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By S. F. Diehl

Weathered mine waste consists of oxidized primary minerals and chemically unstable secondary phases that can be sources of readily soluble metals and acid rock drainage. Elevated concentrations of metals such as Cd, Cu, Fe, Mn, Ni, Pb, and Zn are observed in deionized water-based leachate solutions derived from complex sedex and Cu-Pb-Zn mine wastes. Leachate (USGS FLT) from the Elizabeth mine, a massive sulfide deposit, has a pH of 3.4 and high concentrations of Al (16700 ug/L), Cu (440 ug/L), and Zn (8620 ug/L). Leachate from the sedex Faro mine has a pH of 3.5 and high concentrations of Al (2040 ug/L), Cu (1930 ug/L), Pb (2080 ug/L), and Zn (52900 ug/L). In contrast, higher-pH leachates produced from tailings of polymetallic vein deposits have order of magnitude lower metal concentrations. These data indicate that highly soluble secondary mineral phases exist at the surface of waste material where the samples were collected. Sulfide minerals from all sites exhibit differential degrees of weathering, from dissolution etched grain rims, to rinds of secondary minerals, to skeletal remnants. These microscale mineral-dissolution textures enhance weathering and metal leachability of waste material. Besides the formation of secondary minerals, sulfide grains from dried tailings samples may be coated by amorphous Fe-Al-Si minerals that also adsorb metals such as Cu, Ni, and Zn.

Jan 1, 2011

By Slobodan Radosavljevic

The polymetallic W-Pb-Bi-Ag ore from the ?Nova jama? ore zone of the Rudnik ore field have been investigated. Contact-pneumatolytic (skarn), pneumatolytic-hydrothermal, and hydrothermal mineralization phases are defined in this ore zone. The most significant mineralization phase that gave compact ore bodies is pneumatolytic-hydrothermal phase. A relatively pure Mo-free scheelite is the only tungsten-bearing mineral. Lead minerals are mostly presented by Pb-Bi sulphosalts and much less with galena. The image analysis coupled with Energy Dispersive Spectrometry (EDS) analysis on a Scanning Electron Microscope (SEM) was applied to the characterization of a W-Pb-Bi-Ag ore as an efficient tool for mineral quantification. Results of EDS (Energy Dispersive Spectrometry) analyses gave the empirical formulae: Pb1.91Ag0.05Cu0.08Bi1.93S5 for cosalite, Pb0.98Ag0.03Cu0.05Bi1.99S4 for galenobismutite and galena Pb0.99Ag0.03S.

Jan 1, 2006

By Aylmore M. G

Samples have been taken from a two-stage industrial gold roaster treating a pyrite/pyrthotite/arsenopyrite concentrate, in order to describe the mineral- ogy, composition and surface area of the calcines. Sulfides oxidised to produce a porous magnetite in the first stage and a porous hematite in the second, pyrite predominantly roasted via a pyrrhotite intermediate. Sulfur was eliminated in both the first and second stages whereas arsenic was eliminated in the first but retained in the second, partly as rims on hematite particles. The finer sized particles from the cyclones and electrostatic precipitator, whilst having the greatest surface area, were the most refractory with respect to gold solubilization, probably as a result of incomplete decomposition (through short-circuiting) in the first stage, and through a combination of factors such as overheating and entrapment of sub-micro- scopic gold in the second stage.

Jan 1, 1991

By S Jokanovic, J L. Mauk

The Taharoa ironsand deposit covers approximately 16 km2 and is located 144 km south of Auckland on the west coast of the North Island, New Zealand. The heavy mineral-rich sands predominantly contain titanomagnetite, ilmenite and hematite, along with lesser amounts of amphiboles, pyroxenes, and feldspars. Throughout the Taharoa mine site 142 samples were collected of which approximately 25 samples were used in mineralogical analyses of the magnetic, heavy non-magnetic and light non-magnetic fractions. Mineralogical and petrographic analyses confirmed the high abundance of homogeneous magnetite and magnetite containing ilmenite exsolution lamellae which have oxidised to hematite. A limited number of sand samples were collected from Taranaki beaches. Petrography reveals exsolution textures of magnetite and ilmenite (now hematite), and homogenous magnetite grains similar to those observed at Taharoa. Petrographic analyses from previous research projects were also closely investigated in order to make mineralogical comparisons from along the west coast of the North Island and with other potential source areas. The origin of detrital magnetite grains along the west coast of the North Island is generally presumed to be the eroded volcanic cones of the Egmont volcanoes and active and dormant volcanoes of the central North Island. Electron microprobe analyses of magnetite grains from Taranaki beach samples reveal TiO2 values of between 1.5 and 120 per cent. MgO and A12O3 contents also vary widely from 0.75 to 6.5 per cent. This large variability may reflect different volcanic eruptions, the presence of exsolution textures or alternative source areas for these magnetite grains. Geochemical results from the Taharoa mine site correlate with the Taranaki beach samples suggesting that the Egmont volcanoes are certainly one source area. Variability in XRF results, especially Fe and Ti contents (9.04 - 59.22 and 0.80 - 4.64 respectively), from the magnetic and heavy non-magnetic fractions likely reflect the detrital nature of this deposit.

