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Computer programs for the storage, retrieval and use of basic thermodynamic and physical property data for chemical substances are described. Methods are presented for the collection, critical assessment and pre- processing of source data for files containing enthalpy, entropy and heat capacity data for 3000 compounds, enthalpy and excess entropy for 200 dilute solutions and critical propert- ies and vapour pressure for 600 compounds. Retrieval programs are discussed which allow the tabulation or plotting of many basic and derived thermodynamic properties for chemical substances or balanced reactions. Examples are given of the use of such data to infer the stability or corrosion resistance of materials and the feasibility, yield and heat release of reactions. A general purpose calculation program is discussed which allows the equilibrium compos- ition to be found for complex systems with many species and phases, using the method of Gibbs energy minimization. Methods of correction for non-ideal behaviour in these systems are discussed, as well as methods for fixing, maximizing or minimizing any desired property of the system. Examples are given of the simulation of various laboratory Experiments and industrial processes by this method.

Jan 1, 1977

By King R. L

The Bureau of Mines has developed and deployed three expert systems to give advice on mining health and safety. These are: dust control for continuous miners, dust control for longwall shearers, and methane control. All three systems query about the nature and extent of the problem. Typical questions asked deal with observed methane levels, ventilation type and quantity, cutting sequence, and what control technology is employed. Advice given does not focus on a single issue, but may suggest a variety of approaches consistent with the ability of the operator to implement the Suggestions.

Jan 1, 1988

By Brenchley R

Partitioning behaviour studies for -particles in the 250 to 1,000 micron size range at. the Curragh coal preparation plant are presented. Plant surveys were conducted to compare the partitioning efficiencies of dense medium cyclones and froth flotation. The aim was to assess the potential for improving yield of coal by directing more of the top size of flotation feed material to dense medium cyclones. ovel mass balancing and model fitting NI procedures were used. While flotation offers high yield of low ash particles smaller than 500 microns, dense medium cyclone rejection .of high ash particles larger than 250 microns is superior. These strengths of the two processes are turned to good advantage by the use or desliming sieve bends which tend to perform some density separation on the'size fractions of interest, directing lower ash material to froth flotation than to the dense medium cyclones.

Jan 1, 1987

Carbonation of reinforced concrete is a potential durability issue for vehicular tunnels. This is particularly the case where elevated carbon dioxide concentrations exist and when the design life is 100 years or more. The process of carbonation can result in loss of passive protection to embedded steel reinforcement and initiation of corrosion. Therefore, tunnel design needs to consider the potential for carbonation on internal surfaces and how design life can be achieved in severe environments. This paper examines methods for predicting carbonation and how deterioration can be mitigated through appropriate concrete mix design and construction practices.

Jan 1, 2008

By S M. Mousavi

The issue of estimating evaporation in soils is central to the design of engineered soil caps for mine waste and landfill applications. In general, because evaporation from the soil is difficult to measure in the field, laboratory experiments and empirical methods have been used. Much of the earlier work has been conducted in soil science, although in recent years, geotechnical and geoenvironmental engineers have given great deal effort to this work. The result of this increased interest is the development of numerical models, such as UNSATH and SoilCover for estimating evaporation. In this study laboratory-measured evaporation from soil columns was compared with evaporation predicted using the computer program SoilCover, and the analytical method proposed by Gardner and Hillel. Good agreement among the results was observed. Also the sensitivity of the predicted evaporation to soil hydraulic and geotechnical properties, such as saturated hydraulic conductivity and coefficient of volume change was discussed and the practical implication of the sensitivity were highlighted. The work has application in the design and construction of soil covers over sulfide-bearing mine waste and landfills.

