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By J. Guha, el, G. Bouchard, W. Zuckerk, J. Carignan, G. Archambault

The Gwillim Mine, located 8 km northwest of Chibougamau, is underlain by two mafic volcanic cycles separated by a dominantly felsic cycle. These rocks are part of the Gilman Formation of the Roy Group. The mafic rocks are cut by weak shear zones containing the "North" and "Main" veins, both east-west striking gold-bearing structures dipping 75° to the north. The felsic cycle, which is also gold-bearing, contains textures suggesting a syngenetic origin. The Gwillim Mine presents an excellent opportunity for the study of what may be two coexisting gold deposits, a volcanogenic and a veine type.

Jan 1, 1984

By W. Dong

This paper presents the fundamental study of the temperature distribution in a reforming planar solid oxide fuel cell (SOFC) using mathematical modeling and experimental testing approaches at Versa Power Systems (VPS). In order to investigate the on-cell temperature distribution under high rates of Natural Gas direct internal reforming (DIR), both the computer simulation approach and the experimental testing approach have been developed. In this work, comprehensive in-house DIR and SOFC models were developed and employed for the computational fluid dynamics (CFD) based 3D computer simulation. The current SOFC module has been corrected to take into account both the on-cell electrical leaking effect and the stack stage structural resistance. Meanwhile, an instrumented single-cell test jig with multiple thermocouples was built, and a series of experimental tests were performed at various conditions. The numerical results based on the single-cell jigs are in very good agreement with the physical test results.

Jan 1, 2005

By B. Rivard, D. Francis

A layered Archean magma chamber is exposed at the base of the Yasinski segment of the La Grande greenstone belt. This intrusive complex lies beneath a sequence of mafic volcanics and is underlain by granitoid basement which is crosscut by a swarm of gabbroic dykes. The gabbros of both this complex and the dyke swarm of gabbroic dykes. The gabbros of both this complex and the dyke swarm define a pronounced Fe-enrichment trend. The volcanic patterns of the La Grande and Eas tmain greens tone belts, however, define a series of iron depletion trends which originate in the iron enrichment trend of the gabbroic intrusives. These patterns suggest that the gabbros produced in the intrusive complex may serve as parental liquids for some of the lava suites of the James Bay greens tone belts.

Jan 1, 1984

By Maxim Martel, Karolan Tremblay

Westwood Mine has experienced several episodes of increased seismic activity. While current geotechnical characterizations such as RMR, GSI, and Q' index can identify the general rock quality and zones at risk of convergence, they fail in identifying zones at risk of seismic activity. Previous research at Westwood Mine has shown a correlation between seismicity and areas with strong rheology contrasts. To characterize this contrast, 300 UCS tests were analyzed with their associated geochemical data, and statistical analysis and regression were performed using IOGAS software to establish a relationship between resistance and geochemistry. UCS-generated data with XRF results were transferred to Leapfrog Geo to create a block model of intact rock strength. This block model dataset was used to perform a competency contrast block model, and back-analysis of specific seismic sectors at Westwood Mine were conducted to validate the model. The purpose is to develop an established geomechanical tool capable in identifying areas with greater seismic risk associated to a change in the rock strength characteristics. By identifying those areas, mitigation measures can be implemented to minimize impact of seismicity on the operation.

