Search Documents

By R. V. Kumar, C. Schwandt, S. Subramanian, S. Sampath, S. Vimalnath

Waste waters and industrial effluents containing toxic heavy metals such as Pb, Hg, As and Cr, beyond permissible limits (0.1 ppm, 0.01 ppm, 0.02 ppm and 0.05 ppm, respectively) (WHO, 2011), pose serious threats to the ecosystem, when discharged into the environment. It thus becomes imperative to monitor the concentration of the toxic heavy metals and treat them before discharging. In this study with the above objective in mind, a microbial sensor has been developed using P. aeruginosa cells drop coated onto a carbon paste electrode (CPE) for the detection of Pb(II) ions in aqueous solutions. Detailed biosorption experiments confirmed that complete bioremoval of lead could be achieved using P. aeruginosa cells under optimum conditions of pH and biomass loading. For the electro-analytical determination, the Pb(II) ions were initially preconcentrated on the P. aeruginosa modified CPE, reduced and then anodically detected with oxidation of Pb0 using differential pulse anodic stripping voltammetry (DPASV) technique. All the experiments were carried out in the presence of 0.1 M sodium acetate buffer and KNO3 as background electrolyte. The parameters namely pH, scan rate, biomass loading, deposition potential, deposition time and concentration of Pb(II) ions were optimized for the biomass modified CPE, to obtain maximum voltammetric response. Under the optimized conditions of pH 5.6, scan rate of 0.008 V/s, biomass content of 1.7–1.8×109 cells/mL, deposition potential of –1.2 V, and deposition time of 500 s, the developed microbial sensor showed a linear response for the peak current between 0.5×10-5 M and 1×10-8 M of Pb(II) ions with the R2 value of 0.9979. The lowest limit of detection (LLOD) was determined as 2.4×10-7M of Pb(II) ions (0.05 ppm). The redox mechanisms of Pb(II) ions on the P. aeruginosa modified CPE surface are discussed.

Jan 1, 2016

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015

By E. Ghali, W. Zhang, G. Gabra, N. Sorour, G. Houlachi

The additives polyacrylamide, 1-Butyl-3-methylimidazolium chloride, Tetra-butylammonium bromide, Benzalkonium chloride and chitin are evaluated during zinc electrolysis from synthetic acidic sulphate electrolyte containing Mn2+ ions, in absence and in presence of 0.0055 mg dm-3 of Sb3+ ions. Galvanostatic polarization tests for 2 hours at 50 mA cm-2 and 38oC were carried out to determine the cathodic and anodic potentials, and current efficiency of the deposited zinc. Potentiodynamic polarization and cyclic voltammetry tests have also been employed to study the electrochemical behavior of each additive on the zinc deposit on aluminum electrode. Results showed that, in presence of Sb3+, adding 1 to 3 mg of 1-Butyl-3-methylimidazolium chloride increases the cell voltage by ˜0-7 mV. Current efficiency is increased by ˜4.90-6.40%; power consumption is reduced by ˜147-173 kWh t-1 by adding 1-3 mg, respectively. However, in absence of Sb3+, cell voltage is decreased by ˜7-28 mV, current efficiency is increased by ˜0.70-1.50%; power consumption is reduced by ˜41-47 kWh t-1 by adding 1-3 mg. The effect of the other additives on cell voltage, current efficiency, lead content and morphology of zinc deposit has also been examined. Surface morphology and crystallographic orientation of the deposit was studied using scanning electron microscopic (SEM) and X-ray diffraction (XRD), respectively. The content of lead in the deposit has also been measured using inductively coupled plasma spectroscopy (ICP).

