Search Documents

By Patiño E

Bioleaching is an established technology for the pre-treatment of refractory gold ores and concentrates and the leaching of whole ore copper heaps. In many cases, it offers economic, environmental and technical advantages over pressure oxidation and roasting. However for bioleaching to compete successfully with others pre-treatment processes it needs to be optimized with regard to the parameters that affect the bioleaching reactions and the growth of the microorganism involved. In this sense, this paper focus on the thermodynamic approach applied in bioleaching through of the definition of the growth system and it is thermodynamics analysis, the effect of heat production and energy dissipation on growth and thermodynamic analysis of growth kinetics and the effect of nonstandard conditions.

Sep 12, 2005

By L. Bernoth, I. Firth, S. Rhodes, P. McAllister

As biotechnologies emerge from laboratories into main-stream application, the benefits they offer are judged against competing technologies and business criteria. Bioremediation technologies have passed this test and are now widely used for the remediation of contaminated soils and groundwaters. Bioremediation includes several distinct techniques that are used for the treatment of excavated soil and includes other techniques that are used for in situ applications. They play an important and growing role in the mining industry, for cost-effective waste management and site remediation. Most applications have been for petroleum contaminants, but advances continue to be made in the treatment of more difficult organic and inorganic species. This paper discusses the role of biotechnologies in remediation and pollution control from a mining-industry perspective. Several case studies are presented, including the land application of oily wastewater from maintenance workshops, the composting of hydrocarbon-contaminated soils and sludges, the bioventing of hydrocarbon solvents, the intrinsic bioremediation of diesel hydrocarbons, the biotreatment of cyanide in water from a gold mine, and the removal of manganese from acidic mine drainage.

Jan 1, 2000

By Nelson R. Shaffer

Glamorous, burgeoning biotechnology and mundane industrial minerals would at first glance seem to share little in common, but in truth, modern biotechnology depends on many minerals. Biotechnical processes also can be used in industrial mineral extraction and processing. Biotechnology is broadly defined as the application of biological organisms, systems, or processes to manufacturing and service industries. Genetic engineering has reinvigorated one of mankind's oldest sciences, biotechnology, into a booming business. Many modern processes depend on microorganisms cultivated under very stringent conditions in bioreactors. Minerals from carbonate, sulfate, chloride, nitrate, phosphate, and silicate families are used to provide essential nutrients and to regulate growth conditions (such as pH) in order to assure optimal growth of organisms. Certain cells or enzymes perform better when immobilized upon or within solids, and minerals are often used to immobilize cells, especially in continuous process. Minerals are also used extensively in separating and purifying products of biotechnology. Diatomite, zeolites, and silica are especially useful in purification processes. Industrial minerals also are commonly used to clean up large volumes of process water that must be treated. Biotechnology can be employed in exploration, extraction, and processing of geologic materials and in reducing mining or other environmental problems through bioremediation. Microbes have been shown to solubilize certain elements and so promote extraction of heavy metals, phosphate, aluminum, potassium, and even rare earth elements. In a related technique, unwanted materials such as pyrite impurities can be leached microbially to produce cleaner products in sand and clay industries. Microbial actions can modify surface characteristics and so enhance certain ceramic properties. Certain organisms can accumulate useful elements from dilute sources; others can transform unusable chemical species to more useful forms. Deterioration of stone, concrete, and even glass or brick, can be accelerated by microorganisms. Control of such biodeterioration could improve long-term performance of industrial mineral products. Microbial processes have shown promise in improving several mine-related problems. Certain bacteria help remove clays from phosphate slimes and other suspensions. Others are used to degrade cyanide or other organic chemicals such as floatation aids. Cells immobilized on clays have been especially efficacious in bioremediation. Biotechnology industries, like the industrial minerals industries, encompass huge ranges of materials and processes. Costs of products from these industries range from pennies to thousands of dollars per unit, and their products are vital for maintaining modern life styles. Many biotechnical processes depend upon industrial minerals and certain biological processes can be harnessed to do useful tasks in the minerals field. The interplay of industrial minerals and biotechnology is important today, and as biotechnology advances, its interaction with the industrial minerals industry can only increase.

