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By W. K. Overbey

The Bureau of Mines conducted surface joint and stress measurements, airborne remote sensing imagery studies, compass-oriented borehole televiewer surveys, numerical simulation of fractured wells, and well productivity studies in a four-quadrangle study area of Ohio, to determine the effects of earth fracture systems on the deliverability of gas storage fields. The results of these studies indicate that much useful information about a gas storage reservoir can be obtained and put to practical use by studying--(1) oriented cores for fractures and directional permeability, (2) orientation of induced hydraulic fractures for alignment of well patterns, and (3) aerial photos and multispectral scanner imagery for general surface geology comparison and to determine if some, development patterns can be generated by such results. The absence of known tectonic elements associated with flat-lying sediments, such as faults or fracture zones that can be seen on the surface, indicates that the use of remote sensors such as radar or aerial photography is not likely to be useful in picking well locations for drilling. Studies similar to those discussed here should be conducted in gently folded and strongly folded sedimentary formation areas to determine if the increased knowledge of earth fracture systems under these conditions might be beneficial in gasfield and gas storage reservoir development.

Jan 1, 1974

By J. F. McIlwain

The Bureau of Mines has investigated fumes generated by selected welding electrodes used in mines in order to help determine their relative health hazard potential. Fumes were generated and collected in an enclosed chamber for subsequent generation rate and chemical constituent determination. Shielded metal arc electrodes from the following groups were tested: AWS types E308-16 and E310-16 stainless steel, ECoCr-A Co-Cr hardfacing alloy, ENiCr Ni, an Mn-Cr buildup alloy, E7018 carbon steel, and EII018-M low-alloy steel. Flux-cored wire electrodes of this last group also were tested. Fume generation rates and the chemical composition of the fumes were measured. From these data, exposure in-dices were determined, which give a relative measure of the health hazard potential of using the electrodes. The effect of welding onto build-up alloy layers on the fume composition also was examined for five of the higher alloy groups.

Jan 1, 1987

By W. N. Marchant

[The citrate process for flue gas desulfurization (FGD) is a product of continuing research by the U.S. Bureau of Mines to meet the goal of minimizing the objectionable effects of minerals industry operations upon the environment. The reduction of SO2, in solution by H2S to produce elemental sulfur by the citrate process is extremely complex and results in solutions that contain at least nine different sulfur species. Process solution analysis is essential to a clear understanding of process chemistry and its safe, efficient operation. The various, chemical species, the approximate ranges of their concentrations in citrate process solutions, and the analytical methods evolved to determine them are hydrogen sulfide (~0M to 0.06M) by specific ion electrode, polysulfides (unknown) by ultraviolet (UV) spectrophotometry, elemental sulfur (~0M to -0.001M dissolved, ~0M to ~0.1M suspended) by W spectrophotometry, thiosulfatc (~0M to ~0.25M) by iodometry or high performance liquid chromatography (HPLC), polythionates (~0M to ~0.01M) by thin layer chrornatogrphy (TLC), dithionite (searched for but~ not detected in process solutions) by polarography or TLC, bisulfite (~0M to 0.2M) by iodometry, sulfate (~0M to 1M) by a Bureau-developed gravimetric procedure, citric acid (-GM to 0.5M) by titration or visible colorimetry, glycolic acid (~0M to 1N) by HPLC, sodium (~1.5M) by flame photo¬metry, and chloride by argentometric titration.]

Jan 1, 1980

By Martin H. Rogoff

This publication combines a critical review of the literature on the microbiology of coal with an introduction to those areas of microbiology related to studies of coal as a biological material. The attack on coal by microorganisms as yet remains doubtful. Only the low-rank coals contain an indigenous microbial flora, and even these organisms are not peculiar to coal, but are common soil and water forms. No experimental data have as yet been presented, either in the literature or in the present work, which unequivocally demonstrate the oxidation of coal by microorganisms. Reasons for the resistance of coal to such attack, including insolubility, physicochemical structure, steric hindrance of enzyme action, and the presence of antibiotic materials in coal are discussed. Microorganisms do attack large aromatic molecules and the mode of oxidation of aromatic ring systems by bacteria is presented. Well-defined pathways are known for the oxidation of polycyclic compounds with one to three rings, and these paths with their key intermediates are described and related to the possible oxidation of coal.

