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By R. W. Lawrence

"In the past year, BioteQ Environmental Technologies Inc. have initiated design and construction of new plants to add to an existing list of plants that utilize the BioSulphide® and ChemSulphide™ process technologies for metal recovery and water treatment. In these plants, low cost biogenic sulfide or, in some cases, chemical sulfide reagent is used to selectively remove metals from contaminated water. The process produces high grade, marketable, metal sulfide products even from low grade feed solutions. The revenues generated from the sale of products can allow for water treatment at a profit in some cases, offset treatment costs in others, and generally reduce sludge disposal and management costs. The effluents produced from the process can meet stringent environmental standards. Current plants in operation and under construction range in sulphide demand from 50 kg/day to 3.7 tonnes/day, with the feasibility of larger plants with sulfide demands ranging from 6 to 43 tonnes/day under review.Biogenic sulfide reagent can also be considered for other applications in hydrometallurgy and mineral processing. Uses under consideration by a number of mining companies include: (1) replacement of sodium hydrosulphide in the SART process for cyanide regeneration and copper recovery in the processing of gold-copper ores, and (2) replacement of sodium hydrosulphide for use in the separation of copper and molybdenum in flotation. Biogenic sulphide, produced on demand at site, offers significant cost savings and provides the additional benefit of improved safety due to the elimination of the transportation, handling and storage required for chemical sulphide reagents.This paper reviews the applications of the BioSulphide® and ChemSulphide™ technologies for water treatment and metal recovery, and introduces projects where biogenic sulfide can be applied in hydrometallurgy and mineral processing."

Jan 1, 2007

By Dennis R. Dolinar

Controlling coal mine roofs subjected to high-horizontal stress conditions has always been difficult and uncertain. Traditional supports such as wooden cribs and posts, concrete donut cribs, and standing supports collapse and fail when the roof and floor move horizontally as mining progresses. The former U.S. Bureau of Mines (USBM) (currently the U.S. Department of Energy (DOE)), in cooperation with Western Fuels-Utah, Incorporated, conducted research to provide an alternative for traditional secondary support systems in a 3-entry gate road system subjected to high horizontal movements. The support system used in several other coal mine operations, consisted of internal high-strength galvanized resin-grouted cable supports. The system virtually eliminates the necessity for external crib, timber, or concrete supports. The support system consisted of 2.4 m (8 ft) full-column resin grouted bolts and 4.8 m (16 ft) long cable supports installed in conjunction with wire mesh and "Monster-Mats." Cable loading and roof deformations were monitored to evaluate the behavior of the immediate and main roofs during first and second panel extractions. Additionally, cable trusses were installed on the longwall headgate to protect the coal conveyance system from roof and pillar falls created by the formation of cutters and gutters. The test results indicated that the designed support system successfully maintained the roof during the extraction of two longwall panels and dramatically reduced the cost of secondary support. This paper describes the theory of high-horizontal roof movements, the advantages of vertical cable supports and cable trusses, and presents the roof and cable measurements made to assess the support performance during longwall retreat mining.

Jan 1, 1996

By Vijaya Thangavelu

Biological leaching of low-grade nickel laterite is based on a non-traditional leaching of oxide minerals using heterotrophic micro-organisms. The organisms solubilise metals by excreting organic acids; these acids then form complexes with heavy metals. High salinity of water supplies and soils in the vicinity of nickel laterite ore bodies is a major abiotic stress to fungi and represents a major challenge in the application of bioleaching process in-situ. Salinity exposes fungi cells to Na+ toxicity and osmotic stress. This study examined the salt tolerance development of Aspergillus foetidus based on gradual acclimatization of organism, its salt threshold and the salinity effect on its metabolism. The biological leaching of weathered saprolite ore with the resulting halotolerant organism under saline conditions was assessed. It was observed that salinity stress affected the organism?s growth and energy utilization

