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By R Higashi, D Maruoka, T Murakami, Y Iwami

The ironmaking industry consumes a large amount of fossil fuel derived carbon as heat source, reducing agent of iron ores and carburising agent of reduced iron. Although the demand for drastic decrease of carbon dioxide emission, carbon is an essential element for smelting process of molten iron. The carbon recycling ironmaking process by circulating CO has been already proposed to achieve carbon neutrality. However, the production of molten hot metal is not considered in this process because sufficient amount of carbon does not dissolve in reduced iron by CO. Therefore, our group has suggested a new carbon recycling ironmaking process which can produce hot metal. In this process, free carbon and iron carbides produced by carbon deposition reaction using metallic iron as a catalyst are used. It is known that only Fe3C is obtained as iron carbide by using CO gas, however, Fe5C2 is also produced by adding H2 gas. The composite agglomerated with these carbonaceous materials and fine iron ore (Deposited Carbon-Iron oxide Composite: DCIC) is reduced and melted in a furnace. It is reported that Fe3C in DCIC accelerates the reduction reaction and melting of the composite. In this study, the effects of iron carbides and free carbon on the melting behaviour of DCIC are investigated. Fe3C, Fe5C2 and free carbon were produced by vapour deposition using porous iron whiskers and CO-CO2-H2 gas. These were agglomerated with hematite reagent at a certain ratio to prepare DCIC samples with and without Fe5C2. The samples were heated up to 1300°C in inert atmosphere. The DCIC containing Fe5C2 completely melted and iron nuggets were obtained after the experiment. This behaviour was not observed in the composite without Fe5C2. This indicates that using Fe5C2 is more preferable than Fe3C for molten iron production using DCIC.

Jun 19, 2024

The lignites of Otago and Southland offer a potentially viable future feedstock for electricity production and possible conversion to petrochemicals or liquid fuels. The deposits, when combined, represent New ZealandÆs largest energy inventory; equivalent to about 74 000 petajoules û or approximately 35 times current natural gas reserves. Too often dismissed as irrelevant to New ZealandÆs energy future because of adverse perceptions of the value of low rank coals, the strategic value of this resource is in fact huge.   Investigations of the lignites extend back over more than 50 years (LFTB various, CRL Energy Ltd). Whilst it is not the intention of this paper to review this work, these investigations have confirmed the suitability of the resource as a feedstock for thermochemical conversion. Current estimates of South Island lignite mining costs are NZ$1.0 - 3.0/GJ (Natusch 2005), making these resources amongst the most competitively-priced energy sources available world-wide.   This value, however, will only be captured if we as a country begin to envisage a world-scale, long-life, integrated and multi-faceted development sized to supply world markets for chemicals or fuels. Recent CAE studies (Hooper and Riddolls, 2005) have emphasised the vital importance of ensuring that any exploitation of this resource maximises their value to New Zealand. The question that thus must be applied is how might large-scale utilisation of the resource fit with New ZealandÆs primary energy supply, and its potential for the export of high-value commodities.   From the broader perspective of New ZealandÆs total energy supply equation we need to examine other supply options beyond just the generation of electricity. We face in this country a situation wherein almost all our liquid fuels feedstock has to be imported with projections for an increasing dependence on imported oil. In addition NZ has a natural gas reserves-to-production ratio of less than ten years, and dwindling supply from local production. Without further natural gas discoveries, New Zealand has only a window of approximately five years before we will need to commit to imported LNG or some other thermal fuels option.   In other words, New Zealand is facing an uncertain future unless we can restore energy inventories to cover an adequate strategic reserve capacity as well as enable long-term investment in alternative sources. Within this context the South Island lignite resources are thus deserving of more attention. The extent of the resource is well known, its suitability for conversion reasonably assessed, and its magnitude such that there is little doubt that lignite conversion could adequately meet NZÆs future energy needs for many years out.   This paper reviews coal gasification technology, its application to lignite and the possibilities for future development of the lignite resources. It is argued that the strategic imperative for this country is to secure the lignite resources as a primary energy source for this country well into the latter half of this century.

