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By D. C. Seidel, W. K. Tolley

Supercritical water alters the structure of common sulfide minerals by partially removing sulfur from the mineral structure. This discovery has been applied to the treatment of pyritic gold ores to improve precious metal recovery without generating or utilizing environmentally sensitive products such as S02, chlorine, or cyanide. Pretreating pyrite concentrates in supercritical water under mildly oxidizing conditions provided by certain metal oxides or oxygen improved gold leaching using thiourea. The pretreatment differs from chlorination or roast pretreatments in that elemental sulfur rather than sulfuric acid is the major product. A pyritic ore containing 58 g/mt Au was pretreated with oxygenated supercritical water at 24 MPa and 400°C, then leached with 20 g/L thiourea. With pretreatment, gold recovery was 90%; by contrast, gold recovery was below 10% without pretreatment.

Jan 1, 1990

By J. A. Brierley, C. L. Brierley

The history, current applications and future of biotechnical developments in the metals' extraction industry are reviewed. Bioleaching of copper minerals continues to be the most significant application. Uranium bioleaching was successfully demonstrated at industrial scale. Developments are now being made in biooxidative pretreatment of refractory gold concentrates, ores and low-grade materials. Advancements are forthcoming in water and solid mine waste bioreclamation, including metals' biosorption, wetland treatment of acid mine drainage, and biodegradation of cyanide in spent, heap-leach operations. Better understanding of the types and functions of microorganisms involved in metal interactions could advance genetic engineering applications in bioleaching and bioreclamation.

Jan 1, 1993

By Monica Pavlik, Thomas Wildeman

Water from the Forest Queen mine adit near Silverton, Colorado drains into a natural wetland. Because the pH of the water averages 5 and the iron concentration averages 18 mg/L, it was thought that the wetland might naturally treat the water. Of most concern with respect to the aquatic environment is zinc whose concentration averages 0.60 mg/L. Starting in October 1997, the surface waters, ground waters in the peat substrate, and the sediments in the wetland were sampled and analyzed four times over the course of four months. The adit water primarily remains as surface water where Fe, minor amounts of Al, and no Zn are removed. After the adit water enters the peat, then it is found that the pH rises to 5.8-6.5 and sulfate is reduced. The removal of Zn and A1 is caused by these two changes. However, Fe in its reduced state is quite soluble and may be remobilized in the reduced environment of the peat.

Jan 1, 2000

By Arpad E. Torma

The introduction of biotechnological principles in hydrometallurgy has created new opportunities and challenges for the industry of mineral processing. During the 1950's and 608s, the mining wastes and unused complex mineral resources have been successfully treated in bacterial assisted heap and dump leaching processes, especially for the production of copper and uranium. The economic viability of bio- leaching technology lead to its world-wide acceptance by the mining industries. During the 1970's this technology grew into a more structured discipline which is called "biohydrometallurgy". Currently, bioleaching techniques are ready to be used, in addition to copper and uranium, for the extraction of cobalt, nickel, zinc, gold and silver from diverse mineral resources and for the desulfurization of certain coals. However, in a foreseeable future the biohydrometallurgical processes may be applied also for the treatment of high- grade ores and mineral concentrates using native and/or genetically engineered microorganisms.

Jan 1, 1989

By S. K. Kawatra, S. J. Ripke

Iron ore pellets use bentonite clay as binder at dosages from 0.5to 1.0% (10 to 20 pounds per ton) of moist iron ore concentrate. Bentonite is typically shipped hundreds of miles from Wyoming to the Lake Superior iron ore district. It is therefore best to know how effective a bentonite will be before it is shipped and used to bind concentrate into pellets. Current tests of bentonite effectiveness include: plate water absorption, methylene blue uptake, free swell, exchangeable cations, and glycolated layer expansion. However, these tests have many disadvantages: First, they only measure the ability of a bentonite to expand, disperse, or absorb, not how well it will bond. Second, most of the tests require up to 20 hours to perform. Bentonite only has a few minutes to interact within the concentrate before it is indurated (sintered). These long-term tests may not reflect the true behavior of bentonite. Third, the tests are tedious and often results are inconsistent between different iron ore concentrates, labs, and technicians. Fourth, some of the testing equipment is difficult to procure. Fifth, procedures are often difficult to standardize. In this paper, the Binder Effectiveness Strength (BESt) test to evaluate binders for iron ore pellets is presented that: measures the ability of bentonite to bond, requires only about two hours to complete, is simple and reproducible, and utilizes readily available equipment that has been standardized for decades.