Jan 1, 2003

By Luis Magallanes-Hernández

"Industrias Peñoles, S.A. de C.V. (Peñoles) in Mexico, is a major silver producer. The Peñoles Mining Division has eight Mining Operations and in seven of them, flotation is used to concentrate the metal and mineral values. Common metals and minerals values are: metallic gold and silver, gold-silver alloys, silver sulphide minerals (acantite, pyrargirite, argentite, proustite); lead sulphide mineral, galena; zinc sulphide mineral, sphalerite; and copper sulphide minerals (chalcopyrite and bornite).In the last years, a special emphasis has been given to using modal analysis to identify ore mineralogical limitations, in order to direct efforts into key areas where opportunities exist to improve the metallurgical results.This work aims to share Peñoles mineralogical and metallurgical results, through presenting, discussing and drawing conclusions on these results; as well as pointing out areas where more work is needed to improve the Concentrator´ performance.PEÑOLES BACKGROUNDPeñoles´s mission is to add value to non-renewable natural resources on a sustainable manner. It was established in 1887, and it is a mining group with integrated operations in smelting and refining non-ferrous metals, and producing chemicals. Peñoles is the world’s top producer of refined silver, metallic bismuth, and sodium sulphate, the leading Latin American producer of refined gold, lead, and zinc.Peñoles Mining Division is integrated into eight mining business, located on five different states in Mexico. Metal productions for the Mining Division during 2003 were: 343 thousand gold ounces, 48.4 million silver ounces, 81.3 thousand tons of lead, 235.1 thousand tons of zinc, and 10.6 thousand tons of copper."

Jan 1, 2005

By Lawrence M. Zanko

Eighteen coarse taconite tailings samples were collected in 2000-2001 from five western Mesabi Range taconite (iron ore) operations located in northern Minnesota, i.e., EVTAC, Hibbing Taconite (Hibtac), USX Minntac, Ispat Inland (Minorca), and National Steel Pellet Company (NSPC), to test their physical, geological, chemical, and mineralogical properties [Zanko, L.M., Niles, H.B., Oreskovich, J.A., 2003. Properties and aggregate potential of coarse taconite tailings from five Minnesota taconite operations, Minnesota Department of Transportation, Local Road Research Board, St. Paul, MN, Report No. 2004-06 (also as Natural Resources Research Institute technical report, NRRI/TR-2003/44)]. The goal was to assemble a body of technical data that could be used to better assess the potential of using a crushed taconite mining byproduct like coarse tailings for more widespread construction aggregate purposes, primarily in roads and high¬ways. An important part of the mineralogical assessment included X-ray diffraction (XRD) analyses and microscopic (polarized light microscopy, scanning electron microscopy, and transmission electron microscopy, i.e., PLM, SEM, and TEM, respectively) evaluation of the size and shape (morphological) characteristics of potentially respirable microscopic mineral particles and fragments. Quantitative mineralogy, based on XRD analyses, showed that the dominant mineral in all samples was quartz (55-60%), followed by much smaller amounts of iron oxides, carbonates, and silicates. Specialized microscopic analyses and testing performed by the RJ Lee Group, Monroeville, PA, on both pulverized (-200 mesh, or 0.075 mm) and as-is sample composites showed that no regulated asbestos minerals or amphibole minerals were detected in the western Mesabi Range samples. A small number (26) of non-asbestos and non¬amphibole mineral cleavage fragments/mineral fibers were detected by SEM out of 1000 fields analyzed, but most were identified as min¬nesotaite and talc, silicate minerals common to the Biwabik Iron Formation. Amphibole minerals, absent in coarse tailings samples from the five western Mesabi Range taconite operations, were present in a single eastern Biwabik Iron Formation sample collected in 2003 for Lake County from the Cliffs Northshore operation in Silver Bay, MN. Importantly, the Superfund Method for the Determination of Releasable Asbestos in Soils and Bulk Materials [United States Environ¬mental Protection Agency (USEPA), 1997. Superfund method for the determination of releasable asbestos in soils and bulk materials, EPA 540-R-97-028, U.S. Environmental Protection Agency, Washington], as modified by Berman and Kolk [Berman, D.W., Kolk, A.J., 2000. Modified elutriator method for the determination of asbestos in soils and bulk materials, Revision 1: Submitted to the U.S. Envi¬ronmental Protection Agency, Region 8, May 23, 2000] failed to generate any protocol fibers, i.e., fibers longer than 5 µm and thinner than 0.5 µm, from either the western coarse tailings samples or the single eastern Biwabik Iron Formation sample. The combined findings suggest coarse tailings and other taconite mining byproducts should be treated with the same common sense safety and industrial hygiene approach practiced for all mineral-based materials that have the potential to generate respirable dust. © 2007 Elsevier Inc. All rights reserved.

