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By Heinz W. Sternberg

The literature on electrochemical treatment of coal is reviewed, and possible avenues of further research in this field are discussed in this report. Electrolytic reduction of finely distributed coal resulted in the addition of as many as 9 atoms of hydrogen to 100 atoms of carbon. Reduction of coal extracts at controlled potentials indicated the presence of condensed aromatic hydrocarbons and reducible quinones in coal. As much as 65 percent of low-rank coal can be made alkali soluble by electrochemical treatment. Higher rank coals gave smaller yields of alkali-soluble products. However, the nature of this reaction is not clear. The difficulty of reducing coal electrolytically is probably due to the insolubility of coal and not to any structural peculiarity. Reduction of coal by electrolytically generated radical anions appears to be a promising approach for further research.

Jan 1, 1962

By R. V. Lundquist, H. Leitch

Two hydrated calcium aluminates , formed by side reactions in the leaching step and desilication step of the lime- soda sinter process , were investigated to better define their influence on alumina recovery . The two calcium aluminates , Caз [ Al ( OH) 6 ]₂ and зCa0.Al½ 03 · ( 8-12 ) H₂ ) , were prepared and identified by chemical and X- ray analysis . The relative proportions of each of these compounds formed in typical leach solutions at several temperatures were determined . The influence of free lime as a promoter of calcium aluminate formation was also investigated . The formation and precipitation from leach liquors of calcium aluminates contributes to the low alumina recoveries in the process . The presence of carbonate ion in the leach solution suppresses calcium aluminate formation and precipitation and results in higher alumina recovery . Hydrated calcium aluminates are formed in the aging of lime - soda sinters in the normal atmosphere .

Jan 1, 1963

By Beverly W. Dunning

The effect of vacuum melting on the elimination of gases and nonmetallic inclusions for six low-alloy steels was investigated. The purpose of these studies was the analysis and comparison of differences in gas content and inclusions in air-melted and vacuum-melted steel. Data obtained from melts of 1-1/4 to 20 pounds indicate that vacuum melting decreases the number and size of nonmetallic inclusions and at the same time increases the degree of dispersion of the remaining inclusions. These improvements are undoubtedly related to the elimination of approximately 80 percent of the nitrogen and 90 percent of the oxygen as well as most of the undesirable metallic trace impurities.

Jan 1, 1961

By Debra A. Griffith

The U.S. Bureau of Mines currently is researching the relationship between the level of back strength and the probability of low-back injury. This report is a review of the literature and statistics on over-exertion injuries. Overexertion continues to be a significant source of injury in metal and nonmetal mining, accounting for approximately 24 pct of all injuries yearly. These injuries, particularly to the lower back, can be very expensive in human and monetary terms. An examination of the accident data on overexertion injuries is necessary to provide a background for research into prevention and/or amelioration of those in-juries. The job categories outlined in the Accident Data Analysis data base most affected are "Mechanic/Electrician" and "Mill/Plant Worker." The age group most affected is "30-39" years, and the experience group most affected is "0-.99" years. The most prevalent type of overexertion injury is "Strain/Sprain," and the trunk is the body part most often involved in an overexertion injury.

Jan 1, 1994

By Alla D. Mah

The heats of combustion of three chromium carbides, Cr23C6, Cr7C3, and Cr3C2, were determined by combustion calorimetry. Heats of formation calculated from the results follow: ?Hf°298 (Cr23C6) = -94.7 ± 5.0 kcal/mole, ?Hf°298 (Cr7C3) = -43.3 ± 1.7 kcal/mole, and ?Hf°298 (Cr3C2) = -22.5 ± 0.8 kcal/mole.

Jan 1, 1969

By S. C. Schaefer

The Bureau of Mines investigated tIle standard Gibbs energies of formation, 8Gfo, for MllF2 (manganese difluoride) and CoF2 (cobalt difluo-ride). High-temperature galvanic cells employing CaF2 (calcium diflu-oride) as the solid electrolyte were used to measure the open-circuit potentials for the cell reactions ?

