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By Da-Qiang Cang, Qingde Wang, Wei Wang, Wen-Bin Dai, Min Guo, Yu Li

Utilization of both slag and its heat for hot slag is a great challenge for iron and steel industry. Many methods of hot slag modification for directly converting hot slag into value-added materials were researched in recent years, and waste heat of hot slag could thereby be transformed into inner energy or chemical energy of the materials. In this paper, an experiment of converting hot slag directly into glass ceramics by hot slag modification method was conducted. A cooled modifiers mainly composed of fly ash were firstly heated though a cyclone furnace and then fell into a molten bath to mix with hot steel slag. Half of hot slag was used as raw materials and accordingly about half energy consumption, about 5MJ/kg for melting raw materials was saved in the process compared with that of traditional producing method. Frit quenched from the modified hot slag had a higher basicity of 0.6-0.7 than traditional frits in order to reduce the needed amount of cold modifiers and accordingly utilize more hot slag and its waste heat. Glass ceramics were further prepared from the frit and a heat treatment of one-stage method is more suiter to such frit than that of two-stage method. The glass-ceramics with basicity of 0.6 and heat-treated by one stage method had the best performance with bending strength of 146.46 MPa, Vickers hardness of 6.79 GPa, water absorption rate of below 2% and shrinkage rate of around 10%.

Jan 1, 2015

By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015

By X. Shi

Magnesium, the lightest structural metal, has not yet been considered as a serious contestant for automotive use due to its weaknesses in corrosion. Electroless nickel-boron alloys are well known for their corrosion resistance and hardness. An electroless nickel-boron layer was successfully deposited first on the chemical conversion pre-treated AZ31 alloy and also on the Ni-P coating which was deposited on the conversion coating. The electroless bath contained nickel sulphate and dimethylamine borane (DMAB) as main salts and the samples were activated by a 5 g/L AgNO3 solution before the electroless plating process. The presence of the conversion coating between the nickel coating and the AZ31 substrate acted as a barrier and prevented corrosion of the alloy. The morphology of the nickel-boron layer was studied using SEM. The crystal structure and the composition were examined by EDS and the hardness was measured. The corrosion behaviour of the nickel-boron layer deposited on the conversion coating and on the Ni-P coating was studied using potentiodynamic polarization in a 0.5M NaC1 solution. A saturated standard calomel electrode was used as a reference electrode. The results show that the nickel-boron coatings had a significantly better corrosion resistance than the AZ31.

Jan 1, 2006

By R P. Douglas

During 1955, Cominco commenced an exploration pro-gram in northern New Brunswick; in the following year, what is now the Wedge mine was discovered. The mineralization is mainly pyrite, with associated chalcopyrite and minor amounts of sphalerite and galena. The property was brought into production at 750 tons per day in early 1962. The ore is trucked 10 miles to the Heath Steele concentrator, where a copper concentrate grading about 19.5 per cent is produced and shipped to the Japanese markets through the port of Dalhousie, New Brunswick. Introduction THE Wedge mine, owned by The Consolidated Mining and Smelting Company of Canada Limited (Cominco), is located in the Newcastle-Bathurst area of New Brunswick. It is 42 miles by road northwest of Newcastle and 37 miles southwest of Bathurst (Figure 1). The mine is located on the north side of the Nipisiquit river in one of the more mountainous areas of the Province, the local relief rising to 1,500 feet above sea level. There is an almost complete forest cover of mixed hardwoods and conifers -the val-leys and hillsides being covered by balsam, spruce and pine, the swamps by cedars and black spruce and the highlands by mixed hardwoods.

Jan 1, 1965

By G. Zárate, G. Tapia

Anglo American Chile has been doing copper concentrate leaching studies at the laboratory and small pilot plant scale since 1992. Among the processes evaluated are bacterial leaching and pressure leaching using Mantos Blancos, Salobo Project and Quellaveco Project concentrates. Late in the nineties, it was decided to focus the research on pressure leaching, either medium or total pressure oxidation. Preliminary scouting tests were run with Mantos Blancos concentrate samples during 2000, which were repeated during 2003 together with samples of Los Bronces and El Soldado concentrates, in order to define the most suitable concentrate for running a pilot plant campaign at AARL, which was carried out in two campaigns, a first one from November 2003 through January 2004 and a second one during April 2004. Mantos Blancos was the selected concentrate and the laboratory and pilot plant results are discussed in this paper together with some preliminary economic estimates.

