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By W. Gundaker, F. C. Schwerer

Natural chromium-bearing spinels (chromites), which are used as refractory materials in basic steelmaking, are the only commercially important chromium ore and are also encountered as difficult-to-separate contaminants in ore deposits of potential economic value. Techniques for characterization and separation of ore materials frequently are dependent on the magnetic properties of the constituent minerals. An experimental program was initiated to explore the effects of temperature and of simple mechanical and thermal treatments on the static magnetic properties of several ore-grade natural chromites. Studies of the temperature dependence of the magnetic properties showed that the natural chromites, which are dilute in the magnetic ions Fe and Cr, order magnetically only at cryogenic temperatures. However, mechanical treatment in the form of crushing produces a magnetic component that is ordered at room temperature and that is of sufficient strength to alter magnetic-separation characteristics. The additional magnetic component apparently is associated with surface structures which develop during crushing and disappear after heating to above about 500°C. Preliminary studies indicate that this surface structure enhances the susceptibility of the chromite grain surfaces to gas reactions at moderate temperatures.

Jan 1, 1976

By J. Schmidt

The development of set of laboratory experiments, intended to help undergraduate students meet Canadian Engineering Accreditation Board requirements for Engineering Design outcomes, is described.The laboratory, which is part of a third year level course in hydrometallurgy, is aimed at advancing the ability of students to generate and use experimental results to design an industrial copper leach/SX/EW plant. Emphasis is placed on the students demonstrating the ability to use of their engineering knowledge in weighing the pros and cons of the various process options that they test in converging to a final flowsheet. INTRODUCTION Over the past number of years the Canadian Engineering Accreditation Board, CEAB, has dramatically shifted the way that they evaluate undergraduate programs. In the past, the focus was on measuring of the quantity and quality of material the students were intended to learn as well as the methods and resources used to deliver that material. Now, rather than principally evaluating the inputs of programs, the focus is more on measuring the quality of the outputs from the programs, i.e. the quality of graduating students. In this regard, the CEAB has developed a list of twelve attributes that learners must develop in the course of their studies. Engineering programs must, not only demonstrate that their curriculums provide opportunities to develop these attributes, but must measure student proficiency in each of these attributes as they progress toward graduation. One particular graduate attribute that Laurentian University’s Bharti School of Engineering has encouraged its faculty members to develop content for is “design”. Engineering Canada (2018) defines this attribute as “an ability to design solutions for complex, open-ended engineering problems and to design systems, components or processes that meet specified needs with appropriate attention to health and safety risks, applicable standards, and economic, environmental, cultural and societal considerations”. The previous laboratory component for the hydrometallurgy course was a collection of unconnected experiments covering leaching, solvent extraction, ion exchange, and electrowinning. Like in other undergraduate courses, students would perform stand-alone experiments, make the specified measurements, do the specified analyses of the results, and report the findings, all as strictly detailed in the lab manual. The vision for the new lab was to create an experience that would more closely mimic an industrial research program whereby students would start with a given feed material and would progress through a series of connected experiments. Emphasis is placed on the student demonstrating competency in, not only, generating and analyzing experimental data, but also in using the data along with their engineering knowledge to design and evaluate the pros and cons various plant configuration options. Principally, students are asked to weigh cost, safety, and environmental concerns in converging to their final flowsheet. In designed the leach circuit, students must weigh the costs/benefits of varying leach temperature. Higher leach temperatures will yield faster and more complete copper dissolution, which will allow for the specification of relatively smaller leaching circuits, saving capital costs. However, hotter acid solutions are more dangerous to handle and require increasing amounts of energy to heat the slurry, increasing operating costs. In solid/liquid separation, students must weigh the pros and cons of the addition of a flocculent to assist settling. The flocculant will allow for the design of a thickener circuit that employs units with a relatively smaller area, but will result in a thickener underflow with a lower pulp density, which may necessitate a larger number of thickeners. In addition, the environmental concerns of producing a tailings product that contains an organic contaminant should be addressed. In solvent extraction, students must specify the number of stages of loading and stripping, as well as organic and aqueous flowrates to produce suitable raffinate and rich electrolyte streams. Finally, in electrowinning, students will compare the costs/benefits and risks of the use of precious metal coated titanium dimensionally stable anodes (DSAs) versus conventional Pb based anodes.