Jan 1, 2003

By Thomas C. Wilder, Firoze E. Katrak

As part of a survey on the long range supply of gallium, a comprehensive review of the chemistry of commercial gallium extraction was undertaken Owing to its very small concentration in all commercial minerals, gallium can be produced economically only as a by-product of major extraction processes for other materials. A summary is presented for the chemistry of gallium extraction from many of these process streams included are several procedures for gallium recovery from bauxite, currently the most prevalent source Other processes described are from waste streams from the production of zinc, phosphorus from phosphates, aluminum from kaolin clays, and from coal ash, the largest potential resource A brief review of development of solvent extraction as a unit process for gallium recovery is also presented

Jan 1, 1983

By N. Choi, W. D. Cho

Distribution coefficients of gold and silver between matte and slag during the pyrometallurgical treatment of nickel-copper sulfide concentrates were evaluated as a function of matte and slag compositions in the temperature range of 1,250oC to 1,300oC. It was observed that the composition of the matte phase, including matte grade and copper content in the matte, significantly affected the distribution behavior of gold and silver in the matte-slag system. Both gold and silver preferentially concentrated in the matte phase as the matte grade increased With increasing temperature and copper content in the matte, the distribution coefficients of silver increased, while the gold distribution coefficients decreased. It was also, found that slag additives such as CaO, MgO, and A12O3 caused a significant decrease in the solubility of both gold and silver in silica-saturated iron silicate slag. An activity coefficient of gold in matte was derived from the experimenta1 results.

Jan 1, 1999

By Robert A. Jankowski, John J. McClelland, Charles Babbitt

The purpose of this study was to develop guidelines to enable mine operators to maximize longwall dust reductions, while optimizing the use of ventilating air and shearer water consumption. A recent investigation by Foster-Miller Incorporated, under a Bureau of Mines contract, quantified the effect of increased face airflow and shearer water supply on face dust concentrations. A 70 pct reduction in respirable dust levels was achieved at the shearer operator's position during tail-to-head cutting by an incremental increase in average face air velocity from 83.8 m/min (275 fpm) to 123.4 m/min (405 fpm), while holding shearer water consumption constant. A 60 pct reduction was achieved through an increase in shearer water pressure and flow from 9.1 kg/cm2 (130 psi) at 0.19 m3/min (50 gpm) to 19.7 kg/cm2 (280 psi) at 0.28 m3/min (75 gpm), holding airflow constant. The combined effects of increasing both parameters produced an 85 pct reduction. Optimal usage of ventilating air and shearer water consumption can be achieved by defining a "point of diminishing returns" above which further increases no longer reduce dust concentrations, proportionately .

Jan 1, 1987

By L. G. Sobral, J. E. Hoffman, T. J. Keefe, A. J. Monhemius, O&apos

The kinetics of electrodeposition of gold from dilute solutions of alkaline KAu(CN)2 at different gold and free cyanide concentrations on a gold rotating disk electrode were investigated by use of a steady-state linear potential scan technique. The design and performance of a laboratory electrowinning cell with a reticulated nickel cathode, operating in the flow-through mode, for the removal of low levels of gold ions from aqueous cyanide media is described. During the batch recirculation of oxygen-free gold cyanide solutions, the gold concentration was reduced from 10 ppm to <0.5 ppm with current efficiencies of up to 80%. The influence of solution flow rate through the cathode and of the pore size of the reticulated nickel foam is discussed. The removal of gold ions from solutions of low ionic strength was also investigated.

Jan 1, 1993

By Richard R. Klimpel

The author was the banquet speaker at the 48th Annual MPD meeting, sponsored by the SME Colorado Minerals Processing Section, May 14-16, 1998, in Colorado Springs, CO. Here are his remarks. It has been an exciting experience to have spent 34 years involved with the process of generating patented technology eventually leading to commercialization. In today&apos;s terminology, this process is called technology transfer. I have had the unusual experience of being involved doing basic research as an inventor while also being responsible for managing new product development and commercialization. In addition, I worked for 31 years before my retirement for a large research-oriented company, The Dow Chemical Co. In 1995, the company spent more than $1 billion dollars on research and development. The last three years of my career have been spent working with a research-oriented university, The University of Florida. And I have worked as a consultant helping several companies to optimize their products and processes. It is on this cumulative experience base that the preparation of this article is based.

