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By Charles G. Yale

A few years ago somebody connected with one of those self-constituted bodies of unofficial character, like a Chamber of Commerce, Board of Trade, or State Development Board, started a catch-phrase referring to California as a The Land of Sunshine, Fruit, and Flowers," and the railroad magazines and folders keep it steadily in use, working day and night. Yet it altogether ignores the substance which brought the State into the Union, which peopled it, and which made it famous thronghout the world. You ladies and gentlemen who have come from what wc here call "the East," have in your own States, no matter which one, sunshine, fruit, and flowers. But your Eastern States, having these things as we do, have not the gold that we do. Therefore, the old designation of " The Golden State," applied to California, should be revived, as being the most distinctive term. It is worthy of remembrance, too, that during the dark days of the civil war this State handed over $172,000,000 in yellow gold, and saved the credit of the nation. Gold-mining has been carried on in California since '' The days of old, The days of gold, The days of '49," and it still continues. Since that historic year, and up to the end of 1910, the State has produced, in gold alone, $1,530,214,468. Since 1792 the entire United States production of gold has been $3,261,573,500, so that the single State of California has, in that period, produced within $201,144,564 of one-half of all the gold from Alaska, Arizona, Colorado, Idaho, Montana, Nevada, New Mexico, Oregon, South Dakota, Utah, Washington, and the Southern and scattering States. In other words, all the other 25 States of the United States combined

Jan 1, 1912

By William E. Ford, Edward Salisbury Dana

1. THE SCIENCE OF MINERALOGY treats of those inorganic species called minerals, which together in rock masses or in isolated form make up the material of the crust of the earth, and of other bodies in the universe so far as it is possible to study them in the form of meteorites. 2. Definition of a Mineral. - A Mineral is a body produced by the proc¬esses of inorganic nature, having a definite chemical composition and, if formed under favorable conditions, a certain characteristic molecular structure which is exhibited in its crystalline form and other physical properties. This definition calls for some further explanation. First of all, a mineral must be a homogeneous substance, even when minutely examined by the microscope; further, it must have a definite chemical composition, capable of being expressed by a chemical formula. Thus, much basalt appears to be homogeneous to the eye, but when examined under the microscope . in thin sections it is seen to be made up of different substances, each having characters of its own. Again, obsidian, or volcanic glass, though it may be essentially homogeneous, has not a definite composition corresponding to a specific chemical formula, and is hence classed as a rock, not as a mineral species. Further, several substances, as tachylyte, hyalome¬lane, etc., which at one time passed as minerals, have been relegated to petrology, because it has been shown that they are only local forms of basalt, retaining an apparently homogeneous form due to rapid cooling. Again, a mineral has in all cases a definite molecular structure, unless the conditions of formation have been such as to prevent this, which is rarely true. This molecular structure, as will be shown later, manifests itself in the physical characters and especially in the external crystalline form.

Jan 1, 1922

By L. G. Westgate

PART I.-AREAL GEOLOGY§ PIOCHE lies 240 mi. southwest of Salt Lake City, in southeastern Nevada, 19 in. west of the Nevada-Utah line. It is at the end of a branch line (33 m.), which connects at Caliente with the Los Angeles and Salt Lake division of the Union Pacific System. Its commercial relations are with Salt Lake City and Los Angeles, chiefly with the former. The surrounding area is part of the Great Basin, an arid region of alternating mountain range and intermont plain, the latter floored with outwash from the mountains. About Pioche the plain varies between 4700 and 6000 ft. above sea level. The town lies in a valley at the east base of a low northwest-southeast range (the Pioche Hills) 12 miles in length, which rises about 1000 ft. above the adjacent flat. West of the. Pioche Hills is a higher north-south range consisting of two parts: to the south the Highland Range, between Bennett Pass and Stampede Gap; to the north the Bristol Range, from Stampede Gap to Bristol Pass. This double range reaches altitudes of 8000 to 9000 ft., or more, (the highest point, Highland Peak, is 9395 ft.) and rises some 2500 ft. above the surrounding plain. It is continued in lower hills to north and south. Smaller ranges rise from the flat west of the Highland and Bristol ranges. The area studied and shown on the map (Fig. 1) is covered by 3 one inch to the-mile topographic sheets: the Highland Range, the. Bristol Range, and the Panaca, the latter mapped in part only. The sedimentary rocks of the district include Paleozoic limestones, sandstones and shales, Pliocene tuffs, and modern wash. Igneous rocks are represented by intrusive dikes and stocks and by extensive lava flows of mid-Tertiary time.