Jan 1, 2019

By Fernando Altamirano

"En el presente trabajo técnico justificaremos la necesidad de implementar un Centro de Entrenamiento en Emergencias a nivel nacional, se expondrán los objetivos y beneficios, los tópicos de emergencia que se deben considerar de acuerdo la realidad del país, así como la inversión prevista.En el País la cultura de seguridad está en formación, por lo que vamos a esperar ocurran emergencias con mayor frecuencia, y debemos estar preparados para afrontarlas."

Sep 1, 2017

By Karen Munro

Importance of Aquatic Studies for Mining ?Aquatic habitat is usually the first area where a mine interacts with the ?real world? outside the mine footprint ?Water management is a key consideration for a mine?Effects on the aquatic environment often extend to wildlife and human uses ?There is a lot of regulatory focus on issues of water quality, fish and fish habitat

May 1, 2011

By Mikula PA

This paper presents the results of in-situ and laboratory investigations into a mining method which utilises conventional continuous mining techniques to carry out two passes in thick coal seams, resulting in the development of stable pillars with relatively small width dimensions and heights up to 6 m. Geotechnical investigations included structural mapping, brightness logging and standard laboratory testing. Virgin stress was measured using overcoring techniques. Two approaches to pillar design were used in the study. These were; pillar design based on empirical formulae and laboratory testing, and pillar disign using calibrated mathematical models. A trial panel was developed at 300 m depth to study pillar deformation and stress changes due to mining. The extent of rib deformation was studied using borescopes and extensometers. In-situ geotechnical measurements were used to calibrate displacement discontinuity and finite element mathematical models of the coal seam. These models were then used to predict the behaviour of a small panel of pillars which were to be developed to 6 m height. The mining method was shown to be feasible provided adequate rib support was installed. The benefit of rib support was found to be two-fold, in that it increased confinement of the pillar in zones of low horizontal stress, while reducing horizontal stress relaxation in zones of high horizontal virgin stress. The possiblity of roof control by designing the small pillars to yield on retreat is discussed.

Jan 1, 1986

By Frederick N. Rhines, William A. Anderson

The investigations of Wymanl have demonstrated that copper deoxidized with several of the commonly used agents that confer immunily to ordinary hydrogen em-brittlement can still be embrittled if it is annealed alternately under oxidizing and reducing conditions. During the oxidizing cycle, oxygen diffuses into the copper and frequently deposits a subscale composed of the oxide of the residual deoxidizing agent. Upon subsequent reduction with hot hydrogen, the copper becomes ruptured along the grain boundaries to a depth sharply limited by the previous penetration of oxygen as delineated by the inner boundary of the subscale. Obviously the sensitivity to this kind of hydrogen embrittlement is engendered by the introduction of oxygen during the oxidizing anneal, but beyond this the mechanism of the process, and hence the controlling factors, remain obscure. There are several possibilities: (I) oxygen dissolved in the copper matrix of the subscale may, upon cooling prior to the hydrogen anneal, precipitate as cuprous oxide which is subsequently reduced by hydrogen as in the familiar case of hydrogen embrittlement; (2) oxygen in solid solution in copper may itself confer susceptibility to embrittlement by hydrogen; (3) the normally refractory oxides such as those of aluminum, silicon and titanium may themselves be reduced by hydrogen when in contact with copper; or (4) the precipitated oxides of the subscale may be complex compounds such, perhaps, as SiO2.Cu2O, which are partially reduced by hydrogen. These possibilities have been examined, and it has been concluded that the first three and possibly the fourth are operative collectively or individually under more or less predictable conditions. Effect OF Precipitated Cuprous Oxide and Dissolved Oxygen The literature provides no definite proof that oxygen in solid solution in copper can confer susceptibility to hydrogen embrittlement; indeed, the research of Leiter2 seemed to indicate the opposite—that to produce the effect, cuprous oxide must be present in massive form and in a more or less continuous network along the grain boundaries. To test this point, pure copper has been annealed in hydrogen under conditions designed to ensure the presence in various samples of: (I) precipitated cuprous oxide, (2) dissolved oxygen only, and (3) no oxygen in any form. Very pure copper" said to contain no oxygen and no spectro-scopically detectable traces of any other element (that is, no individual detectable impurity in quantity greater than 0.0001 per cent) was used. Strips of this material cold.-rolled 75 per cent to 1/8 in. in thickness were subjected to the following treatments, the results of which are noted:

Jan 1, 1941

By Eirik Sundvor, Hany Doss, Peter Vogt, Kathleen Crane

"Abstract - In 1989-1990, the SeaMARC II side-looking sonar (11 to 12 kHz) and swath bathymetric system imaged more than 80 000 km2 of the seafloor in the Norwegian-Greenland Sea and southern Arctic Ocean. One of our main goals was to investigate the highly oblique (115°) junction between the Mohns and Knipovich ridges, and to determine, using new morphotectonic data, whether or not this junction is stable or in a state of readjustment. These findings are presented in this paper.Along the northern Mohns Ridge, we observed a highly segmented rift valley undisturbed by transform faults. In contrast to the elevated Reykjanes Ridge, the Mohns Ridge is dominated by deep en echelon fault-bounded troughs, which are bordered by high rift valley volcanoes. These segment boundaries are interpreted to be sites of recent to present volcanic activity, based on their high acoustic reflectivity. The northwestern flank of the Mohns Ridge is marked by shallow quasi-linear ridges parallel to the present orientation of the Mohns Ridge. The orientation and geographic position of these ridges suggest that they were formed at the Mohns Ridge. Only in the northernmost cases are some of these off-axial ridges non-linear. The degree of the non-linearities increases slightly with proximity to the Mohns-Knipovich bend. In addition, because no transform fault was detected between the Mohns and Knipovich ridges, we conclude that the Knipovich Ridge must be obliquely spreading to the NW-SE."

Jan 1, 1999

By Draper J. J, Jell J. S

The Burdekin Basin in the Townsville hinterland is an intracratonic extensional basin which contains up to 4500 m of marine and continental siliciclastics and carbonates. The basin sequence is recognised as having accumulated during five major episodes of deposition. Facies analyses of these show that each consists of one or more transgressive or regressive phases. Each episode led to the accumulation of thick sequences in several half-grabens in a transtensional back-arc setting. The depositional episodes can be recognised in comparable sequences in the Broken River Province to the west and Drummond Basin to the south.An Early Devonian episode resulted in the deposi-tion of dominantly marine facies, currently mapped as Fanning River Group, in the northern part of the Burdekin Basin. Two transgressive phases are recorded there, firstly in the Pragian, then later in the late Emsian to early Eifelian. A Middle Devonian episode is represented by dominantly marine facies of the Fanning River Group, representing the peak of a widespread late Eifelian to Givetian transgressive phase. A Late Devonian episode is characterised by continental facies of the Dotswood Group. Deposition occurred during a major regressive phase in response to regional uplift of surrounding areas, and the onset of acid-intermediate volcanism to the south. A Late Devonian to Early Carboniferous episode followed, which was a period of alternating marine transgressions and non-marine regressions that resulted in the deposition of the Keelbottom Group. A final Early Carboniferous episode, marked by the deposition of calc-alkaline volcanics and non-marine faciesòof the Glenrock Group, was a direct outcome of Early Carboniferous subduction further to the east. Compression of the basin followed in the Late Carboniferous, resulting in folding and reactivation of basement faults.

