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By V. Iordachita

In the beginning of the third millennium, the world mining industry has to cope with many challenges; the continuous need for mineral resource deposits and the mostly unsolved economic efforts should be accompanied with ecologic measures mankind has to take in order to avoid self-destruction. The present paper analyses the possibilities of using underground mining spaces in Romania for storing dangerous waste and suggests viable solutions. The characteristics of dangerous wastes and their disposal in suitable underground spaces are analyzed. Also, some methods for deactivating dangerous solid wastes as well as the importance of monitoring underground spaces in order to eliminate environmental impact risks are presented.

Jan 1, 2008

By B. J. Scheiner

The presence of organic materials in gold ores cyanidation. The presence of organic materials interferes with gold extraction by The carbon contained in the ore has been shown to adsorb gold cyanide complex from solution. Removal of the carbon content by roasting or chemical oxidation prior to cyanidation results in gold extractions of 85 to 95 pct. This paper by the Bureau of Mines, U.S. Department of the Interior, discusses how the mineralogy of the carbonaceous gold ores affects gold recovery by cyanidation. It also discusses the advantages and disadvantages of roasting and chemical treatment to render the ore amenable to cyanidation.

Jan 1, 1987

By S. K. Kawatra, H. Haselhuhn

"In many mineral processing applications it is necessary to know the isoelectric points of the various minerals in the ore to properly perform flotation and other mineral separations. However, current zeta potential analysis technology used to determine the isoelectric point of a particle suspension cannot deliver the isoelectric point of each individual mineral, just an average of the mineral system. Traditionally, individual isoelectric points have been gathered by testing pure, synthetic minerals. These values can vary widely depending on the mineral synthesis procedure and the water quality used during the isoelectric point analysis. A more robust approach for determining the actual isoelectric point of a particular mineral in a mixture of minerals is needed. This paper details a method for determining the isoelectric point of an iron oxide mineral in a siliceous iron ore. The method uses a laser scattering particle size analyzer and a pH electrode to determine the pH at which the liberated mineral particles begin to flocculate as pH is decreased. The pH at which the average particle size rises dramatically is the isoelectric point of the mineral with the highest isoelectric point in the ore. This measurement technique was used on natural hematite, goethite and siderite ores as well as a synthetic mixture of pure silica and pure hematite. The results for synthetic hematite mixtures were comparable to literature values.IntroductionRecently there has been an increased interest in the processing of low-grade iron ores (Bolen, 2014; Carlson and Kawatra, 2008, 2011, 2013; Halt et al., 2014; Halt and Kawatra, 2014; Haselhuhn 2012, 2013; Haselhuhn et al., 2012a, 2012b; Kawatra and Halt, 2011; Liu et al., 2014; Manouchehri, 2014; Sandvik and Larsen, 2014; Semberg et al., 2014). The zeta potential of iron ore minerals is a very important and often overlooked aspect of iron ore mineral processing. Zeta potential is the charge at the shear plane of a surface in an aqueous environment (Carlson and Kawatra, 2013). Many ores consist of a variety of minerals differing in zeta potential. This property of a particle surface in water is responsible for either keeping the particles dispersed from each other or flocculated to each other. This is important during many operations such as flotation, desliming and thickening. Zeta potential is primarily a function of the pH of the water and the mineralogy of the particles, though certain ions within the water can also have a significant impact (Haselhuhn, 2012). Consider the following situation: silica (SiO2) particles and hematite (Fe2O3) particles are suspended in an aqueous solution. These two types of minerals have drastically different zeta potentials throughout the pH spectrum (Esumi et al., 1988). In alkaline conditions, both types of particles exhibit negative zeta potentials and will tend to disperse from each other. In acidic conditions (between pH of 3 and 6), silica has a negative zeta potential while hematite has a positive zeta potential, so these surfaces will tend to be attractive to each other and the particles will flocculate and settle. This phenomenon is visually described in Fig. 1. The pH at which the two minerals begin to attract to each other, or destabilize, is near hematite’s isoelectric point. The isoelectric point is defined as the pH at which the surface has a net zero zeta potential (Carlson and Kawatra, 2013)."