Jan 1, 2005

Our modern cities are almost incapable of sustaining themselves without subsurface infrastructure, which is not identifiable at first glance. This very soon becomes evident when the chaotic conditions prevailing in some cases in the multi-million cities on the African, Asian and South American continents are taken into consideration. This does not simply apply to the hopelessly congested streets in the downtown areas. If anything, it is shown here too that a subsurface infrastructure represents an important prerequisite for public health right up to banishing the danger of disease. Even during the 1990s, this has been clearly underlined through examples of cholera and plague epidemics in parts of Central and South America as well as on the Indian subcontinent. The overriding significance of an inner urban subsurface infrastructure in order to create decent conditions in the major built-up areas was once again emphasised not all that long ago at the United Nations HABITAT-II Conference in Istanbul, Turkey, in June 1996. More than 15 000 delegates from all over the world mulled over and discussed the prerequisites for humane living conditions in human settlements taking the varying climatic, topographical and cultural marginal conditions in different regions of the globe into account. Apart from the built-up areas themselves, the utilisation of underground space is experiencing high and ever increasing significance in less densely populated regions. Attractive and fast transport links between industrial centres call for high- performance transport arteries for the economic, speedy and unhampered carriage of people and goods. Important impulses for the economic power of a region or nation are provided by transport development and links. As a consequence, tunnels for roads and railways are being built or planned to a great degree for crossing mountain ranges, rivers and straits.

Jan 1, 1999

By A Cornelius, P Connor, S Fraser

Iron ore mining is a major source of export income for Australia. However with the decreasing reserves of high-grade, low-phosphorus hematite ore, there is mounting pressure to provide consistent mineralogical ore grade. Enhanced 3D characterisation and modelling are crucial to respond to these exigent requirements. To tackle this problem a revolutionary mine-based, imaging system (based on Visible Near Infrared û Short Wave Infrared reflectance spectroscopy û VNIR-SWIR) has been developed. This innovative, CSIRO-built prototype produces mineralogical maps that will have a major impact on ore grade characterisation. Australian iron ore companies will benefit immensely by pioneering this emerging and unique mining technology. The significance of VNIR-SWIR reflectance spectroscopy is well demonstrated with field portable spectrometers and airborne hyperspectral systems. At the mine-scale level, this newly developed imaging system will allow accurate and objective mineralogical mapping of mine faces and benches with very closely spaced sampling. These spectral mineral maps will improve deposit delineation and bring accurate and objective ore grade characterisation that will minimise drilling and enhance ore recovery. This will in turn lead to cost saving and better long-term block model planning. This system will also improve safety for mine geologists in providing mineralogical information at a distance, avoiding the need for any close contact with the mine face. The mine imaging concept is a logical response to the industry need for automatic and objective tools for sustainable and future mining practices.

Jan 1, 2002

By Gupta A, Hall ST

The grinding characteristics of quartz which is normally associated with gold bearing ores in Kalgoorlie area was examined in a stainless steel laboratory size ball-mill in the presence of inorganic and organic surface active reagents. The cationic species considered were Fe3+, Cu2+ and Ca2+, and the anions were CO? and S2 as these are normally present during the process of grinding of gold ores in the region. The organic surfactants examined were K-amyl- xanthate, dodecylamine-hydrochloride and the Grinding Aid XFS-4272 manufactured by Dow Chemical The study was primarily based on an examination of the electrokinetic properties of quartz surface in the presence of the grinding reagents. Zeta potential at different reagent additions and pH values in the presence of individual reagents were examined and the corresponding grinding charcteristics determined. A correlation has been indicated between the grinding characteristics, as measured by the -53um size fraction produced, and the surface energy of quartz. It was observed that an

Jan 1, 1978

By S S Solomons

In 1991 the uranium spot market price dropped to approximately US$7/Ib U308, a historical low in real terms and the short-term outlook for the industry in the next five years was grim. At this time the Ranger operation was producing uranium concentrate at its design capacity of approximately 3 000 tonnes/year. The loss of two major long-term contracts owing to price and reduced power utility demand due to excess inventories meant that the company could not match production to sales. Continuance at this production level would have resulted in a rapid buildup of product inventory and the tie-up of significant cash reserves. After analysing various options, an innovative operating strategy was devised such that production and sales were approximately balanced without a significant impact on the unit production cost or a long term effect on the plant or operation. A campaign mining/milling operation commenced and approximately 40 per cent of the workforce were retrenched. Multi-skilling of all employees was a critical aspect of ensuring a successful outcome. This paper examines the strategy and reports on the success of the operation two years after the restructuring exercise was effected in November 1991.