Jan 1, 1998

By Zhang Dekuan, Wang Haifeng, Yi Weiping, Wan Liping, Yu Yunzhen

The fundamentals of domain knowledge, knowledge base building, system structure, principle of inference mechanism, function of explanation mechanism, application analysis on Expert System of In-situ Leaching of Uranium (ESILU) are described, especially the Dempster/Shafer theory on inexact reasoning, which was used in ESILU, is detailed discussed. The application of in-situ leaching for abstraction of uranium and the analysis of parameters required for evaluation of uranium deposit. the procedure of evaluation of uranium dewsit for the purpose of in-situ leaching as well as the concept related were introduced. For building knowledge base, discussion is emphasized on production rule, which wasused in ESILU, on representation of rules and facts and application as well. From the system menu provided in the paper, the readers will, in a certain content, under- stand the functions of system structure and the way to set up. Several paragraphs are written concentrated on the procedure of backward reasoning and the principle of inference mechanisms combined with knowledge bases. Tracing interpretation and acquisition of knowledge with interactive method, which the system flexibility is considerably strengthened, are the main specific features of ESILU.

Jan 1, 1996

By P. D. Rao, D. E. Walsh, W. W. McClintock

A column flotation system was designed to conduct release analyses on a very finely disseminated, stratiform copper ore from the Denali Copper Prospect in Alaska. Chalcopyrite is finely disseminated in a carbonate matrix, and pyrite is disseminated in both the chalcopyrite and the gangue. Grinding to -20 µm is required for adequate liberation. A 25-mm x 2.4-m glass flotation column was designed. The ore and its flotation tailings were repeatedly floated to obtain a rougher concentrate. The rougher concentrate was then repeatedly floated to produce release fractions. These fractions were analyzed for copper, iron, calcium and magnesium, and release curves were plotted. The procedure was replicated at each of two grinds, i.e., 99% and 88% passing 37 µm (400 mesh). The procedure should find application for flotation characterization and process selection. Bond grindability testing was also conducted.

Jan 1, 1996

By Tad S. Golosinsk

Use of computers for hoist evaluation and design dates back to the early 1960&apos;s. Mine hoist production calculations, repetitive in nature, were computerized first. More elaborate modeling of hoist operations followed soon. Typical for this, early period are the models described by Touwen (1973), and by Albert and McIvor (1984). Apart from the simple hoist production calculations, the models were very complex, typically written in Fortran, and often required advanced computing facilities and expertise to run the simulation. The early models were strictly deterministic, with no consideration given to the random nature of hoisting operations. The effects of randomness of the hoisting process on hoist performance were often accounted for by introduction of the deterministic factors, most notably of an "utilization factor" related to the hoist production. The value of the latter was based on observations of actual hoist performance, and could vary in a wide range. For example Harvey (1973) reports values of the "utilization factor" to be between 0.7 and 0.92.

Jan 1, 1989

By O. A. Bascur

In recent years, metal-producing companies have increased their investment in automation and technological innovation, embracing new opportunities to enable transformational change. Transformation to a digital plant can fundamentally revolutionize how industrial complexes operate. The abundant and growing quantity of real-time data and events collected in the grinding and flotation circuits in a mineral processing plant can be used to solve operational issues and optimize plant performance. A grade recovery model is used to identify the best operating conditions in real time. A strategy for increasing the value of instrumentation in current plants is reviewed. An optimal Gaudin size distribution model provides augmented information from traditional sensors to find the optimal grind cut size to reduce metal losses in the flotation circuits. Sensors in flotation circuits enable an estimate of the recovery and determination of the optimal froth depth and aeration using an air hold up flotation model. A strategy of classifying data for online generation of insights to using operational intelligence tools is described. The implementation of a recovery/grind strategy with industrial examples in nonferrous mineral processing is presented.

By K. A. Natarajan, J. M. Modak, B. Saha

Nonliving waste biomass consisting of Aspergillus niger attached to wheat bran was used as a biosorbent for the removal of copper and zinc from aqueous solutions. Copper and zinc uptake by the biomass obeyed Langmuir isotherms. The binding capacity of the biomass for copper was found to be higher than that for zinc. The metal uptake, expressed in milligrams per grain of biomass, was found to be a function of: •the initial metal concentration (with the uptake decreasing with increasing initial concentration), •the biomass loading (with the uptake decreasing with increasing biomass loading) and •pH (with the uptake increasing with increasing pH in the range of L5 and 6.0). The metal uptake was significantly affected in the presence of a co-ion. The uptake of copper by the biomass decreased in the presence of zinc and vice versa. The decrease in metal uptake was dependent on the concentrations of metals in the two-component aqueous solutions. The effect of copper on zinc uptake was more pronounced than the effect of zinc on copper uptake.