Jan 1, 2015

By A. Ducastel, S. Connemann, A. Stark, F. Bouillot, C. Fricke-Begemann, LSA, H. Knapp, L. Horckmans

"Refractory materials are essential for all high-temperature applications in industry. Depending on the position in the furnace and specific process requirements, refractories are produced from several raw materials, such as dolomite, magnesite, bauxite, graphite or chromite. Most of these raw materials are not rare but strict quality requirements limit the producers of refractories to only a few deposits in the world. Thus, raw material supply is a critical factor for the production of refractories and accounts for 40-50 % of the total costs of refractories.A possible way to lower dependency on raw material supply is recycling of spent refractories. Main challenge in recycling is the separation of different brick types from each other and the removal of impurities, such as steel or slag. The European FP7 project REFRASORT aims to apply sensor-based sorting for separation of spent refractories. Sensor-based sorting is known from food industry, recycling and mineral processing and has proven its reliability. Nevertheless, some adjustments are necessary compared to applications in mineral processing because of other sensor-types and a higher number of products in one sorting step. This paper presents the results of feasibility tests for sensor-based sorting of refractories with near infrared spectroscopy and laser-induced breakdown spectroscopy (LIBS). Both sensors showed the potential to identify different brick types but the most promising results were obtained using LIBS technology. INTRODUCTIONRefractories are solid, ceramic products, which can sustain temperatures of more than 1500°C, without losing their stability or shape. Bricks of refractories have to withstand corrosion in contact with liquid steel or slag. Various high temperature applications, such as the production of glass, steel, copper or cement, require high quality refractories. The quality requirements of refractory bricks are strict, because small impurities can lower the thermal strength significantly."

Jan 1, 2016

By M. Abouhamad

According to the Canadian Urban Transit Association (CUTA), 140 Billion CAD is required to maintain, rehabilitate, and replace subway infrastructure between 2010 and 2014. The current practice adopted by transit authorities for prioritizing subway stations for rehabilitation is based on the station structural needs. While this classification is reflective of station condition, other factors, such as station size, location and passenger capacity, play an important role. The criticality of a station is an index that represents the functional importance of a station depending upon a set of identified factors. The system criticality is based on several attributes, such as station location, size, and nature of use. This paper presents a novel method of clustering subway stations for rehabilitation priority based on their criticality level. The different stations in a subway network are rated according to their relative importance against predefined attributes. The weights and scores of the attributes are computed with the help of experts and current subway network data. The analysis is done using the Fuzzy Analytic Network Process (FANP) to accommodate the subjectivity of human judgment as being expressed in natural language which entails ?fuzziness? in real-life problems and account for the interdependency between the selected attributes. The output of the model is a criticality based clustering of subway stations. The proposed framework helps authorities prioritize stations for rehabilitation and highlight stations with more criticality for a more robust asset analysis.

Aug 1, 2013

By William A. Napier

The Mantaro Phosphate Property is located ~ 250 km east of Lima, Peru in the Andean altiplano near the city of Huancayo, Junin District. The Mantaro deposit is a mineralized zone of phosphatic rock currently defined by surface outcrops, trenches and drilling extending over a strike length of more than 30 km and a width of more than 5 km covering ~27,700 hectares. Mineralization is exposed as three roughly parallel exposures (?mantos?) trending in a northwest-southeast direction along the Mancaspico syncline. Estimated mineral resources1 contained in Manto 1 of the Property (4% P2O5 cut-off) as of February 21, 2010, are: Measured 5.548 million tonnes @ 10.8% P2O5 Indicated 33.975 million tonnes @ 9.9% P2O5 Measured + Indicated 39.523 million tonnes @ 10.0 % P2O5 Inferred² 376.265 million tonnes @ 9.0% P2O5 1Tonnes rounded to the nearest 1,000 and grade to 1 decimal place. 2Inferred material reported with no cut-off and an assumed grade. There is considerable potential to expand the resource base. Mantos 2 and 3 of the deposit have been geologically mapped and exhibit surface mineralization widths similar to Manto 1. Given that the deposit is of marine sedimentary origin, it is reasonable to infer that comparable grades and depth of mineralization are present within Mantos 2 and 3. Based on this assumption, the potential mineral deposits within Mantos 2 and 3 are estimated to be approximately: Manto 2 425-435 million tonnes @ 9% P2O5 Manto 3 280-290 million tonnes @ 9 % P2O5 These potential quantities and grade are conceptual in nature, there has been insufficient exploration to define a mineral resource and it is uncertain if further exploration will result in these targets being delineated as a mineral resource. However, should such conceptual resources be confirmed by trenching and drilling, the Mantaro Phosphate Property would rank as one of the most significant phosphate deposits in the world.