Jan 1, 2015

By A. S. Ibrado

Research investigations on the chemistry of the adsorption of gold cyanide on activated carbon have mostly reduced the role of activated carbon as the provider of the large surface area needed for adsorption. Most do not go beyond suggesting that oxygen functional groups on carbon play a key role in the adsorption process. Our research shows that the nature of the material, specifically its structure, is a crucial factor in the adsorption equation. To delineate the effect of adsorbent properties, gold cyanide was adsorbed on a series of carbonaceous adsorbents, including lignite, coals, anthracites, carbon blacks, graphite and activated carbon, which covers wide variations of composition, surface acid group content, and degree of graphitization. The results show that the adsorption of gold cyanide per unit area of adsorbent is not related to the amount of oxygen groups on the surface or even the total oxygen content of the material. However, they show very strong correlation with the degree of graphitization of the adsorbent, which indicates that the graphitic plates of activated carbon play the most important role. The findings suggest that majority of the adsorption occurs on the plate faces of the graphite crystallites of activated carbon.

Jan 1, 1992

By X. K. Jiang

Upgrading molybdenite ore can be technically difficult and expensive if talc is a major impurity in the ore. The layered structure of molybdenite and talc decreases the surface specificity of floatation and suppression agents, thereby making molybdenite ore beneficiation inefficient if under some wet processing methods. However, oxidic talc surfaces may be distinct from the sulfidic or oxysulfidic molybdenite surfaces, such distinction related to electron work functions and/or densities of electron donors/acceptors sites. If such differences are present, the upgrading of finely sized molybdenite ore by dry triboelectrostatic methods may hold advantages over traditional wet methods.

Jan 1, 1999

By P. Sotiropoulos

In the framework of the Specific Programme: ?Promoting Competitive and Sustainable Growth? a detection system was designed and developed in order to provide an added value service beyond standard instrumentation. In the hydrocarbon industry it will be possible for the first time to detect in a pulse regime, two types of radiation emissions using a single device. This means that any saturation of hydrocarbons can be detected, irrespective of the degree of formation water mineralization, which is a major limitation on currently available neutron-gamma tools, where the formation water has a low mineralization.

Jan 1, 2006

By S. S. Klima, A. L. Mazzella, J. S. Driscoll, T. W. Beck

Previous testing was performed by researchers at the National Institute for Occupational Safety and Health (NIOSH) to improve longwall dust control using underside shield sprays with a longwall directional spray system. This testing provided encouraging results toward respirable dust exposure reductions for longwall personnel, achieving as high as 99% dust reduction at some sampling locations along the longwall personnel walkway. Additional laboratory testing was conducted to test these underside shield sprays in conjunction with a shearer-clearer spray system located on the longwall shearer body. The purpose of this testing was to determine if the underside shield sprays interacted positively or negatively with the shearerclearer sprays. Results from this testing indicate that while the shearerclearer system influences where the respirable dust particles are directed, underside shield sprays can still lower respirable dust exposure for longwall personnel.

Mar 2, 2022

By H. Y. Yang, L. L. Tong

For gold recovery, a Chinese refractory, high-sulfur gold concentrate was subjected to biooxidation with high pulp density in a single stirred-tank reactor. The flotation concentrate contained 36.9 percent sulfur (S) and 33.9 percent iron (Fe). Different experimental regimes for biooxidation were applied. With a mixed culture and by controlling the amount of addition of the gold ores and the pH of the biooxidation system, maximum iron oxidation of 82.6 percent and sulfur oxidation of 79.3 percent were achieved. The experimental results indicate that the pH control was beneficial to the biooxidation of this concentrate. Approximately 28.4 percent of elemental sulfur (S8) was found in the oxidizing slags. Two dissolution mechanisms of elemental sulfur are proposed: (1) FeS2 → S80 → S2O32− → SO42− and (2) FeS2 → S80 → SO42−. The high pH had a positive effect on the reduction of the S8. The results of thermodynamic analysis indicate that as an oxidant the dissolved oxygen can effectively reduce the Gibbs free energy of the pyrite oxidation process and, compared with the reaction of ferric iron as the single oxidant, the oxidation of pyrite is easier. The efficiency of the gold recovery was related to the iron oxidation as well as the sulfur oxidation. Gold and silver recoveries of 92.4 percent and 66.4 percent, respectively, were achieved.

