Search Documents

By A. Wedepohl

Selective leaching of phases in charge chrome is used in a variety of industrial processes for the production of chromium chemicals. A mineralogical study was made of a range of local charge chrome samples, at various stages of leaching in sulphuric acid (20g/l at 90°C), using mainly a scanning electron microscope (SEM) together with an energy-dispersive spectroscopy analyzer (EDS), and X-ray diffraction techniques. It was found that the leaching behaviour of the different types of charge chrome depends largely on the nature of the secondary phases, which in turn depends upon whether the silicon content is above or below 4 per cent by mass. The leaching behaviour of high-chromium ferrite is anomalous, and it is postulated that the process is analogous to the corrosion of brass by dezincification. Keywords: charge chrome leaching, scanning electron microscope

Jan 1, 2000

The wealth of a nation can be measured many ways, but one of the most important measures is its natural resources, particularly minerals. Minerals provide the foundation upon which economic prosperity and defense preparedness rest. Assessing our energy and mineral resources and assuring their development is in the best interests of all our people continues to be an important national goal. Since its founding in 1910, the U.S. Bureau of Mines has established itself as the world's premier minerals information and research agency. Its authoritative, comprehensive data and pioneering research have contributed significantly to a strong U.S. mineral position in the world.

Jan 1, 1990

By D. van Heerden

In the mining industry abrasion caused by both sliding and impact have over the years resulted in costly damage to installations such as ore passes and silos. Good geotechnical practices combined with the use of a high quality abrasion resistant concrete can prolong the life of such an installation and minimize problems associated with abrasion. In order to maximize the life of an abrasion resistant concrete, the choice and combination of the correct raw materials (cement, aggregate and fibre) and overall mix design needed to make up such a concrete are important. This paper presents technical data and practical experience showing that concrete formulated with calcium aluminate cement resists severe abrasion conditions better than similar OPC-based concretes.

Jan 1, 2005

Basic parameters affecting the stability of foams have been studied. We used the thin film pressure balance (TFPB) technique of Scheludko and Exerowa (1959) to measure the surface forces in foam films stabilized with various frothers such as pentanol, octanol, MIBC, and PPG. The results were compared with the froth stabilities measured using the shake tests and the film elasticity calculated using the model developed by Wang and Yoon (2006). It was found that the froth stability is controlled by both film elasticity and surface forces (or disjoining pressure), the relative contributions from each changing with frother concentration and type.

Jan 1, 2006

The National Mining Hall of Fame will hold its 13thAnnual Induction Banquet during MINExpo International 2000 in Las Vegas, NV. The gala black-tie (optional) event will honor eight legendary leaders of the mining industry. The event will take place at the Las Vegas Hilton Hotel on Sunday, Oct. 8. The induction ceremonies will salute mining greats elected by the board of governors from a list of nominees submitted by mining industry partners and the public. The members of the Class of 2000 will join 151 other inductees enshrined in the Mining Hall of Fame in Leadville, CO. The evening will begin at 6 pm with a cash bar reception followed by the banquet and program at 7 pm. Keynoting the banquet program will be Harrison (Jack) Schmitt. He was the geologist/astronaut of the Apollo 17 mission to the moon in 1972 (see related story on page 26). And he is the only scientist to “kick rocks on the moon.” Schmitt is also a member of the Mining Hall’s board of governors. Schmitt was also the keynote speaker at the First Annual Induction Banquet in Denver, CO in 1988.

Jan 1, 2000

By R. Duncan Gardner

This paper describing the milling practice at the concentrator of the Harmony Mines Co. is one of a series being; prepared by the Bureau of Mines on milling methods and costs in the United States. For the period February 15, 1929, to June 1, 1929, the concentrator treated 200 tons of copper ore per day containing 3.84 per cent copper and recovered 99.2 per cent of the total copper in concentrates averaging 26.61 per cent copper. Milling practice at the Harmony Mines is in most respects similar to the usual practice at the average flotation concentrator producing bulk flotation concentrates. The exceptionally high recovery is due to a number of minor conditions. These minor details will be stressed throughout this paper.

