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By K. Adham

Both the dry and the wet fluorination systems require hydrogen fluoride (HF) for the process of uranium conversion to uranium hexafluoride (UF6). The dry methods depend on the electrolysis of HF to generate the fluorine (F2) required for the high temperature pyro-fluorination. The wet methods require aqueous HF in water solutions for the low temperature hydro-fluorination (Argonne, 2019). This paper uses the available HF safety guidelines and industry information to discuss the issues of transportation, storage and utilization. Health effects and environmental considerations are reviewed. Safe practices for handling the HF (both as anhydrous and as aqueous) are considered. Proper selection of different materials of construction are discussed, for both the anhydrous and the aqueous HF.

Jan 1, 2020

By François Robert, Steve Green, Tyson Birkett, Dan Richardson

Abstract -Detailed sampling using a portable diamond drill, and interlaboratory comparison of selected samples have been combined with statistical studies of truncated populations to establish the gold content of several outcrops in the Val d'Or area. The outcrops chosen are non-mineralized. The background gold concentration in the rocks of the region is 5 ppb or Jess. Gold is distributed relatively homogeneously within the outcrops studied except for slightly increased concentrations within quartz-tourmaline veinlets. Three samples, of which 20 grams of powder are analyzed for each, can adequately determine the gold concentration of a structurally simple outcrop in the Val d'Or area.

Jan 1, 1992

By Ajit K. Sinha

"Abstract - Electromagnetic surveys were conducted over the Yava sandstone-hosted lead deposit in Nova Scotia to evaluate the usefulness of such surveys for detecting and mapping sedimentary­ hosted metallic ore deposits. Both transient and multifrequency systems were used for that purpose. The deposit consists of three zones of disseminated galena which also contain minor amounts of pyrite and sphalerite filling the interstices of the sandstone grains. Each zone overlies a basement depression and is separated from the adjacent zone by an intervening basement high. A conductive shale layer underlies the galena-rich sandstone formation at all three zones.Because the concentration of galena (3% to 4% ) and other sulfides is too low to affect the resistivity of the sandstone formations for detection by ground electromagnetic (EM) methods, the strategy for our survey was to look for areas of basement depressions and the presence of conductive shale in those depressions by EM depth soundings. The presence of the galena-rich sandstone formations could be inferred because of the close association of these two features with the deposits in the Yava area. Both transient and multifrequency EM systems were successful in mapping the basement depressions and detecting conductive shale at the three known mineralized zones. The technique, therefore, seems to offer good prospects for mapping similar stratabound sedimentary-hosted sulfide deposits."

Jan 1, 1993

By G. J. Birnie

Introduction The preparation of the following paper has been undertaken in the belief that a description of the development methods and equipment used at Lake Shore, at the present time, will prove of general ? interest. Working depths of nearly a mile and a half in shaft sinking and of more than one mile for stoping operations have imposed problems not encountered at shallower horizons. Among the problems contributing to the difficulty of mining at extreme depths might be mentioned: Rock pressures Ventilation Hoisting Shorter work period at the face Geological considerations In the main, the effects of these factors add to the difficulty of mining at depth, but it is not entirely true to say that each must necessarily become more pronounced as mining operations proceed to greater depths. Corrective measures may, in some cases, retard the effect and in others may even relieve some of the difficulty. It is proposed here to discuss these features in the light of the experience at Lake Shore, and to present, in some detail, the current practice in shaft sinking and in driving ore and waste passes, raises, drifts and cross-cuts.

Jan 1, 1950

By A. Paulin, J. Roth, S. Spaic

This experiment was carried out to see whether copper-iron ingots from Late Bronze Age hoards could have been produced by smelting ferruginous copper ores. Since ferruginous copper-ores are chalcopyritic, chalcopyritic concentrate from a present day copper mine was dead roasted in our experiment in lieu of a rich chalcopyritic ore. Charcoal was used as a reducing agent in the reduction of calcine (i.e., a product of dead-roasting), and quartz sand was used as a flux. Two separate metallic solutions, a copper-base and an iron-base alloy, were obtained as a result of two factors: the presence of carbon and the miscibility gap in the Cu-Fe-C system. The metallic melts appeared in a form of bigger or smaller droplets, enclosed by a molten slag which, during the cooling, solidified into metallic beads. The presence of both metals was noticed in the majority of the examined beads. It was therefore concluded that calcine consisted of an intimate mixture of oxides of both metals which were simultaneously reduced during the reduction process. Due to the miscibility gap in the Cu-Fe-C system, separate iron and copper regions were formed in the beads. In both regions, sulphide inclusions were found. The formed molten copper and molten iron solution were found to be saturated solutions. The metallographic analysis revealed the precipitation of iron out of copper and that of copper out of iron during the cooling and solidification of melts. The formed slag contained little iron and no copper oxide.