Jan 1, 1927

By Werner Goldsmith

This discussion is confined to the first section of Professor Clark's paper entitled 'Elastic and Nonelastic Waves' and its application to wave propagation in rocks. Some published results by other investigators concerning measured decay of peak strain and variation of pulse duration with travel distance are cited, but the principal subject of this section is a detailed mathematical analysis of spherical (and, to a lesser extent, of plane) wave propagation in various homogeneous, isotropic media. The materials selected include an elastic substance, a Voigt and a 'modified' Voigt solid-the latter incorporating the assumption of a constant loss factor (defined here as the product of frequency and the ratio of the imaginary to the real part of the shear modulus)-and a solid friction model. While other possible representations of a solid continuum model are mentioned, corresponding solutions are not presented. The pulse inputs considered comprise exponential decay, a unit step, and steady- state sinusoidal excitation: the process of conversion from one solution to another in the operational plane is indicated. The basic problem relative to the analysis of wave propagation in rocks concerns the specification of the appropriate material behavior, since the equations of motion for a given geometry of the source and medium are well established. In principle, the required information can be deduced from two types of measurement: 1) field observations of underground explosions or seismic disturbances, and 2) laboratory tests on small samples of the pertinent rock. However, in practice both types of approaches are beset with difficulties and subject to valid criticism. Field observations must be carried out under relatively uncontrolled conditions, including, in general, a lack of knowledge of the precise arrangement of the medium, stratification, faulting. inhomogeneities, etc. Specimens investigated in the laboratory can not represent the environment found

Jan 1, 1967

By J. Mizrahi, A. Brillantshtein, A. Mitzmager, O. Schächter

The separation of synthetic mixtures of heavy minerals by hindered settling classification and jigging was comparatively tested in water and five organic heavy liquids, of various specific gravities and viscosities. It was found that in the hindered settling classification process the separation efficiency was directly proportional to the concentration criterion, the liquid viscosity being a minor factor. There is therefore a decisive advantage in using heavy liquids as classification medium. In the jigging process the advantage of using a heavy liquid is masked by the detrimental effect of a higher liquid viscosity, which, in this case constitutes an important factor. Considerable interest has been aroused lately by the development of mineral beneficiation techniques 1,2 using TBE (tetrabromoethane), a heavy liquid of specific gravity of 2.96, which has been made available for industrial use by a new process3 producing TBE directly from the Dead Sea brines at a reasonable price. Most of the applications investigated until now were based on the sink-float separation of minerals in a heavy liquid of intermediate specific gravity. The TBE can be conveniently diluted with many organic solvents, and thus sharp separations are possible in a wide range of specific gravities up to 2.96. Although this maximum specific gravity is sufficient on most cases for the elimination of the bulk of the barren gangue and the production of marketable concentrates, some practical problems came up for investigation in which the separation of two (or more) minerals, heavier than TBE, was required.* *Among the cases studied in the IMI Laboratorles which fall into this category we can mention: alluvial deposits, such as heavy minerals in sea sand, tin deposits, or ground coarse-grained rocks, such as pegmatites. In such cases where, due to the petrographic structure, further fine grinding is required in order to achieve the liberation of the heavy components, the

Jan 1, 1964

By H. C. Vacher

THE limiting concentrations of carbon and oxygen which may co-exist at equilibrium in liquid iron are important in determining the degree to which liquid steel may be refined before it is deoxidized. Most refining processes depend upon the oxidation of a highly carburized iron which invariably results in contaminating the steel with oxygen. The oxygen .thus introduced presents many problems to the refiner, who in turn has attempted to rid the steel of this impurity by deoxidation with elements such as manganese, silicon and aluminum. The importance of the limiting concentrations of carbon and oxygen is accentuated in view of a number of recent researches which have indicated in many instances the existence of relations between oxide inclusions and dissolved oxygen and physical properties and chemical behavior of steel. The determination of the equilibrium concentrations of carbon and oxygen existing in iron under steelmaking conditions is obviously of fundamental importance. It has been generally assumed that the product of the equilibrium concentrations of carbon and oxygen in liquid iron is a constant and that this product is directly proportional to the carbon monoxide pressure in equilibrium with the liquid iron. Herty1,2 has computed values for this product based on open-hearth data which are all in the neighborhood of 0.01 to 0.03 (per cent. FeO X per cent. C) for temperatures in the vicinity of 1550° to 1600 C. and one atmosphere pressure. Kinzel and Egan3 have attempted to determine the value of this product by exposing liquid iron to carbon monoxide at one atmosphere pressure. The value reported by them was 0.0005 at 1550°. C. In. order to apply certain equations to the rate of carbon elimination in the open-hearth process, Feild4 found it necessary to assume. a value of 0.0102 at 1580° C. for this