Jan 1, 1930

By S. R. Sankaranarayanan, T. Sowmya

Slags and fluxes used in metallurgical processes are typically made up of oxides (especially silicates), with additions of fluoride and carbonaceous matter. Despite the efforts made towards understanding the role of slags in various processes, little information is available on the structure of these slags. Tools such as X-ray diffraction, spectroscopy, and electron microscopy could be used for this purpose. This paper is based on an ongoing spectroscopic and structural investigation of slags and related materials. Spectroscopic studies of various commercial slags (predominantly ferrous), ores, glass and related materials, covering a wide range of compositions, have been carried out to understand the structure. The infrared spectra were recorded, predominantly, using FTIR spectrometer (Bruker IFS 66U) spanning 4000 to 100 cm-1using the KBr pellet method. The resolution was typically 4 cm-1. The spectral outputs have been compiled in terms of bands present (corresponding to different bonds) and then compared with the typical bands expected for such bonds. Efforts are in progress to identify the trends with respect to the chemical composition?for example, the effects of SiO2, Al2O3, and non-bridging oxygens. Data obtained so far indicate some trends such as (i) a shift in the Si-O band (969 to 1099 cm-1) towards a higher wave number with increasing silica content (almost 2 to 92 weight percentage) and (ii) further strong shifts as a function of the alumina content. These are being further investigated structurally and in terms of chemical composition/parameters. Keywords: slags, silicates, structure, spectroscopic analysis, shifting of bands

Jan 1, 2004

By Alexander Garcia

Roof and rib falls are the basic ground control hazards associated with underground roadways during development, stand up and, if applicable, retreat. Falls of ground can happen following the deterioration of supports or rock conditions over time, and particularly as a consequence of continuing rock deformation and/ or failure to install adequate support. Once developed, the risk of a failure is increased due to the effects of time as well as to front abutment stresses through retreat mining. The measurement of strata displacement using monitoring equipment is a form of ground control risk assessment. These monitoring systems are active, or ?live?, in a sense that risk is assessed real-time. However, there are circumstances in which falls of ground can occur without the prior recording of excessive movement. In addition, monitoring equipment is typically placed at set intervals, and strata conditions could vary between these points. Consequently, a visual assessment of other factors contributing to the risk of a fall should be made in order to complete a ground control risk assessment. Such surveys are usually one-off, thus capturing roadway conditions at one particular point in time. Ongoing deterioration is not documented through such one-time surveys, and there is a requirement for real-time or live assessment where a system is in place so that observation data can be updated on an ongoing basis, and a useful summary of prevailing roadway states produced on demand. To address the shortfalls of one-time assessments, a ?live? computerbased quantitative ground control risk assessment process has been developed. It combines visual observations processed in a quantitative manner with existing monitoring data into an interpretable output which indicates zones of roadway where there is an increased risk of a fall of ground from the roof or sides, so that remedial action can be carried out to mitigate that risk. Through improved procedures, it is now possible to generate a ground control risk assessment for each roadway, and one which can be updated frequently. This paper aims to outline and describe the assessment process.

Jan 1, 2012

By P. R. Richardson

"Milling is the weak link in the process chain of many mineral operations. While this activity accounts for only a relatively small proportion of the direct costs of most mineral processing complexes, there are intangible and indirect costs associated with milling which are extremely large. For example, significant opportunity costs are associated with the relatively low yields which characterize this stage of the process.There are changes abroad in the world which I believe are going to cause us to reformulate the whole concept of milling. Increased competition in mineral markets are going to force managers to look anew at the high mineral values reporting to tailings which are a high opportunity cost for many operations. Tailings recovery plants are not the ultimate solution to this problem. Greater environmental concerns are going to increase the costs associated with tailings disposal and force the mining industry to look for other ways to dispose of waste products. Technology changes currently underway in manufacturing and other process industries, such as the automated 'lights-out' plant are going to be brought into this industry, and the changes will be dramatic.These are major long term changes which probably seem rather remote to many managers and professionals in existing operations which are faced with much more mundane challenges arising from day-to-day operations. However, I believe that milling is increasingly a 'lean and keen' operation involving fewer and fewer people, but who are increasingly skilled and professional. Traditional cost management approaches are no longer adequate and the industry has to take a new look at the nature of cost reduction in this core activity. This stage in the mineral process provides opportunities for value creation leading to a significant unit cost advantage for the corporations willing to adopt a total cost approach."