Jan 1, 1990

The completion of the Hot Strip Mill at the Port Kembla works of Australian Iron & Steel Ltd., makes possible the production of steel plates and wide strip of a quality and in quantities not possible previously in Australia, and will also enable the production of tinplate to be undertaken in this country.The site chosen for the mill was a mud fiat underlain by a hard stone bottom at 5, to 801 feet below the surface; and a total area of one hundred acres was reclaimed to a level of 20 feet above the original surface.Three adjoining buildings were constructed to house the slab receiving yard, mill equipment and electric drive, together with the plate finishing line.After slabs have been heated to 2250°F at a rate of 90 tons per hour, they are transferred to the vertical scale breaker which is the first stand in the hot roughing mill. Here the primary furnace scale is first cracked and then blasted off by high velocity water descaling sprays.The next stand is the horizontal scale l;Jreaker, where any remaining primary scale is broken and then blasted off. After descaling, the slabs pass to the broadside mill, where short slabs are turned and rolled on broad side for wide plate.The next step is a slab squeezer which squares up the edges after broadsiding ready for the reversing mill. This is the finishing stand for plate and the last roughing stand for strip, which then passes to the finishing mill.The hot strip finishing mill consists of six stands with a maximum finishing speed of 2,230 feet per minute. Strip is cooled for coiling by water sprays on a hot run table and then coiled on a mandrel type downcoiler, from whence coils of hot strip are weighed and transferred by conveyor to the coil storage building.Plates are transferred from the reversing mill to the plate finishing line where operations consist of levelling, inspection, branding, cutting to width and length:INTRODUCTIONDue'to the increasing production of cars, refrigerators, washing machines and similar consumer goods in Australia, together with the increased requirements of galvanised iron...

Jan 1, 1956

By Michael Perlow

Helical screw piles in use since 1838 are routinely used for energy, transportation, municipal, industrial, marine and coastal infrastructure as well as for excavation support, environmental remediation, and foundation repair. They are especially well suited for work in constrained areas, renovations and structure retrofits. Helical pile design procedures over the past 10 years have gone through a remarkable evolution with the establishment of the 2007 AC358 Helical Pile Acceptance Criteria and inclusion of helical screw piles in the 2009 International Building Code (IBC). New 2009 IBC building code requirements and AC358 Acceptance Criteria are presented along with advances in helical pile design procedures, installation, QA/QC, and recommended load test verification criteria. Use of helical smart piles to validate helical pile design and verification of ultimate pile capacity is highlighted.

Jan 1, 2011

By Arsenio Enriquez, Adrian Deneys, Ryan Walton, Jenny Esker

NOx emissions at the Rio-Tinto Kennecott Copper (RTKC) smelter, near Salt Lake City, Utah, are regulated to a compliance emission limit at the Main Stack of 15.9 kg/hr on an annual rolling average. The paper discusses RTKC efforts and improvements, particularly related to the anode furnace operations, since the Smelter modernization in 1995 to comply with the air quality approval limit. This includes replacement of gaseous ammonia to Steam-Gas Refining (SGR) system during the copper reduction stage, upgrade anode furnace oxygen-fuel burner from Praxair’s Stabilized Jet (S-J) to Jet Lance (J-L) technology, development and implementation of operational best practices and continuing to investigate and evaluate NOx control technology and strategy in the industry. In early 2016, changes to Praxair J-L Burner technology on both anode furnaces, utilizing wider lance spacing, was adopted and further improved NOx emission levels well below the compliance limit. INTRODUCTION Since the establishment of the Clear Air Act in 1970, the Environmental Protection Agency (EPA) has been regulating emissions of nitrogen oxides (NOx) to reduce impact on public health and the environment (USEPA, CAA, USEPA, NAAQS). As a requirement of the Clean Air Act, the EPA evaluates the standards for NOx and criteria pollutants on a periodic basis and as a result, standards have been revised and ultimately reduced over time (USEPA, CAA, USEPA, NAAQS, UDAQ, SIP). To remain competitive with changing regulations and in conjunction with Rio Tinto environmental standards for continuous improvement, the RTKC smelter has been motivated to research and implement NOx control strategies. NOx health and environment impacts NOx refers to a group of seven compounds including the most common, nitrogen dioxide (NO2). (USEPA, NO2). The EPA enforces both short-term (1-hr average) and long-term (annual average) standards for NO2 to protect against associated respiratory system impacts. Short-term exposure of elevated NO2 concentrations can aggravate respiratory diseases and lead to symptoms such as coughing, wheezing or difficulty breathing while longer exposures may contribute to the development of asthma and potentially increase susceptibility to respiratory infections. (USEPA, NO2) Additionally, NOx is necessary in the formation of ozone and particulate matter less than 2.5 microns (PM2.5). Ozone concentrations can negatively impact lung function and in some cases, contribute to chronic obstructive pulmonary disease. (USEPA, Ozone) The particles associated with PM2.5 can reduce lung capacity and aggravate heart conditions. (USEPA, PM2.5) For all NOx related pollutants, children and the elderly are generally at greater risk for the health effects. (USEPA, NO2, USEPA, Ozone, USEPA, PM2.5)