Jan 1, 2003

By Bilbrey J. H

Land utitized duxting the past 45 yeans by the mining industty in the United States con all puxpos ez to tal4 neatly 4 million sexes. Ob this axes, 13 pexeent is used bon dL4posal ob bLne -sized mtinexal wastes dL4eaxded by one milling plants. These wastes, especi- ally the inactive taLeLng4 ponds, xequixe some type ob stabULzation to pxevent aix and watex pollution. Because these tailings ponds axe locat- ed undex wideey vaxyting etLmctLe conditions and thetix physical and chemi- cal ehaxactexti5tLes axe not constant, many methods have been developed by the Fedexal Buxeau ob Mines and oXhex inve4- ttigatoxs box 4tabLtLzLng taLtLngs. This papex detfnea.e4 the magnitude ob the pxoblemz associated with the xeelametLon ob milling plant wastes and discusses the vaxtious methods that have been developed and used. Data bxom selected Buxeau o4 Mines taboxato&y xeseaxch pxojects and a s.abAJLzetLon field txtial axe pxesen.ed.

Jan 1, 1976

By Schmidt LC

The method of supporting excavated roofs in underground coal mines by conventional roof bolting systems is challenged due to its shortcomings of being time-consuming and leading to possible unsafe installation. Though a few alternatives have been considered, the ultimate and most efficient bolting method has often been conceived as one using a self-drilling roof bolt, or a Rapid Face Bolting System (RFBS). The on-going Rapid Face Bolting Project undertaken by the University of Wollongong includes a special tubular bolt design.The tubular bolt designed for the RFBS is a "single-pass" bolt equipped with cutting tips used to drill a bolthole to accommodate the bolt. Different from that of the coring bit employed in geological site investigations, the principal design consideration for the tubular bolt is low cost associated with a small working life for the cutting tip.

Jan 1, 1991

The Geological Survey of the U.S. Department of the Interior is primarily a domestic agency whose responsibility is furnishing impartial data and analyses to the public, private, and academic sectors of the Nation. The Survey concentrates on earth-science issues, such as mapping the land surface, determining the quality and quantity of water resources, estimating the nation's endowment of fuel and nonfuel minerals, and predicting and mitigating geologic hazards, such as those inherent in the tectonically active Pacific Rim. One of the challenges to managing this program is striking a sustainable balance between concentrating on the problems society wants solved today and investing in the research that seeds our vitality for the future. The Geological Survey's role in the Pacific results from the Nation's geography and the Nation's long standing interest in and commitment to the region. The longest segment of the U.S. coastline borders the Pacific Ocean, one of our states is a Mid-Pacific island chain, our lands are 80 degrees--nearly one-fourth--of the Pacific perimeter, and our Exclusive Economic Zone (EEZ) underlies significant parts of the eastern, northern, and central Pacific waters. Thus, the program of marine and terrestrial science operating in these areas make substantial contributions to the world's growing understanding of the Pacific realm.

Jan 1, 1990

By J de Vries

Arthur Page, a past President of AT&T said:All businesses in a democratic society begin with public permission, and exist by public approval. Product stewardship in its most basic form is simply risk management applied to the products we produce. Conceptually it may be considered as a more expansive approach to many existing safety, heath and environmental programs. Key differences include the extension of responsibility beyond the direct control of management, and consideration of the implications your products and processes have on the broader community, as opposed to the confines of an individual mine site or operation. This paper reviews the processes used by Orica Ltd to manage its product stewardship program. OricaÆs product stewardship program is expansive and supports activities and business that range from manufacture and delivery of commercial explosives and sodium cyanide to mines throughout the world, supply and operation of municipal water facilities, and manufacture and distribution of consumer products such as household paints and adhesives. We highlight the development of the program through experience both good and bad, and by use of case studies to illustrate how an active product stewardship program is an effective business risk mitigation strategy.

Jan 1, 2006

In the Ora Banda area of the Eastern Gold- fields, the ultramafic rocks tend to be more deeply lateritized than most of the surrounding rock types, and lateritic nickel concentrations have been formed. Extensive drilling_has shown that, of the two intermixed suites be- neath the laterite - an extrusive peridotite- pyroxenite suite and an intrusive, highly magnetic dunite - the latter weathers to a more nickel enriched laterite. The top horizon I of the laterite consists of ferricrete. Horizon II consists mainly of bands of secondary silica in a clay matrix, formed in the reworking zone around the water table and stranded as the weathering profile migrated downwards. Horizon III ('ºaprolite") is composed of serpentinite, magnesite, iron oxides and silica, and grades dowil to the fresh bock composed variously of olivine, ser- pentine, talc, amphibole-chlorite and iron oxides. The main locus of nickel deposition is the zone containing the bottom of horizon II and the top of horizon III. The water table is also at this general level. .