Jan 1, 1988

By D. K. Matlock, D. J. Hamre, J. G. Speer

Ultrafine ferrite (UFF) grains may be produced in surface layers of plate steels using controlled intermediate cooling followed by deformation. Experiments were conducted using a 0.12 C - 1.26 Mn steel on a Gleeble 1500 hot deformation simulator. Taguchi designed experiments were used to evaluate prior austenite grain size, intermediate cooling rate, intermediate cooling temperature, intermediate hold time and amount of reduction in order to observe the effects of variables and their interactions on the final microstructure while minimizing the number of required test runs. Evaluation of resulting microstructures and mechanical properties revealed a preferred thermal and mechanical history for developing ultrafine microstructures in surface layers of plate steels. Application of the fundamental concepts of phase transformations to industrial plate rolling is considered.

Jan 1, 2004

By V. Tathavadkar

Worldwide TiO2is extracted from natural ilmenite, rutile, and anatase minerals via the sulphateand chloride processes. The sulphate process generates large volumes of less toxic wastes, whereas the chloride process, including the ilmenite-chloride process of DuPont, yields much lower volume of wastes, which are highly toxic and hazardous. The treatment and disposal of such hazardous chloride wastes is both expensive and difficult in terms of long-term monitoring. Besides the waste management and disposal, there is also a shortage of high-grade titanium dioxide minerals in nature, which consequently yields much larger tonnages of sulphate and chloride wastes. In the present investigation we report the results of an alternative titaniferous mineral beneficiation process based on soda ash roasting of minerals. Compared to the conventional processes for beneficiation of TiO2- ores, the alkali roasting of titaniferous offers several advantages including the zero process wastes. In the soda ash roasting process, the mineral is mixed with sodium carbonate and heated above 1023 K in air. The oxidative roasting of ores yields several complex alkali compounds, some of which produce a liquid mixture above 1123 K. In this paper, we have attempted to characterize the composition and physical chemistry of alkali-rich liquid phase. The phase equilibria in the Ti-(M:Fe)-Na-O system are evaluated and compared with the phases formed as a result of roasting reaction. The experimental results revealed that the composition of complex alkali liquid at the reaction interface plays an important role in determining the transport of O2-ions and decomposition of ilmenite. The roles of the crystal structure of mineral phases and their energetics are also emphasized in controlling their decomposition during alkali roasting. The presence of molten alkali in controlling the partitioning of water-soluble alkali salts and insoluble sodium titanate is also explained. Keywords: ilmenite, anatase, alkali roasting, phase equilibria.

Jan 1, 2004

Grinding and Flowing Investigation on Dry Stirred Ball Milling in Order to Determine the Influence of Grinding Aids Huge difficulties of the great ultra fine ground material production in dry stirred ball mill are the cohesion and agglomeration of the particles. During grinding the material stick on the grinding wall and the grinding media furthermore the grinds start cohere, making aggregation and agglomeration to appear. Due to these effects the particle size will not decrease after a certain value during grinding and the energy demand increases significantly. According to experience on fine grinding in ball mill, it is well known that these effects can be reduced with the use of grinding aids. The influence of grinding aids has three different effects: due to the adsorption strength reduction (Rebinder effect) the grinding resistance of the material decreases; the surface energy diminishes and the agglomeration liability decreases; and the flow properties of material improve. The aim of this study is to investigate the flow properties of fine grinds and the effect of grinding aids on flow properties in case of dry stirred ball milling. In addition, the influence of grinding aids was investigated based on the particle size distribution and specific surface area of grinds and the specific energy demand of grinding. The examinations were carried out with three different model materials (limestone, clinker, quartz) using the usually applied grinding aid. The flow properties were measured by the Jenike shear cell; the particle size distribution and specific surface area were measured by laser particle size analyser (Fritsch Analysette 22), grinding energy demand was measured with microcomputer controlled digital energy meter. It can be said that under certain measuring circumstances the influence of grinding aid on flow properties can be demonstrated by Jenike shear cell, so the grinding result is in correlation with the flow properties of grind.