Jan 1, 2001

By J. Hendry, K. Brady, J. Yorzyk

Drawing from the experience of nickel, copper, aluminum and mineral borates, this paper illustrates the business value that the mining, minerals and metals industry as a whole can gain from applying life cycle assessment (LCA) to products and operations. Through the use of case studies, the paper explores how companies and industry associations have used LCA to their advantage: from evaluating capital investments, meeting customer information needs, supporting new product applications, and developing credible marketing information on the environmental performance of their products. It also explores the dynamics of LCA adoption and integration within companies, and provides recommendations to further strengthen institutionalization of LCA.

Jan 1, 2010

By J. Nesset, F. Rosenblum, P. Spira

"Sulphide concentrates may exhibit self-heating to various degrees during storage or shipping, the worst cases presenting a serious hazard from fire and SO2 emission. Based on measurements of heating rates on a wide variety of concentrate samples in a special apparatus, combined with field experience, a methodology has been developed which allows concentrates to be rated for their heating potential. This has proven to be very useful in practice, for example, in deciding on the need to take preventive measures. Oxidation under ambient conditions in the presence of moisture initiates heating locally within a stockpile. In the case of highly active materials, such as those that contain abundant pyrrhotite, heating may progress through three stages to temperatures well above 5000C. However, most concentrates show little or no propensity to selfheat. Heating rates were used to estimate values of the heat output, or self-heating capacity (in joules per gram), which sustains the process at each stage. Thermal data from differential scanning calorimetry are also reported. Variables which affect self-heating are discussed and an actual case of heating control on a stockpile by covering is described. A simple apparatus which can be used to simulate stockpiling conditions has been tested successfully and is proposed as a convenient test system.INTRODUCTIONPrevious publications from this laboratory on the evaluation of self-heating in sulphides dealt with tailings backfill (Rosenblum et al. 1982) and waste rock (Rosenblum and Spira 1995). Sulphide concentrates may likewise exhibit self-heating in storage or during shipping. In a comprehensive but dated review, Kirshenbaum (1 968) pointed out the conflicting nature of information on means of controlling the problem, particularly with regard to the application of water and ventilation. Modelling by Simpson (1 97 1) of autogenous heating in stockpiled zinclead concentrate and associated field measurements by Wright et al. (1972) showed that the supply of oxygen by wind and the shape of the piles were the major factors in the development of hot spots. Simpson did not attempt to explain the complex mechanism of self-heating, simply ascribing its onset to oxidation. Pearse (1 980) investigated a potential method of testing for selfheating which consisted of (i) reaction with hydrogen peroxide and (ii) differential thermal anal sis, to characterize the response of concentrates at both ambient and temperatures above 100 C. He found the method sensitive enough to identify the need for careful handling but not to predict ignition. He recommended compacting concentrates and covering stockpiles with plastic sheeting to prevent ingress of air. All these workers recognized the key role played by oxygen and moisture in triggering self-heating."

Jan 1, 2001

By K. G. Chipman

IN 1936, the Department of Mines and Resources was formed by the amalgamation of the former Departments of Mines, Interior, Indian Affairs, and Immigration. In the amalgamation, the Geological Survey and the Topographical Survey became the major divisions of the Bureau of Geology and Topography, which is a part of the Mines and Geology Branch which, in turn, is a part of the Department of Mines and Resources. The Topographical Survey was formed by combining the former Topographical Division of the Geological Survey and the air and ground mapping sections of the former Topographical and Air Survey Bureau of the Department of the Interior. The latter organization, previous to 1933, had been known as the Topographical Surveys Branch of the Department of the Interior. The amalgamation of 1936 definitely placed on the Topographical Survey the responsibility for the original mapping required for the development of our natural resources. The war has brought upon us the situation where all work has had to be in the furtherance of the war effort. With decreased staff and limited appropriations, the mapping on those scales which are directly concerned with the natural resources has been confined to the search for oil and strategic minerals. The reconstruction period will produce a different situation, with different problems. The past is behind us and it is necessary to prepare for the future. First, we should consider briefly a few general principles in the making and using of maps, then take stock of what we have, see what the needs are, and consider how we are to meet these needs.

