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By Charles P. Lazzara, Alex C. Smith, Mark W. Ryan

The U.S. Bureau of Mines developed an experimental method to evaluate the relative effectiveness of water additives on the extinguishment of coal fires. The experiments were conducted in the fire zone of the multiple entry section of the Bruceton Experimental Mine. Chambers filled with one hundred and eighty kilograms of Pittsburgh seam coal were ignited and allowed to burn until well developed fires were achieved. Extinguishing agent-water solutions were then applied to the fires and the quantity required to extinguish the fires compared to the amount of water alone required to extinguish similar fires. A 20% diammonium phosphate-water solution required an average of 22 L to extinguish the coal fires, while two commercially available additive-water solutions required an average of 30.6 and 30.3 L, respectively. The average amount of water required to extinguish the fires was 28 L. An analysis of covariance, using the thermal energy of the coalbed, Q, to quantify the fire at the time of extinguishment, showed that the diammonium phosphate-water solution was slightly more effective at extinguishing these coal fires than water alone, while the two commercially available additive-water solutions were statistically equivalent to water alone.

Jan 1, 1992

By Richard H. Gates

INTRODUCTION The U. S. Army Corps of Engineers is developing chemical explosive excavation as a construction technique for use on Civil Works projects. Large chemical charges are being used in multiple charge arrays in a variety of media and topographic situations to achieve actual construction projects. The target is the development of chemical and nuclear explosive excavation as an accepted cost-competitive construction technique. Military research using explosive excavation is also being conducted to apply this technique to military engineering for combat purposes and to military construction. The information gained from both the civil and military research is integrated into the overall development of explosive excavation. This research and development work is being conducted under the auspices of the U. S. Army Engineer Waterways Experiment Station Explosive Excavation Research Laboratory (EERL) located at Livermore, California. This organization was formed in 1962 as the Nuclear Cratering Group (NCG) to carry out the Corps of Engineers (OCE) portion of a joint agreement with the Atomic Energy Commission (AEC) to develop nuclear explosives for construction purposes. The AEC, through the Plowshare Division of the Lawrence Livermore Laboratory at Livermore, California, has been responsible for developing nuclear explosives, conducting nuclear cratering experiments, developing nuclear safety information, and developing methods for predicting the shape of the craters. The Army part of the program includes corollary chemical high-explosive cratering experiments, participation in the AEC's nuclear cratering experiments, and development of

Jan 1, 1997

By P. E. Richardson, N. P. Finkelstein, Z. Chen

The large band gap and insulating properties of sphalerite have limited the application of standard electrochemical techniques for studying its reactions with flotation reagents. This problem has been overcome by developing electrodes that rely on the surface conductance produced when sphalerite is activated with copper or other heavy metals. A brief exposure of the mineral in copper sulfate solutions results in electrodes that exhibit significant electrochemical activity characteristic of copper sulfides. Voltammetry studies conducted on sphalerite activated in 10-4 M CuS04, solutions at pH 4.6 provide information on both the amount and the nature of the activation product(s). It is shown that copper activation is strongly dependent on the electrochemical potential applied during activation. Activation at potentials increasingly negative of the rest potential causes a progressive increase in the amount of copper on the surface; activation at potentials positive of the rest potential decreases the amount of copper on the surface. The results indicate that both the kinetics of copper uptake and, possibly, the chemical composition (stoichiometry) of the activation product are controlled by the electrochemical potential.

Jan 1, 1995

By W. K. O’Connor, J. C. White, P. C. Turner

The US Bureau of Mines is investigating the cobalt and manganese resource of the West-Central Arkansas district through field investigations, mineralogical characterization, beneficiation and hydrometallurgical tests. Located within the Ouachita Mountains, these structurally-controlled deposits occur along the axes of anticlines that form the mountain ridges. Brecciated novaculite is cemented with a mixture of manganese oxides, primarily cryptomelane and psilomelane. Cobalt is concentrated within lithiophorite, a particular Mnoxide phase. Chemical analyses of head samples reported up to 25% Mn and 0.17% Co. Magnetic separation yielded products containing up to 41 % Mn and 0.22% Co at recoveries of 95% and 93%, respectively.