Jan 1, 2006

A genesis based on new developments in the physical chemistry and flow properties of colloidal substances is proposed for the pipe-like Peko orebody. The rheological behaviour of sediments is governed by the contained colloids. Remobilization of thick pasty sediment during diagenesis is regarded as an essential step in the concentration of metal dispersed in sediments. At a high concentration the sediment pore fluid is a dense gelloid such that van der Waals attractive forces between the colloidal particles exceeds the coulombic repulsion. This permits accretion of the colloids into globular clots and their fracture fragments. These have a uniform size distribution dependent upon the rate of shear, and the sediment lithifies to clotted, porphyry-like, "gritty", dolomitic or igneous-looking intrusions and flows. The physical chemical properties of natural sediment colloids appear adequate to account for ore formation.Adsorption accounts for the dispersion and retention of metal in sediments. Accretion accounts for the segregation of the colloidal materials to give the various types of clotted igneous-looking intrusive source rocks. Syneresis enables the colloids to spontaneously draw together and to dehydrate. Formation of an ordered lattice achieves a lower energy state and desorbs metals and insoluble metal compounds "particle by particle" into the escaping water of hydration and pore water. Peptization enables migration of the metal hydrosols as stable dispersions until they merge for outflow through seepage zones or water extrusion channels. Nucleation and concretion precipitate the metal dispersoids from pore waters seeping through hydrous parts of the source rock, porous beds, faults, and zones of weakness by which the connate waters leave the lithifying sediments. Gelatinous precipitated mineral matter in the ore channels is capable of thixotropic reliquefaction when disturbed by shock or movement. Local reintrusion, flowage, interveinings,brecciation, and intermixing of the materials is the result.The principles of the suggested genesis are applicable to both syngenetic and epigenetic mineral accumulations.

Jan 1, 1966

By Tracy. L. D.

"Since the introduction of pulverized coal as a substitute fuel for natural gas in the various types of heating furnaces used, in steel mills, a number of fires and explosions have occurred, resulting in the loss of life and property.As one of the primary functions of the Bureau of Mines is to conduct investigations in the utilization of mineral substances with a view to increasing safety in the use thereof, it was deemed advisable to investigate the hazards involved in the industrial use of pulverized coal and, if possible, to devise methods of preventing future accidents arising therefrom. The knowledge of the explosive qualities of coal dust which the Bureau has gained in studies affecting dust explosions in coal mines was of material assistance in these investigations.Several plants were visited in which either fires or explosions had occurred, and data obtained as to the probable cause of the accidents.There was found to exist, among some of those employed about the furnaces, a lack of knowledge of the explosive and inflammable qualities of powdered coal.A small stream of pulverized coal leaking down from a defective joint in a coal transport line did not attract much attention, whereas, had a leak in a natural gas line occurred -wider similar circumstances, no doubt it would have had immediate attention.As a matter of fact, if by any means the duet cloud should come in contact with an open flame or hot metal, the effects would be as disastrous as if it had been gas.This is exceedingly well illustrated by an accident which came to the writer's attention. In the system used at this particular plant, the pulverized coal is transported to the furnace through compressed-air lines. The fuel is fed from a storage bin to a blowing tank in quantities as desired, after which compressed air is admitted and the powdered coal blown to the furnaces. At the time of the accident some repairs were being made to the tank, and it was supposed that the air pressure had been entirely released as the pressure gage stood at zero. There was, however, one or two pounds air pressure remaining and when one of the connections was taken off, a cloud of dust was blown across the room, 30 or 40 feet towards the drier furnace where it came in contact with some live coals. Immediately the entire room was filled with flame which rolled back and forth over a specs 50 feet or so in length."

Apr 1, 1921

The Cannington silver lead zinc deposit is located near Mt Isa in North West Queensland. This world class orebody is owned by BHP World Minerals (BHP) and is estimated to contain 45 million tonnes of ore at an average grade of 11 per cent lead, four per cent zinc and 500 grams/tonne silver. At BHPÆs planned 1.5 Mtpa extraction rate, the mine life will exceed 20 years. Construction of the underground mine, which commenced in August 1993, was carried out by Peabody Resources Ltd (Mining Services Division) (PRL) for BHP Minerals Pty Limited (BHP) under contract packages totalling approximately $100 M using several innovative techniques to deliver safety, quality and time related project goals. Client/Contractor Partnering, resulting in harmonious working relationships, a combined commitment to the achievement of an excellent safety record, and a seamless transition from the construction phase to operation of the mine, has been a feature of the project.

Jan 1, 1998

By C. R. Stephan

Explosion-resistant seals in underground coal mines isolate the environment within the sealed area from the active workings of the mine. The current United States Title 30 Code of Federal Regulations (CFR) requires these seals to be constructed of solid concrete blocks. The CFR also allows for alternative methods or materials to be used to create a seal if they can withstand a static horizontal pressure of 138 kpa (20 psi), provided the method of installation and the material used is approved in the ventilation plan. The purpose of this report is to identify those explosion- resistant seals that have been tested and meet or exceed all the requirements of the CFR.