May 1, 2011

By D. Yuan, M. Sitter, S. St. Jean, M. Collins

The Ambatovy Joint Venture comprises an operating lateritic nickel mine, ore slurry pipeline, pressure acid leach plant and nickel refinery in Madagascar. The hydrometallurgical process selected by Sherritt for treatment of the Ambatovy ore is a long-term, sustainable approach to producing nickel. Sulphur, used to prepare hydrogen sulphide, which is used to produce mixed sulphide intermediate, is recovered in the refinery as ammonium sulphate fertilizer. Additional sulphur is used to generate sulphuric acid for treatment of the ore in the high pressure acid leach (HPAL) step; fossil fuel consumption is minimized by using the heat generated from the exothermic reaction between sulphur and oxygen in the acid plant to produce power and steam. Steam consumption is minimized by design of efficient flashing and preheat systems for HPAL, while the high temperature of the HPAL step serves to minimize acid consumption. Fossil fuel consumption by the operation as a whole is further minimized by locating the leach plant and refinery near the port of Toamasina and utilizing a 220 km slurry pipeline to transport ore from the mine to the leach plant. In addition, Ambatovy has demonstrated a strong commitment to sustainability programs such as the biodiversity management program at the mine and local procurement in Madagascar. In this paper, the hydrometallurgical process for nickel and cobalt recovery from Ambatovy ore is described, along with highlights of Ambatovy’s approach to sustainability in Madagascar.

Jan 1, 2015

By E. G. Bazeley

The paper reviews the scope, timing and financial impact of this significant project, which involves the supply and transportation of nearly 4 million tons per year of bituminous coal and lignite from sources in British Columbia. Alberta and Saskatchewan to Ontario Hydro's generating stations. The critical factors involved in the selection and utilization of these coals are discussed in relation to the three types of coal to be utilized initially. The paper then deals with each of the significant project elements to be undertaken by the various companies involved in the mining and movement of the coal, beginning with production at the mine through rail shipment to Thunder Bay, train-to-ship terminalling, shipment by lake vessel from there to the generating station, and finally blending the bituminous coal with United States coal prior to combustion. The review discusses the key features of the facilities involved in each case and the status and timing of the project elements , which are phased for the start of coal shipment by mid-1978. The paper concludes with some observations on the capability of the project to handle increased tonnage s and the challenges facing the movement in terms of quality , quantity and cost.

Jan 1, 1978

By I. Ruiz Bustinza, L. F. Verdeja, Daniel Sbarbaro, R. Parra, J. Mochón

The oxidation of sulfides is a complex process involving gaseous products and intermediate species given rise to emission and absorption spectra which carry out important information about the reaction process. This information could be used for on line monitoring of pyrometallurgical reactor if the appropriate sensors were available. We present in this paper an analysis of the concept that has been successfully applied in iron and steel making industry, as well on fuel combustion control, where the spectra measurement gives the possibility for online monitoring and automatic control of high temperature processes. This concept has not been widely applied in the nonferrous pyrometallurgical primary production. The design of new sensors is discussed from the analysis of spectra measurements during flash combustion of copper concentrates at laboratory scale.