Jan 1, 1985

By E. K. Kleespies

The rate of the heterogeneous reaction between titanium-oxygen solid solutions and titanium trichloride in molten sodium chloride was determined at high temperatures. In the alpha phase, the reaction rate decreases uniformly with the increasing concentration of oxygen. The gamma crystalline form of titanium (above 33 atomic percent oxygen) was much less reactive than the alpha phase, and the reaction rate approached zero at 50 atomic percent oxygen. The activation energy for the reaction of titanium-oxygen solution containing 22.8 percent oxygen was 11.7 kcal/mole of TiCl3 as compared with 8.3 kcal/mole of TiCl3 for pure titanium.

Jan 1, 1967

By Oliver Q. Leone

Electrorefining tests using titanium-nitrogen alloys as anode material showed that no significant quantity of nitrogen was transferred to the cathode deposit. The nitrogen of the anode remained in the scale, and the titanium-nitrogen alloy was anodically insoluble in the electrolyte when the nitrogen content was 11 weight-percent.

Jan 1, 1966

By L. M. Demers, R. E. Edelson, M. P. Rose, D. T. Superdock

The pulmonary alveolar macrophage is a major defensive cell which counteracts the invasive properties of bacteria and particles when these substances invade the pulmonary environment. Pulmonary exposure to coal dust particles is believed to activate these macrophages to release a host of d1emical mediators which can neutralize or contribute to the harmful effects of these dust particles. Our efforts have been concerned with assessing a specific family of mediator substances produced by the alveolar macrophage from arachidonic acid when these cells are in contact with activating substances such as coal dust. Metabolites of arachidonic acid produce a vast array of effects which can impact significantly on pulmonary function both with normal pulmonary events and with pathologic processes of the lung. Our studies demonstrate that isolated alveolar macrophages obtained from rats or guinea pigs cultured in vitro release appreciable amounts of the cyclooxygenase products prostaglandin E2 and thromboxane A2 and release significant amounts of the lipoxygenase products .5-HETE and LTB4. In the presence of l x 104 -1x10·7 g/ml of a coal dust suspension, alveolar macrophages from the rats and guinea pigs alters their pattern of arachidonic acid metabolite release. In the rat, exposure of alveolar macrophages in vitro to the higher concentrations of coal dust causes a significant reduction in PGE2, TXB2 and LTB4 in a 4 hour time course study. In contrast, macrophages from the guinea pig in response to coal dust had little change in TXB2 release, only a slight inhibition in PGE2 production and an initial stimulation in LTB.t release over the 4 hour time course. Cells from guinea pigs released considerably more TXB2 than the rat under these conditions while rat cells formed considerably more LTB4 than guinea pig alveolar macrophages. These findings support the following conclusions.

Mar 1, 1989

By I. AITKENS

Turquoise is prized solely for its attractive color ; it is dull and opaque , wholly lacking the brilliant luster that is the chief attraction of transparent gems . The best quality of turquoise is blue , of a soft and pleasing tone , like the color of clear sky but distinctive , as indicated by use of the term " turquoise blue . " Often its value is lessened by a greenish cast ; in many stones the green predominates . A large proportion of the turquoise that is mined is utterly worthless , so inferior and unattractive is its color . The finest grade of turquoise comes from Persia , notable from Nishapur . Large quantities have been mined in the Southwestern States of the United States , and less important deposits have been found in a number of the other States .

Sep 1, 1931

By James C. Cawley

The Bureau of Mines conducted an investigation to statistically determine the mean current or voltage for resistive, inductive, and capaci-tive circuits that would cause spark ignitions in 8.3% methane-air, 5.3% propane-air, and 7.8% ethylene-air mixtures. Each mean ignition current or voltage was determined on the basis of 100 trials. Each trial consisted of 400 revolutions, 200 in each polarity, at 80 rpm of the standard breakf1ash apparatus. In general, spark ignition curves published in UL 913 for resistive and inductive circuits represent approximately the mean current values determined in this study, while published capacitive circuit values in methane are considerably less than the mean voltage values from this study, especially for a capacitance of less than 100 ~F. For resistive and inductive circuits, spark ignitions were obtained at currents con-siderably below those in the published curves, but this study was not optimized to find minimum ignition values. This report defines "safety factor" as applied to intrinsic safety testing as the energy ratio of the mean values of ignition current or voltage for two test gases. The safety factors presented in this report are not constant with voltage or current and, therefore, are not recommended for use.