Jan 1, 1931

By Pope Yeatman

THE Committee on the Elimination of Waste in Industry, of the Federated American Engineering Societies, in its report says that "Waste in -industry is attributable to four causes: 1. Low production, caused by faulty management, of materials, plant, equipment, and men; 2. Interrupted production caused by idle materials, idle plants, and idle equipment; 3. Restricted production intentionally caused by ,owners, managers, or labor; 4. Lost production caused by ill-health, physical defects and industrial accidents. The committee sent out elaborate questionnaires, and in them divided the responsibility into Manage-ment, Labor, and Outside Contracts. These question-naires showed that in the different industries examined the responsibility of Management was from 50 to 80 per cent. and of Labor from 9 to 28 per cent. The percentage of responsibility that Management was held accountable for was much larger than any of us supposed. However, when this question is studied, we realize how necessary it is to select, in the first instance, suitable personnel, in the form of directors, managers, heads of departments, experts, etc. We would like to -believe that the percentage of responsibility of Management for waste in the mining business was less than that quoted above, but there are so many mining properties started up and operated by men of no experience in such lines, and there have been so many improvements in late years in mining and metallurgical methods not taken advantage of, that we can not believe that. the percentage will vary much from that already quoted. Quoting from a report approved by the Committee on Management of the American Society of Mechanical Engineers: Management is the art and science of preparing, organizing, and directing human effort applied to control the forces and util-ize the materials of nature for the benefit of man.

Jan 3, 1922

By C. C. Griggs

From its inception, a limestone quarry or mine should be under the direction of a capable engineer. Before it becomes a reality, he should outlinc the future results, plan the most economical methods for moving the materials and the most efficient equipment, and pilot the undertaking along the narrow pathway of success, avoiding the pitfalls of uneconomical production and the precipitous walls of scanty profits. Inspection of successful limestone properties shows that all have had difficult engineering problems, the solution of which have required keen engineering ability. In approaching a subject of this nature, it is logical to follow the progress of the limestone operation from its inception to the end, as reflecting the engineering required. There are four major divisions: Investigation, equipment, development, and operation. Investigation On the reliability of the engineer's estimates and the soundness of his judgment depend the success or failure of the enterprise. When one visits a prosperous concern, realizes that the limestone is of a constant chemical composition, sees the mechanical devices installed, and watches the output leave the plant in trains of railroad cars or fleets of vessels, he may overlook the fact that in the remote past this great creation was born in some man's brain and evolved through competent engineering. Many factors must be considered before a promoter could procure the money necessary to launch such an enterprise, for a conservative banker will only recommend a successful producer while the promoter must provide funds on his own and his engineer's judgment. An engineering investigation must be made preliminary to expenditure for actual operation, which, for a limestone deposit, would' naturally embrace such subjects as : ' Readily available. 1. Tonnage available........ Possibly available. Chemical analysis.

Jan 1, 1925

By J. G. Puterbaugh

MARCH 31, 1922, undoubtedly will be long remembered as the ending of an important epoch in the coal-mining industry. On that date, contracts fixing the wages and terms of employ-ment at all anthracite mines and at approximately 60 per cent. of the bituminous mines of the country expired. For the past two years, the consuming public has been complaining bitterly against continued high cost of coal. Coal operators employing union labor have felt obligated to carry out contracts entered -into under the direction of the Bituminous Wage Commission appointed by President Wilson, and in order to do this, they have sacrificed millions of tons of business to non-union mines, and millions of dollars in wages that would have been distributed throughout unionized districts have been diverted to the non-union miners, many of whom never obtained the peak wages granted by the Bituminous Commission and others of whom accepted reductions early in 1921. Heretofore, wage contracts have overlapped as to expiration dates in different districts and renewals have had to take into consideration the competitive balance; the present situation is unique in that practi-cally every contract in the country expired on March 31, and the questions now confronting those responsible for the operation. of the coal mines of the country are: 1. Shall the operators that have heretofore employed union labor endeavor to continue contractual relations with United Mine Workers of America? 2. Shall they undertake to operate their mines with non-union labor? 3. Shall they encourage and endeavor to work out some plan of regulation or arbitration by a Government commission such as President Roosevelt appointed to settle the anthracite strike in 1902? 4. Shall the country give consideration to the demand of the miners that the coal-mining industry be "nationalized?"