By S. Mathur

Oxide particles are commonly used as fillers in plastics, paper, rubber etc. (particulate composites). The successful fabrication of such composites is dependent upon the adhesive strength of the filler particles to the matrix. The compatibility of the matrix and the filler particles is generally enhanced by adsorption of surface modifiers such as surfactants and polymers at the particle-matrix interface. In order to develop a scientific basis for selection of appropriate modifiers it is necessary to understand their adsorption mechanism(s). Specifically, adsorption of polymeric additives is attributed to a combination of chemical and electrostatic interactions, hydrogen bonding and van der Waals forces. Hydrogen bonding has been suggested to be the primary adsorption mechanism for non-ionic polymers. However, a literature survey of Poly(ethylene oxide)(PEO)-oxide system suggested PEO, a non-ionic polymer, to be substrate specific. A systematic study was undertaken to investigate the adsorption mechanism(s) of a PEO on oxide particles. It was determined that strong Bronsted acid sites on the surface interact with the ether oxygen, a Lewis base, of PEO to induce adsorption. In this work characterization of PEO binding sites on oxides is reported and the mechanism(s) of PEO adsorption discussed.

Jan 1, 1997

By S. E. Phillipson

Slickensides cause potentially hazardous ground conditions in underground coal mines. Investigations by MSHA’s Roof Control Division indicate that many slickensides represent bedding plane faults and drag folds that formed during coal bed decollement, a style of faulting that occurs in shale units above coal seams. These slickensides formed in response to regional tectonic compressional stresses, rather than by differential compaction, and are parallel to folds and thrust faults. This paper relates slickensides in the Appalachian, Illinois, and Black Warrior basins to the structural grain of the Appalachian Mountains, provides descriptions of slickensides, and advocates geologic mapping as a predictive method for identifying areas with adverse ground conditions.

Jan 1, 2003

By Gy. Deák

The Romanian mining and especially the salt mining industry is going through a restructuring phase; among others it has to respect the European Environment Act. One of the most important deficits of the salt mining industry is the implementation of monitoring systems for geomechanics phenomena, in order to develop an important information database and form a real base for salt mines stability, prediction and prevention measures. Monitoring system solutions, involving discontinuous and continuous measurements of displacement / deformation fields, around underground excavations, are presented and discussed. In addition, a case study for the stability prediction of an experimental salt off-set, located in the Praid salt mine, using DKRControl method, is presented. The two monitoring systems use different tools, namely measuring tapes (to determine distance between markers in T-D station) and ultrasonic transducers (SM-TDA equipment).

Jan 1, 2006

By G. Xu, A. R. Kumar, N. A. Amoah

Prolonged exposure to high concentrations of respirable coal mine dust causes coal workers’ pneumoconiosis and silicosis. Underground coal mine roof bolter operators are more prone to elevated exposure to coal and silica dust. The canopy air curtain (CAC) was developed by NIOSH to protect roof bolter operators from the exposure. The CAC supplies filtered air over the breathing zone of the operator. This dilutes the high coal dust concentrations and provides for an impenetrable air curtain. Many studies have been carried out to improve CAC efficiency. However, field test has shown variable dust control efficiencies indicating rooms to further improve due to the nonuniform airflow distribution across the plenum and ineffective perimeter flow. This study therefore redesigns the CAC with optimized flow distribution that effectively protects roof bolters from coal dust exposures. Computational fluid dynamics (CFD) simulations are used to optimize the uniformity of airflow distribution across the plenum to achieve the best possible uniformity. A lab experiment validates the CFD model and confirms the ability of this design to reduce floor dust pickup, prevent external wind infiltration, and offer an improved protection efficiency