Jan 1, 1986

By Kenneth M. Earl

In its investigation of deposits of strategic minerals, the Bureau of Mines did same development drilling at the Perkiomen Creek deposits, 5 miles east of Phoenixville, Pa. This area was the center of much copper mining from 1851 to 1858. The most productive vein was the Perkiomen-Ecton mines, owned by the Perkiomen Consolidated Mining CQ. The mines were closed in 1858, and no further production has been recorded. The Perkiomen-Ecton vein ranges in thickness from 2 to 19 feet. The principal mineral of value is chalcopyrite, with minor amounts of galena and sphalerite. No definite record was found as to the grade of ore min d. It was reported that 617 tons of 18-percent copper are obtained by hand sorting 12,200 tons of mine-run ore was shipped in 1851-1852. To cut the vein below the old mine workings, the Bureau of Mines diamond-drilled five holes aggregating 2,216.2 feet. The vein, where intercepted by drilling, carried narrow stringers of copper, lead, and zinc minerals.

Jan 1, 1950

By A. B. Hooker, L. C. IlsLey

"The last previous Bureau of Mines publication relative to details of permissible electric mine lamps is Bulletin 332, which describes 16 lamps approved prior to May 1930. Some of the lamps have become obsolete through the development of improved models which, with several new types, make it desirable to supplement the Bureau's published data relative to permissible electric mine lamps.In the following descriptions, lamps approved since May 1930 and prior to July 1, 1935, are placed in the three following groups: (1) Electric cap lamps, (2) electric hand lamps, and (3) lamps for miscellaneous applications,ELECTRIC CAP LAMPS APPROVED UNDER SCHEDULE 6B1. Edison model J lamp, approval no. 24. - The features that distinguish this lamp from earlier models of Edison electric cap lamps are:(a) The battery consists of two F-2 cells of square cross section and about 1-1/4 inches higher than M-14 cells in the model H lamp, making the battery narrower and higher than any of the earlier models of Edison cap lamps.(b) The cells are insulated from each other and the Monel-metal casing by enclosure in vulcanized-rubber baglike enclosures. Both cell terminals are insulated from the cell jar.(c) The battery is equipped with rubber-tube Bunsen-valve-type gas vents.(d) The battery casing is secured by a new-type magnetic lock.(e.) The battery and cover terminal clips have been redesigned to give a wiping contact."

Jun 1, 1936

By Peter K. Mathison

The U.S. Bureau of Mines has developed a hydrologic monitoring system for in situ leaching operations. This system records and displays flow and pressure information from sensors located in leachant injection and recovery wells. Continuous monitoring of hydrologic conditions is important during leaching operations because hydrologic factors such as aquifer permeability, solution injection rates, injection pressure, and solution recovery rates interact and change over time. This hydrologic monitoring system has been tested in an underground setting at the Cyprus Casa Grande copper mine. The system consists of hardware and computer software components and includes two Bureau-developed software applications. This publication describes the implementation of the hydrologic monitoring system and the software developed at the Bureau in support of in situ leaching research.

Jan 1, 1994

By V. Castranova, T-M. Ong, V. Vallyathan, M. J. Keane, W. E. Wallace Jr.