Jan 1, 1995

By John F. Spisak

Versatile living organisms, historically exploited as functionaries in the food processing, pharmaceutical and chemical industries, have not been successful in achieving similar or significant acceptance within the minerals industry. The current biotechnical revolution coupled with its expanded understanding, dictate that a flagging minerals industry reconsider the use of biotechnology in metallurgical applications. Living resources, either singly, in commensal association or in complex communities, are capable of duplicating fully integrated and complex processing functions. Organisms can mine and extract metals, detoxify chemical effluents and synthetically produce compounds. They have been criticized as exhibiting poor kinetics, excessive energy consumption and environmental sensitivity. However, expanding knowledge reveals that these organisms are surprisingly adaptable, variable and extremely durable. Applied biotechnology in specific cases offers favorable economic returns, environmental benefits and aesthetic value. Selective implementation of living systems can offer opportunities for reduced labor, increased productivity and technological advance. Success will not come easily. Capital must be risked, controversial decisions made and new ground plowed. Traditional, specialist thinkers will of necessity give way to interdisciplinary expertise and unorthodox methodology if success is to be achieved. Those who vigorously persevere, however, are likely to be rewarded with a dynamic and profitable new role in a restructured minerals industry.

Jan 1, 1985

By S. K. Kawatra, T. C. Eisele

"Recent advances in microbiology have made the application of biotechnology to metallurgical processes possible. Hydrometallurgy stands to gain the cost from the use of microorganisms, as they are useful for both dissolution aids and for removing metals from solution. The development of genetic engineering techniques promises to greatly increase the importance of bioprocessing of metals and minerals by the year 2000.In this paper, the basic effects of microorganisms on metallurgical processes are reviewed, and the applications which are currently either in use or near being used are presented. Representative data collected at Michigan Technological University is also given.IntroductionMany hydrometallurgical operations exist which are thermodynamically possible, but which are industrially impractical due to slow kinetics, high reagent costs, or the need for a highly corrosive environment. However, recent discoveries in microbiology indicate that in many cases these difficulties can be reduced greatly by the action of bacteria and other microorganisms (1-8).A major advantage of using living organisms in hydrometallurgy is that once the culture is established the microorganisms produce their own reagents either from the material being processed or from low-cost nutrient supplements. They thus allow extremely complex chemical reactions to be carried out at reasonable cost. The major drawback of using microorganisms is their inability to tolerate extremely high temperatures, excessive concentrations of toxic metals, or very highly acidic, alkaline, or corrosive conditions. However, the complex reactions which bacteria make possible frequently eliminate the need for such extreme conditions. Also, in recent years a number of organisms have been isolated from such exotic environments as hot springs and deep-ocean vents which can tolerate temperatures higher than was previously thought possible for any organism, and can catalyze a number of metallurgically important reactions (8)."

Jan 1, 1988

By D. S. Holmes

Biological processes for metal solubilization and ore beneficiation are in widespread use today. There are also some promising new applications of biotechnology in the areas of metal concentration and toxic metal cleanup. Recent progress in genetic engineering promises both to revolutionize the existing biological process and to expedite the adoption of the new biological applications. But before it can do so effectively, progress must be made in many areas of fundamental research and in biochemical engineering. These issues are addressed with special reference to the biotechnology of semi-enclosed containers (bioreactors), dumps, heaps, in situ and under- ground leaching, and with respect to the biotechnology of metal concentration. Finally, certain biological considerations for bacterial strain improvement are discussed.

Jan 1, 1987

By H. Dijkman

The PAQUES Bio Systems' core technology, marketed under the name THIOPAQ®, consists of various high-rate biological processes for metal-sulfur-water systems, complemented with common solid/liquid and gas separation steps. Sulfur species are converted to sulfide, which is a valuable component as it can be used for metals reduction and precipitation. Selective recovery of valuable metals can be employed, leading to revenue from metal values. In this paper, biotechnological systems for the treatment of metal sulfate solutions and dilute SO, gases are described. These installations can be designed to either produce predominantly aqueous (NaHS) or gaseous (H2S) sulfide. The emphasis here is on hydrogen sulfide gas. The main case history discussed is the demonstration plant that ran on hydrogen gas at Kennecott Utah Copper. Three years of operating experience clearly show that sulfate reduction with hydrogen gas is a viable option. Furthermore, the selective recovery of copper from leach water with the hydrogen sulfide produced was shown to be very effective.