Sep 13, 2010

By I. A. Minaev

The conditions of a stability of metallurgical films on a surface of solid on the basis of classical regularities of a thermodynamics are considered. For specific conditions of metallurgical processes the basic equations relevant to non-metallic inclusions (product of steel killing) migration and transfer through the interface boundary of metal-slag are obtained. The basic criteria equations of conditions of stability of metallurgical dispersed systems are developed in view of films formation. The probable thermodynamics reason of wetting due to formation of stable films are discussed. The experimental measurement of thin and thick films elastic resistance for metallurgical systems are carried out and the results are discussed. The presence of a wetting thick film increases stability of dispersed systems (facilitates an inverse implication of non-metallic inclusion in a melt) due to a barrier effect of wetting films. The quantitative evaluations of non-metal inclusion stability for steel in contact with any metallurgical slag are carried out. The results are in accordance with technological experience. Keywords: Inclusion removal, Film thermodynamic, Slag-metal dispers system

Jan 1, 2004

By H. Krogerus, P. Jokinen, T. Lintumaa

The energy consumption and recovery of chromium are important economic factors in ferrochrome production. Outokumpu has a lot of experience of the reduction behavior of the sintered pellets in industrial-scale furnaces and also on the grounds of numerous laboratory and pilot-scale investigations. Sintered pellets have shown a superiority over lumpy ore and briquettes made of the same chromite grade. The good performance of the pellets has also resulted in investigations on the reasons for such a performance. In this study, the factors affecting pellet behavior in smelting furnace were investigated. This study is divided into two sections, i.e. the investigations were on the factors affecting solid state reduction and on the factors affecting reduction under melting. These tests were performed by means of thermo gravimetry and by smelting tests. The correlation between the pellet characteristics and reduction behavior was shown and its influence on industrial-scale furnaces was discussed. Factors worth of consideration are for instance, the extent of oxidation during sintering, slag formation and chemistry in respect of molten state reduction, and the grain size of the chromite mineral in the raw material in respect of kinetic reasons (retention time in smelting).

Jan 1, 2007

By A. Renton Amell

The rate of dissolution of U02 was measured in acid solutions similar to those used for in situ leaching, with S04 of 10-1.82 to 10-4 M, Fe(III) of 10-2 to 10-4 M and pH's of 1.1 to 2.3. The dependence of dissolution rate on pH was small and inconsistent, probably reflecting the combined effects of a very weakly polar oxidizing complex, probably FeSO4+, and a nearly neutral U02 surface. Differences in the state of the U02 surface may explain this variability as well as contrasts between these results and results reported in other work. Changing either S04 or Fe(III) concentrations significantly affects dissolution rates. Increasing low sulfate concentrations in solutions containing 10 2 M Fe(III) at pH 2 results in formation of FeSO4+. In such solutions, rates increased with (S04)/(Fe(III)) up to 1:30, thereby indicating that the oxidation of U02 by FeSO4 is more rapid than by Fe3+. However, the dissolution rate decreased at higher (SO4)/ (Fe(III)), due either to sorption of SO42- on the UO2 surface or to formation of other less reactive sulfate complexes such as Fe(S04)2 or FeHSO4+ However, Fe(III) concentration is the dominant factor in determining solution rates. The rate was directly proportional to ferric iron concentration, indicating that the rate-determining step of the dissolution reaction is a single-electron oxidation by a ferric complex. Dissolution rates were lower in solutions of 0.1 and 1.0% H202 (0.029 and 0.29 M) than at similar concentrations of ferric iron because of formation of an insoluble surface coating of uranium peroxide, UO4?4H20. This phase may limit the value of hydrogen peroxide as an oxidant in lixiviants, not only by its very low solubility, but perhaps also by filling pores and reducing permeability in the ore body.