Jan 1, 2019

By Rao S. B, Baafi E. Y

A venturi based multi-scrubber air cleaning system has been developed for dust control along a longwall face in coal mines. The system consists of a number of scrubbers. strategically placed along the wall face which deliver cleaned air at high exhaust velocity into the middle section of the longwall cross-section thus dividing it into two zones. The aim is to maintain the walkway on the powered support side as a zone of relatively clean air. Laboratory studies have shown that the scrubber's average efficiency is 90 per cent. Field trials in three longwall faces have shown that. under normal operating conditions. 40 to 50 per cent average protection efficiency can be achieved within 3 m to 4 m downstream of the scrubber. A three-dimensional finite element computational fluid dynamic model. FIDAP. was used to simulate the airflow patterns the dust concentration and the scrubber dust control technique at a typical longwall face. Results of simulations tally very well with the field results.

Jan 1, 1995

By Eric Zahl

Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health, Spokane, WA, have collaborated with three Western longwall coal mines in an ongoing effort to develop technologies that will aid in providing safe and stable working areas. The goal of the research described here is to develop a stress monitoring system that will provide immediate information to mine managers for making daily safety decisions as areas of poor ground are mined through. Initial work has focused on answering preliminary questions regarding the reliability and use of stress change patterns. Research is concentrated on monitoring horizontal stress because horizontal stress is transmitted over long distances through stiff strata, thus allowing an extended length of entry to be monitored. This paper presents an explanation of the concept, key results from field tests at two mine sites, and a proposed process for imple¬menting a monitoring system. System design layouts, instrument use, data collection and interpretation methods, and processes to present findings to mine staff are described. Additional validation and correlation with actual failure mechanisms are required before this approach can be recommended at ongoing operations. How¬ever, initial results indicate that this approach shows promise in mines prone to bumps and roof falls associated with large stress changes. In particular, analyses of measured changes in horizontal stresses appear useful.

Jan 1, 2002

By B. W. Gandrud

In 1927 Coghill5 showed that there is considerable liberation of the iron oxide mineral from gangue when the Alabama red iron ores are ground to a size suitable for classification and tabling, but that there is not sufficient to make possible a high extraction and a high grade of concentrate. Coghill states: High extraction and high grade of concentrate cannot be obtained without grinding to a size comparable with flotation or cyanide practice. If grade of concentrate be sacrificed the grinding need not be so severe.

Jan 1, 1934

A forecast of energy demand in the non-commu- nist world to the year 1990 is presented with com- ments on the expected effectiveness of conservation efforts in achieving more efficient utilization of energy. A forecast of energy supply for the same period is presented showing the contribution of oil, gas, hydropower, coal, and nuclear fuels, with brief comments on the factors constraining the rate of growth of non-oil energy supplies. The role of `synthetic fuels', i.e. liquid or gaseous fuels produced from coal, oil shale, and tar sands, is reviewed with brief discussion of factors affecting the development of this industry. In somewhat greater details, the growth of demand for oil by geographic regions is analyzed. Particular attention is directed to the source of the oil supplies which will be required. The anticipated rate of discovery of new oil reserves is discussed with comments on lead times required in the development of new discoveries in hostile environments such as the Arctic and deep oceans. The continuing importance of oil supplied from countries which are members of the Organization of Petroleum Exporting Countries (OPEC) is illustrated. Oil will continue to be the marginal ('balancing') source of world energy supply throughout the forecast period and although it now appears that oil supplies will be sufficient to balance the energy equation during the 1980s, little flexi- bility will exist to cope with unexpected growth in demand or slippage in supply. Prudent energy re- source management will require major efforts to stimulate conservation and also to stimulate the rapid development of conventional and new forms of energy supplies and changes in energy consump- tion patterns to utilize the new supplies. Because of the long lead times and the massive capital require- ments involved, governmental policies are needed soon which will stimulate conservation and which will encourage businesses to move rapidly to assure the energy supplies the world will require in the 1990s.