Jan 1, 2023

By C. Arson

"Optimizing hydraulic fracture injection parameters in order to maximize hydrocarbon extraction and to avoid extensive borehole spalling is still an open issue. In this paper, the Differential Stress Induced Damage (DSID) model is employed to simulate the anisotropic damage distribution around pressurized boreholes drilled in fractured shale. The loading path is purely mechanical: excavation and fluid injection are simulated by stress relaxation followed by pressurization. We investigate the effect of pre-existing fracture orientation, in-situ stress and injection pressure on the propagation of anisotropic damage during pressurization. Finite Element results indicate that (1) damage initiates and develops when the ratio of two in-situ stress component deviates from 1, and the magnitude of damage is proportional to this stress deviation; (2) For a given in-situ stress field, damage initiates for a certain threshold of injection pressure, and the damage zone extends as the injection pressure increases; (3) A pre-existing fracture only affects the damage zone locally; the orientation of that fracture does not affect the damaged zone, which is controlled by in situ stress and injection pressure.INTRODUCTIONHydraulic fracturing is used to increase shale permeability and to enhance hydrocarbon extraction. In order to maximize the extraction ratio and to avoid wellbore spalling and clogging during fluid injection, the parameters related to injection for each particular site need to be optimized. Therefore, it is necessary to clearly understand how shale responses upon excavation and pressurization.It is well known that breakouts grow in the direction of minimum compression and that plastic deformation around wellbores tends to arrest breakouts (Zoback et al., 1985). Laboratory acoustic emission tests revealed that fractures propagate along the direction of maximum compression stress, and fractures (breakouts) are surrounded by the Excavation Damaged Zone (EDZ), in which rock properties are weakened by the presence of micro cracks (Eberhardt et al., 1999; Martino et al., 2004). The anisotropy from orientated foliations and cracks may influence the development and propagation of fractures and breakouts (Everitt et al., 2004). Sonic televiewer logs proved that during hydraulic fracturing, fluid injection further alters the stress distribution (Evans et al., 2005). Shale natural fabric strongly affects the evolution of the EDZ around boreholes."

Jan 1, 2015

By M. Vaillé, B. Bossé, N. Durupt, A. Michaut

Imouraren is a sedimentary uranium deposit (> 150,000 tU @ 800 ppm), located approximately 100 km North-Northwest of Agadez (Niger); its depth reaches 110 to 170 meters. For low-grades ores, heap leaching is commonly considered as the appropriate technology for metal recovery. More precisely, the ore is crushed (≤ 300 mm) and agglomerated before being stacked. In this case, sulfuric acid can be added during agglomeration and/or irrigation (for three months to a year) to improve uranium recovery. It is known that mineralogical, chemical and physical properties of the uranium ore impact recovery, yet many challenges remain to increase recovery using this process. For example, ore heterogeneity and spatial variability (e.g., variation in uranium, carbonate and/or clay contents) can affect heap leaching performances (i.e., metal recovery, acid consumption or neutralization, percolation rate). However, laboratory column tests using composite ore sample that do not consider ore heterogeneity are widely used to anticipate recovery. Consequently, a new approach that consists in using Imouraren drill core ore samples was recently investigated. This latter also enabled a better assessment of the main parameters that influence uranium recovery and proposed a new predictive model to optimize mining operations.

Jan 1, 2020

By A. Vervoort, A. Govaerts

Geostatistical concepts are often difficult for students to understand, even those with a strong mathematical background. One of the main problems is the link between the variation of the parameter value in space or time and the calculated experimental semivariogram. Another challenge is differentiating between directional and omnidirectional semivariograms and their interpretation. For these reasons, interactive tools were developed based on the free public domain software R. The use of these interactive tools is limited to educational situations only (i.e., to visualize basic concepts). The interactive modules can be accessed at www.bwk.kuleuven.be/geostatistics.

Jan 1, 2014

By L. Voisin, K. Yamaguchi, D. G. Mendoza, K. Ltagaki

The behavior of arsenic and antimony in the Cu-0 system was thermodynamically investigated to understand their elimination during a blister-making stage in copper smelting. Firstly, the phase relations in a miscibility gap composed of the liquid slag and copper phases in the Cu-0-As and Cu-0-Sb systems at 1523 K were established by a quenching technique. It was found that arsenic and antimony distributed preferentially into the slag phase in the miscibility gap. Secondly, the activities of arsenic and antimony in the miscibility gap of these systems were determined at 1523 K by using a double Knudsen cell - mass spectrometer method. It was clarified that the activity of arsenic in the copper and slag phases showed the negative deviation from ideality while that of antimony in the copper phase a slightly positive deviation. These data obtained in this study suggest a possibility to eliminate arsenic and antimony by means of over-blowing in a converter after discharging the slag.