Jan 1, 2004

By E. B. Wright

THE property of Falconbridge Nickel Mines, Limited, is in Falconbridge township, approximately thirteen miles northwest of Sudbury. From the mine and townsite, a gravel road leads to Sudbury and a branch line of the Canadian National railway to Sudbury Junction. The ore deposit is at the southeastern corner of the 'Sudbury Basin'. It lies in a sheet-like mass, striking in an east-west direction, between norite to the north and greenstone to the south. The general attitude of the ore-body is vertical, but with frequent variations in dip of as much as 10° to the north or south. The deposit is very irregular in outline, the width varying from a few feet to eighty or ninety feet. In the vertical plane, rolls are frequently encountered. Gouge is very often present at one or both ore contacts. The norite to the north shows much jointing. The chief ore minerals are pyrrhotite, pentlandite, and chalcopyrite. The nickel content of the ore is usually double the copper content, average assays ranging from 2 to 2.5 per cent nickel and 1 to 1.5 per cent copper. The ore is of three main types: massive, breccia, and disseminated. The breccia ore, the most common type, consists of sulphides containing rounded inclusions of highly-altered country rock, which, in places, are so large that sorting is necessary in the stopes. In the norite, the breccia ore may grade into disseminated sulphides, which frequently are sufficiently concentrated for profitable mining. In places in the breccia ore, concentrations of solid sulphide masses occur. Until early in 1935, all mining at Falconbridge was by shrinkage scoping, but this method was found to be less and less suitable as greater depth was attained. When mining had reached the 1,000-foot level, ore drawn from large shrinkage stopes was found to have been diluted as much as fifty per cent by sloughing of the wall-rocks, caused by increased rock pressure and insufficient support. It was apparent that this method of stoping was un-suitable and -Mr. E. J. Martin was engaged to superintend the introduction of a method of cut-and-fill stoping.

Jan 1, 1938

By A. Brown

"The first printed report on Canada's coal resources was published in Paris in 1672(1. Written by Nicholas Denys, then Governor for France of Isle Royale (Cape Breton Island), the report dealt exclusively with the coal of the Atlantic region because little or nothing was known about the interior of North America. Clearly, also, he wrote about a resource of which much was known among the military and early settlers of that day. This early knowledge is not surprising because the presence of coal is clearly displayed in the coastal cliffs of Cape Breton as it was also, at a later date, to the first arrivals on Vancouver Island.An example of early use was that of the French garrison at Fort Louisburg in the first half of the 1700s. Still earlier, in 1643, Governor Winthrop of New England reported the receipt of a small ship load of coal from New Brunswick (2). Despite this early knowledge there was no significant development of coal mines until the 1800s. This had to await the ending of wars between the French and British factions and the growth of population. Basically, also, its development awaited the beginning of the Industrial Age. Organized coal mining began in Canada in 1825 with the formation of the General Mining Association. This British firm was the creation of a group of London jewellers which had been granted royal rights, by the British crown, to all minerals in Acadia (substantially the present Maritime Provinces). The Association took over a number of existing small mines and opened up larger operations in the Sydney coal field. Subsequently, it expanded to the mainland Nova Scotia fields at Stellarton and Springhill. The Association continued in existence as the major coal producer in Canada until 1899 when it sold its properties to the Nova Scotia Steel and Coal Company, Limited (3). This Montreal-based firm managed the coal mines as a major Canadian producer of coal until 1968 when financial problems led to the expropriation of the mines by the Government of Canada. The federal government established the Cape Breton Development Corporation to operate the larger mines on Cape Breton Island. This Crown corporation continues to be a .major producer of coal in Canada."