Jan 1, 1999

By A. Kapoor

Gold mill effluents contain toxic pollutants such as cyanide (CN), thiocyanate (CNS), ammonia (NH4-N), and a variety of toxic metals. Various practical and economical technologies are in use for the removal of CN and toxic metals from gold mill effluents, however, the removal of CNS and NH4-N is challenging. The presence of CNS and NH4-N may make effluents toxic to aquatic life. The new Canadian Metal Mining Effluent Regulations will require mine effluents to be nontoxic. As a result, there is a need to develop practical and economical technology for CNS and NH4-N removal. The Mine Effluents Program in the Environment Group is presently evaluating biotechnology processes for the removal of CNS and NH4-N from gold mill effluents. The processes being evaluated are attached growth systems such as a Rotating Biological Contactor (RBC) and completely mixed suspended growth systems such as a Sequencing Batch Reactor (SBR) operating in a batch mode. The research to date at MMSL has shown that the RBC is very effective in removing CNS and NH4-N from simulated effluents. The NH4-N removal project showed that the RBC is capable of removing 0.8 g NH4-N/m2 of RBC disk area per day at an average temperature of 4.5 oC and hydraulic loading rate of 0.02 m3/m2/d. The RBC was also found to be very effective in removing CNS (feed = 200 mg/L and effluent < 1 mg/L) at 8 oC and a hydraulic loading rate of 0.02 m3/m2/d. The SBR was effective in removing CNS and NH4-N (generated from CNS degradation) at SBR operating conditions of two-12 h treatment cycles and a temperature of 12 oC. The end product of CNS and NH4-N oxidation was NO3-N, which is relatively non-toxic.

Nov 1, 2002

By Lee R. Martin, Michael R. Taber

Bird Balls™, the latest development in the ongoing battle at mine sites across North America, help to eliminate accidental avian mortality caused by birds ingesting cyanide leachate. Bird Balls™ are a 4-inch sphere made of high-density polyeth­ ylene (HDPE). They weigh 40 grams and are black in color to provide optimum life in UV intense environments. A floating blanket of bird balls totally excludes birds from a liquid surface. Federal agencies that enforce the Migratory Bird Treaty Act do not specify how to keep migratory birds out of leachate basins. Some state agencies, however, specify that a physical barrier must be in place to exclude migratory birds if cyanide levels are high enough to cause mortality. Industry standards for protecting waterfowl now include Bird Balls™ as well as net­ting, detoxification, and heap leach systems designed in such a manner that no exposed solution ponds or channels exist. Hazing is no longer an option. A bold statement to make? Perhaps, but W. R. Jeffress (1990) covers the subject well when he stated that, "Hazing techniques as a whole have not been effective in excluding waterfowl or other species of wildlife from toxic heap leach solution ponds or tailings impoundments. Research and devel­opment of the new 'Star Wars' hazing techniques, such as laser netting and radar systems, are interesting concepts and will pos­sibly offer an alternative to total physical exclusion or neutral­ization in the future. All of these methods are going to have to be thoroughly tested." For those who may want further docu­mentation, we have included a special reference section cover­ing hazing. R. J. Hallock (1990) stated that, "The Fish and Wildlife Service is particularly interested in migratory birds. In fact, a large portion of our effort, nationwide, is focused on migratory birds. Bird habitats are managed directly through the National Wildlife Refuge System and indirectly through other agency programs. We also have a responsibility to protect birds under the Migratory Bird Treaty Act. Most birds attracted to mine ponds are covered under this Act. The only migratory birds not protected under the Migratory Bird Treaty Act are English Sparrows, Starlings, and Pigeons. Since this is a treaty with five nations, the concept of acceptable losses does not apply. It is not a negotiable situation. There are a few exceptions noted in the Act, including prescribed hunting of selected waterfowl, scien­tific collection, and game bird farming. There is no exception for the loss of migratory birds exposed to solutions of cyanide."

Jan 1, 1996

By J. D. Bateman

DURING the summer of 1942 several chromite deposits were discovered in the Lac du Bonnet district about eighty miles northeast of Winnipeg. The deposits are confined to the Bird River complex, a folded composite sill of basic and ultrabasic igneous rocks of early Precambrian age that lies to the north of Bird river (1). The outcrop of the sill represents the trace of an easterly plunging anticline, the south limb extending from the northeast bay of Lac du Bonnet eastward to Bird lake, and the other limb, 6 to 12 miles north, lying between Maskwa river and Euclid lake. The south limb of the sill is 20 miles long, and the northern counterpart 15 miles; but its continuity is interrupted by faulting and by the intrusion of younger granite, so that the total length of outcrop of both limbs does not likely exceed 25 miles. The sill is intrusive into early Precambrian greenstones and associated sedimentary rocks. The chromite discoveries have been made at several localities on both limbs of the sill, and in each case at the same geological horizon. The sill comprises an upper layer of hornblende gabbro and a lower layer of serpentinized peridotite, and altogether is from 500 to 3,500 feet thick. The chromite zone is within and near the top of the peridotite layer, and thus about midway of the sill, both of the limbs of which stand nearly vertical. This geological relationship was established early in the exploration of the initial discoveries and served as the basis for successful predictions of later discoveries. The chromite zone probably persists throughout the length of the sill, but its width and chromite content are not everywhere the same. The initial exploration along both limbs of the sill has shown a combined total length of about 12,000 feet of chromite ore varying in width from 6 to 12 feet. In many places the overburden is thick and obscures the continuity of the chromite zone; but as investigation proceeds the known deposits will be extended and new ones will be found. Thus, although a total length of 12,000 feet of ore has been investigated up to the present time, there is an indicated length of approximately 31,000 feet along which the ore is more than 4 to 5 feet wide. This estimate is based on geological considerations and represents a total tonnage in the order of 15,000 tons per vertical foot of depth.