Mar 2, 2022

By Marshall D. Himes, Erich U. Petersen

The Sheep Creek deposit near White Sulfur Springs, Montana, is a middle Proterozoic stratabound and strataform sediment- hosted massive sulfide containing 4.5 million tonnes (5.0 million tons) averaging 2.5% copper, and 0.1% cobalt in the upper sulfide zone (USZ) and 1.8 million tonnes (2.0 million tons) averaging 6% copper in the lower sulfide zone (LSZ). Mineralization is hosted in lower Newland shales and debris flow conglomerates in the graben controlled Helena Embayment of the Belt Basin. USZ mineralization is characteristically high in Cu, Co, Ni, Ba, As, Pb, and Ag. Mineralogically it consists of barite, pyrite, chalcopyrite, and tennantite with minor amounts of marcasite and various cobalt minerals. By contrast, the LSZ is higher in Cu, Ni, and Au and lower in Co, As, Pb, and Ag. Mineralogy of the LSZ consists of dolomite, pyrite, and chalcopyrite. In both zones significant amounts of cobalt, nickel, arsenic and copper are incorporated in pyrite rims. Tennantite controls the abundance of numerous trace elements in the ores. Fluid incluison data from hydrothermal USZ barite suggests that mineralization took place at temperatures in excess of 250°C, under relatively oxidizing conditions (f02 = 10-32+1) from moderately saline (1.1-3.5m), metal rich brines. The absence of barite in the LSZ suggests mineralization under more reduced conditions (f02 = 10.38+2). Mineralization was initiated following basin subsidence in excess of 400m. Contemporaneous with movement along a growth fault(s) was upward migration of hot metal-bearing fluids which permeated the loosely consolidated sediments and may have vented on the sea floor. The differences in the two zones may be explained by the effects of variations in local basin morphology and solution chemistry.

Jan 1, 1990

By Robert J. Whiteley, Colin Parker

Two major tunnel projects with a combined value of about $US700 million have been recently completed in Sydney using both soft ground and hard rock Tunnel Boring Machines. The first of these and the main entry in Australia for the Year 2000 Olympics was the New Southern Railway. This is 10 km of mainly soft ground tunnel linking the Sydney’s International Airport with the Central Business District. The second tunnel was designed to alleviate major stormwater pollution of Sydney Harbour and involved construction of the Northside Storage Tunnel. This is19 km of hard rock tunnel at depths exceeding 90 m that connects many of the northern Sydney suburbs of Sydney with the North Head Ocean Outfall. Case studies of these projects describe the use of innovative geophysical technologies comprising gravity and seismic tomographic imaging with geotechnical testing at the feasibility and design stages. This approach minimised construction and financial risk by effectively quantifying the significant geological and hydrogeological issues along these tunnel routes that exerted major controls on these projects.

Jan 1, 2001

By P. Otto, G. Borm, Th. Dickmann, F. Amberg, R. Giese

Based on many years experience, the well approved Tunnel Seismic Prediction System (TSP) has been substantially enhanced for online geological prognosis in underground construction. The method provides high resolution seismic images of the rock mass ahead of a tunnel face via an array of standard anchor rods. These contain3D-geophones and can routinely be installed during the excavation process. A further outstanding feature of the system is the newly developed high frequency repetitive seismic source which can easily be fixed at a tunnel boring machine. A user-friendly software package enables online data acquisition, processing, 3D-visualization, and interpretation.

Jan 1, 2001

By B. Kolonja

This paper considers simulation of truck dispatching system designs using maximum expected production of the truck-shovel system as the measure of performance. Two methods are utilized, multiple comparisons with the best (MCB) and the combination of MCB and the variance reduction technique known as common random numbers (CRN). These two techniques are compared via simulation experiments. The results show that the combined procedure of MCB with CRN is the superior tool to reduce the total number of replications needed to ensure the specified probability of correct selection over the finite number of designing systems. In this case study, MCB with CRN reduces the variance by 29% and the number of required replications by 48%. Also, the MCB with CRN procedure narrowed the confidence interval by 18%.