Jan 1, 1962

By Catharine T. Fogg

The Bureau of Mines investigated the availability of flake and high-crystalline natural graphite from 4 domestic and 25 foreign mines and deposits in 11 market economy countries (MEC's). Demonstrated resources were estimated to be 95 million metric tons (Mmt) containing 5.61 Mmt of recoverable flake and high-crystalline graphite products. Fifty-five percent (3.17 Mmt) of the total recovered product is estimated to comprise plus 100-mesh (150-µm) flake pro-ducts and "lump" and "chip" high-crystalline products, designated as "graphite A" in this study; 45 pct (2.44 Mmt) of the total is minus 100-mesh (150-µm) flake products and "dust" high-crystalline products, designated as "graphite B." Total production costs, including all costs needed over the life of each operation, were determined at a 0-and 15-pct discounted-cash-flow rate of return (DCFROR) for both graphite A and graphite B products. For a 15-pct DCFROR, 1.74 Mmt (54.9 pct) of the graphite A products is available at $600/mt or less and 2.13 Mmt (67.2 pct) is available for $800/mt or less. For the same DCFROR, 1.08 Mmt (44.3 pct) of the graphite B is available at $200/mt or less, and 1.71 Mmt (70 pct) is available at $325/mt or less. No domestic resources were determined to be economic at present prices. A sensitivity analysis of the relative economics of the Alabama graphite deposits under various operational parameters is presented in an appendix. All evaluations are in January 1984 dollars.

Jan 1, 1987

By IRENE AITKENS

The emerald is the most costly of all gems , due to the scarcity of flawless stones . This fact gave rise to the ancient axiom , " As rare as an emerald without a flaw . The finer gems not only command the highest prices at all times , but when flawless are considered the most highly prized of all gem stones . George F. Kunz divides emeralds into two distinct classes : " Exceptional specimens , " which bring as much as $ 6,000 a carat ; and " fine- quality specimens , " which bring about $ 1,000 a carat .

Jul 1, 1931

By M. Mentser

The exchange of oxygen between carbon dioxide and carbon monoxide that occurs reversibly on carbon surfaces was studied at temperatures of 750° to 850°C and a pressure of 1 atmosphere. Carbon-14 was used to detect and measure the exchange reaction. The extent of oxygen exchange was a linear function of com- position of the gas mixture, and this relationship was used to evaluate the forward and backward rate constants of the reaction. Equilibrium constants, directly determined for oxygen exchange in this study, agreed well with values in the literature that were derived only by indirect procedures. This result establishes the validity of oxygen exchange in the mechanism of carbon gasification by CO2. Rates of carbon gasification were less than an order of magnitude slower than rates of oxygen exchange. Activation energies for these two processes were 58 and 53 kcal/mole, respectively. The closeness in the activation energies argues against any change in the rate-controlling step over a wide temperature span at atmospheric pressure. The role of CO as a retardant on the CO2-C reaction, and the nature of the carbon-oxygen complex are also discussed in view of the data obtained.

Jan 1, 1973

By F. Matanzo

[Nine wire rope terminations were pull tested and fatigue tested to destruction to measure the termination efficiency and relative fatigue life. The terminations were selected on the basis off mine site visits and the specimen were assembled in a manner similar to industrial slings. To measure a termination's sensitivity to poor workmanship, both standard and modified assembly specimen were tested. Lang and Regular construction of the 6x19 and 6x37 class wire ropes were used in diameters of 13 mm (1/2 in.), 19 mm (3/4 in.), 25 mm (1 in.), 38 mm (1 1/2 in.), and 51 mm (2 in.). In static pull tests rope class, construction, and diameter interacted with the termination to influence the efficiency of the termination. In axial fatigue tests using only the 6x19 class rope, the effect of rope construction was negligible since failure was primarily dependent on the termination type. The Swaged Socket, a termination requiring a high capacity hydraulic press, gave the best overall performance in terms of efficiency and fatigue life. The short body length of the Zinc Poured Socket (RR-S-550) was attributed with the short fatigue life of this termination. The use of thermosetting resins as a replacement for zinc was demonstrated successfully for some socket designs. The fatigue life of the termination, expressed as a percentage of the fatigue life of the wire rope, was shown to be a guide for the retirement of the wire in these applications where the wiry' rope is primarily in axial loading.]

Jan 1, 1978

By Foster Fraas

One of the lithium minerals most widespread in the earth's surface is spodumene (Li2O-A1203-4Si02) a lithium aluminium silicate. For some time, deposits of this mineral were known to exist in the Black Rills of South Dakota, but it was only quite recently that Hess4/ pointed out the great magnitude of the low-grade e deposits it s in North Carolina. The theoretical lithia (Li20) content of spodumene is 8.04 percent. The only other minerals with such high lithia content are the phosphates, but these occur only in pockets and are not in extensive deposits5/. Actually, however, the lithia content in spodumene is never found to be this high, being nearly always below 7 percent for the pure mineral, and part of the lithia is apparently replaced by other alkalies.