Jan 1, 2007

CSIRO Minerals, in association with the AJ Parker CRC for Hydrometallurgy, has an active program of hydrometallurgical research in which physical and computational modelling are used to better understand and improve a range of different unit operations. The modelling is based on flow simulation (Computational Fluid Dynamics or CFD), but incorporates other physical and chemical phenomena of importance, such as droplet break-up and coalescence, species transport and reaction. This paper reviews some of the major projects that have been undertaken at CSIRO Minerals and will illustrate the critical importance of hydrodynamics to the performance of unit operations and the improvements that can be made to performance using such modelling techniques. Unit operations that are discussed include solvent-extraction, gravity thickeners, flotation cells, bio-heap leaching and stirred tanks.

Jan 1, 2005

By H. Chaouki

The aim of this work is to simulate the forming process of a green anode. For this purpose, a nonlinear compressible viscoelastic constitutive law is presented. The concept of natural reference configuration is considered. Within an isothermal thermodynamic framework, a Helmholtz free energy is proposed to take into account the nonlinear compressible deformation process occurring between natural reference configuration and current configuration. A dissipation potential is introduced in order to characterize the irreversible aspect of compaction process. Thus, the constitutive law is formulated through two equations: 1) an expression of Cauchy stress tensor and 2) a differential equation characterizing the evolution of the natural reference configuration. Material parameters are assumed to be a function of the bulk density. This allows capturing the micro-mechanical phenomena within the chosen macroscopic approach. An experimental study based on compaction tests is carried out in order to characterize the mechanical behaviour of the anode paste. A user's material VUMAT subroutine for finite element dynamic explicit analysis has been developed and implemented in the ABAQUS commercial software. To evaluate the model predictive capability, numerical simulations of the compaction forming process of anode paste were performed. Simulation results show that the constitutive law predicts the experimental trends and gives interesting physical responses. This constitutes a first step toward making a benchmark with experimental results on the forming process of anode paste.

Jan 1, 2011

By A. Warczok

Metal losses in discard slag are the main factor determining overall recovery. The metals are present both in dissolved form and as matte or metallic inclusions, varying in size from 2 to 1000 µm. Pyrometallurgical slag cleaning usually consists of heating the slag, reduction of oxides and settling of matte/metal droplets. Heating the slag decreases viscosity and accelerates reactions. Reduction of magnetite liberates inclusions and facilitates co-reduction of dissolved metal oxides. A significant amount of the matte and metal is present as very fine metallic inclusions, too small for settling. The coalescence of these matte or metal inclusions is required to remove them from the slag. The developed new concept of slag cleaning combines DC furnace technology with an extra magnetic field for vigorous slag stirring, enhancing mass transfer to the reductant surface, accelerating the rate of reduction, and destabilizing the emulsion of matte or metal inclusions. Intensive slag stirring increases the probability of collision of inclusions, will accelerate their growth and will therefore improve settling. The process is carried out in a patented DC channel furnace, where the liquid metal or matte layer acts as a cathode and the floating coke bed on the slag surface is the anode. In the first part of the furnace, a superimposed magnetic field induces a Lorentz's force causing the slag to start an intensive circular motion. The next furnace zone does not experience any stirring and is dedicated for quiet sedimentation of the inclusions. A mathematical model of gravitational coalescence combined with forced slag motion showed the possibilities of effective removal of copper matte inclusions. The results of laboratory pilot scale tests of continuous slag cleaning showed fast slag reduction and confirmed the improved matte removal from the slag. Conceptual analysis shows the potential use of the technology in various other non-ferrous industries, like for example nickel plants. It is also possible to use this technique batch wise.