Jan 1, 1994

This paper discusses equipment replacement strategies and specifically addresses the upgrading of technologically superseded equipment. The process of equipment replacement evaluations is reviewed, and areas have been highlighted where currently accepted practice results in a bias towards retaining existing equipment longer than otherwise justified. The Discounted Average Cost Method is described and the advantages of the technique for this style of decision making discussed. Several key issues influencing the replacement evaluation are also presented together with examples from recent consulting work.

Jan 1, 1992

Present knowledge of the Pacific floor in- dicates: Postulated subduction zones and/or moving basements overlain by undisturbed sediments. Contiguous mantle convections of conflict ing directions and variable rates. Disharmony between transform faults and mantle convections. =hese features are shown to be difficult to reconcile with conventional hypotheses of sea f 1mr spreading and cast the model into serious doubt.

Jan 1, 1987

By X Yu, Y Shen

The iron ore products should be assessed in terms of in-furnace behaviour and overall furnace performance, their operation should also be optimised under industry-scale blast furnace (BF) conditions, in order to be sustainable and competitive, especially in the context of decarbonisation efforts in ironmaking. While lab and pilot-scale experiments can provide useful kinetics, they are expensive and risky and cannot replicate industry-scale blast furnace conditions for proper assessment and optimisation. In this paper, we review our recent progress at Shen Lab of UNSW in using state-of-the-art Computational Fluid Dynamics (CFD) models to assess iron ore products and examine the effects of their operations on BF behaviour in basic terms, including in-furnace phenomena (flow field, temperature field, species distribution fields etc) and overall BF performance (coke rate, reduction efficiency and top gas temperature etc). We have developed state-of-the-edge CFD models for different purposes, ranging from the static-state BF model featuring unique layered burden structures for offline assessment and optimisation knowledge building-up for iron ore products, to the transient-state BF model for online assessment and optimisation of iron ore productions by describing the transient behaviours of iron ore productions under industry-scale conditions. First, we have studied several iron ore products including the iron ore products used in the present BFs and emerging iron ore products like carbon composite briquette and iron-coke. Second, several iron ore operations are studied including optimisation of conventional burden operations like oxygen enrichment, batch weight tuning and new operations like coke central charging and hydrogen injection in BFs. Third, some time-sensitive operations are also investigated including the use of wet burden materials and the drop in blast temperature on BF performance. These CFD models offer cost-effective research tools for understanding the effect of iron ore products on BF performance and serve as a reliable marketing tool for existing and emerging iron ore products under a wide range of BF conditions.

Sep 18, 2023

By A D. Paktunc

The surface reactivity of underwater deposited, high-sulfide copper mine tailings was evaluated under fresh and saline water cover conditions by measuring the surface and pore water quality as a function of time. The experiments were conducted in aquarium type lysimeters having a shallow, well-aerated water cover up to approximately 0.25 m over the tailings. Natural lake water was used for the fresh water cover and seawater for the saline water cover scenarios. The tailings showed significant surface reactivity and oxidation under both fresh and saline water cover conditions. The surface water quickly became moderately to highly acidic, and surface oxidation of the tailings resulted in increased dissolution and release of sulfates, iron (total), calcium, magnesium, aluminium, manganese, copper, nickel, zinc, lead, cobalt and silicon to the water covers. A moderate to slightly increased loss of total sulfides, including pyrite, chalcopyrite and sphalerite, occurred in the tailings surface layer to a very shallow depth. In comparison to the fresh water cover, the complete acidification of the saline water cover was delayed by approximately 30 - 40 days because of its additional available alkalinity. Whereas the rate of surface water acidification and release of aluminium and silicon were moderately reduced under saline water cover conditions in comparison to those for the fresh water cover, the release of calcium, magnesium, iron (total), copper, nickel, lead, zinc, sodium and potassium were enhanced. The mass transfer fluxes for dissolved copper, nickel lead, zinc and iron (total) from the tailings substrate to the surface water cover following surface water acidification were higher by 50 per cent or more in the saline water cover than those in the fresh water cover. This release was also reflected in moderate loss of pyrite, chalcopyrite and sphalerite in the very shallow upper surface layer of the tailings at the tailings-water interface, although the loss of pyrite in the surface layer was less pronounced. In both cases, the dissolution of aluminosilicate minerals moderated, to a certain extent, pH and acidity in the water cover.