Jan 1, 1973

By Liu H, Chen S

Natroalunite is one of colouring minerals in kaolin. In this investigation, natroalunite, on which Ca(II) was adsorbed, was flocculated by HPAM and kaolin was depressed in suspension. The adsorption of Ca(II) on the natroalunite surface was studied by zeta-potential measurement and Auger Electron Spectroscopy analysis. Ca(II) was adsorbed more on the natroalunite surface than on the kaolin surface. The mechanism of Ca(II) adsorption was considered to be chemical adsorption on natroalunite and to be physical adsorption on kaolin. It has been found that Na6P6O18 and Na2Si04 can strongly affect Ca(II) adsorption on the surface of kaolin, but weakly on the surface of natroalunite. The effects of degree of hydrolysis and the molecular weight of HPAM, the effect of pH and the effect of Ca(II) have been studied. The kaolin ore, containing SO3 1.05 per cent has been processed with this method. The products only containing S03 0.36 per cent and the weight ratio of concentrate 52.27 per cent were Obtained.

Jan 1, 1993

By Peres EC

The flotability of monazite, zircon and rutile in the presence of sodium oleate, potassium octyl hydroxamate and a commercial hydroxamate was investigated through microflotation tests in a modified Hallimond tube. Zeta potential determinations in the absence/presence of collectors were performed in a microelectrophoretical cell. The microflotation testwork showed that, in general, the flotability characteristics of all three minerals are very similar. Commercial hydroxamate is, by far, a stronger collector than the pure potassium octyl hydroxamate. Electrokinetic studies indicated that the adsorption of collectors shifts the isoelectric point (IEP) of the minerals towards lower pH values. These collectors also are capable of changing the zeta potential values to more negative figures in the pH region above the isoelectric point. An increase of the conditioning temperature, generally, enhances the floatability of the three minerals. A depressant is required in order that selective flotation is feasible in the system monazite-zircon-ruffle. Sodium metasilicate is an efficient depressant for zircon and rutile and affects only slightly the flotability of Monazite.

Jan 1, 1993

By J A. Brown

Osborne Mine commenced hydraulic filling of three stopes in April 1999. Two of these stopes experienced barricade failures in July 1999 and January 2000. As a result, a review of hydraulic filling was commissioned in April 2000. The design of a trial of revised specifications and practices is in the final stages, prior to the trial commencing in mid-2002.

Jan 1, 2002

By A Quigley

The Northside Storage Tunnel Project in Sydney includes over 20 km of TBM driven tunnels, over 3 km of declines and major caverns and pump rooms. The paper describes methods used for design on the project. Emphasis is given to the refinement of the use of empirical rock mass classifications, and to the use of discontinuum numerical methods.The use of empirical rock mass classifications in Sydney sandstone has usually led to conservative design because the systems are based on a random orientation of joints in the rockmass. Because the joint sets are usually oriented in a way that is beneficial for tunnelling, limits must be placed on the parameters used in the classifications system. The paper discusses these limits and the derivation of the parameters.The use of numerical methods in Sydney sandstone is discussed. Continuum methods have their uses, but discontinuum methods are preferred. The use of UDEC has been validated against a previous project, the New Southern Railway. Recommendations are given for UDEC models.