Jan 1, 1985

By C. Fortin

The subject of gold flotation has been reviewed extensively in a number of publications. The focus in most of these reviews has been on the theories of gold flotation as well as the physical and chemical effects that may impact the efficacy of the gold flotation process. It is evident that the current status of gold flotation chemistry as it is being applied in industry has not been addressed widely. It is the intent of this paper to review current gold flotation practice and how these applications tie in with the current understanding of the chemistry of gold flotation.

Jan 1, 2011

By C. R. Julian

MECHANIZATION During the last fifteen years, numerous attempts have been made to mechanize the operations of loading ore and placing till. It is to be regretted that, to date, little progress has been made in this direction. The comparative efficiency of manual labour in Spain is the factor largely responsible for the failure to cheapen costs by mechanization. The necessity for careful classification of the ore and the need for keeping all openings small also makes the problem one of difficulty. It may be of interest to describe the various attempts at mechanization that have so far been made. CONVEYORS: (1) When stoping by layout III in San Dionisio, a trial was made of transporting the filling by jigging conveyors. This method proved un-economical, as the wall building and spreading of the till could not keep pace with the delivery, with the result that the machinery was idle a great part of the shift. (2) The transport of ore from the working places to the ore-passes by jigging conveyors and belts was also tried. Although more successful than in the case of the fill, the method could not compete with that of hand tramming, principally due to the high cost of (a) maintenance caused by the abrasiveness of pyrites, and (b) labour constantly employed on re-aligning the conveyors owing to the constant settlement of the floor. In a few cases, where a sill floor was being blocked out in virgin ground, the method showed a saving. SCRAPERS: Frequent attempts at loading by scrapers have been made, but again the only success obtained has been in the blocking-out of sill floors. The principal obstacle to the successful application of scraping, other than on the sill floor, has been that the openings, which have to be small, call for a light scraper outfit, whereas, in practice, a heavy scraper and at least a 25 h.p. winch are necessary for handling satisfactorily the ore, which is heavy and which breaks somewhat blockily.

Jan 1, 1940

By Hyung Sup Choi

The preparation of high-purity zirconyl compounds was studied in order to develop an economical process for obtaining pure zirconium via the caustic fritting of zircon sand. The direct dissolution of caustic frits with concentrated hydrochloric or nitric acid at 80c. followed by the addition of a small amount of acidified gelatin, gave high-purity zirconyl chloride or nitrate. The addition of a small amount of gelatin caused a mutual flocculation between colloidal silica and gelatin. The precipitation of this silica floc markedly lowered the content of silica in the product. The silica content of the compounds (or solution) so produced, generally less than 100 ppm., was sufficiently low for tributyl phosphate extraction for nitrate solutions. It was found that the degree of purification de-pends not only on the procedures employed but also on the nature of the frit itself. Silica was more effectively eliminated from the fritted product produced at higher temperatures, and less silica was present in the com-pound prepared from the frit produced in a shorter heating time. In order to ascertain the nature of the

Jan 1, 1965

By Michael W. Hinds

X-ray Fluorescence Spectrometry (XRF) is used at various stages of gold refining. Initially, incoming impure gold is analysed for deleterious elements such as As, Cd, Hg, Se, and Te. Based on the levels of these impurities the material can be returned to the client or accepted for refining. XRF is also used to determine the metal concentrations after the impure gold has been melted and sampled. This information is used to assist the final Fire Assay determination of gold and silver. An energy dispersive XRF is used to determine the end point of chlorination refining step.

