. The maximum yield of silver 94% was achieved after 120 min of leaching in 7.9 mol/L HNO3 at 50°C for the sample mechanically activated for 30 min. Based on calculated activation energy values from the Arrhenius equation, a mixed leaching mechanism consisting of diffusion and surface chemical reaction as the rate-controlling steps of the solidliquid reaction was assessed.

Mar 4, 2023