Jan 1, 2007

By Khosrow Ebrahimi

We document the occurrence, mineralogy and firing properties of magnesite from hydrothermal deposits in the upper Cretaceous ophiolites of Eastern Iran. These deposits occur as thin veins of nearly pure cryptocrystalline magnesite with only trace amounts of quartz, calcite, and dolomite. Ratios of CaO/SiO2 in the bulk ore are variable. The composition of dead-burned magnesite from these deposits, calcined at different temperatures and durations, is predictable from phase equilibria. Textures of the calcined magnesite were studied by SEM; results show that the principal impurites produced during calcination are forsterite, monticellite, merwinite, dicalcium and tricalcium silicates, and that these are located principally at triple junctions of the periclase crystals. The size of periclase crystals increased with temperature and duration of calcination and the amount of periclase-periclase grain contacts was reduced by increasing the concentration of impurities in the starting products. EPMA show: 1) that CaO and FeO contents in periclase increase steadily with an increase in the CaO/SiO2 ratio and the FeO content of the bulk ore, respectively, and 2) that limited solid solution exists between impurites. This study demonstrates that high quality dead-burned magnesia refractories can be produced from the Iranian magnesite with low CaO, SiO2 and FeO contents.

May 1, 2004

By Roy O. Ifill, W. Charle Cooper, Alan H. Clark

"A detailed study of the compositional relationships of the Uand Th-bearing minerals in Elliot Lake uranium ores has been conducted, particularly with regard to uranothorite, which clearly plays a critical role in hydrometallurgical processing. Application of the rotating disc progressive-leaching technique to individual mineral grains and intergrowths of known compositions has defined for the first time the solubilization behaviour ofthe minerals in question.In descending order of leachability, regardless of leaching conditions, the phases are: uranothorite, uraninite, and monazite. Inclusions of secondary uranothorite enhance the dissolution kinetics of uraninite, which exhibits a complex dissolution mode. U-rich uranothorite dissolves more readily than Th-rich. Monazite is soluble in HJ)04 and HCI solutions only at temperatures exceeding 85°C. Consequently, it is deduced that the 15% to 20% of thorium not leached from the ore is lost both as monazite and as uranothorite inclusions locked in monazite which persists to the tailings. INTRODUCTIONThe importance of precise information on the mineralogy of ore and gangue constituents for the optimization of metal recovery in hydrometa Uurgical processing has been recognized for some years (e.g. Burkin, 1969), and numerous investigations integrating mineralogical studies and experimental leaching have been reported for ores of gold, nickel, copper and uranium (see summary by Henley, 1983). The complex mineralogy of uranium ores hosted by Precambrian pyritiferous, quartz-pebble, conglomerates has prompted particular attention in this regard (e.g. Liebenberg, 1956; Liebenberg and Taverner, 1958; Feather and Snegg, 1978). In the great majority of documented studies, however, petrographic examination has been followed by bulk leaching, an approach which, although providing valuable information, does not permit precise definition of the evolution of mineral dissolution processes. The authors contend that experimentation involving the step-by-step leaching and mineralogical study of ores is more likely to reveal the actual dissolution events which control the release of metals and, hence, may better define the optimal conditions for hydrometallurgical processing. Such studies (e.g. Hausen, 1983; Horlick et al., 1981) in addition lend themselves to the prediction of changes in the leaching behaviour of ores in which one or more mineralogical feature is subject to modification, a common characteristic of mineral deposits."