Jan 1, 1937

By C. B. Manula

This report is volume 5 of an eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment. The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation, and ventilation. This volume of the final report describes the Subsidence subsystem of the Master Design Simulator. This subsystem uses the finite element method to simulate ground movement caused by an advancing mining face in an underground coal mine. The model is structured around the concept that the ground mass is a layered media of different thicknesses and material properties. Gob areas are considered to be unfilled with broken rock at the beginning of mining. After mining starts, the gob areas are filled with broken material which provides resistance to the lowering of the overlying strata. The model is tied to the Geology and Reserves subsystem, but it can also operate as a free standing routine. A case study is presented illustrating the application of the model. A detailed user's manual, including a program listing, is included in the appendices.

Jan 1, 1974

By I. Liebman

A Bureau of Mines study is in progress to determine the effectiveness of passive water barriers in suppressing coal-dust explosions. A 2.9-ft3-capacity water-filled plastic tub was found effective in suppressing dust explosions propagating at speeds of 250 to over 1,000 ft/sec. Work directed at determining the limitations of water barriers showed that the passive water barrier technique is also feasible for the suppression of weak dust explosions propagating at speeds of 100 to 250 ft/sec. For relatively slow accelerating flames, dynamic wind forces appear to be the important quantity governing fragmentation of the plastic tub and subsequent water release and dispersion, whereas dynamic impulse appears to be the significant quantity for rapidly accelerating flames. The acoustic approximation (relation between static pressure and flame or wind speed) is shown to be valid in a long single mine entry. This relationship appears to be useful in predicting the regions within a long single entry where passive water barriers are effective in quenching a dust explosion.

Jan 1, 1974

By S. J. Rodgers

This report presents guidelines on methods of dust control in conventional coal mining operations. The normal mining cycle and equipment used in a room and pillar conventional section are described. Main ventilation, section ventilation and face ventilation are discussed in detail. Proper installation of line brattice, maintenance of proper air flows at the face and split ventilation are stressed. The effects of maintaining the end of the line brattice near the face are described. The advantages and disadvantages of blowing and exhausting face ventilation are presented. The use of water sprays on cutter bars and loading machines is described. The design of a nonclogging water spray system developed under a Bureau of Mines contract is presented. Other methods of reducing dust exposure are discussed and include alternative procedures for shot firing and administrative controls.

Jan 1, 1983

By Rudolf E. Greuer

This report contains the practical application of a computer program for the simulation of ventilation systems under the influence of mine fires and other emergencies on five hardrock mines. The introduction describes the need for such a program, its basic features, and the range of its applicability which is mainly a function of the available ventilation data. The second chapter discusses program modifications, whose necessity or desirability was, during the application, discovered. The following five chapters, which comprise the major portion of the report, give the detailed description of the program application on the five mines. For every one of the selected mines, the ventilation system, the source of the used ventilation data and their preparation for computer simulations are outlined. Based on data for the airflow distribution solely, fumes concentrations in the mines are calculated for several assumed fire locations. Based on data for airflow and pressure distributions, ventilation disturbances caused by fires as well as the resulting fumes concentrations and temperatures are determined. The consequences for escape routes and the possible means to keep them free of fumes are discussed. To investigate the capabilities of the program, other contaminant sources and other potentially dangerous ventilation factors, like fan failures and changed surface temperatures, are simulated also. The results of the calculations have been entered into ventilation plans which makes them easier to scrutinize. All significant computer printouts have been attached.

Jan 1, 1981

By John C. Edwards

To increase the capability to predict the effectiveness of a flame arrester in the cooling of hot combustion gases expelled through a flame arrester, the U.S. Bureau of Mines developed an equilibrium. model and one-and three-dimensional transient thermal models of a flame arrester, which were used to predict the temperature evolution within the arrester and the maximum temperature at the external surface of the arrester. The models account for convective and conductive heat transport within the arrester and radiative losses at the exit surface. The gas flow through the arrester is established from an empirically derived relationship between the gas velocity and the pressure gradient across the arrester. Lateral heat loss from the arrester to the enclosure wall is accounted for in the three-dimensional model. The model calculations for maximum outside surface temperature of the arrester showed an approximate agreement with measured values for vent-area-to-enclosure-volume ratios between 12 and 28 in2?ft-3.

Jan 1, 2010

By Suresh K. Bhatt

A mathematically simulated modeling technique is used in this U.S. Bureau of Mines report to represent a hypothetical mining operation with existing mining technology and prevalent mining costs. Mining scenarios were prepared and evaluated for potential benefits and costs available through computer-assisted mining. Base criteria, parameters, and methodology are described.