Jan 1, 1943

By Cyril S., Smith

WE cannot but marvel at the fact that fire is necessary for almost every operation. It takes the sands of the earth and melts them-now into glass, now into silver, minium or other lead or some substance useful to the artist or physician. By fire, minerals are disintegrated and copper produced; in fire is iron born and by fire is it subdued; by fire, gold is purified; by fire, stones are burned for the binding together of the walls of houses.... Fire is the immeasurable, uncontrollable element, concerning which it is hard to say whether it consumes more or produces more." Thus wrote Pliny in his "Natural History," that great collection of fact and error which constitutes the principal contemporary description of Roman technology and which until the seventeenth century was the authority most often quoted and requoted by those who wrote on metals, as on many other subjects.

Jan 1, 1940

Jan 1, 1889

Jan 1, 1925

By J. M. Silliman

Several years ago, having occasion to determine the amount of some very slight atmospheric depressions, I devised and had constructed by a skilful tinsmith the manometer shown in the accompanying drawing. It consists of a cylindrical vessel of tin, 6.6 inches in diameter, through the sides of which, at a distance of about six inches from the top, passes an air-tube D, its upper extremity terminating 3.5 inches from the top. Within the vessel is a combined cylipdrical

Jan 1, 1889

By William H. Pettee

A few weeks ago the Institute lost, by death, from its list of members one who in recent years, by frequent attendance at meetings, by the preparation of papers, and in many other ways, had shown a warm interest in Institute affairs; who had an extensive acquaintance among his fellow-members, and whose memory it is fitting to perpetuate by a permanent record in the volumes of our Transactions. Dr. Byron William Cheever, acting Professor of Metallurgy in the University of Michigan, died at his home in Ann Arbor, on the 6th of March, 1888. He was born September 17th, 1841, in Ellisburg, Jefferson County, New York. In 1844, the family moved to Geneva, Illinois, and thence, in 1857, to Dundee, Michigan. Two years later, a third removal was made to Ann Arbor to take advantage of the educational facilities there offered; and in 1859 the subject of this sketch, with his two brothers, entered the University of Michigan. In 1863, he took the degree of Bachelor of Arts. After a year or two of business life, he entered the medical department of the University, and graduated as Doctor of Medicine in 1867. A taste for scientific work had been developed in him in early life; and, even while carrying on undergraduate and medical studies, his proficiency in chemistry found recognition in his occasional employment as assistant in the University laboratory. The interval between the close of his course in Arts and the commencement of his course in Medicine was also devoted to chemical work, partly in the city of Philadelphia, and partly in the West Indies, where he was employed in the service of a commercial company engaged in the guano trade. Dr. Cheever never took up regular practice as a physician. After receiving his medical diploma he went again to Philadelphia, and for about two years was employed as an analytical and consulting chemist in that city. A favorable opportunity occurring for work in the Rocky Mountain mining region, he left Philadelphia and

Jan 1, 1888

By H. E. Mussey

When the American Institute of Mining Engineers visited the Birmingham district in May, 1888, the four Ensley furnaces (Fig. 1) then completed were referred to as monumental.&apos; Their dimensions are givcn in Table 1. Mr. Gordon stated, with considerable satisfaction, that on the preceding day one furnace had produced 165 tons. The blast was