Jan 1, 1989

By Roy O. Ifill, W. Charle Cooper, Alan H. Clark

"Queen’s UniversityIn representative, run-of-mine samples from the Panel and New Quirke mines of the Elliot Lake uranium district, Ontario, brannerite, ametamict uranous titanate, occurs in microscopic grain-aggregates which display wide variations, both in textural habit and in the relative proportions of brannerite, titania polymorphs and/or “uraniferous titania”. As is widely documented, much of the brannerite occurs as trellis-like arrays of laths and needles pseudomorphing rutile oranatase. In some cases, the laths and needles are cemented by coffinite. Brannerite, with an average composition of (U0.629Th0.039Ca0.20)(Ti2.199Fe0.13)O69contains =3 wt% Th and is distinctly Ti-rich relative to the ideal composition, UTi2O6. Much of the Si reporting consistently in electron microprobe analyses (between 1 wt%and 5 wt%) is tentatively attributed to contamination by the quartz-sericite matrix, and a minor proportion is attributed to the presence of coffinite intergrowths. “Uraniferous titania” (average par-tial composition by weight: 10.8% U, 0.3% Th,32.9% Ti) is considered to represent an intermediate stage in the conversion of titania to brannerite.The leaching behaviour of brannerite in its different modes of occurrence was studied qualitatively by the rotating-disc (polished section) method in H2SO4and HCl solutions at 25° to70°C. Redox potential was not measured. The progress of the dissolution of the individual brannerite crystallites and grain-aggregates was monitored by optical and scanning electron microscopes. Regardless of its morphology and texture (laths or needles, reticulate or blocky),brannerite is not readily leachable. Regardless of the process conditions, the rate-controlling step appears to be the initial leach-pit formation. These pits expand radially through the aggregate as leaching proceeds. This dissolution mode is independent of the relative amounts of brannerite and titania, i.e. the type of grain-aggregate. Secondary coffinite intergrowths are readily leachable and enhance the overall leaching kinetics of brannerite by accelerating leach-pit formation. These data provide, for the first time, information on the controls on the leaching of the uraniferous phases which dominate the lower-grade ores in the Elliot Lake district."

Jan 1, 1996

By Jiuhua Xu, Shuiku Jia, Weiren Sun

"The Jinqingding gold deposit, situated in the east Jiaodong Peninsula of Shandong province, is typical of the pyrite-quartz vein gold deposits in the Muping-Rushan gold belt of China. The gold deposit is controlled by a great NNE fracture zone and is composed of several lenticular orebodies within the fracture rone occurring in the Kunyushan granite massif. The Kunyushan granite massif was formed by the replacement of the Archean Jiaodong group.The main minerals associated with gold are pyrite, chalcopyrite, galena and sphalerite; the gangue minerals are dominated by quartz, sericite, microcline and calcite. The mineralizing event can be divided into four stages: (1) pyrite-quartz; (2) quartz-pyrite; (3) siderite-polymetallic sulfides; and (4) calcite-quartz. Gold occurs mainly as native gold and electrurn in stage I and stage II. There are some evident differences between pyrite from major stages of gold mineralization and that from minor stages; these include differences in crystal forms, size and composition of fluid inclusions.Wallrock alterations consist of sericitization, silicification, pyritization and potash-feldspar alteration. Five alteration zones can be distinguished from unaltered granite (zone 0) to vein lodes (zone IV). Au and Ag increase rapidly from zone 0 to rone IV, Cu increases continuously, while Pb and Zn increase slowly. R-type geological factor analysis indicates that the Au, Ag, Cu, Pb and Zn bear a close relationship to wallrock alteration."