Jan 1, 1993

By D. S. Young

The random variable transformation technique was introduced to make probabilistic structural analysis simple for such structures as slopes, dams, foundations, or retaining walls, where two shear strength parameters are required to analyze their stability by deterministic engineering methods. The Gaussian transformation was performed by using the Hermite orthogonal polynomial function. This transforms the experimental histogram into the standard normal distribution, whose mean is zero with a variance of one. Then, the transformed standard Gaussian variable was used for the bivariate normal probability analysis on the structure. The Gaussian transformation technique and the Hermite polynomial functions were chosen because the bivariate joint normal distribution is well-known and easily available for engineers. The binormal probability analysis was made on the probability region of a certain confidence level by superposing the critical line on the same probability region that divides the region into two zones: stable and unstable zones. The critical line was determined from the back calculation of the deterministic engineering method of the structural design. Finally, the probability of structural failure at a desired confidence level was calculated by simply integrating the volume of the binormal density surface above the unstable zone in the probability region. A simple case of slope analysis is introduced to illustrate this probabilistic approach, and its effectiveness and simplicity is demonstrated.

Jan 1, 1987

By J. A. Organiscak

Data on dust-control practices, mining conditions and occupational exposures were gathered for approximately 80 underground continuous mining units. Despite silica contents on dust samples in excess of 5%, nearly forty units successfully maintained silica concentrations at or below 100 µg/m3 on a majority of occupational dust samples, while the remainder had difficulty maintaining this level. These two sample sets were termed Group A operations and Group B operations, respectively. This data was compared to identify causes of high occupational silica dust exposures. Analyses of dust-control parameters and geologies revealed only minor differences between these two groups. However, subsequent comparisons of face ventilation design showed considerable differences in silica exposure and silica content between Group A and Group B at the continuous mining machine and roof bolter operator occupations. These differences were minimal when using exhaust curtain ventilation with a dust scrubber. This face ventilation system can benefit operations having difficulty controlling silica dust exposure and silica dust content. The collected data also showed that occupational samples from Group B operations possessed generally higher silica exposures and silica content than similar samples from Group A. The single head roof bolter (helper) possessed among the highest silica exposures and silica contents in both groups.

Jan 1, 2002

By A. A. Odunaike, E. G. Okafor, M. H. Mokwe

Microscopic Studies were performed on ore samples from the Muro banded iron ore deposit in Nigeria and the Marampa iron ore deposit in Sierra Leone. Ore characteristics that affect processing of both ores were compared with a view toward assisting mineral processing engineers in choosing the most suitable methods for upgrading the ore. The Nigerian ore contains 30% to 37% (by weight) Fe and the Sierra Leonean ore contains 34% to 51% (by weight) Fe. Hematite is the main iron mineral in both ores. The Sierra Leonean ore is relatively coarse grained (typically around 250 µm) and can be upgraded by conventional gravitational methods. In contrast, the Nigerian iron ore is fine grained and must be ground to -74 µm to liberate the hematite for recovery by flotation. Both ores contain high percentages of phosphorus and sulfur, which are above the required specifications for direct reduction and blast-furnace practice. These deleterious elements can be rejected by grinding and flotation.

Jan 1, 1999

By R. M. Balderrama

Bench-scale laboratory flotation and gravity separation tests were conducted on tailings samples to remove the sulfidic material, mainly pyrite, the source of acid generation. A combination of xanthate collectors, promoters, and frothers were used during flotation. Pyrite recoveries were in the range of 42 to 97%, depending on the tailings being treated. Sulfide sulfur contents of 12.8 to 0.37% in the feeds were reduced to 8.68 to 0.01% in the treated tails. Flotation tests were conducted to evaluate the ARD potential as a function of percent pyrite remaining in the tails. Standard ARD predictive tests were used to evaluate the success of the treatment. In some cases, removal of only 50 to 55% of the pyritic fraction was required, thereby demonstrating the conversion of the waste material from acidic to non-acidic. A laboratory vanning table was used to evaluate the amenability of sulfide-bearing tailings samples to gravity separation. The pyrite recoveries varied from 38 to 86%. The sulfide sulfur content of 12.8 to 0.37% in the feeds was reduced to 6.0 to 0.14% in the treated tails. Predictive ARD tests performed on tailings before and after the gravity removal of pyrite showed that most samples changed from "probably" acid producing to the "uncertain" range. Data reported and analyzed in this paper demonstrate source control for ARD prevention through the removal of metal sulfides from sulfide-bearing wastes using conventional flotation and gravity separation techniques.