Jan 1, 1944

By H. H. Bleakney

The merit of reduction-in-area as a criterion of quality in metals is shown to lie in its influence on breaking stress, but the virtue of elongation is not easy to find. In order to assess the value of elongation, either as a measure of quality or as a guide to design, it will be necessary to separate the overall de-formation occurring in tension tests from the localized deformation associated with localized reduction in area. The obstacles to a successful solution of this problem have been shown to be more formidable than is generally appreciated, and a new solution to the problem has been suggested. This solution involves a de-vice by which an electric circuit is broken when the particular value of strain is reached that is to be taken as the point of separation between general and localized deformation. The report presents results from a number of tests on both low-carbon and alloy steels. These results indicate that the selected criterion of separation is accurately identified by the proposed method; that it

Jan 1, 1962

By Zdenek D. Hora

British Columbia is an important producer of a variety of industrial minerals for both domestic and export markets. Some commodities such as limestone, dolomite, gypsum, calcium carbonate, silica, barite and magnetite are raw materials for well-established industries located in British Columbia, Alberta and northwestern USA. Others, like magnesite, sulphur, jade, asbestos, dimension stone and clay products, are mainly exported in processed form to overseas customers. Companies are developing markets for relatively new mineral products, including pumice, volcanic cinder and zeolites. A number of attractive geological targets have been identified by industry while research by government geologists has outlined the potential for refractory minerals, gemstones, garnet, nepheline syenite, carbonatites, residual kaolin, igneous apatite and peat.

Jan 1, 2001

By I. Farr, H. Wittens

"In 1989 and 1990 abnormally high levels of arsenic in ore from the Thompson Open Pit Mine threatened Manitoba Division's electro-nickel production. The paper will discuss our development of a flotation process to separate pentlandite and gersdorffite (the prime nickel and arsenic bearing minerals).The presentation will focus on the development of the process from conception, through lab and plant test work, to plant optimization and full scale production. The paper will conclude with the benefits and cost of the completed project.INTRODUCTIONRejection of arsenic from nickel sulphide ores was not a primary concern in the Manitoba Division until 1989. At that time increased production in the Thompson Open Pit mine, which contains high arsenic ore zones, resulted in excess amounts of arsenic in the Thompson Refinery affecting electro-nickel quality. This problem was resolved through extensive efforts by Mill personnel. The purpose of this paper is to familiarize the reader with- the Thompson Mill.- the mineralogy of the Thompson orebody.- the evolution of Ni/As separation in the Mill.- the metallurgical impacts of the separation on the Mill.- the importance of the separation to the Manitoba Division."

Jan 1, 1991

By K. Niboucha, M. Zergoug, S. Brick-Chaouch, H. Houali

"Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items:•,Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists;•,Range of protection (potential of protection along the pipeline);•,Influence of the isolation resistance of the coating on the range of protection;•,Effect of the aging of the coating and its influence on the current of protection."

Jan 1, 2005

By A. Dubé

Introduction It is common experience that on re-heating a fully martensitic steel below the Ac, point, a softer and tougher structure is formed as the tempering temperature is raised. The mechanism of tempering of plain carbon and low-alloy steels has been the subject of many investigations. In a very comprehensive study, Cohen and associates have recently established three different tempering stages, the last of which reaches completion at about 700°F., with heating rates of 5°F. per minute. This latter stage has been established ta be the carbide-forming stage, so that the steel consists of a mixture of ferrite and carbide, which are the metastable equilibrium phases. Any subsequent changes which take place at higher temperatures below the Ac, point in the absence of graphitization or carbide lattice conversion normally consist of agglomeration of the carbide particles. This naturally results in the softening of the steel. However, in many cases the Ac, point, as determined by dilatometry, thermal analysis, etc., only gives a rough estimate of the temperature where the reaction, ferrite plus carbides to austenite, is initiated. This appears to be especially true in the case of alloy steels in which three phases can co-exist in certain temperature ranges. Bain has given data on the three-phase equilibrium in both manganese and nickel steels. In these steels, the formation of austenite at temperatures just above the AeIL apparently involves the diffusion of the alloying elements to the first pools of austenite, thereby making the process very sluggish. As a consequence, the critical Ac points determined by ordinary methods at normal rates of heating can be quite distant from the true equilibrium Ae temperatures.

Jan 1, 1946

By G. H. Agnew

When water floods are initiated after gas-oil ratios have increased, the transition period from the start of injection until" the gas-oil ratios are returned to the solution gas-oil ratio may be important for either economic or technical reasons. The transition period is longest, and consequently most critical in water floods where injection is equal to withdrawals. This paper describes a theoretical basis for predicting the behavior of such a system and outlines a procedure for making the necessary calculations. The calculation procedure is illustrated for two actual cases: a line drive water flood and a five spot water flood. In each case there is a reasonable similarity between the actual and calculated performance.