Jan 1, 1994

Some of the problems associated with drill core evaluation of alluvial tin deposits and correlation with plant-scale recovery are discussed. Panning churn-drill cores on site tends to undervalue such deposits because of failure to recover completely all the available liberated cassiterite, and secondary gravity processing may also fail to give an accurate determination of potentially recoverable tin. However, by using a combination of heavy liquid separations, x-ray fluorescence analysis for Sn, and normal methods of reflected and transmitted polarized light microscopy, a quantitative assessment of alluvial material can be carried- out. The information obtained may include the liberation characteristics and distribution with size of the cassiterite, the nature and quantities of the various gangue minerals, and the amount of potentially recoverable cassiterite in the material as compared with the amount locked with light gangue minerals and hence difficult or impossible to recover. In addition, an analysis of the efficiencies of the various gravity processes, such as panning, jigging, and tabling, used to determine "recoverable tin" in the alluvial material, can be carried out. A detailed example is given of this type of investigation, in which an assessment was made of a churn-drill core from Uncia, Bolivia.

Jan 1, 1970

By S. L. R. Lenharo, H. Kahn, H. Born

Different ore types result from the irregular spatial distribution of the associated alkaline/carbonatite rocks and the zoned alteration profile within which apatite may have undergone reprecipitation. Different flotation responses are caused by their mineralogy, iron oxide impregnation and grain-size characteristics. Samples from seven deposits were crushed, screened and separated before being studied by chemical analysis, optical microscopy, X-ray diffraction, FTIR spectroscopy, cathodoluminescence and scanning electron microscopy. Two main apatite varieties with peculiar crystal morphology were identified: hydroxy-fluorapatite as the primary phase and carbonate-fluorapatite as the reprecipitated phase. The former occurs as prismatic or ovoid grains and the latter as polycrystalline aggregates or crusts on the primary grains; both are associated with iron oxide coatings (primary) or intergrowths (secondary). Microflotation tests showed variations in flotability for particular apatite associations as well as intensity of iron oxide coatings. The differences in flotation behaviour can be related to morphological properties and chemical substitution in the apatite structure

Aug 1, 1996

By P. Tong-jiang

We studied mineralogical characteristics of the vermiculite samples from seven mines in China. We found three types of interstratified structures in the investigated samples: 1:1 regular interstratified structure, segregated interstratified structure, and random interstratified structure. The vermiculite samples from six mines are mainly composed of phlogopite?vermiculite interstratified minerals, and the samples from the other mine are composed of chlorite?vermiculite interstratified mineral. The samples with phlogopite?vermiculite structure have high contents of K2O, TiO2 and Na2O. The samples with chlorite?vermiculite structure have the highest contents of MgO and Al2O3. The cation exchange capacity of the samples is 17.3?99.0 mmol/100g.The exchangeable cations of phlogopite?vermiculite samples from Weili Mine mainly include Na+ and Ca2+, while those of phlogopite?vermiculite samples from Tongguan Mine mainly include Mg2+ and Ca2+. The thermal expansion ratio of the samples is between 9 and 32. The exfoliated vermiculite products from Weili Mine have the best mechanical strength.

Feb 27, 2013

By M. Sommerfeld, U. Schwarz-Schampera, B. Friedrich, D. Friedmann

The steadily growing demand for metals and their price increase at metal exchanges make the mining and utilization of marine mineral resources like polymetallic nodules, manganese crusts or sulfide deposits in the near future a viable option to potentially increase the supply of base and precious metals. For a country with low potential to mine land-based resources like Germany, the industrial recovery of metals from marine mineral resources could lead to a decreased dependency on imports. In this study, seafloor massive sulfides from the German license area in the Indian Ocean (Kairei field, Southern Central Indian Ridge) are treated to recover copper and precious metals. The aim of the project is to demonstrate the transferability of existing metallurgical techniques to the raw material of deep-sea massive sulfides. As a starting point to process this unconventional resource, samples from the Indian Ocean are chemically analyzed and mineralogical characterized. A comparison is carried out between the samples and land-based copper resources, to highlight the potential which lies in mining the deep-sea floor. This paper will show the general possibility of applying a two-stage pyrometallurgical process, based on a concentrate smelting operation, followed by a converting operation in lab-scale to the provided samples of massive sulfides. Generated slag from the concentrate smelting and the converting operation are investigated by X-ray diffraction to determine the mineralogical composition. The two-stage pyrometallurgical process is investigated by the thermochemical modelling tool FactSageTM 7.2 to evaluate the phase distribution of relevant elements between the metal, matte, slag and gas phase. The thermochemical boundaries of the pyrometallurgical process are therefore set and the results of the thermochemical study can be used as an indicator for the efficiency of an up-scaled process and the generated amount of side-streams, which need to be further treated or circulated back into the process. INTRODUCTION Seafloor massive sulfides (SMS) are the third kind of discovered deep-sea minerals besides ferromanganese nodules and cobalt-rich ferromanganese crusts (Sharma, 2017). They occur in water depths around 250–4,000 m (Koschinsky et al., 2018). SMS are characterized by a high base metal and sulfide content. They were created by fluid circulation and hydrothermal convection over time (Han et al., 2018). Commonly, areas rich in SMS are associated with hydrothermal vent fields on the seafloor (Keith et al., 2018).