Feb 24, 1997

By J. W. Jamieson, J. Escartin, A. Steinführer

Evidence of hydrothermal activity on two Mid-Atlantic Ridge oceanic core complexes (OCCs), at 13º30’N (the Semyenov 1 through 5 fields) and 13º20’N (the Irinovskoe field) (Fig. 1) were studied using CTD casts, dredges, TV-grabs and SP surveys during previous research cruises to these sites (Cherkashev et al., 2013, McLeod et al., 2009). In late 2013, the Semyenov and Irinovskoe fields were revisited, this time with an autonomous underwater vehicle (AUV) and a remotely-operated vehicle (ROV) during the ODEMAR (Oceanic Detachments at the Mid-Atlantic Ridge) cruise on the French research vessel "Pourqoui Pas ?". Here we present the first visual surveys and direct sampling of these vent sites. High-resolution (~2 m) bathymetry of the 13º30’N and 13º20’N OCCs and their associated vent fields was collected during 4 and 5 AUV dives, respectively, using the GEOMAR AUV "ABYSS" (Fig. 1). These surveys were flown between 70 m and 100 m above the seafloor, typically at a constant height to reduce vehicle movement. The AUV was equipped with Eh, turbidity, and temperature sensors in order to detect active hydrothermal venting. Over twenty ROV dives with the ROV "VICTOR 6000" allowed for the visual exploration of the OCCs and collection of 59 hydrothermal rock samples from the vent fields. As a result of these exploration activities, the first robust estimates of the size of the deposits, and the geologic controls on sulfide accumulation at these sites can be determined.

Sep 1, 2014

By Thomas Jancic

Two of the open-pit, copper-molybdenum mining operations of Duval Corporation are located in the foothills of the Sierrita Mountains approximately 30 miles southwest of Tucson, Arizona. In March 1959, mining from a moderate sized porphyry deposit known as the "Esperanza orebody" was begun at a rate of 10,000 tons of ore per day. Some five years later, a sizeable group of mineral claims west of Esperanza became available to Duval. Earlier exploration and development drilling in this area by others indicated an orebody of greater size but lower tenor than that of Esperanza. A drilling program conducted by Duval not only verified the results of the prior drilling but in addition, revealed a continuation of the mineralization to the south and east. Thus was developed the Sierrita orebody. Open pit design delineated 414 million tons of ore containing an average copper content of 0.35 percent and a molybdenum content of 0.036 percent. In April 1966, the office of Emergency Planning authorized General Services Administration to undertake a program under the Defense Production Act to en¬courage additional domestic production of copper in the interest of national defense. Duval's Sierrita Project was brought to GSA's attention in May 1966 on November 28, 1967, an agreement providing for the development of the Sierrita Property was consummated with GSA. In March 1970, the first copper-molybdenum concentrates were produced in the 72,000 tons-per-day concentrator. Pre-production stripping exceeded the scheduled 105 million tons despite the comparatively short lead time available to equip the mine, build the mine plant facilities, and staff the technical, supervisory, and labor forces. Shortly before the first concentrates were produced, plans were being formulated for a program to increase processing capacity by approximately 15 percent, which entailed increasing overall mining capacity by approximately 50,000 tons per day. This program is scheduled for completion early in 1971.

Jan 1, 1971

By Emil B. Milosavljevic

Problems associated with distillation and other classical methods for analyzing operationally defined cyanide (CATC, WAD, Total and Free Cyanide) will be discussed. These methods often achieve incomplete, species dependent cyanide recoveries and suffer from serious interferences. Depending on the relative concentrations of interferents and other matrix constituents, underestimation (ultimately Type II errors probability of not detecting a constituent when it is actually present) or overestimation (ultimately Type I errors -probability of deciding a constituent is present when it is actually absent) of the cyanide levels present in a ,given sample may occur, causing in the first case false security and in the second case, excessive cyanide treatment costs. Mahy, if not all, enumerated problems can be solved by using novel flow injection (FI) gas-diffusion amperometric methods. A modification of the recently approved FI ligand exchange (FIILE) method for determination of available cyanide (USEPA Method OIA-'l677) that obviates sulfide interference will be discussed. Eight laboratory round-robin data obtained for the FI UV -digestion (FIIUV) method that determines total cyanide (Proposed Method OIA-1678) will also be presented. In addition, some methods for cyanide speciation will be presented. Finally, research needed for developing reliable methods for determination of operationally defined cyanide in solid samples will be summarized.