Jan 1, 2011

By E. Ghali, W. Zhang, G. Gabra, N. Sorour, G. Houlachi

The additives polyacrylamide, 1-Butyl-3-methylimidazolium chloride, Tetra-butylammonium bromide, Benzalkonium chloride and chitin are evaluated during zinc electrolysis from synthetic acidic sulphate electrolyte containing Mn2+ ions, in absence and in presence of 0.0055 mg dm-3 of Sb3+ ions. Galvanostatic polarization tests for 2 hours at 50 mA cm-2 and 38oC were carried out to determine the cathodic and anodic potentials, and current efficiency of the deposited zinc. Potentiodynamic polarization and cyclic voltammetry tests have also been employed to study the electrochemical behavior of each additive on the zinc deposit on aluminum electrode. Results showed that, in presence of Sb3+, adding 1 to 3 mg of 1-Butyl-3-methylimidazolium chloride increases the cell voltage by ˜0-7 mV. Current efficiency is increased by ˜4.90-6.40%; power consumption is reduced by ˜147-173 kWh t-1 by adding 1-3 mg, respectively. However, in absence of Sb3+, cell voltage is decreased by ˜7-28 mV, current efficiency is increased by ˜0.70-1.50%; power consumption is reduced by ˜41-47 kWh t-1 by adding 1-3 mg. The effect of the other additives on cell voltage, current efficiency, lead content and morphology of zinc deposit has also been examined. Surface morphology and crystallographic orientation of the deposit was studied using scanning electron microscopic (SEM) and X-ray diffraction (XRD), respectively. The content of lead in the deposit has also been measured using inductively coupled plasma spectroscopy (ICP).

Jan 1, 2015

By L. Gutierrez, M. Pawlik

The rheology artificial mixtures of bitumen with fine quartz of varying bitumen content, as well as actual oil sand ores, was investigated under different physicochemical conditions (pH, temperature). All rheological measurements were conducted using a Haake Rotovisco VT550 rotational viscometer, connected to a fixture specifically designed to measure properties of settling suspensions. It was found that at low bitumen contents (1 %, wt.) the pH of the slurries was the most important parameter that controlled the rheology of quartz-bitumen slurries. At higher bitumen contents (10%, wt.), it was a combination of high temperature and high pH that gave the lowest apparent viscosities and yield stresses of the model mixtures. These model observations correlated well with the rheology data obtained for slurries of actual oil sand ores. The overall results were discussed in terms of aggregation-dispersion phenomena between bitumen and mineral particles.

Jan 1, 2009

By Descarreaux. Jean

"The Abitibi volcanic belt was sampled along a cross section extending from Matagami to a point east of Rouyn. A few samples were also collected in Louvicourt township, Quebec. The major elements were determined for 344 samples, and rock names were defined using normative minerals. The analytical data were studied by means of variation diagrams. The Abitibi volcanic belt is characterized by rocks belonging to both the tholeiitic and calc-alkaline magmatic series, but they show some differences as compared to some typical reference series, particularly those from Japan. Basalt is the predominant rock type and accounts for 44 per cent of the sampled outcrops. The volcanic rocks are relatively poor in K2O and TiO2. Regionally, the volcanogenic copper-zinc mineralization is associated with the calc-alkaline volcanic sequences. Locally, within such sequences, some types of abnormal deviations from the averages are recognized only in association with the copper-zinc mineralization. The anomalies are ascribed to hydrothermal alteration consisting of the introduction of MgO and removal of N a20; enrichment in K20 is also observed where zinc mineralization predominates. Examples of such anomalous zones show that, in places, this alteration phenomenon can be quite extensive. Petrochemical characteristics can be used as geochemical ore guides in exploration programs."

Jan 1, 1973

By J. D. Wright

This paper describes current milling practice at Endako Mines Ltd., a molybdenum producer in central British Columbia. The various steps in the crushing, grinding and flotation of the ore are outlined, with emphasis on the metallurgy of the latter operation. Tailings disposal and concentrate assaying methods are also described.

Jan 1, 1969

By C. Gravel, A. Fathi, P. Rivard, G. Ballivy, Z. Moradian, M. Quirion

Knowing shear mechanism of discontinuities under monotonic and cyclic loading conditions is a key factor in stability analysis of rock slopes and rock foundations. In this paper, the effect of cyclic loads on the shear mechanism of joint asperities is described. For this purpose, a fresh tension-split joint from a granite block was used as a reference and thirty five mortar replicas were fabricated. Cyclic shear tests were conducted on replicas under low values of constant normal load (CNL) using a servo-controlled loading system. Tests were performed in two consecutive steps; load-controlled and then displacementcontrolled. In the load controlled part, after initial increase of shear stress to 0.25 MPa, the test was stopped for 2 minutes, then increased to 0.5 MPa, and finally decreased to 0.25 MPa. This process was repeated ten times. At the end, the test was continued up to 10 mm shear displacement under displacement-controlled loading in order to pass the peak shear strength and reach the residual strength. Characterizing joint surface and modeling of involved asperities during the tests was undertaken using a Matlab code developed with new mathematical expressions. The algorithm used in the code is based on three-dimensional coordinates of the scanned joints’ surfaces before and after the test. It was found that a high percentage of degradation happens during the first cycle of loading and during the other cycles, degradation occurs gradually. While comparing tests conducted in monotonic and cyclic loading conditions, it was observed that under low number of cycles, the pronounced mechanism is consolidation of the joint surfaces. This consolidation increases contact areas and, therefore, shear strength parameters.