Jan 1, 2003

The mobility of radionuclides released into aquatic, terrestrial and subsurface environments by mining, industrial processes is an area that deserves significant scientific attention. The presence of microorganisms in these environments can influence the transport of radionuclides. Free-living microorganisms constitute mobile suspended particles that may have a radionuclide sorbing capacity higher than that of the environment. Radionuclide transport will then proceed faster with than without microorganisms. In contrast, if the majority of the microorganisms are growing in biofilms on surfaces, transport of radionuclides may be reduced. Microorganisms can directly sorb radionuclides either within the cell structure or on the cell wall. Radionuclides could also be sorbed by minerals precipitated by microorganisms. Microorganisms produce complexing agents that can influence radionuclide mobility. The involvement of microorganisms in biogeochemical processes is related to their ability to include various chemical elements and their combinations into biochemical redox reactions. Microorganisms can alter the extent of radionuclide oxidation that results in their deposition as a result of the formation of insoluble forms. Some studies have shown the bioremediative potential of stimulating reducing bacteria to use some of the soluble radionuclides as electron acceptors and thus precipitate them out of solution. The microbial involvement in providing a barrier for radioactive element migration (uranium, technetium) and the formation of ores (eg uranium) has been justified. The mediated impact of microbial activity on radionuclide migration occurs through its effect on the ambient geochemistry by geochemical speciation changes, pH changes and changes to the ambient redox potential. As the mobility of many radionuclides depends on the pH and redox potential of the environment, these microbially mediated geochemical changes can influence radionuclide migration through changes to both the dominant radionuclide species and mineral phases.

Jan 1, 2004

By J Naude

The TauTona (Sotho for Great Lion) Mine near Carletonville, which is one of AngloGold AshantiÆs most profitable operations in South Africa, has started a multi-million dollar expansion project that is expected to extend the operational life of the mine by at least three years. The project will also secure some 1900 jobs for existing workers and contract workers. The $US140 million project entails the development of the orebody to a record depth of almost 4 km underground. It means that TauTona, which already mines gold at the deepest levels in the world, will deepen its mining activities from 3600 m to a new record depth of 3910 m. There is great anticipation about the expansion program, especially because of new technology that will contribute to a safer working environment. It includes a simplified hoisting system that will minimise safety risks in conveyance activities. Due to the unique nature of this project, depth below surface and working through a three-tier shaft system, various innovative measures were incorporated into the planning of the endeavour. Special support equipment was designed to reduce cycle times and enable the crews to install the extensive support, prescribed by the mineÆs rock engineering department, right up to the face before every blast. Both declines dip at 23¦. The personnel/material (P/M) shaft is 4.4 m wide x 3.9 m high. This shaft is unique in that the conveyance will have an onboard driver. The rock shaft is 4.5 m wide x 3.6 m high. Rock will be hoisted with two, ten-tonne overturning skips. In both cases, P/M and rock, the winders were designed for the highest duty cycle, which is encountered during sinking.