Jan 1, 2007

By C. H. Lau, I. T. Ng

Uniaxial Compressive Strength (UCS) of rocks is an important mechanical parameter for many civil engineering and rock engineering applications such as tunnel excavation, slope stability and foundation design. Macau is one of the world's fastest growing and most densely populated cities, many large and important infrastructures have been being continuously built using pile foundations which are designed to be supported by granitic bedrock. In Macau, the UCS of the granitic bedrock is required almost for every project involving pile foundations and is always measured directly from UCS test in the laboratory. However, direct measurement of UCS requires high quality rock core sample which is not only time-consuming and expensive but also requires high level of operating skill. In view of this fact, estimation of UCS using some empirical correlations will be more practical and efficient because they are relatively fast and economical compared to the direct measurement from UCS test. In the past, some empirical correlations had been established and widely used for estimating UCS of rocks in common engineering practice. However, it has been well recognized that the rock properties are generally varied with sites or geological regions in other words an empirical correlation developed from one region or one country may not be applicable for other regions or countries. Due to the reason that the empirical correlations for predicting UCS for granite are scarce in practice, in this study an extensive experimental program has been performed and a large database containing data such as UCS, Point Load Index (Is50), Schmidt Rebound Hardness (RL), porosity (?), water absorption (S), specific gravity (Gs) and dry density (?d) has been developed. An attempt has been made for developing a new empirical correlation for estimating the UCS of Macau granite. Accordingly, a comprehensive statistical analysis for correlating UCS with Is50, RL, ?, S, Gs and ?d has been performed and a local empirical relationship based on the developed database is proposed for obtaining reliable estimation of UCS for the granite of Macau. Finally, the performance of the proposed correlation is accessed by using another independent testing database developed in this study. It indicates that Is50, RL, ? and S have strong correlation with UCS whereas Gs, ?d have poor correlation with UCS. This study not only proposed a proper predictive empirical correlation for UCS determination for Macau granite but also provides detailed statistical information which is beneficial to engineers for obtaining better characterization of Macau granite.

Jan 1, 2015

By G. Knight

"Results of a program of dust research carried out at the Mines Branch Laboratory, Elliot Lake, indicate that dust-concentration estimates vary greatly, depending on the sampling instrument, the assessment technique and the properties of the dust cloud. The wide range of the ratio between the estimates by any pair of instruments shows that the correlation between the health hazard and dust-concentration estimates by most existing sampling instruments must be questionable. Important studies are being carried out to permit the definition of mine environments in more precise technical terms. The influence of size selection, the physical property measured, composition and sampling period on the assessment of the health hazard are discussed."

Jan 1, 1969

By H. R. Shakeri, R. Mayer, M. J. Worswick, A. Rahem

The current focus of research and development in transportation industry is to use lightweight materials such as aluminium alloys for more structural components. In this regard, maintaining safety of the passenger and vehicle is the most important; therefore crashworthiness of components made of lightweight materials must be evaluated prior to sizable application of these materials. The focus of the present study is to understand failure and damage mechanisms during the axial crushing of aluminium tubes made of A1Mg3.5Mn alloy of 2 and 3.5 mm thickness. Due mainly to complexity of the crushed tubes, a microstructural approach is considered. In this study optical, stereo as well as scanning electron microscopy techniques have been used to study damage and failure mechanisms in these types of tubes, which are essential energy absorbing components in passenger vehicles.

Jan 1, 2006

By Gurinder Kaur

Selenium (Se) based materials find wide applications in rectifiers, solar cells, photographic exposure meters, data storage devices, xerography and anticancer agents. They are also used in the glass industry to eliminate bubbles and remove undesirable tints produced by iron. In addition, Se is highly reactive towards a wealth of chemicals that can be potentially exploited to convert Se into other functional materials such as CdSe, ZnSe, Ag2Se. Here, we report a review of structural investigations of Se based materials in glassy and nanostructured forms. Glasses having varying amounts of Se and Tellurium (Te) were doped with group IV and V elements such as antimony and tin. Structural changes accompanying the composition variation were characterized with x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray absorption near edge spectroscopy. At the same time Se-Te nanoalloys were synthesized in aqueous micellar phase using Na2SeO3/Na2TeO3 as the Se/Te source. Morphology change from nanoparticles to nanoribbons was investigated using Scanning and Transmission Electron Microscopy (SEM/TEM) techniques. Structural investigations were also done for well defined morphologies of Se based nano-biomaterials obtained in the presence of water soluble protein bovine serum albumin (BSA).