Jan 1, 2019

By I. G. Gonçalves

For most industrial minerals, the color is directly associated with economic value. In terms of physics, the principal property that defines the term ?color? is the intensity of light reflected (or transmitted) by an object over the visible band, comprehended between 400 and 700 nm. This reflectance spectrum serves as the starting point for a variety of color-describing factors, the most common in the mineral industry being the brightness (TAPPI, 1977 and 1986) and the L*a*b* system (HunterLab, 2008). Quality specifications for mineral products are usually based on these colorimetric parameters. This market is becoming increasingly more selective and demanding over the quality of raw materials and alongside the traditionally controlled characteristics, such as particle size distribution and chemical composition, a trend exists towards the establishment of increasingly more strict specifications for the optical properties of these materials. This is due to the fact that most plants consuming these industrial minerals incorporate them into products in which the visual appearance is controlled. For these plants, most of them being the manufacturers of plastics, paper, paints, and ceramics, variations in the color of mineral materials result in difficulties to achieve the right color in the final product. Therefore, these plants set strict specifications for colorimetric parameters such as whiteness and yellowness, as well as colorimetric coordinates like L*, a*, and b*. For the manufacturer of industrial minerals, this translates into difficulties simply because many of these parameters are usually alien to the tradition of the mining industry. The main quality parameter in the kaolin industry is brightness, which is a weighted average of reflectance values over the range of 400-510 nm (TAPPI, 1977). Due to the lack of a better property, producers tend to use brightness to also assess the quality of the in situ ore and along the processing operations. However, the unprocessed kaolin is often accompanied by ?contaminant? minerals. For Brazilian kaolins, which are the object of this study, the most important contaminants are hematite (Fe2O3), goethite (FeOOH), and anatase (TiO2). Each of these contaminant minerals has a distinct color and behaves differently during the processing of the kaolin ore. Hematite and goethite in particular are particularly strong pigmenting agents and at concentrations as low as 100 ppm they can make the difference between a high-quality white pigment product for paper coating and waste material. As each Fe-bearing contaminant has a different color and responds differently to processing operations (for example, magnetic separation, chemical bleaching, selective flocculation, and/or flotation in the case of kaolin), the in situ brightness tends to show a poor correlation with the brightness of the final product. Brightness measurements are sometimes complemented with X-Ray Fluorescence (XRF) analysis of Fe and Ti, but the total oxide content provided by XRF is also poorly correlated with product quality because Fe may be in the form of goethite, hematite, or inside the crystalline structure of kaolinite. Thus, a more robust technique capable of distinguishing each mineral phase is desirable. Diffuse reflectance spectroscopy has been used to analyze iron oxide/hydroxide content both qualitatively (Torrent and Barrón, 2003; Liu et al., 2011) and quantitatively (Jiet al., 2002 and 2006). These authors correlate slopes and inflection points at characteristic absorption bands with oxide/hydroxide content in natural soils. The approach presented here involves the extensive use of the Kubelka-Munk (K-M) theory, which has been used for color matching (Schabbachet al., 2009 and 2011) and particle size determination (Otsuka, 2004) in a simplified version. Unfortunately, the scattering constant S is very difficult to measure for dry powders, because the equations require a thin layer of material. Attempts have been made (Gonçalves and Petter, 2007, and Gonçalves, 2009) but the experimental errors tend to be high. Thus, this paper aims to develop a tool for the quantification of contaminant minerals in kaolin based on the K-M theory without resorting to measurements over thin layers. This tool is based on a new two-constant approach, which takes into account differences in scattering between materials over the whole measured spectrum. The experimental dataset consists of the reflectance spectra of mixtures between a bleached kaolin and synthetic Fe pigments.