"Inhalation of certain forms of silica, asbestos and some other respirable dusts can result in pulmonary fibrosis, characterized by destruction of the surfaces of alveoli and respiratory bronchioles. Fibrous thickening of the alveolar septa decreases the lung's capacity for gas exchange.Pulmonary macrophage damage by respired dust may initiate the fibrotic response.In one proposed mechanism, dust particles interact with the plasma membrane of a macrophage. This damages the cell or induces some hyperactivity of the cell, resulting in excessive release of lysosomal enzymes and reactive forms of oxygen (1). These reactive enzymes or radicals then damage the alveolar surface epithelial cells. A second mechanism has also been pro¬posed (2,3) in which dust damage to the macrophage causes the release of mediator substances which induce pulmonary fibroblast cell proliferation and increased collagen synthesis. This produces fibrous tissue in the terminal air spaces (4,5).Mineral surface interactions with plasma membrane lipoproteins have been proposed as a mechanism of lytic damage of pulmonary cells by silica dust in numerous models (6,7). The significance of dust surface proper¬ties has been further revealed in studies showing significant changes in dust induced cytotoxicity as a function of dust surface crystallinity and organic or inorganic contamination or coating of mineral surfaces (8,9). Such modification of the mineral surface might interfere with surface sites responsible for the toxicity of dusts for pulmonary macrophages, thus interrupting the early stages of the process of fibrosis.In vitro cellular assay systems using erythrocyte hemolysis or the release of macrophage cytosolic or lysosomal enzymes following dust challenge, have been used to analyze the initial mechanism of dust damage to cells. However the ability of these assays to predict the pulmonary disease producing potential of various dusts is imperfect owing to some ""false positive"" results. These assays as performed are therefore questionable models for the initial lesion in pneumoconiosis or silicosis. In particular, kaolin frequently is found to have comparable biological activity to silica quartz in these assays (10,11).Silica and kaolin have distinctly different fibrogenic potentials. Silica is highly fibrogenic, resulting in both acute and chronic silicosis (12). Some epidemiological data and animal experimentation data have indicated that long term exposure to kaolin can result in pneumoconiosis; however, kaolin is relatively benign as compared to silica (13-18). Kaolin is also of interest because it is one of the major mineral inclusions in Eastern U.S. bituminous coals. We have observed that exposing respirable sized native silica or kaolin for two hours to pulmonary macrophages results in a greater enzyme release for kaolin exposures, on a dust mass basis. Exposure of erythrocytes to the dusts also results in greater levels of hemolysis by kaolin for equal mass respirable dust doses. Therefore, these results do not correlate positively with known disease inducing potentials of the two dusts.Characterization of physical and chemical surface properties of dusts involved in occupational exposures, and characterization of the alteration of those surface properties which are likely to occur upon deposition of the dust in the lung, should improve the identification of respiratory disease hazards.Inhaled dust particles deposited in the lower respiratory tract will come in contact with pulmonary surfactant. This surfactant forms a surface film on and emulsion in the liquid hypophase coating of the alveoli and respiratory bronchioles. The primary constituent of this pulmonary surfactant is the lipid diacyl glycerophosphorylcholine, lecithin (19). Because this lipid is also a major component of cell membranes, it is possible that surfactant can interact with mineral dust to alter its Interaction with macrophages and other pulmonary cells and, thus, it"

Jan 1, 1988

By L. L. Brown

As part of the Federal effort to help maintain an adequate supply of fertilizer materials, the Bureau of Mines conducted research to characterize complex low-grade Michigan phosphate materials and to devise methods for recovering fertilizer-grade phosphate concentrates. The rock is from middle Precambrian sedimentary formations in the Marquette Range located in the central part of the Upper Peninsula of Michigan. Occurrence of phosphate-bearing sediments in Precambrian rocks is rare. This deposit, containing 12 to 15 pct P205, is believed to be the richest Precambrian phosphate deposit in the United States. Petrographic examination showed that the conglomeritic rock contains crystalline apatite both in "black pebbles" and in quartz matrix. Attrition scrubbing and sizing tests showed that there is no tendency for phosphate to concentrate in any of the sized fractions. In beneficiation tests, which included grinding to minus 325 mesh followed by phosphate mineral flotation using a fatty acid-fuel oil collector, a phosphate concentrate was obtained that had a grade of 30 pct P205 and a P205 recovery of 72 pct. This concentrate should be suitable for fertilizer manufacture.