Jan 1, 1995

By S. Chander

Neutralization of acidity by addition of alkaline materials is a commonly used method to treat acid mine drainage. However, this procedure requires large amounts of reagents based on acid-base accounting. The potential use of organic additives in preventing or ameliorating acid mine drainage was investigated in this research. The tests were conducted in weathering columns using refuse samples from a coal cleaning plant. Both cationic and anionic compounds were tested. For a comparison, tests were made in the presence of limestone and lime. The results show that some of the reagents substantially retarded the rate of oxidation whereas others even enhanced it. The suppression of the rate of pyrite oxidation was ascribed to surface chelation. Formation of surface compounds prevented the pyrite particles from further oxidation. Such a treatment required only small quantities of reagents since the reaction was confined to the surface.

Jan 1, 1992

By 1980, the US mining community had reached a broad consensus regarding coal pillar design. The pillar load could be estimated from tributary area theory, and the pillar strength could be estimated from empirical formulas and laboratory coal strength testing. Then the growth of longwall mining required new thinking. Recently, powerful design methods have emerged from analysis of large databases of real-world pillar successes and failures. These include the analysis of retreat mining pillar stability (ARMPS), the analysis of longwall pillar stability (ALPS), the Mark-Bieniawski rectan¬gular pillar strength formula and guidelines for preventing massive pillar collapses. Sophisticated numerical models have also helped transform the pillar design landscape. In the process, the understanding of pillar mechanics has been greatly enriched. A new paradigm identifies three categories of pillars according to the types of failure that are associated with them. These categories are slender pillars (w/h < 3.0), which are subject to sudden collapse; intermediate pillars, in which pillar squeezes seem to be the most common failure mode; and squat pillars (w/h > 10), which are dominated by entry failure (rib, roof or floor) and coal bumps.

Jan 1, 2000

By D. R. Spears, D. A. Stanley

The US Bureau of Mines investigated the fundamental aspects of shear-flocculation using a rapid, in-situ particle size analyzer. Silica was stirred in the presence of an aliphatic amine to determine the effects of collector coverage, stirring speed and solids concentration on the kinetics of shear-flocculation. The results showed that shear flocculation is a two-stage process. In the first stage, which occurs during the first 1-2 min. of the reaction, the mean particle size increases rapidly, and in the second stage, an equilibrium is set up between the rates of floc growth and floc decay. Collector dosage affected the position of the equilibrium by altering the number of surface sites for particle-particle attachment. A minimum stirring speed was necessary for shear flocculation, which was dependent on solids concentration and collector dosage. This stirring speed was the minimum necessary for particles to overcome the electrostatic energy barrier, and that results in keeping the conditioned particles dispersed. Larger particles flocculated more rapidly. At very high stirring speeds, large flocs became unstable, resulting in a narrowed particle size distribution in the slurry.

Jan 1, 1995

By Y. C. Kim

One aspect of long-range mine planning in an open-pit mine is first to define the ultimate pit limit, i.e., the projected size and shape of the pit at the end of its life. This chapter is concerned with various techniques that are currently in use today in determining the ultimate pit limits using the computer. Prior to the early 1960&apos;s, open-pit limits analyses were entirely performed manually. This manual technique has been well explained by Soderberg and Rausch in Surface Mining (1968). Soderberg and Rausch also explain clearly the need for establishing the ultimate pit limits in long-range mine planning, i.e., location of surface facilities, dumps, etc. Consequently, the need for ultimate pit limit design will not be reiterated here. Nor will the definitions of the most commonly accepted terminologies such as break-even stripping ratio, economic cutoff grade, ultimate and working slope angles, preproduction stripping, etc. be repeated here. Briefly, the objective of the ultimate pit limit design (which is also frequently referred to as pit design in short) is to determine the projected final pit limits of an ore body and its associated projected grade and tonnage, which will maximize some prespecified economic criteria while satisfying practical operational requirements.