Feb 27, 2013

By Ari I. Kogut

Impurity minerals in fluorspar ores and concentrates from a deposit in Southern Africa have been studied by reflected light, transmitted light, and cathodoluminescence microscopy. The principal impurities are quartz, calcite, aegirine, apatite, ankerite, magnetite, goethite, and synchysite [Ca(La,Ce,Nd)(C03l2Fj. Cathodoluminescence microscopy was found to be very useful in studying the character of the fluorite and especially for recognizing the presence of apatite and calcite impurities. Fluorite exhibits blue, calcite shows yellow, and apatite has white, light purple, and pink cathodoluminescence. The cathodoluminescent character of apatite varies with its geological environment and position in the orebody. The results of this microscopic study show that phosphorus present in flUorite concentrates occurs principally in binary locked apatite-fluorite particles. Successive fluorite cleaner concentrates contain progressively smaller amounts of locked apatite-fluorite particles. Free apatite has been effectively partitioned to the final tailings.

Jan 1, 1995

By J. W. Cash

The mineralogy and textures of cyclone dust, sludge, and occasional build-ups in the American Iron and Steel Institute (AISI) direct iron making pilot plant at Universal, Pennsylvania have been studied by reflected light, transmitted light, and cathodoluminescence microscopy, and phase compositions have been determined by SEM-EDS. The cyclone dust consists of particles of carbon, metallic iron, sulfur-bearing iron, and wustite. Measurements of particles in the sludge indicate that 69% are less than 2.5 µm across, 21 % are 2.5-5 µm, and 10% are larger than 5 µm. Mineralogically the sludge particles are mainly carbon and metallic iron, with minor wustite and sulfur-bearing iron. Build-ups that sporadically develop in the furnace consist of olivine, hercynite spinel, metallic iron, wustite, pyrrhotite, pseudobrookite, akermanite-ferroakermanite and gehlenite. The microtextures shown by the build-ups indicate that much of that material has precipitated at the build-up loci. This study has been supported by AISI and the U.S. Department of Energy.

Jan 1, 1995

By John W. Cash

The mineralogy and textures of cyclone dust, sludge, and occasional build-ups in the American Iron and Steel Institute (AISI) direct ironmaking pilot plant at Universal, Pennsylvania have been studied by reflected light, transmitted light, and cathodoluminescence microscopy, and phase compositions have been determined by SEM-EDS. The cyclone dust consists of particles of carbon, metallic iron, sulfur-bearing iron, and wustite. Measurements of particles in the sludge indicates that 69% are less than 2.5 um across, 21 % are 2.5-5 um, and 10% are larger than 5 um. Mineralogically the sludge particles are mainly carbon and metallic iron, with minor wustite and sulfur-bearing iron. Build-ups that sporadically develop in the furnace consist of olivine, hercynite spinel, metallic iron, wustite, pyrrhotite, pseudobrookite, akermanite-ferroakermanite and gehlenite. The microtextures shown by the build-ups indicate that much of that material has precipitated at the build-up loci. This study has been supported by AISI and the U.S. Department of Energy.

Jan 1, 1995

By M. A. W. Bryson

Platinum group metals are extracted almost exclusively in South Africa from three very different zones in the Bushveld Igneous Complex, called the Plat, Merensky, and the UG-2 reefs. The Plat reef is currently being exploited only by Anglo American Platinum, whereas the Merensky reef is exploited by them, Impala Platinum, Northam, and Lonplats. The UG-2 reef, on the other hand, is also processed by these producers, but Kroondal and Barplats have operations that exclusively treat ore from this reef. At present the extraction of pgms from ores in South Africa follows the traditional route of upgrading to a concentrate in a minerals processing circuit, further upgrading to a matte in a smelter, and final upgrading and separation of the individual metals in a refinery. Thus all operations that extract pgms require a minerals processing circuit, the design and performance of which is a topic of much interest, as it is a poorly understood and not a very efficient process in relative terms, compared to the other processes. Recoveries across the minerals processing circuit of between 75 and 90% are the norm.

Jan 1, 2004

By Gregory L. M, Phillips G. N

Although it has long been recognised that there is a diversity of minerals associated with Victorian gold deposits, the degree to which this mineralogy is systematic or haphazard has remained uncertain. Recent work by the authors and students under their supervision permits a sharp delineation of the boundaries between different mineralogical domains, and these are interpreted in terms of recent rapid advances in Victorian tectonics, and the regional framework of Victorian gold geology described in Phillips and Hughes (1996).

Jan 1, 1997