Jan 5, 1922

These pages may be used as order sheets. Mark the number desired opposite title of pamphlet wanted, add your name and address, tear out the sheets and mail them to us. Single orders 25 c. Pamphlets 10 c. each in lots of three or more. Pamphlets 5 c. each in lots of fifty or more. These prices prevail for orders for pamphlets of the same or different titles, when cash accompanies order. The pamphlets listed on the following sheets are advance copies printed to facilitate discussion at the meetings of the Institute. They are offered for sale at the reduced prices given above as long, as the supply lasts. This list is published in the Bulletin in order that members may have the first opportunity to secure pamphlets, which sometimes are in such great demand that the supply is exhausted before the wants of members can be supplied. The following list includes only a fraction of the pamphlets-that have been published by the Institute. Any other paper published by. the Institute may be obtained for the price of $1, except those published in Volume XXXI, which are rare. The, Institute is still selling back volumes of Transactions at reduced prices, but some of these volumes are becoming rare. and members who desire to complete their sets of these very important books on mining and metallurgy are advised to send in their orders as soon as convenient. The attention of members is also called to the bibliographical index of the science of ore deposits contained in the Emmons Volume which is selling at $3 in paper and $4 in half morocco. The Posepny Volume is already exhausted and members who do not get in their orders for the Emmons Volume at the present reduced price may soon find themselves unable to obtain it on such favorable terms.

Jan 7, 1917

By H. W. Miller, V. H. Wilhem

Although the year 1933 was a period of uncertainty, considerable new development was initiated, with a high percentage of favorable results, for owing to financial conditions only projects of merit were proposed and developed. Unfavorable marketing conditions caused severe financial losses to refinery and sales departments of nearly all companies during the first half of the year. In anticipation of stabilized Government control, earnings were generally favorable during the third quarter but failure of the Government to take legal action against violators of the proration orders, and lack of agreement on a definite plan of curtailment, resulted in considerable overproduction and demoralization of the market structure during most of the final quarter. However, toward the close of the year Government action against violators of the Oil Code had a tendency to decrease overproduction materially and give the market a firmer tone. As a whole, the price structure of crude oil was maintained at a high level during the year; in fact, at a much higher level than the price of refinery products warranted. At no time during the year was production within 10,000 bbl. daily of the state allotment, overproduction of crude reaching a peak of 70,000 bbl. on Sept. 7, average daily average for the year being about 27,000 barrels. Numerous plans for equitable curtailment were prepared and tested during the year, none of which fully solved the many and intricate problems faced by operators who were in most cases willing to curtail if they could feel that cooperation was being practiced by their neighbors. Outstanding events in California oildom during the period under discussion may be classified under the following headings: 1. New discoveries. (a) New development in proven areas. (b) Deeper zones in settled pools. 2. Unproductive wildcat operations. 3. Whipstocking practice and procedure. 4. Progress of unit and orderly plans of development.

Jan 1, 1934

By Ancel St. John

At the New York meeting of the Institute of Metals Division in February, 1927, Jeffries and Tarasov presented a paper on Tungsten and Thoria,' in which the experimental facts were interpreted in accordance with the prevailing point of view that the thorium is present as the oxide, thoria. In discussing that paper the writer of this article stated that his own investigations, which had been unavailable to Messrs. Jeffries and Tarasov, showed that the so-called "thoriated" tungsten filament failed to disclose any sign of the oxide when subjected to X-ray diffraction analysis, but did give plenty of evidence of the presence of metallic thorium and, in certain cases, of a material believed to be an alloy of tungsten in thorium. Since these results were completely at variance with the results reported in the paper under discussion and with other papcrs which had preceded it from time to time in the past, it was felt that further discussion should be withheld until the new evidence could be presented adequately. Arrangc-mcnts were therefore made to present that evidence at this meeting. Material Examined The material exalllined was high-ernission filament such as is used in radio tubes, supposed to contain about 0.75 per cent. thoria. The actual analysis was not stated. Scope of the Investigation The investigation was undertaken because of a feeling that the thorium present in filamentary material of this type exists as metallic thorium or as an alloy of thorium and tungsten and not as the oxide. Attention was therefore directed to determining: 1. The minimum amount of thoria detectible in a mechanical mixture of thoria powder and finely divided tungsten. 2. The amount of t.horia detectible in the filament. 3. The condition of any thorium present in other form than as thoria. 4. The amount of thorium dissolved in the tungsten.