Jan 1, 1979

By R. L. Garrett

The quality of mineral additives used in a drilling fluid (mud) can dramatically affect the fluid&apos;s properties and the overall cost of drilling an oil or gas well. The principally wed minerals are bentonite, barite, barite/hematite blends, and hematite alone. The high specific gravity minerals, barite and hematite, are used to increase drilling fluid density. Bentonite clay is used to increase drilling fluid viscosity and gel strength and to provide a low permeability filter cake. A multimillion dollar investment in a well and the safety of the personnel on the drilling rig can depend on how effectively these mud additives perform with other constituents in the mud. This paper points out effects caused by small amounts of certain carbonate and sulfide mineral impurities in barite or hematite and how polymeric extender additives in bentonites contribute to unpredictable behavior of a mud. Effects like these are the reason oil companies using these materials sometimes set their own quality standards beyond those already specified in APZ Spec. 13A. Also discussed in this paper are the current standardization activities of API Committee 13 on these minerals.

Jan 1, 1988

By K. G. Sutterer, P. T. Wang, R. Sweigard

One possible alternative for the disposal of flue gas desulfurization (FGD) by-products is to use it as backfilling support material in highwall mine adits. The finite element method was used to analyze the variation in stresses and displacements within and around a highwall adit backfilled with FGD materials. The engineering properties of the rock material and the optimum mix of the FGD materials were obtained from laboratory tests. Finite element analyses show that, for the case in question, the roof displacement would decrease about 48% and the peak stress could be decreased by about 58%. The study indicates that fairly weak FGD materials can eventually lead to the stability of backfilled highwall adits.

Jan 1, 1998

By E. J. Beckman, R. M. Enick, C. Powell

Liquid carbon dioxide can be used as a replacement for organic solvents in the extraction of anionic platinum group metal complexes from an aqueous phase. However, because conventional extractant-metal complexes are not soluble in liquid carbon dioxide, this can be achieved only if highly carbon dioxide-soluble extractants are developed. For example, trioctylamine-gold chloride is not soluble in liquid carbon dioxide, although trioctylamine is CO2 soluble. The novel CO2-soluble extractants presented in this paper have a CO2-philic fluorinated tail to enhance solubility and a conventional amine head group for extraction of metals. Both the extractant and the extractant-metal complex are soluble at ambient temperature at pressures from 7 to 35 MPa. Efficiency factors as high as 2.23 have been measured using 1,1,2-trichlorotrifluoroethane (TCTFE), a low pressure screening liquid for carbon dioxide, indicating that these compounds will strongly bind the metal chloride. For example, 84% of Pt-chloride was extracted into TCTFE using a 3.5:1 ratio of a double¬tailed fluoroalkyl amine extractant: metal chloride. An 88% recovery of Pt-chloride into high-pressure liquid carbon dioxide was achieved using the same extractant at a 3.5:1 ratio. Therefore, it appears possible to replace organic solvents with liquid carbon dioxide during the extraction of platinum chlorides if highly carbon dioxide-soluble extractants agents are employed.

Jan 1, 2002

By James S. Goff, Stephen J. Navin, Wesley W. Moulton

The White River Shale Oil Corporation (WRSOC) is developing a prototype oil shale facility on Federal Lease Tracts Ua and Ub located in northeastern Utah. This paper covers the successful driving of 1,525 m (5,000 ft) of dogleg downgrade decline with a 70-ton Paurat Roadheader mining machine and a conveyor muck-handling system. Ground support is with rock bolt and shotcrete; welded wire mesh is optional. The Upper Decline of 3.89 m by 8.69 m (12.75 ft by 28.5 ft) was mined through the Uinta Formation sandstones and shales in 210 days. The sandstones have a compressive strength in the 48 MPa (7,000 psi) range with a few bands of shale up to 137.8 MPa (20,000 psi). Green River Formation dolomitic marlstone with some sandstone lenses was mined in the Lower Decline 3.89 m by 5.64 m (12.75 ft by 18.5 ft) in 175 days. The Green River marlstones are tough massive formations ranging up to 206.8 MPa (30,000 psi). Roadheaders for use on steep slopes must be modified to accommodate the particular problems associated with mining downdip. The paper concentrates on the application of Roadheaders to steep slopes and the problems of mining tough materials such as marlstone. The paper also shows the advantage of using the method of excavation on long drives.