Jan 1, 1994

By Sureshan K. Moothedath

This paper provides a mechanistic representation for floc formation, growth and degradation and presents results from an experimental study of batch flocculation in which step changes were made in the impeller speed, flocculant addition, and slurry concentration. A discussion of the experimental results is included in terms of the mechanisms of floc formation and size-change.

Jan 1, 1993

By K. Y. Haramy

A scale-invariant theory of the strength and deformability of rock masses in static equilibrium and at incipient failure is proposed. The theory provides a rationale for designing structures in rock. This paper presents results of experiments conducted by the U.S. Bureau of Mines and theoretical methods to determine and interpret in situ strength of rock masses using the borehole shear tester.

Jan 1, 1995

By Sebastian Avalos, Julian M. Ortiz

The long-term mine scheduling is the optimal decision on how to extract and process the mining reserves. The resulting plan is mainly driven by economic, metallurgical, and geological factors. Accounting for their uncertainties leads to a robust solution and the feasibility for economic-risk quantification. In this work, we model the spatial uncertainty of grade distributions of multiple correlated elements, by using a multivariate morphing transformation. The result is a set of multivariate geostatistical realizations of the grades, which honor the conditioning data, the direct and cross variograms, and the multivariate statistical distribution, inferred from a set of samples. These models are the input in a reinforcement learning framework, adopted to train a deep neural network that considers the grade uncertainty and leads to an optimum mine plan after training using deep Q-Learning. Mining and processing capacities, as well as economic parameters and metallurgical constraints, are incorporated as the reinforcement learning environment rules. The method is validated on a real deposit, providing insights for future applications.

Jun 25, 2023

By David A. Holmes

Zeolites are crystalline, hydrated aluminosilicates of the alkali and alkaline-earth metals. Their crystalline framework is based on a three dimensional network of SiO4 tetrahedra with all four oxygens shared by adjacent tetrahedra. The alkali and alkaline-earth cations are loosely bound within this framework structure and may be exchanged, to varying degrees, with other cations or molecular water. Most zeolites can be reversibly dehydrated. At present, close to 40 natural zeolite minerals have been identified and over 100 zeolites have been synthesized. Zeolites are a family of hydrous aluminosilicate minerals whose physical properties provide unique features for a wide variety of practical applications. Zeolites have been known for more than 200 years, but it was not until the middle of this century that their economic potential and widespread occurrence in sedimentary rocks were known. Since 1950, literally thousands of articles and patents have appeared in technical literature, and commercial pro¬duction of natural zeolites may now exceed 1 Mt worldwide an¬nually. In the past 40 years, the zeolite mineral group has changed from that of a museum curiosity to one of an established industrial mineral commodity. According to Breck (1974), zeolites are characterized by the following properties: 1) High degree of hydration, 2) Low density and large void volume when dehydrated, 3) Stability of the crystal structure of many zeolites when dehydrated, 4) Cation exchange properties, 5) Uniform molecular-sized channels in the dehydrated crys¬tals, 6) Ability to adsorb gases and vapors, 7) Catalytic properties. All zeolites are molecular sieves, but not all molecular sieves are zeolites. Activated carbon, activated clays, alumina powder, and silica gels are also molecular sieves. Molecular sieves are materials that can selectively adsorb molecules on the basis of their size, shape, or electrical charge (Clifton, 1987). Commercial application of zeolites is based on the following physical properties: molecular sieving, ion exchange, adsorption, and catalysis. Potential commercial utilization includes hundreds of possible applications. The principal uses at this time, however, are as fol¬lows: -Ammonium-ion removal in waste stream treatment, sewage treat¬ment, pet litter, and aquaculture, -Odor control, -Heavy metal ion removal from nuclear, mine and industrial wastes, -Agricultural use, such as soil conditioner and animal feed supplement. An estimated 800 kt to 1 Mt of natural zeolites were produced and consumed worldwide in 1991. Eight small operators reported collective production and consumption of an estimated 18 kt of natural zeolites in the United States during 1991, mostly for feed additives and for odor control, aquacultural, agricultural, catalytic, and ion exchange applications (Eyde, 1992).

Jan 1, 1994