Jan 1, 2005

By C Zhang, I Canbulat, S Saydam, H Yu, H Chen

Natural rocks are frequently exposed to groundwater and complex geological conditions. Environments with water presence are more susceptible to chemical corrosion, which notably affects rock’s micro properties. Generally, the pH of acid mine drainage in hard rock mines can be low to 5, and the pH of quarrying waste deposits can be below 3. With the expanding scope of mining engineering in aquifers and salty areas, chemical corrosion can also caused by different types and concentrations of anions. The anions can significantly affect rock’s mechanical properties. Therefore, it is critical to emphasise the impact of anion and acid on the mechanical and micro characteristics of rock. This paper commences with an introduction to representative corrosive environments. Then the UCS tests are conducted on granite samples corroded by chloride ions and sulfate ions. Anion has negative effects on the strength of granite. The reason is that certain minerals can react and be dissolved by anions and hydrogen ions, such as Al2O3. Furthermore, the scanning electron microscope (SEM) shows that the roughness of the fracture surface increases with the anion concentration. The effect of acid is notably more pronounced than anion on the micro properties of granite. The initiated fissures and pores also increase with the concentration of SO42- and Cl- ions, which is the micro explanation for the impact of anion on rock strength and stability. Subsequently, the permeability of the granite specimens is tested. The reason that granite performs insensitivity to acid and anion is attributed to its low permeability and high content of inactive oxides, such as quartz. To summarise, anionic and acidic conditions can slightly deteriorate the mechanical and micro properties of granite. While SO42- demonstrates a higher level of corrosiveness on granite than Cl-.

Sep 1, 2024

Geostatistical conditional simulation is a method to assess variability and risk in mineral deposits and the tool has wide potential applications in the iron ore industry. Correct reproduction of multivariate relationships is important in iron ore simulation, especially between Fe and impurities such as Al2O3, SiO2 and P. The turning bands simulation method, using a full model of coregionalisation for multiple attributes, is the main multivariate conditional simulation algorithm used in the Western Australian iron ore industry. This paper discusses the results of a more recent approach using minimum/maximum autocorrelation factors (MAF) to transform and decorrelate the multivariate data prior to independent sequential Gaussian simulation (SGS). MAF-SGS results are compared to those of the turning bands approach in the Yandicoogina channel iron ore deposit (CID), and both methods performed well in simulating Fe, SiO2, Al2O3 and P distributions. Extensive checking of simulations showed that both approaches could reproduce multivariate statistics and spatial continuity of the original conditioning data. Both approaches reproduced the histograms and variography of input sample composites. While the MAF-SGS approach requires additional transformations when compared with the single normal scores transformation required for the turning bands method, MAF requires only that the direct semivariograms be modelled. In contrast, using turning bands with multiple attributes requires modelling a full linear model of coregionalisation, which can be difficult to model because of the need to ensure the model is positive semi-definite. Turning bands may be preferred if there are a modest number of correlated variables allowing construction of a linear model of coregionalisation that adequately models the multivariate behaviour. MAF-SGS is preferable for larger numbers of correlated variables. Both MAF-SGS and turning bands methods performed well in conditional simulation of correlated variables at Yandicoogina.

Jan 1, 2007

The seam gas content at Westcliff Colliery is 12-15m3/tonne of coal.Composition ranges from 99% CH4 to 52% C02 in one area. Desorption rates are proportional to gas contents and CH4 is preferentially desorbed. A crushed zone of reduced permeability advances with the face - at Westcliff ribside crushed zones are 2.5 to 6.5m wide. Poor strata control widens crushed zones. 12 months of pre-drainage allowed 2 heading development and longer pillars to be used in a virgin area instead of 3 or more headings without drainage. Machined coal may lose as much as 1.6m3/tonne being conveyed out of Westcliff Colliery. Experience differs from mine to mine. Permeation is affected by time, strata movements, changing water content, and changing stress. Permeabilities vary from lOmd for Pittsburgh Seam to less than 1 and for the Bulli Seam. All these data and differences await further investigation.