Jan 1, 2015

By E. J. Marcotte

"INCO LIMITED'S Shebandowan Mine and Mill is located in a scenic tourist and cottage area near the western tip of Lower Shebandowan Lake, approximately 90 Km west of Thunder Bay, Ontario. This nicely designed complex is a positive indication that mining operations can co-exist in harmony within the natural environment.The Shebandowan complex processed nickel-copper ore from 1973 to 1985, inclusive, after which operations were shut down.In late 1988, INCO LIMITED decided to place the Shebandowan complex back into operation, under contract, to mine and mill the remainder of the ore body, according to their specifications. MaclSAAC'S EXPLORATIONS was the successful bidder for the project. Following preliminary rehabilitation, operations were re-activated in late March, 1989. The ore mined to date is of a moderately lower nickel grade than the majority of previous years. However, a higher tonnage rate, combined with improved nickel recoveries, has contributed to a viable operation.A series of mill operating and equipment modifications has enabled MaclSAAC EXPLORATIONS to achieve the quality and grade of nickel-copper concentrates specified, and at the same time, expand mill tonnage throughput while attaining increased nickel recovenes."

Jan 1, 1992

By Grant D. Nicholas

This paper compares an integrated evaluation approach to decision-making with more traditional sensitivity analysis and Monte Carlo simulation. The primary objective is to highlight the differences in NPV that can arise from using these evaluation methods in a top down and bottom-up approach. Results from three resource scenarios, derived from sampling a "virtual" ore body (reality) on grid spacings of 75m, 50m and 25m, are analyzed and compared.

May 1, 2007

By T. Krumins, L. Zunti, R. Frischmuth

Mercury is known to occur in sulphide-bearing refractory gold deposits in the form of sulphide minerals or elemental inclusions. These deposits typically require an oxidative pre-treatment process, such as pressure oxidation or roasting, to achieve economic gold recovery. However, these processes also have the potential to liberate mercury, a portion of which may then be released to the environment through gaseous emissions. Mercury emissions from mine processing operations have been of particular interest in recent years, as governments impose lower emission targets and organizations adopt better industry practices to reduce the environmental and health aspects of releasing mercury into the environment. This paper describes various mercury removal technologies with respect to pressure oxidation gas handling circuits, with a focus on key design variables and technology selection criteria.

Jan 1, 2014

By Olav Mejia

The rising energy costs and environmental considerations in mining necessitate the development of energy-efficient copper and gold processing plants. This paper presents an analysis of technical strategies aimed at reducing energy consumption in these plants. Key approaches include the integration of advanced ore sorting technologies, High Pressure Grinding Rolls (HPGR), Coarse Particle Flotation (CPF), and high-intensity flotation. Ore sorting enables early-stage waste removal, reducing the downstream processing load and associated energy use. HPGR technology, recognized for its energy efficiency, contributes to significant energy savings in comminution circuits by reducing reliance on traditional grinding methods. CPF technology further optimizes flotation performance by enabling the recovery of larger particles, thereby decreasing the need for fine grinding and reducing overall power demand. High-intensity flotation units enhance separation efficiency and mineral recovery in a compact footprint, offering further reductions in energy consumption. Together, these technologies provide energy saving opportunities to achieve a more sustainable and economically viable processing operation. This paper evaluates the effectiveness of each method, highlighting their potential impacts on energy consumption, operational efficiency, and cost-effectiveness in copper and gold processing

May 4, 2025