Jan 1, 1981

By G. W. Jones

The Bureau of Mines has advocated the use of stenches as warning agents in metal mines and in gas-distribution systems since 1920 A considerable amount of research has been conducted on ethyl mercaptan and other compounds to determine their effectiveness when used for this purpose.4/5/6/7/8/9/10/11/12/13/ Miners are warned of danger by a stench injected, in measured quantity, into a compressed-air line through which it is rapidly carried to the working faces, where it escapes from the compressed-air equipment and imparts a characteristic odor to the air. This method is not applicable to mines where only a limited number of com-pressed-air lines are used, as for example, many coal mines; the ventilation currents available in these mines may be too slow for warning purposes.14/

Jan 1, 1954

By Elizabeth A. Johnson

The vaporization thermodynamics of the aluminum-silicon carbides Al4SiC4 and Al8SiC7 were studied by the Bureau of Mines over the temperature range of approximately 1,500 to 1,700 K. Vapor pressures were measured by a Knudsen effusion-mass spectrometry technique in which powdered samples were effused from graphite crucibles through small orifices. For each compound, a total of six orifice diameters was tested to verify equilibrium within the cell. Aluminum, mass number 27, was the only vapor species detected over the range 4 to 200 amu. Experimental results are based on the following equations for incongruent decomposition: A14SiC4(cr) - 4A1(g) + SiC(a,hex) + 3C(gr); Al8SiC7(cr) - 8A1(g) + SiC(a,hex) + 6C(gr). The observed vapor pressure-temperature relationships determined with a cell orifice area of 2.0 x 10-3 cm2 for Al4SiC4 and 1.81 x 10-3 cm2 for A18SiC7 are the following: Log P - (-18,682/T) + 12.476, for Al4SiC4 (1,550 to 1,643 K) and Log P = (-19,308/T) + 12.421, for Al8SiC7 (1,526 to 1,784 K), with P in pascals and T in kelvins. Third-law analysis of the data provided the following heats of formation: A14SiC4 ?H at 298.15 K - -50.0 kcal/mol and A18SiC7 ?H at 298.15 K - -92.1 kcal/mol.

Jan 1, 2011

By J. A. Eisele

The Bureau of Mines has reviewed the literature related to the recovery of A1203 (alumina) from coal ash. A small amount of unpublished data is also reported. Of the processes studied, the alkaline-sinter process is the most promising from a technical standpoint. However, owing to the high cost of processing coal ash, the dispersed location of powerplants, and the domestic availability of higher grade alternate materials, coal ash does not rank as a primary source material for replacing imported bauxite.

Jan 1, 1979

By I. L. Nichols, K. C. Dean, P. H. Johnson

Hydrochloric acid , sulfuric acid , and chloridizing roast- water leaching methods for dissolution of cesium and rubidium from Maine , Canada , and Southern Rhodesia pollucite ores and their flotation products were investigated by small- scale tests . Optimum conditions were determined to be ( 1 ) for hydrochloric acid leaching , use 12.7 equivalents of 8.8 normal acid per equivalent of cesium in the sample and leach for 6 hours at 100 ° C ; ( 2 ) for sulfuric acid leaching , use 12.7 equivalents of 14.4 normal acid and leach for 2 hours at 120° C ; and (3 ) for chloridizing roast - water leaching , roast minus 200 - mesh ore, limestone , and calcium chloride in a ratio of 2 : 4 : 1 , respectively , for 1 hour at 900 ° C , and leach the calcine for 1 hour at 80 ° C with enough water to give 35 pct solids . Extractions of cesium from ores and flotation products containing over 20 pct cesium were in excess of 97 , 93 , and 96 pct for the hydrochloric acid , sulfuric acid , and chloridizing roast - water leach processes , respectively .

Jan 1, 1964