Jan 1, 1997

By Lijun Xu, Ragula Bhaskar

The transport of dust particles from a turbulent air stream on to the surface of a mine entry is mainly due to the effect of diffusion, sedimentation and inertial impaction. While the literature in aerosol science contains many references on particle deposition, most studies apply to smooth surfaces in small, short tubes. The deposition data from those experiments may not be applicable to deposition in mine airways that have large areas of rough surfaces and extend several thousand meters. This paper describes the mechanisms of mine dust transportation and deposition, specifically, by estimating the turbulent deposition velocity for coal dust in mine airways. Data from in-mine experiments on ambient dust concentration and dust deposition along a straight entry were used. A statistical model for dimensionless turbulent deposition velocity was developed, and compared with the models developed by other researchers. The model shows that the distance from the dust source is an important factor in the turbulent deposition of mine dust.

Jan 1, 1995

By M. W. Rutland, E. Manev, R. J. Pugh

Data collected from several different fundamental surface chemical techniques were compared to study the interfacial interactions in the dodecylaminelmica flotation system. In the present study, the method used was the microinterferometric free foam film technique of Scheludko (1967) in which the stability, thickness and interfacial potentials at the air/dodecylamine solution interface were determined. These results were compared to previously published data, obtained from surface force measurements (Rutland et al. 1992), in which the interaction and hydrophobic adhesion (pull-off force) between molecularly smooth mica sheets in the amine solution had been reported. Also equilibrium contact angle measurements were used for comparison. The data was collected over a range of pH values and related to the batch flotation response of mica in dodecylamine solution. It was found that maximum flotation occurred at pH 8, but this did not correlate with the minimum in double layer interaction potential. However, it appeared to correspond with a tightly packed collector monolayer giving maximum hydrophobicity to the mica surface. Finally, from the extended DLVO theory, it was shown that heterocoagulation between the bubble and the mica could only occur, providing there was a very long range hydrophobic interaction force to counterbalance the repulsive van der Waals and electrostatic forces.

Jan 1, 1995

By J. M. Mutmansky

The objective of this study was to produce coal dusts for laboratory research that are similar to mine airborne dusts in chemical, mineral, and physical characteristics. In this investigation, dusts produced in laboratory comminution equipment were compared with continuous-miner-generated dust for similarity in physical characteristics. Mining-generated dust (MGD) and bulk coal samples were first collected from an underground mining operation. The bulk samples were then processed in the laboratory for size reduction in various comminution devices. These laboratory-generated dust (LGD) samples were subjected to size and microscopic analyses. Physical properties of the dust particles were studied on a scanning electron microscope (SEM). A numerical shape coordinate system (SCS) was also developed and applied to 300 particles from each sample. Statistical analysis was then performed on the collected data and characteristics of the MGD and LGD samples were compared.

Jan 1, 1995

By J. A. Herbst, T. I. Martinovic, Y. C. Lo

This study was concerned with the application of a computer simulation methodology to optimize the performance of mills grinding iron ore concentrate prior to pelletizing. The methodology involves batch and plant testing, modeling and computer simulation. The analysis of grinding performance was carried out and capacity increases were predicted in the context of detailed population balance models developed for the plant ball mills. Model developnent and plant confirmation were performed using data obtained in a series of batch tests and three plant tests. From experimental data and computer simulation it was found that ball size, percent solids and classification all had a significant effect on mill throughput. Based on the findings of this study, a 12-152 increase in capacity was predicted to be available by a proper combination of ball size charge and optimum percent solids. These predictions have been confirmed by plant tests in which the recommended operating changes have been made.

Jan 1, 1990

By Flavio Moreira Ferreira

In mining industry, one of the simplest methods to smooth the standard deviation of a given ore controlled property is to build longitudinal blending piles. The effect of homogeneization is obtained due to the fact that an entire cross-section of the pile is reclaimed at each time. The variance of the pile output is the sum of the internal cross-section slice variance plus the reclaimed slice variance. While the first term is a tipical short-term parameter and is absorbed by the process, the second one may be or may not be absorbed. The goal of designing blending piles is to minimize the reclaimed slice variance. Conditional Simulation as described in this paper, is an alternative method to do it. It is devised to design longitudinal blending piles, taking into consideration economical, geometrical and statistical parameters of the ore to be blended, in order to estimate the resulting effect. It presents advantages in relation to other methods for its adaptability and flexibility in simulating pile performances.

Jan 1, 1992