Jan 1, 1999

By R Nakia, R Livingstone

Historically the Goldfields of Victoria produced large volumes of gold. Interest in these historical Goldfields has grown over recent years with a view to restarting production of gold. A notable example of this is the Bendigo Goldfield. There is also interest in the Ballarat Goldfield and Ballarat Goldfields Ballarat East Project is a particular example of this. The aim of this paper is to describe the ventilation aspects of the potential Ballarat East project. The mine is proposed as a decline access. The paper gives an overview of the project and in particular the ventilation planning associated with a number of possible equipment scenarios. The paper also analyses the main ventilation pollutants that are likely within the proposed mine as it develops to increasing depth. An attempt is also made to determine the depth at which mine climate will become the dominant pollutant rather than diesel exhaust pollutants.

Jan 1, 2003

By Collins AR, Meares RMD, Graham JM

Exploration programs for both alluvial (placer) and hardrock platinum group metal deposits are being conducted in Papua New Guinea by a joint venture between Degussa AG and Pancontinental Mining Limited. Prospective areas were defined on the basis of ultramafic/ophiolitic source rocks shedding detrital platinoid grains. Field sampling techniques including churn drilling, together with appropriate laboratory analytical and mineralogical techniques, were developed and are contributing to the success of the exploration programs.

Jan 1, 1987

Reserves of high-grade quartz gravel, lignite, and timber suitable for the production of silicon metal and ferrosilicon on large scale occur within 40 miles of Bluff Harbour. Undeveloped hydroelectric power resources on the Clutha River are located within 50 miles of the most promising quartz gravel deposits while opencastable lignite, potentially suitable for electric power production, occurs in the same locality as the quartz gravels. A preliminary study of production economics indicates that the commercial feasibility of silicon/ferrosilicon production would depend mainly on the cost of electric power, total capital cost of plant, and the market value of the products. The proximity of Bluff Harbour is advantageous for the export of products.

Jan 1, 1971

This paper describes the characteristics of blasting which set it apart from other methods of breaking rock. The mechanism of rock breakage and the influence of rock proper- ties are then discussed. The strain and fragmentation produced by a cylindrical charge does not change once the charge is longer than 16 blasthole diameters. The influence of bench geometry, charge length and drill diameter are then examined. It is shown that spherical charges have advantages over long slender cylindrical charges. By selection of the appropriate drill diameter, explosive and charge configuration the optimum blasting practice for a given rock to give suitable fragmentation and muckpile profile for sub- sequent handling can be found. The fragmentat- ion depends not only on rock and explosive properties but also on the pattern which dictates how effectively the cracking is utilised. The size distribution of the fragments is given by the Rosin - Rammler equation. Undesirable cracking of the rock in the final wall can be controlled by the careful design of blasts as they approach the final wall. Finally, it is concluded that because of the distance to which blasting can fracture and then displace rock it is suited for the breakage of large volumes of rock.

Jan 1, 1978

By Ryan CG, Ramsden AR, Sie SH, French DH, Griffin WL

Proton microprobe and electron microprobe analysis are being used in combination for in situ determination of the trace element contents of oxide, sulphide and silicate minerals in a sample of the Merensky Reef. Initial results indicate that chromites contain only Ni, Zn, Ga, Zr ar d Nb. Platinum-group elements, if present, are at concentrations less than 2 to 6ppm. Ru, Rh and Pd are the only platinum group elements to be consistently detected in the sulphides. PentLindite is the most important host for these elements with the concentration of these elements being dependant upon the mineral association in which it occurs

Jan 1, 1989

By C Deacon

It is common practice to include microspheres or similar density reducing agents in inherently insensitive water-based commercial explosives to achieve detonative sensitivity in the absence of chemical sensitisation. It has recently become possible to similarly include microspheres in LDAN (low density ammonium nitrate). Further to previous studies and publications to determine the benefits resulting from the use of microsphere enhanced LDAN technology in blasting, additional advantages are described in this document. These include range tests at independent testing facilities (Universal Tech Corporation û USA) which reflect results observed in the field, and support theoretical assumptions made when the products were introduced. Additionally, on-site studies in opencast pits using Heavy-ANFO blends incorporating modified LDAN, show that monetary savings can be realised through significant advantages gained in plant throughput and explosives use.

Jan 1, 1999