By M. R. Louthan

The susceptibility of titanium to stress orientation of hydride precipitates was investigated. It was determined that, when hydride precipitation occurred in titanium under an applied tensile stress of 30,000 psi, the hydrides precipitated on the titanium habit plane oriented most nearly perpendicular to the stress axis. Stress orientation of the hydride platelets occurred because the precipitation of the lower density hydride phase perpendicular to the stress axis caused expansion of the matrix in a direction that tended to relieve the applied stress. The Ti-H system has received considerable study in recent years, mainly because of concern over the effects of hydrogen on the mechanical properties of titanium. The amount of hydrogen present in commercial titanium is now quite low and should have no appreciable effect on its mechanical properties; however, many titanium applications require ex- posure to hydrogenous atmospheres under conditions in which hydrogen pickup is likely. In such cases continued exposures may cause the hydrogen content to increase to the extent that titanium hydride does precipitate as a second phase. The hydride phase has been shown 1,2 to have an adverse effect on the mechanical properties, particularly the impact properties, causing reductions in strength and ductility. BACKGROUND The behavior of titanium is often quite similar to that of zirconium and zirconium-base alloys, and the technology developed on one metal can often be applied to the other. Marshall and Louthan3,4 have shown that Zircaloy is susceptible to stress orientation* of zirconium hydride platelets, and that the platelet orientation has a pronounced effect on the mechanical properties of Zircaloy. They showed that when zirconium hydride precipitated in Zircaloy under an applied stress the hydride platelets tended to be aligned parallel to a compressive stress and perpendicular to a tensile stress. They also showed

Jan 1, 1963

By J. E. Hackford

IN SOME research. work carried out by the writer, certain results have bean obtained which bear on the fundamental nature and origin of coal and the relationship between coal and petroleum. Without entering into a discussion of the details of the experiments, which were conducted on petroleum and derived bitumens, there are given here, by way of definition, some of the relations that the writer has established between certain classes of bitumens of petroliferous origin. Bitumen.-A natural organic substance, gaseous, liquid, or solid, consisting of hydrocarbons and the oxy- or thionic derivatives of the same, or of a mixture of all three. Diasphaltenes.-Those portions of bitumens that are soluble, in ether or carbon disulfide, but are insoluble in a mixture of equal parts of ether and alcohol. Diasphaltenes are produced by the oxidation or thionization of petroleum oils; they have, as the name indicates, twice the molecular weight of asphaltenes, into which they are converted when subjected to moderate temperature. For example, an artificially produced diasphaltene, which was readily soluble in pentane and ether, was quite insoluble in either of these solvents after heating for three weeks at a temperature of 100° C., and was converted into an insoluble asphaltene. Asphaltenes.-Those portions of bitumen that are insoluble in ether or ether alcohol but are soluble in carbon disulfide. Asphaltites.-Those solid or semisolid natural bitumens that are composed, for the most part, of asphaltenes or diasphaltenes. A pure asphaltite1 would be composed wholly of asphaltenes and diasphaltenes, but most asphaltites contain small percentages of oil and wax, which have not yet been converted into asphaltenes; they may also contain a small percentage of kerotenes, which represent the next stage of the metamorphosis of asphaltenes. Among the naturally., occurring oxyasphaltites may be mentioned grahamite; and among the thioasphaltites, gilsonite.