Jan 1, 1978

By C. H. Mahoney, A. L. Tarr, P. E. Le Grand

Magnesium, it is now generally realized, differs in some important aspects from most other structural metals, not excepting even its close neighbors, the aluminum-base alloys. This is particularly true with respect to the effects of elevated temperatures on the two light metals when in the molten state. Aluminum, 0' the one hand, should not be raised above its melting point any higher than is absolutely necessary if one is to avoid danger of gas absorption and a tendency toward grain growth in the resultant casting.' Magnesium alloys, in sharp contrast, actually benefit by being heated to temperatures considerably above their melting point, It is a commonly accepted practice to establish the desired fine grain in the industrial magnesium alloys of the aluminum-hearing group by raising the temperature of the melt after the refining treatment to some 250°C (482°F.) above the melting range. To recall briefly the typical practice for magnesium alloys, the molten metal is refined by fluxing at about 730°C. (I350°F.), and after the melt has been covered with a suitable flux, the temperature is raised to between 870°C. (I600°F.) and 930°C. (1700°F.). It is then cooled as quickly as possible to the casting temperature. This superheating, as it is called, results in a fine-grained cast metal structure which has superior mechanical properties, enhanced amenability to 'solution heat-treatment, and better machinability than cast metal that has not been superheated. The minimum temperature of superheating varies to some extent with the composition of the alloys to be treated and usually increases with the percentage of magnesium in alloys containing the same constituent metals.' It should be noted that the grain-refining effect of superheating is markedly apparent only in connection with the alloys containing aluminum as an alloying Constituent—the binary alloy containing 1.5 per cent manganese, for example, is not refined in grain to any noticeable extent by a superheating effort. While the phenomenon of superheating is well known in the magnesium industry, the mechanism of the process has remained a mystery During the superheating cycle something occurs that forces a fine grain upon the solidifying metal. The process has been controlled in an empirical manner, and occasionally, especially on large-scale melts, and for no apparent cause, no grain refinement is obtained from a superheating treatment. Only a few papers of importance have been published on the subject. Of these, one of the most helpful is the paper by Achenbach, Nipper and Piwowarski,3 which gives considerable data concerning the effect of superheating on various properties such as fluidity, shrinkage and hot crack

Jan 1, 1945

By William Greenawalt

The Greenawalt electrolytic copper extraction process is applicable to suitable oxide ores, sulfide ores and concentrates, and low-grade matte. The process is self-sustaining in acid on sulfide ores or concentrates, on mixed ores, on high-grade oxidized ores; and on low-grade oxidized ores the amount of acid to be purchased or manufactured is greatly reduced. The ferric iron is under easy control, and copper may be effectively deposited from solutions of any acid or iron content likely to be used in copper leaching. From 60 to 75 per cent. of the copper may be removed from the solution in passing through the electrolytic department, before returning the solution to the ore. The amount of copper requiring chemical precipitation, from the waste and foul solutions, is only about 5.0 per cent, of the total copper produced, and this 5.0 per cent. is converted into the electrolytic metal in the regular operation of the process. The entire process can be made practically automatic, and can be carried out mechanically. There is no uncertain departure of any kind in the application of the process; no unusual or unproved apparatus is used. EVER since electrolytic copper refining gave promise of success, about a half century ago, efforts have been made to apply the idea to the extraction of copper from its ores. The methods of attack have, usually, been to leach with a dilute acid and then to deposit electrolytically the copper from the resulting solution with the simultaneous regeneration of the solvent used in the process. Many efforts have been made, and many patents have been taken out, both in the United States and abroad, to give this idea practical application, but only within the past few years have the difficulties been surmounted. Leaching and electrolysis, as applied to copper ores, are among the most promising fields in modern metallurgy. New conditions are arising, which will bring the wet methods into prominence; while high freight rates and increasing cost of fuel will tend to limit smelting to highly favored localities. The possibilities offered by the installation of hydro-electric plants and the greatly enlarged range of power transmission will greatly widen the field of electrolytic methods.