Jan 1, 1925

By Frank C. Roberts

Neglecting the hydrogen and hydrocarbons, 1 will assume the following analysis as a fair average composition, by weight, of the waste gases escaping from a coke-burning blast-furnace: CO2............17.25 CO,............25.25 N,.............57.50 100.00 The 25.25 CO requires for combustion 62.6 of air, or 11.398 of oxygen, necessitating the passage of 48.202 nitrogen into the products of combustion. The latter, therefore, have the following composition: CO2,,............ 56.9 N,............105.7 Tile total specific heats of these quantities of the respective gases are 12.31 and 25.79, giving for the combined product, 38.1 approximately. That is, the product of combustion will absorb 38.1

Jan 1, 1889

By H. S. Geismer

Campbell,&apos; in 1896 said: "The Birmingham district in Alabama has certain great advantages for there are few places in the world where fuel and ore are so near together, although, unfortunately, both are of inferior quality; the ore being low in iron and high in phosphorus and the coal giving a weak and impure coke." This statement could not have been questioned in 1894, but by 1896 several Robinson-Ramsay washers had been put into operation and weak and impure coke was a thing of the past. The Warrior coal field of Alabama contains six seams that yield coking coal of excellent quality. In descending order, they are Brookwood, Milldale, Pratt, America, Mary Lee, and Black Creek. In each of these, however, bands of rock and bone coal of varying thickness are stratified with the coal; and while some of these impurities can be separated from the coal by the miner, much of it must be loaded out with the coal. Consequently, unless the coal is washed before being coked, it will yield a coke of varying ash and sulfur content quite unsatisfactory for blastfurnace use. At present, the Gulf States Steel Co. is producing run-of-mine coal at its Virginia mine, from the America seam, that is uniformly low enough in ash to permit of coking without washing, but this is the only exception to the above statement. Alabama was the first state to experiment seriously with coal washers, was the first to install washers on a large scale and, up to the present, has maintained the lead. The Alabama State Mine Inspector reports that during 1923 20,919,303 tons of bituminous coal was mined in Alabama; 12,858,499 tons of which was delivered to coal washers for treatment.

Jan 1, 1925

By Wilbur A. Nelson

All of our accounts say that the discovery of copper ore at Duck-town, Tenn., was made in August, 1843, yet it would appear that samples of copper from this district were found by DeSoto, when he wandered into southern Tennessee, in 1539, in his four years of exploration through the Southern States. The following quotation is taken from his diary: "Towards the north there was a province named Chisca; and that there was a melting of copper, and of another metall of the same colour, save that it was finer, and of a farre more perfect colour, and farre better to the sight, and that they used it not so much, because it was softer. And the selfe same thing was told the governor in Cutifa-Chiqui, where we saw some little hatchets of copper, which were said to have a mixture of gold. But in that part of the country it was not well peopled; and they said there were mountains, which the horses could not passe; and for that cause, the governor would not goe from Cutifa-Chiqui directly quicker." DeSoto sent two of his company to try to find these mines, but after five days&apos; wandering through the mountains they returned, stating that their guides had become lost. Although the Ducktown area may have been known to the ancient Indians, the copper deposits were actually discovered in August, 1843, when a Mr. Lemmons, while panning for gold on Potato Creek, in the Ducktown basin, found some reddish-brown decomposed rock. His disgust on finding that this yellow metal was not gold was so great that he did not try to develop his find. In March, 1847, B. C. Dugger erected an iron forge at this same place, but was unable to work the iron as it contained so much copper that on cooling it would break to pieces. The finding of copper in the iron ore by Mr. Dugger led to further explorations; and in April, of the same year, A. J. Weaver, who was passing through that country, told the people that the black rocks they had dug out were rich copper ore. Mr. Weaver began the

Jan 1, 1925

By Alfred F. Brainerd

There has been no enterprise undertaken in this and adjoining States which has attracted so much interest, or has been watched so closely as this, the first successful attempt to convert our ordinary high-phosphoric pig-iron into steel from native material. Our iron-masters have noticed intently every attempt to convert high-phosphorus pig-irons into steel by the Clapp-Grifith process in this country, and the basic process on the Continent, and studied the various patents aiming to accomplish the same purpose, and the various litigations arising among various patentees over their rival claitns; but up to August, 1887, nothing was done, and no move had been made to introduce any process for making steel. At the time above named, Mr. James Henderson, of New York, came to this place with a view of introducing his patent furnace and other metallurgical processes and appliances. After some delay and personal interviews between parties interested and the inventor, a party of gentlemen, all of moderate means, and entirely unacquainted with the manufacture of either steel or iron, decided to form themselves into a body corporate, known as the Henderson Steel and Manufacturing Company, with a capital stock of $20,000,

Jan 1, 1889