Jan 1, 1998

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015

By Y Yamaguchi, S Nomura, M Matsumura, C Kamijo

In order to increase productivity and decrease reducing agent rate (RAR) of blast furnaces, slag content of sinter ore must be decreased. However, gangue content in iron ore tends to increase because of resource depletion. Therefore, amount of high-grade concentrate in sinter ore feeds should be increased, but this situation causes a decrease in permeability of the sintering bed so that the productivity of sinter process decreases. In order to increase the amount of concentrate, NSSMS has developed the P-type separate granulation method, RF-MEBIOS and SPEx II technologies. These technologies have been introduced to actual sintering machines. In this report, a new technology using microparticles of iron ore is proposed to increase the amount of concentrate in sinter blends. Basic experiments simulating the sinter making process using microparticles of iron ore were undertaken. Crushed pisolite, containing >60 wt per cent -10 µm was prepared for binder. The pisolite microparticle binder was mixed with another Australian sinter feed ore in a high-speed agitating mixer. They were mixed for about one minute, and then granulated using a pan pelletiser. After that, they were added to another raw material mixed by a drum mixer, and then charged in a pot for a sinter pot test. As a result, when the amount of concentrate increased from 13 wt per cent to 20 wt per cent, productivity was almost kept constant using pisolite microparticle binder.CITATION:Kamijo, C, Yamaguchi, Y, Matsumura, M, Kawaguchi, T and Nomura, S, 2017. Development of an iron ore microparticle binder for increasing the concentrate content of sinter blends, in Proceedings Iron Ore 2017, pp 69–74 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By W. R. Crank

[Rock bursts are phenomena associated with mining operations, particularly with deep mining, although they occur throughout a wide rump, of depth, from 600 feel downward. The intensity is usually in direct proportion to the depth, varying from a loosening and sloughing off to a violent rupture, giving rise to the term, "explosive rock." The more or less violent breaking of rock in mine working, tins been variously designated as " flaking," "pressure hoists," "strain bursts," "bumps," "quakes," and "air blasts," which indicate opinions as to cause and effect. The term "air blast" lots probably beat most widely used, and naturally so, as a more or less rapid movement of air often accompanying the more violent phenomena of rock failure. Furthermore, there is an implied if not definitely expressed degree of magnitude in the action designited by a given term and in the cause and character of the action. For example. flaking, pressure bursts, and quakes are terms ranged to indicate action of increasing magnitude; and pressure bursts, strain bursts. bumps, and quakes are ranged according to the cause and character of the action.]

Jan 1, 1929

By R.P. Edwards, B.C. Flintoff

Froth flotation is one of the most widely used and effective processes for mineral benefication. First introduced in 1911, flotation technology has seen many developments over the past 80-plus years. Innovations in reagent chemistry, equipment design, process analysis and process control have given design and plant engineers a powerful set of "tools" for process optimization. However, it does not follow that all flotation systems are optimized. As Klimpel observes: "The problem with the industrial flotation process is that it is relatively easy to get reasonable results, and relatively difficult to get excellent results." Klimpel [1988] While reasonable was sufficient in the past. competitive forces will make excellent necessary in the future. Judging by the activities in many Canadian plants this transition is already underway.

Jan 1, 1995

A pilot program was undertaken to evaluate a process developed by the U.S. Bureau of Mines to recover nickel, cobalt, copper and chromite from domestic nickel laterite resources. An existing five ton per day pilot plant was modified to accommodate treatment of laterite by the Bureau process, which employs reductive roasting, ammoniacal sulfate leaching, solvent extraction, and electrowinning to extract, separate, and recover nickel, cobalt and copper as high purity cathode products. Three distinct types of laterite i.e., limonite, saprolite and a mixture of limonite/saprolite were processed through the plant during three operating campaigns. Nickel cathode was made during all three campaigns, while cobalt cathode and chromite concentrate were recovered only during processing of limonite. Leach extraction of nickel and cobalt averaged 83 and 67 percent, respectively, while the overall recovery was 80 and 63 percent for nickel and cobalt, respectively. Initially, over-reduction of iron in the saprolitic calcine contributed to poor settling of the leached solids. This problem was overcome by careful control of reducing conditions and flocculant addition. An economic feasibility study was made for a 5000 TPD grassroots laterite processing facility scaled-up from pilot plant data. Estimated (+ 30) percent capital cost for a Nine and plant is $367 million with an estimated $103 million per year operating cost. The study indicates that low-grade domestic laterite may he processed with marginal profit- ability.