Jan 1, 1960

By J. Lobel, M. Bourassa, J. A. Kozinski, B. Peng

Non-isothermal kinetics studies of the reduction phenomenon of electric arc furnace (EAF) dust generated in stainless steelmaking have been carried out. The dust was mixed with carbon as a reducing agent and dolomite as a binder to form pellets. A Thermo-Gravimetric Analyzer (TGA) was used to determine the weight loss of pellets heated at an average rate of 40 K/min. up to a temperature of 1500°C. The degree of metal reduction was calculated by considering the pellet weight loss, and evaporation of moisture, dust, zinc and lead at high temperature. The reduction process was divided into three different steps. The first covers the 300°C to 760°C temperature range (from 7 to 18 min.), the second step ranges between 760°C and 980°C (18 to 24 min.), and the third covers temperatures above 980°C. Each step is characterized by different chemical reactions. Non-isothermal reduction kinetics equations were set up to describe each step. The kinetics parameters such as apparent activation energies and frequency factors were established. It was found that the first step was chemically controlled, while the second step was diffusion-controlled. Reduction behaviour in the third step was strongly dependent on the initial carbon content in the pellet. Chromium oxide (CrO) could only be reduced in this last step. High temperatures and higher initial carbon content favoured the reduction of CrO.

Jan 1, 2001

By H. Houali

Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items: ? Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists; ? Range of protection (potential of protection along the pipeline); ? Influence of the isolation resistance of the coating on the range of protection; Effect of the aging of the coating and its influence on the current of protection

Jan 1, 2005

By S. Mathieu, R. Mennillod-Blondin, P. Cousin, N. Valle, H. Bouzahzah, P. Marion

The gold deposit of the Lapa mine has a complex mineralogical gold state with coarse and fine native gold, aurostibite and submicroscopic gold within arsenopyrite. A specific mineralogical characterization of the refractory fraction was conducted combining various techniques such as optical microscopy, electron microscopy, electron microprobe and secondary ion mass spectrometry. In parallel, the mineral processing behaviour and the recovery of the refractory gold were studied by pressure oxidation and cyanide leaching. This paper presents the mineralogical methodology developed to characterize the refractory gold distribution within arsenopyrite. These results are presented and interpreted in order to plot gold recovery versus sulphide oxidation. The comparison of the metallurgical behaviour yields predicted from the mineralogical data and the one calculated from leaching tests shows a good agreement and allows mineralogical explanations of the gold metallurgical behaviour.

Jan 1, 2011

By Ch. Enkhbold

Underground mining of minerals is becoming an increasingly complicated technological and ecological problem. It can be explained both by worsening of geological conditions of mining and by a specific character of mining industry, which, in contrast to processing branches of industry, intrudes into one of principal components of the nature ? the Earth's interior. At a traditional organization of mining industry, the entire volume of the produced rock mass is brought to the Earth's surface, where valuable components are extracted. This entails not only power over expenditure for long-distance transfer (especially in the vertical direction) of the waste rock forming a part of the original mineral, but also the formation of huge volumes of worked-out spaces. The latter leads (nature cannot stand emptiness!) to an irreversible development of geomechanical processes of shifting of overlying rock masses resulting in an irreparable damage of all surface structures located on the territory undermined by deep mining. Owing to their high productivity combined with low power consumption and instrumental compactness, novel bifunctional technological processes of minerals dressing successfully solve the problem of rock mass processing in underground conditions with subsequent operative disposal of final tailings of such underground dressing in the worked-out space. Besides, an integration of two processes into one is achieved, for example, a decrease in the rock mass coarseness with a simultaneous precise separation of valuable and waste components.

Aug 1, 2013

By Tyson Birketi, Françoi Robert, Steve Green, Dan Richardson

Detailed sampling using a portable diamond drill, and inter laboratory comparison of selected samples have been combined with statistical studies of truncated populations to establish the gold content of several outcrops in the Val d'Or area. The outcrops chosen are non-mineralized. The background gold concentration in the rocks of the region is 5 ppb or less. Gold is distributed relatively homogeneously within the outcrops studied except for slightly increased concentrations within quartz-tourmaline veinlets. Three samples, of which 20 grams of powder are analyzed for each, can adequately determine the gold concentration of a structurally simple outcrop in the Val d'Or area.

Jan 1, 1992

By H. A. Gorrell, S. R. L. Harding

"The potash beds in the Saskatchewan portion of the Williston Basin occur in the upper portion of the Prairie Evaporite formation of the Devonian Elk Point Group. They represent the late stage of a major evaporitic cycle. Two other evaporitic cycles are known in overlying beds, but these apparently never reached the stage of potash salt deposition. The basin in which salt deposition took place extended from the northwestern corner of Alberta southeastward across Saskatchewan into Manitoba, North Dakota and Montana. Deposition of potash salts was apparently restricted to the southeastern portion of the evaporite basin. On a regional basis, five major stratigraphie divisions of the potash-bearing strata have been made. Locally, several of these units may be divided into correlatable sub-units. The potash-bearing strata are separated and overlain by predominantly halite layers of varying thickness. Cross sections show the regional correlation of the potash-rich zones, and maps show the present distribution of the individual potash-bearing zones and the areas of richer development for each zone. The maps tend to substantiate the interpretation of considerable subsurface solution of salt and potash beds."

Jan 1, 1967