Jan 1, 1924

The treatment of mixed lead carbonate and lead sulphide concentrates at Mount Isa presents a problem which is unique ,in the lead smelting world; a problem whose solution is far from simple, and is not yet complete. Two years of study under plant conditions have definitely proved, however, that a most satisfactory sinter can be made in a single-pass roast.The object of this paper is to present a brief record of the development of the single-pass roast and a resume of current practice in the smelting plant. The sintering operation is discussed in greater detail, as it is upon this phase of the work that every item in the smelter operating programme depends.The smelter, to-day, presents a very much simplified layout, equipped for economical, straightforward operation, requiring, however, very careful and constant supervision, due to the extreme delicacy of the sintering operation and to the rapid and wide variati9n in the nature of the concentrates which are to be handled.

Jan 1, 1933

The tankhouse of the electrolytic zinc plant at Nordenham is operating with a very high operating efficiency of 99 per cent. This has been achieved not only by strict control of the quality of the zinc sulphate cell feed solution but also by all the improvements in housekeeping in the tankhouse developed during the past years: aluminium cathode specification, cathode stripping cycle, edge strips, copper contacts, anode isolators, cell cleaning, fittings and washing devices. During 1987 to 1992 the casting department was completely remodelled in order to improve the quality of the zinc products, the safety of the operations and the flexibility. The remodelling includes the enlargement of the area for the casting shop, the storage buildings and the five casting lines on the same ground level. New lines for alloying products and for SHG25 kg zinc ingots have been constructed. The line for galvanising products has new equipment in some parts and the other lines have been modified.

Jan 1, 1993

By Henk Dijkman, Wageningen University, Paula Gonzalez Contreras, Irene Sánchez-Andrea, Jan Weijma, Silvia Vega

"More than 20 years ago, Paques B.V. introduced innovative biotechnologies to recover metals and to remove sulfate from aqueous streams. These technologies find their origin in the exploration of microorganisms involved in the global sulfur cycle. Currently, several sulfur cycle biotechnologies are applied successfully at full-scale. The sulfur cycle is closely linked with the iron cycle, and also the latter offers opportunities for application of innovative biotechnology for the mining industry. Microorganisms of the natural iron cycle carry out reactions that are not feasible by chemical methods such as ferrous iron oxidation with oxygen at pH below 4. Iron oxidation with oxygen can be conducted using microorganisms living at pH between 0.5 and 7 and at temperatures between 0 and 95ºC. Remarkably these microorganisms can also carry out arsenite oxidation at similar acidic conditions and high temperatures. Making use of the extreme features of these microorganisms, Paques and Wageningen University have developed a biological process to precipitate arsenic as scorodite. This biological formation of scorodite is a novel combination of biological oxidation and biocrystallization. Depending on the level of saturation, biological oxidation rates and operational conditions, we could control the formation of the iron precipitates such as jarosite and scorodite. Currently new microorganisms have been harvested from hot springs and rock acid mine drainage to foster the growth of specialized microbial communities with potential high iron and arsenic oxidation capacities and higher resistance to other metals. In our paper we address the ongoing research and development of the bioscorodite process.THE USE OF IRON TO REMOVE ARSENIC In 2015 several environmental disasters related to the release of mine wastewater and tailings occurred. On August 5th, a waste water spill occurred from the Gold King Mine near Silverton, Colorado. A dam holding the tailing pond was damaged and spilled three million US gallons (11 ML) of mine wastewater and tailings, including elements such as cadmium, lead and arsenic, into Cement Creek, a tributary of the Animas River in Colorado. “At their peak, arsenic levels were 300 times the normal level and lead was 3,500 times the normal level” (The Guardian, 2015). In early November, another collapse of a mining dam in the Brazilian state of Minas Gerais spilled between ten and sixteen thousand US gallons of water and sediment after a dam failed from an iron ore mine. Arsenic and mercury polluted the Doce River, arsenic levels were found more than ten times above the legal limit in some places of the river (The Guardian, 2015). Waste production is inevitable during Mining. However, a preventive waste management strategy could have minimised waste production, maximised waste reuse and classified waste by their hazardous degree."

Jan 1, 2016