Jan 1, 1991

By M. P. Ristenbatt

A new automated post-disaster signaling system, intended to use through-the-earth EM propagation, was demonstrated in the laboratory at an input SNR of -34 dB. The system presently available requires an input SNR of +6 dB, and uses a human-ear detector. The work here demonstrated coherent integration, for the automated system, in multiples of 17 s, up to 1088 s (18 minutes). A repeating pseudorandom (or pseudonoise) signal is used, which offers an ideal auto-correlation at the receiver matched-filter output. A novel decision-variable algorithm achieves the estimate of noise level by using those matched-filter output samples that occur between the signal auto-correlation peaks. This work included corraboration that the received signal power decreases as distance to the tenth power, for through-the-earth propagation. Thus, the above 40 dB reduction in required input SNR permits an automated system to have a range 2.5 times that of the present system. In addition, an automated system permits the possibility of operating receivers around-the-clock; this would reduce the initial-detection-time from a few hours (present system deployment time) to a few minutes (signal processing time).

Jan 1, 1981

By J. R. Hoskins

This is the final report for Research Contract No. 00101300 (Min. 34) granted by the U.S. Bureau of Mines to the University of Idaho Mining Research Bureau. The research project is entitled "Development of Improved Ventilation Technology for Non-coal Mines and Other Underground Excavations.' The duration of the project was six calendar months, from 16 April to 16 October 1970. The budgeted cost was $34,867.00 of which $31,953.00 was to be furnished by the U.S. Bureau of Mines. The sequence of reporting that follows is to state the objectives as contracted, outline the program of investigation, highlight briefly the important technological factors peculiar to vein-type metal mine ventilation, and describe the normal methods of control. This is followed by the results achieved by the survey, and an itemization of the observed deficiencies in current technology. There follows a section dealing with the adopted Federal Regulations.

Jan 1, 1970

By J. R. Ross

Recovery of uranium from slightly alkaline mine water, available in the Ambrosia Lake district of New Mexico, was studied using countercurrent ion exchange columns developed by the Bureau of Mines. Approximately 5 million gallons of mine water containing 9 to 12 ppm U308 was treated by ion exchange using a 14-inch-diameter absorption column composed of five or six compartments each 4 feet deep. Uranium recoveries averaged in excess of 98 percent at solution flows ranging from 15 to 25 gallons per square foot per minute and resin loadings up to 3.6 pounds of U.08 per cubic foot. In subsequent tests, loaded resin was continuously eluted in a countercurrent elution column with a diameter of 4 inches and containing a bed of resin 9 feet deep. The resin was eluted to a residual loading of less than 0.06 pound of U305 per cubic foot, at a resin-retention time of 224 minutes, using only 1.9 volumes of 1.1 M NaCl-0.05 M NaHCO3 solution per volume of resin. Compared with existing ion exchange practices for recovering uranium from mine waters in the Ambrosia Lake district of New Mexico, use of these improved ion exchange contactors would reduce ion exchange resin requirements at least 70 percent and allow further substantial reductions in capital and operating costs.

Jan 1, 1971

By B. W. Haynes

This Bureau of Mines report describes the laboratory processing of manganese nodules and the results of tailings characterization obtained during the cooperative program with the Department of Commerce's National Oceanic and Atmospheric Administration (NOAA) and the Bureau. Five technically feasible first-generation nodule processing methods were operated at bench scale to generate sufficient tailings and slags for physical and chemical analyses. A description is given for the laboratory operation of the individual unit operations of each process. The laboratory-generated tailings and slags were tested for physical properties, mineral content, elemental and ion content, and leachability for all five processes. The results of leachate testing using the Environmental Protection Agency extraction procedure (EP) toxicity test, the American Society for Testing and Materials shake extraction test, and the EPA-U.S. Army Corps of Engineers seawater elutriant test showed very low to negligible leaching of metals from the tailings and slags. Results of the EP toxicity test demonstrated that the wastes are nonhazardous as defined in the Resource Conservation and Recovery Act (Public Law 94-580).

Jan 1, 1985

By Frank D. Lamb, D. A. Woodard

"INTRODUCTION The iron-ore deposits near Cranberry, N. C., were worked as early as 1820, and records show that to date at least 1,500,000 tons of ore has been mined.. The early operators depended on selective mining and hand cobbing to yield a product containing 40 to 50 percent iron. Later, a magnetic concentrator was erected by the Cranberry Furnace Co. and was operated periodically until 1930. The magnetic cobbing method employed yielded satisfactory concentrates, but the plant was shut down because costs were too high. 4/Early in 1944, in connection with the sponge-iron program of the Bureau of Mines, North Carolina and Tennessee were surveyed for the purpose of finding a readily available source of high-grade iron ore for use in the experimental production of sponge iron at Salisbury, N. C., and samples from various sources were tested in the laboratory. The Cranberry ore proved to be best with respect to grade of magnetite concentrates produced, and it was decided that a pilot mill should be built on the Cranberry mine property and that the concentrate made there should be shipped to Salisbury for direct-reduction tests in a commercial brick kiln."

Dec 1, 1946