Jan 1, 1982

By J B. Holman, P A. Weber, P Lindsay

Underground and opencast coal mining has occurred since 1896 on the Stockton Plateau, West Coast, New Zealand. Acid Rock Drainage (ARD) from historic and current mine workings has had an adverse environmental impact on the surrounding aquatic environment. The two main catchments affected by ARD from historic and current mine workings are the Mangatini and St Patrick Stream catchments. Solid Energy New Zealand Ltd (SENZ) is using active (e.g. alkali dosing) and passive (e.g. engineered cover) technologies to mitigate the adverse environmental effects associated with ARD contaminated waterways. This paper discusses the passive technologies. Principal strategies include the capping of high capacity potentially acid-forming volumes of overburden. The mudstones were found to generally have the highest sulphur levels compared to other overburden lithologies. Areas with high mudstone volumes are prioritised to be encapsulated and 390 Ha is planned to be capped in the Mangatini catchment in the near future.   Monitoring beneath granite, cement kiln dust and coal combustion product covers show oxygen can be reduced to less than 10% of atmospheric levels. Laboratory column leach tests that were subjected to oxygen flux rates of 10 % showed reducing oxygen ingress into acid-forming material can result in significant acid load reductions.   The oxygen content below the cement kiln dust cover was generally lower than 5% and water quality measured in lysimeters beneath this cover improved after 50 weeks of emplacement. Column leach tests containing saturated samples were undertaken to determine the most appropriate water medium in preventing pyrite oxidation. The sample saturated with ARD (pH ~ 3) had a negligible acid production rate and leached very minor Al concentrations although Al is soluble at low pH. This indicated saturating waste rock dumps with ARD can be an effective method in mitigating ARD formation.

Jan 1, 2007

The Mobile Miner MM130 (Figure 1) is designed to tunnel or mine in hard rock. It has a 4.1 m diameter cutterhead mounted on a horizontal axis which in turn is perpendicular to the line of the machine. The cutterhead rotates at 15 rpm and is supported on a boom which swings the cutterhead through a horizontal arc.

Jan 1, 1993

By Watson K, Pollard D. M

The electrolytic recovery of metals from solution requires an understanding of the characteristics of the particular system employed, and the current efficiency and morphology of the deposit are influenced by such factors as cell design, metal ion and supporting ion concentration, acid concentration, temperature, impurity levels and cell design. The electrolytic deposition of both cadmium and silver present individual difficulties, and special cell designs are used for each of these metals. It was found that cadmium deposition was plate-like at lower cadmium concentrations, and at higher current densities. The presence of zinc in the electrolyte promoted nodular growth. Current efficiency remained high even at 50C in contrast to published information. Silver deposition morphology was relatively unaffected by changes in silver concentration, pH and current density. Current efficiency was reduced as temperature was increased.

Jan 1, 1989

By J M TORLACH

Learning is an iterative process, and we might reasonably expect that after more than a century of mining during an era of sustained technological development, (following a millenium or two of unrelieved hard physical graft), that the more obvious physical hazards could by now be competently managed. It is perhaps a reflection on the perversity of human nature that we have not fully learned our lessons in this exacting environment, and that worse, we have still too often failed to profit by the experience of those lessons. The more obvious underlying factors which impact on this situation are examined briefly, as a prelude to consideration of some outstanding examples of recurrent problems experienced in recent years. Reasons for the continued existence of sub-standard practices are outlined, with a focus on the human element, and finally proposals for appropriate remedial strategies are summarised. This paper therefore seeks to examine and discuss some of our deficiences and to suggest some directions for the way ahead.

Jan 1, 1992

The Coal Corporation of New Zealand Ltd (CoalCorp) is the largest coal producer in New Zealand, with extensive properties in both the North and South Islands. CoalCorp's North Island operations are kilcmetres to the south of Auckland. opencasts, are located in the catchment wildlife, historical and scenic values. in this catchment is the single most mining operations. centred on Huntly, a town some 80 Five coal mines, four of which are of Lake Waahi, a lake with significant The discharges of mine lodgement water important environmental constraint on Throughout New Zealand the use of water is controlled by a statute called the Water and Soil Conservation Act 1967. All industrial water users are required to hold Water Rights, which are in effect licences to take, use, dam, divert or discharge water. Water Rights are obtained through a legally defined process and any potentially affected party has the per to object to their granting. A special tribunal hears the evidence for and against an application, and issues its decision, which is reviewable in a higher court on Appeal. Rights, if granted, are issued subject to conditions and, in the case of mining discharges, limits would be set on flaw rate, suspended solids concentrations, turbidity, pH and the concentrations of any potential toxicants. This paper presents a case study of an integrated, catchment wide water management plan for Lake Waahi, that was prepared by the author, and others while the author was in the employ of CoalCorp, and its predecessor, State Coal Mines. The author is grateful to CoalCorp for their permission to submit this paper.

Jan 1, 1988