Aug 1, 2013

By M. Bouchard et G. Martineau

In the Chibougamau area, a large portion of the glacially tranported boulders which were deposited at the surface were later partly remobilized by the waters of Glacial Lake Ojibway. In the dispersal studies of these boulders, it is sometimes difficult to discern the effect of this reworking process. In addition, depositional processes in the lake contributed material to the original block deposits through the formation of boulder lag by littoral wave action and through direct sedimentation in the form of deltaic deposits. In spite of these complicating factors, dispersal studies at carefully selected sites which were unaffected by the above processes make it possible to unravel the general patern of glacial dispersion. In this study, indicator lithologies of the Albanel and Chibougamau formations were used. They give a coherent image of dispersal throughout the area showing transport toward the southwest. Considering the particular geological context of the region, and in view of the extensive mineral exploration studies which are being carried out, the results of this study are encouraging for the tracing of source areas of glacially transported mineralized boulders.

Jan 1, 1984

By Waghmarem Umesh V., Vinay Jain, Pradip, Beena Rai

"The hematite surface plays a vital role in several processes of industrial and technological importance, such as, in beneficiation of iron ores, catalysis, and geochemical processes. Therefore, it is imperative to have a clear description of the structure and composition of this surface, which forms the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. In this work, the hydroxylated hematite (0001) surface was modeled using density functional theory (DFT). The computed planar relaxations are consistent with X-Ray crystal truncation rod diffraction results reported in the literature. It is demonstrated that only one type of surface, that is, the (OH)3-Fe-H3O3-R is stable under aqueous conditions, as the relaxations for the second type of termination: (OH)3-Fe-Fe-R do not match quantitatively with experiments suggesting that its coexistence with the (OH)3-Fe-H3O3-R surface is unlikely. A detailed analysis of this surface shows that two of the three (OH) groups are not connected to the Fe surface atom. Instead, they form H2O molecules by combining with the H-atoms on the O-layer beneath the Fe-terminated surface leaving the Fe surface-atom bonded to only one OH-group. This undercoordination of Fe-atoms on the surface explains its higher reactivity as compared to hydroxylated alumina.INTRODUCTIONThe hematite surface plays a vital role in several processes of industrial and technological importance. A few examples are: flocculation/froth flotation of iron ores (Ravishankar, Pradip & Khosla, 1995), catalysis (Muhler, Schlögl & Ertl, 1992; Samsonov, 1973), and geochemical processes (Brown, Henrich, Casey, Clark, Eggleston & Felmy et al., 1999; Sposito, 1989). Therefore, it is imperative to have a clear description of the structure and composition of the hematite surface, which form the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, this is an important problem, as a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. Our current research focus is at employing molecular modeling techniques to come up with such selective reagents and then test their efficacy in the practical scenario through selective dispersion – flocculation labscale experiments and subsequently plant trials. Obviously, the correct structure and composition of the hydroxylated hematite surface is a fundamental prerequisite for such investigations."