Jan 1, 1982

By S. P. Pearton

"Pumpable emulsion explosives have been available to surface and underground massive mining operations for decades, and their unique properties offer significant advantages in terms of improved safety, reliability, and performance. However, the benefits of pumpable emulsions have been unavailable to narrow-reef mining operations due to the lack of technology necessary for their successful implementation in this challenging environment. Despite efforts to promote and enhance the safety and performance of bulk emulsions for narrow-reef stoping, little research has been undertaken to advance the pump technologies required for their implementation. This has resulted in a gap in knowledge and technology, and as a consequence the successful implementation of a pumpable emulsion system has consistently eluded the narrow-reef environment.The purpose of the following investigation was to evaluate the viability of pumpable emulsion explosives for use in South African narrow-reef mining operations. By approaching the problem from multiple perspectives, this research aimed firstly to propose a theoretical framework and suite of equipment suitable for the implementation of pumpable emulsions within the narrow-reef environment. Through the development of this suite of pumpable emulsion technology, tests could be undertaken on the proposed narrow-reef emulsion formulation and pumpable emulsion technology to obtain the necessary understanding of the performance of the system under controlled operating conditions prior to its implementation in the broader mining industry."

Jan 1, 2015

By Louis J. Cabri, Donald Hoy

"Samples with contrasting gold mineralization were studied quantitatively prior to metallurgical tests. The AD samples are coarser-grained and characterized by abundant Sb minerals (jamesonite, berthierite, stibnite). The finer-grained MW sample has abundant pyrite and pyrrhotite, with arsenopyrite and galena next in abundance. A large number of gold mineral particles were determined by SEM investigation of hydroseparation concentrates, ranging from 150 to 597 per sample. The grain-size distribution of the gold minerals shows evidence of bimodal grain-size distributions (volume %), with the coarse fraction being most significant in sample MW-1 (maximum ECD=308µm). The coarsest gold minerals in the AD samples range from 139µm to 281µm ECD.The deportment of gold minerals is as electrum, aurostibite, native gold, and a possible new mineral (AuNiSb4). Gold also occurs in nisbite. The gold minerals are dominated by electrum in three samples and aurostibite is next in abundance. The major gold minerals are probably representative of three stages of gold mineralization. The first stage is represented by electrum, which is partly to completely replaced by Sb-rich mineralization forming aurostibite, and the last stage is native gold, often occurring as rims on one or the other earlier gold mineral. The gold minerals are strongly associated with sulphides in the AD samples (55 to 60 vol.%). At the grind used for the hydroseparation the liberated gold mineral quantity (volume %) is also significant, ranging from 65% for sample MW-1 to 30 to 37% for the AD samples.INTRODUCTIONThe Clarence Stream deposit is located 70 km south-southwest of Fredericton and 25 km northnorthwest of St. George, south-western New Brunswick, near the international boundary with Maine (Fig. 1)."

Jan 1, 2007

By D. A. Bruce

Small diameter cast-in-place bored piles (pinpiles) have been installed throughout the world since 1952, but only more recently in the United States. The special features of their construction and performance makes them ideally suited for structural underpinning applications in difficult ambient and geological conditions. This paper describes the underpinning of part of a major industrial facility near Mobile, Alabama. In addition to being a most interesting and successful case history, per se, the paper also describes in detail a fundamental test pile program which has afforded a unique insight into the basics of load transfer mechanisms.

Jan 1, 1992

By Mahesh C. Meyer Jha

AMAX has developed a chloride refining process to produce pure nickel and cobalt metals from mixed sulfide .precipitates, Metal chloride solutions, generated in a hydrochloric acid leaching step and purified in a solvent extraction circuit, are converted to metal oxides .and HCI gas by pyrohydrolysis. A pilot plant consisting of a 30-inch diameter fluidized bed reactor and other ancillary units was designed, constructed, and operated for over one year. Process design was aimed at minimizing energy consumption, maximizing conversion efficiency, and achieving simplicity of operation and control. The operation provided valuable information on process scale up parameters, process control strategies, and materials of construction., Several process variables such as bed temperature, solution composition, solution feeding system, bed particle size distribution, and fines recycle system were investigated to determine their effects on process efficiency and the physical and chemical characteristics of the product.

Jan 1, 1985

By Z. G. Lin

In Xian, China, compaction by means of soil (or lime-soil) piles is one of the effective methods widely used for densifying loess and eliminating its collapsibility. However, as a result of groundwater table rising, it is no longer applicable in many areas. This paper is the summary of the first-time use in Xian of sand-gravel compaction piles aimed at densifying the miscellaneous fill (already partially under water) and saturated loess at a certain project site. In-situ tests, conducted before and after the treatment and including several kinds of penetration tests backed up and confirmed by a set of plate loading tests, yielded very satisfactory results, strongly testifying to the viability of the method.

Jan 1, 2010