Jan 1, 1978

By Nicolae Dobritoiu

The literature in this field and the practical activity record that a method, respectively the technology used for an underground mining work have many components which, in order to be applied, demand that for each of the parameters that describe the environment of the mining work and that influence the chosing of that method and that technology of execution, must have values in an interval well determined. There are situations when one or many parameters of the set of parameters that describe the environment of the mining work, can modify its values, and, as a result, one or more components of the methods or technology cannot be applied anymore, making necessary a replacement of their values. The information offered by this graphical-analytical model allow the determination of optimum solutions for the process of digging of the underground mining work and thus it will result the incresing of the technical-economical efficiency of the digging process and, also the increasing of the quality of the underground mining work.

Oct 1, 2009

By Mandy Korff

Walls consisting of CFA-piles are often used for vertical cut offs for building pits. Several methods of installation and geometry may be used and sizes, depths and strengths of walls necessary vary widely. Based on experience with secant CFA-pile walls in The Netherlands, requirements for this type of wall can be set with a risk management view to it. This paper describes those requirements, based on specific local conditions.

Jan 1, 2006

By M. Berger

The ‘Metallurgical Operations’ Department of Grinaker-LTA Process Engineering (GLTA) currently undertakes then primary mining as well as the re-deposition of tailings forTicor South Africa (Ticor) at their Hillendale mine near Empangeni, KwaZulu-Natal, South Africa. The mining plant, which was designed by GLTA on a Build, Own, Operate and Transfer (BOOT) basis, is capable of mining 780 000 tons per month of ROM material which is then pumped to the Primary Wet Plant for treatment by Ticor. Hydraulic mining via high pressure water cannons and subsequent transfer of the heavy mineral slurry at an RD of between 1.35 and 1.48, has never before been undertaken successfully at this level of production on an in situ reserve. The presentation will take the form of a case study in which the unique site operating conditions will be detailed and discussed, as will the innovative process and engineering solutions employed by GLTA to overcome the engineering and production challenges encountered. In order to protect the intellectual property involved in this operation, this paper is fairly general in nature, and attempts merely to provide the reader with a broad perspective understanding of the operation, and some of the difficulties encountered during the early stages of production.

Jan 1, 2003

By T. Y. Chong, J. A. Folinsbee, M. Fullam

PJV Dome Mine has used some form of gravity concentration since start of milling operation in 1909 to recover free milling gold. Amalgamation and conventional jigs were first used and were replaced with the Knelson Concentrators in 1993. The Knelson concentrates produced were upgraded on a conventional shaking table prior to smelting and refining into gold bullion. In May 2002, a comprehensive review of the latest gravity recovery technology led to a piloting campaign aimed at further improving gravity recovery. The Knelson concentrates, subjected to intensive cyanide leaching in an Acacia pilot plant, were found to be amenable to intensive cyanide leaching with over 98% of the gold being dissolved within 24 hours. An Acacia Intensive Leach Reactor was successfully installed and commissioned in December 2002, to replace the shaking table. his paper describes pilot scale testing, installation, commissioning and optimization of the Acacia Intensive Leach Reactor. Also, the economic impacts on down stream processes are highlighted.

Jan 1, 2005

By A. Nieto

A dump edge and vehicle proximity warning system is being developed at the Colorado School of Mines using GPS and wireless local area networks to improve the safety of off-highway trucks in open pit mines. After two years of research, software development, and testing in the laboratory, field tests are currently being carried out at operating limestone quarries and open pit mining operations to evaluate the effectiveness of the system under rugged operating conditions. This paper describes the progress made on this NIOSH-funded project and discuss, tests carried out recently, at the Morenci open pit copper mine in Arizona.

Jan 1, 2002