Jan 8, 1920

By N. J. Gran, W. R. Opie

HYDROGEN in molten aluminum and aluminum alloys, which precipitates during cooling and solidification, is the principal cause of pin hole porosity in ingots and castings. Much attention has been given to determining the effect of temperature and pressure on the solubility of hydrogen in pure aluminum, but little data are available on hydrogen solubility in aluminum alloys. This investigation was undertaken to check results reported for pure aluminum and to show the effect of silicon and copper additions on the amount of hydrogen contained by molten alloys. Previous determinations of the solubility of hy-drogen in molten pure aluminum are plotted in fig. 1. The most reliable data appear to be those of Ransley and Neufeldl and of Baukloh and Oester-len.' The latter authors also report some results on the effect of copper and silicon additions. Up to 6 pct these elements decrease the solubility of hydrogen quite rapidly, with a definite minimum noted at 6 wt pct for both copper and for silicon, although no reason is apparent for these minima. Experimental Procedure The solubility of dry hydrogen in pure aluminum, aluminum-silicon, and aluminum-copper alloys was determined by the method of Sieverts.8 This consists of determining the volume of the gas system above the molten metal at a given temperature and pressure by using an insoluble gas. This volume is referred to as the "hot volume." The system is then evacuated and the soluble gas is introduced at the same temperature and until the same pressure is reached. It is necessary to introduce enough of the soluble gas to fill the space above the metal plus the soluble amount. The difference in the volume of soluble gas and the "hot volume" is the solubility. The accuracy of solubility measurements by the Sieverts' method is primarily depend-

Jan 1, 1951

By Lester Tarnopol, Ralph Hultgren

A considerable interest in the subject of superlattices has been manifested by many papers and reviews that have recently appeared, both in physical and metallurgical publications. This interest is due largely to the apparent simplicity of the ordering process, which permits the explanation of many phenomena on the basis of elementary theory. Moreover, ordering may cause important changes in the physical properties of alloys. In this paper, we shall discuss the causes of superlattices in terms of simple properties of the elements that give rise to them, together with a series of experiments performed to test our conclusions. Evidence is presented that in some cases the process of ordering is more complex than might be supposed. While the different species of atoms are usually found in random positions in alloy lattices, in some cases unlike atoms tend to be nearest neighbors. Bethe's1 "order of neighbors" is a statistical measure of thib tendency. At suitable compositions it is possible for atoms in large regions to be regularly arranged, which causes superlattice lines to appear. in X-ray diffraction patterns. Bragg and Williams2 haw dealt with this "long-distance order" in their fundamental work 011 superlattices. Excellent discussions of superlattices are to be found in current reviews TheRmodynamic Considerations Thcrmal vibration tends to destroy order. The magnitude of the effect can be determined from the entropy of mixing, which is calculate from first principles. Since the ordered state has the lower entropy, it must also have a lower internal energy to be stable at any temperature. The difference in internal energy determines the critical temperature at which long-distance order disappears. According to the, theory of Bragg and Williams,~

Jan 1, 1939

By Julianne H. Glarmaty, Peter J. Conroy

INTRODUCTION In 1970 the percentage of underground coal extraction by longwall mining methods in the U.S. was 2.1 percent. This figure rose to 4.4 percent in 1976 and is expected to rise to 12 percent by the year 1985. This figure represents 46.0 million tons (51.0 million st) of annual production (Kuti, 1978). In addition, OSM regulations are placing emphasis on subsidence prediction. Section 784.20 of the Office of Surface Mining regulations for underground mining permit applications requires the sutauission of a subsidence control plan which may include monitoring. Because of its nature, longwall mining does not have flexibility in leaving pillars under structures as does room and pillar. Mining in some areas, particularly in the Eastern Coal Field, is approaching more developed areas; therefore, a greater number of structures are expected to be undermined in the near future. Subsidence engineering is becoming an important aspect of mine planning, and should be directed at predicting potential structural damage. The question operators are increasingly faced with is "what will be the subsidence effects for a specific structure at a specific location in respect to a longwall panel?" The most significant variable in assessing the subsidence effect on structures is not vertical subsidence. The variables of strain and tilt are responsible for more structural damage than is the vertical movement. Table I presents threshold values of strain for various structures (Geddes 6 Cooper, 1962). Based on National Coal Board experience, horizontal strain is approximately inversely proportional to the radius of curvature of a circular portion of a subsidence profile; therefore, the radius may be useful in estimating the magnitude of strain caused by subsidence (Hoebs, 1982). The radius of curvature can be determined by the following equation:

Jan 1, 1982

By Lester Tarnopol, Ralph Hultgren

A considerable interest in the subject of superlattices has been manifested by many papers and reviews that have recently appeared, both in physical and metallurgical publications. This interest is due largely to the apparent simplicity of the ordering process, which permits the explanation of many phenomena on the basis of elementary theory. Moreover, ordering may cause important changes in the physical properties of alloys. In this paper, we shall discuss the causes of superlattices in terms of simple properties of the elements that give rise to them, together with a series of experiments performed to test our conclusions. Evidence is presented that in some cases the process of ordering is more complex than might be supposed. While the different species of atoms are usually found in random positions in alloy lattices, in some cases unlike atoms tend to be nearest neighbors. Bethe's1 "order of neighbors" is a statistical measure of thib tendency. At suitable compositions it is possible for atoms in large regions to be regularly arranged, which causes superlattice lines to appear. in X-ray diffraction patterns. Bragg and Williams2 haw dealt with this "long-distance order" in their fundamental work 011 superlattices. Excellent discussions of superlattices are to be found in current reviews TheRmodynamic Considerations Thcrmal vibration tends to destroy order. The magnitude of the effect can be determined from the entropy of mixing, which is calculate from first principles. Since the ordered state has the lower entropy, it must also have a lower internal energy to be stable at any temperature. The difference in internal energy determines the critical temperature at which long-distance order disappears. According to the, theory of Bragg and Williams,~

Jan 1, 1939

By Dorsey Hager, G. W. McPherson

The rapid increase of water troubles in the Mid-Continent oil fields is causing much alarm. Troubles occur at Towanda, Eldorado, Augusta, Cushing, Blackwell, and Healdton, although they had not been acute in the Mid-Continent field until about two years ago, when the unusual conditions in the deeper oil fields were first encountered. California faced the same situation, but, thanks to aggressive measures, has largely overcome the dangers. The following analysis of water trouble may throw some light on the subject and be of assistance in solving the problems involved. Water Troutles Classified The presence of water in large quantities in oil sands has the following results: 1. Diminishes oil production. 2. Diminishes casing-head gasoline production: (a) By curtailing the gas flow. (b) By making the use of vacuum pumps unsuccessful. 3. Increases lifting costs: (a) By making it necessary to pump large quantities of water, which requires a fast motion and long stroke (third hole). (b) By requiring the use of compressors for air lift. (c) By causing break-downs and delays due to the high speed necessary to pump water. (d) By making it necessary to treat "cut" or emulsified oil. Oil production is seriously curtailed by the presence of large quantities of water. Lease records show that wells are shut down 40 to 60 per cent, of the pumping time where serious water trouble occurs. While a small quantity of salt water may cut the paraffine and keep the oil moving, several hundred feet, or a hole full of water, effectually "kills" the oil and gas. The quick return of wells to production, once the water is shut off, shows how wells have been affected. The killing of gas sands

Jan 1, 1920

By S. Frederick Ravitz, Kenneth E. Fisher

Four liquids are ordinarily present in the lead blast furnace during lead smelting. At the bottom is the lead bullion, which is metallic lead containing about one per cent of impurities, including gold, silver, copper, bismuth, arsenic and antimony. Above this is the speiss, which consists essentially of arsenides and antimonides of iron and copper. The speiss is followed by the matte, which consists principally of sulfides of iron, copper and lead1. The top layer is the slag, of which the major constituents are silica, lime, alumina, zinc oxide and iron oxide. Similar products are obtained from the dross furnace, which treats the dross obtained in decopperizing lead bullion. The distribution of gold and silver among these various products is of considerable importance in the smelting of lead. In general, the matte and speiss cannot be treated in the lead smelter, and usually are sent to a copper smelter. It is usually desirable, therefore, to keep their gold and silver contents as low as possible, and to collect the precious metals in the bullion. If the bullion, speiss, matte and slag exist together in equilibrium, the gold and silver should distribute themselves among these four liquids in a definite manner, which, other conditions being equal, should depend only on the amounts of gold and silver in the charge to the furnace. It is thus apparent that a knowledge of whether such equilibrium exists is necessary before attempting to study the effects of various compositions of matte and speiss on the distribution of gold and silver among the furnace products2. Moreover, systems consisting of four liquids in equilibrium are very rare, and are of considerable scientific interest. In order to ascertain whether equilibrium existed, the distribution of gold and silver among the four liquids was determined. The speiss,

Jan 1, 1937