Jan 1, 2016

By D. K. Sarkar, J. Perron, J. D. Brassard

"Nearly perfect spherical shaped water drops rolling-off from the surface of lotus leaf is one of the beauties of nature. This kind of surface is called superhydrophobic, since the water does not like it. Physically, a superhydrophobic surface provides a contact angle (CA) of water over 150°. The combinations of both mico-nanostructure topography as well as low surface energy are essential to have such high CA on a surface. Nano-micro structured superhydrophobic surfaces have been developed in different methods. (i) Monodispersed fluorinated silica nanoparticles have been synthetized via Stöber Sol-Gel process and deposited on various surfaces, such as aluminium or glass, to obtain transparent superhydrophobic thin films. (ii) Similarly, zinc stearate nanocomposite coating has been fabricated by spray process on the same substrates. These thin films are found mechanically robust with drag reduction of coefficient 16% lower than as-received surfaces. (iii) By electrodepositing pure zinc on steel surfaces and further coating it with diluted room-temperature vulcanized silicone rubber, the surface become superhydrophobic. This superhydrophobic surface protects the steel against corrosion by increasing the polarization resistance from 1.5 k? on steel to 44.4 k?. This coating also reduced the ice adhesion on the steel surface 6.3 times as compared to bare steel substrates. Globally, these superhydrophobic surfaces have tremendous applications against corrosion reductions, drag reductions and ice adhesion reductions.INTRODUCTIONSuperhydrophobic coatings are increasingly attractive to the industry and academia due to their unique self-cleaning properties as a result of their water repelling characteristics. Fabrication of superhydrophobic coating is an inspiration from nature as water is seen to repel on many natural surfaces such as those of the lotus leaves, butterfly wings, water striders’ legs, and so on (Gao & Jiang, 2004; J. Huang, Wang & Wang, 2006; Neinhuis & Barthlott, 1997; Zheng, Gao & Jiang, 2007). This non-wetting phenomenon is well understood on lotus leaves, shown on the Figure 1 (a), and it is considered as the basis of the studies of superhydrophobicity. The existence of this binary structure on the surface of the lotus leaves allows a large amount of air entrapment and consequently reduces the contact area of water on it and the presence of low surface energy waxy components with reduced affinity to water together leads to the superhydrophobic properties. The phenomenon is shown on Figure 1 (b). Cassie and Baxter (Cassie & Baxter, 1944) as well as Wenzel (Wenzel, 1936) proposed two mathematical models to explain the wetting phenomena on rough surfaces that leads to superhydrophobic properties. By definition, superhydrophobic surfaces are characterized by a water contact angle value = 150° with the rolling off of water drops from the surfaces (Sarkar & Saleema, 2010). Superhydrophobic surfaces find tremendous importance in the technological world where it can applied in domains such as anti-corrosion, anti-biofouling, electrowetting, icephobic and even in drag reductions (Bushnell & Moore, 1991; Cao, Jones, Sikka, Wu & Gao, 2009; Carlborg & van der Wijngaart, 2010; Carré & Mittal, 2009; Y. Huang, Sarkar & Chen, 2010a; R. Karmouch, Coude, Abel & Ross, 2009). However, the most important challenge faced by industries is their feasibility large scale in an effective an economical manner."

Jan 1, 2016

By Boris Yacksic, R. W. Bruce

"The flotation of a cassiterite ore with oleic acid will recover primary or rougher concentrates assaying over 10 per cent Sn, with a recovery of 80 to 90 per cent. These rougher concentrates cannot be up-graded to a marketable grade by normal reflotation. Experiments were conducted on low-grade tin ores, and a process was developed for up-grading the rougher flotation concentrates by a reverse flotation technique. The process was tested on a number of samples of ore from the Catavi mine in Bolivia. The results of these tests showed that a concentrate assaying 40 to 60 per cent Sn could be readily produced, with a recovery of 60 to 75 per cent of the tin in the ore."

Jan 1, 1967

By P. Duran

The metallurgical gas handling system at Chagres Smelter, like that of many smelters, can be the limiting constraint to processing more concentrate through the smelter. Mass and energy balances for the metallurgical gas handling system processing off-gases from the flash furnace and Peirce-Smith converters have been used by both operations and process engineering groups to help evaluate different operational scenarios in which the use of the installed capacity could be maximized and/or an operational strategy can be change with the purpose of removing a bottleneck or justifying an investment to relieve a constraint in the gas handling system. The present work describes the development of these process balances that were carried out in Exce®. The results were validated with operational data and, subsequently, some cases of industrial interest were simulated, detecting some conditions that were limiting the operation due to the present installed capacity in the Chagres Smelter.

Jan 1, 2007