Jan 1, 1985

By S. K. Kawatra, T. C. Eisele

Coal-cleaning operations commonly produce a fine-waste stream containing a considerable amount of coal. The recovery of this coal is normally not economical because the coal is mixed with large amounts of difficult-to remove clay slimes and is often heavily oxidized or contaminated. Conventional froth-flotation machines cannot, in a single flotation stage, produce an acceptable product from such material, and even flotation columns often have difficulty cleaning this type of feed. A new type of flotation column was designed specifically to deal with these problems, and a column of this design was installed and tested in a coal-cleaning plant in Ohio. The feed coal tested was the plant&apos;s tailings-thickener product. The coal was 80% -176 µm and had a heating value of 8401 Btu/ lb. The coal contained 39.8% ash, as fine clay, and 2.83% total sulfur. Because previous attempts at conventional flotation of this type of material had been abandoned, plant personnel believed that the coal was too heavily oxidized and contaminated for flotation to be effective. However, by using the new column it was possible to recover up to 85% of the calorific value in a product containing < 11 % ash, and it was possible to recover 60% of the calorific value in a product containing <8% ash. In addition, the bulk of the pyritic sulfur was also rejected from the coat.

Jan 1, 1996

By P. Somasundaran, S. E. El-Mofty

A comparison of the IMC Anionic Process and the CLDRI Process, based on pilot plant testing of waste pebble by Jacobs Engineering is presented. Estimated costs for constructing and operating a beneficiation plant utilizing dolomite flotation are given. Research to develop practical flotation processes for removing dolomite from low-grade phosphate rock has been a high priority for the Florida Institute of Phosphate Research. The Institute funded the above pilot plant programs in 1998 and 2000. The Florida Phosphate industry currently deals with the increasing dolomite content of ore reserves by practicing selective mining. Heavy media separation plants installed at two mines to remove dolomite from pebble are not being operated. The flotation separation of dolomite from waste pebble requires that the flotation feed be ground. Grinding liberates the mineral species and produces particle sizes small enough to be floated. Only two dolomite flotation processes, the IMC Anionic Process and the CLDRI Process, have been successfully demonstrated on flotation feed that has not been deslimed after grinding. Deslimed flotation feed, relative to undeslimed feed, has improved flotation performance and reduced reagent consumption. However, for the above mention processes, undeslimed ground feed increases the yield of concentrate because the phosphate desliming losses are avoided.

Jan 1, 2002

By L. W. Saperstein

In this paper, a number of novel hypotheses that provide a fresh perspective on the characterization of strata movements associated with longwall mining are developed by analyzing subsidence measurements with an influence-function-based computer program. Using an inverse application of the traditional influence-function technique, easily obtained surface displacements are used to analyze some of the complicated, expensive, and difficult-to- measure movements of the intermediate roof strata in a longwall panel. The primary hypothesis developed by this analysis proposes the existence of an area of partial roof caving near the edge of a panel called the "edge effect." A secondary hypothesis, interrelated with the first, promotes the importance of the effect of gate-entry closure on the observed strata movements. Both the primary edge-effect hypothesis and the secondary hypothesis concerning gate-entry closure are justified and quantified in an extensive analysis of surface subsidence that uses supporting information from related theories, design criteria, and in situ measurements. Next, the edge effect and the gate closure hypotheses are extended further and used to provide an explanation of the complex subsidence interaction of adjacent longwall panels in what is termed a "redisturbed" effect. Finally, the importance of accurately understanding these longwall strata movements for proper subsidence prediction or gate design is stressed.

Jan 1, 1988

By Marvin Barnes

The Sacaton mine is a relatively new open¬pit copper mine owned by Asarco, Inc., which has been in production only a few years. The mineral deposits consist of two ore zones; a western, near-surface zone minable by open-pit methods, and a deeper eastern zone which will have to be mined underground, probably by block caving. The copper deposits are related to small quartz monzonite intrusives implaced into Precambrian granites. Both rock types act as hosts for the copper mineralization, which has been secondarily enriched sufficiently to constitute ore. In the western zone the enriched supergene chalcocite has been subjected to postenrichment oxidation processes with partial destruction of the chalcocite blanket. The deeper eastern chalcocite zone has not been as severely affected by later supergene processes. Several mineralogical populations are represented in the total copper deposit. Leached capping overlies the chalcocite enriched zone, and in the western ore body there is a very irregular interface between the leached and enriched zone, which is complicated by oxide copper minerals irregularly distributed. Primary lower-grade chalcopyrite mineralization occurs below the enriched zone. When mining commenced near the top of the enriched zone, considerable difficulty was encountered in correlating the actual grade of ore in place with the estimated grade of the mining blocks. The mineralogical complexity and fairly wide spacing of diamond drilling made reliable grade estimation of individual ore blocks a difficult procedure.

Jan 1, 1979