Jan 1, 2015

By K. Barbetti

"The carbon-in-pulp (CIP) process has been the dominant gold recovery process since the early 1980s. CIP has proven to be very adaptable for a wide range of ores and circuit configurations. The key performance indicator for CIP circuits is the minimisation of soluble gold losses to tailings, however, it is also important to operate the circuit efficiently (maximising gold loadings on carbon and minimising carbon inventory). Over the last 30 years the Curtin Gold Technology Group has studied CIP circuits as part of an on-going collaborative industry funded project (the AMIRA Gold Processing Technology Project). In the early years the project undertook basic research into understanding activated carbon, and its management in the circuit. More recently the development of process models and instrumentation has provided additional tools to assist operators. The results show that while most CIP circuits operate well, there are still significant opportunities for further cost savings, or additional revenue. This paper reviews the observations arising from this work, including key requirements for good carbon management, the results of benchmarking and industry surveys of carbon circuit over 20 years, the value of process modelling of CIP circuits to establish operating parameters, and the use of automated instrumentation to better optimise carbon control in the circuit.INTRODUCTION The introduction of activated carbon to recover gold from cyanide leach solutions in the last quarter of the 20th century was the most significant development in gold ore processing since the advent of cyanidation seventy years before. Replacing the Merrill–Crowe zinc cementation step with carbon-in-pulp (CIP) or carbon-in-leach (CIL) circuits provided a process that allowed the treatment of lower grade and problematic ores (e.g. high-clay ores), at lower capital and operating costs, and higher metal recoveries. The CIP circuit was first developed in the 1950s at the Carlton Mill, Cripple Creek, Colorado. All the components of the modern CIP process came to fruition at the Homestake Mine in South Dakota in 1973 (Fast, 1988). From the late 1970s onward a variation of CIP, carbon-in-leach (CIL) which combined the leach and adsorption stages, became the preferred circuit design in most parts of the word."

Jan 1, 2017

By O. G. Olvera

"Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Typical cyanide operations show poor performance and require oxidative pretreatments to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. This work focuses on evaluating the effect of the addition of a carbon resin as a sulfur collector on the oxidation of different arsenopyrite concentrates under atmospheric tank leaching (ATL) conditions. The addition of the resin improved the oxidation of sulfides and favored the formation of elemental sulfur over the generation of sulfate. The use of AF5 in ATL resulted in higher gold recoveries under standard cyanide carbon-in-leach and thiosulfate leaching.INTRODUCTION Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Gold is not readily accessible to solutions in these types of ores and typical cyanide operations show poor performance, thus making the use of oxidative pretreatments a requirement to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. The use of carbonaceous materials to enhance the dissolution of sulfides is not novel, and leaching additives such as coal, activated carbon and carbon powder have been considered for the improvement of bioleaching, atmospheric leaching, and pressure oxidation leaching processes. However, this type of technology has been focused mainly on the recovery of copper from copper concentrates containing chalcopyrite with less attention paid to other sulfides."

Jan 1, 2017

By H. C. L. Reemeyer

"The mining industry faces increasing economic, environmental and social challenges, as easier deposits deplete and ores become more difficult to mine and process; head grades decline; projects migrate to increasingly remote and difficult geographies; and the industry faces more stringent environmental and social standards. While these factors increase costs and risks, they also present opportunities for a more integrated approach to mining, processing, materials handling and waste management. Two key areas of risk are in tailings and water management. As mining and processing tonnage rates continue to increase, the disturbance footprints, water and energy consumption and scale of tailings storage facilities also rise. These factors can be mitigated by more selective mining, ore sorting and pre-concentration, and more intensive tailings dewatering. Such alternatives must be considered in conjunction with the selection of mining method, metallurgical flowsheets, major equipment selection, and key process design criteria. For example, increasing the grind size of a concentrator reduces energy consumption and eases tailings dewatering, but may cause challenges with metal recovery. Emerging technologies will be reviewed, and economic and environmental trade-offs for eco-efficient alternatives will be presented for metal sulfide mines.INTRODUCTION The metals mining industry faces significant challenges that can affect its financial viability and social license to operate. There has been a consistent decline in ore grades and a relentless push towards larger operations to capture perceived economies of scale. With these larger operations, the environmental footprint of mines has increased. Water and energy consumption, and resulting GHG emissions have also risen. In recent years, two issues have raised special concerns for stakeholders and companies: • Water scarcity, particularly in drier regions of the world such as Northern Chile, SW USA, Southern Africa and Australia • Tailings risks, following the high-profile failures of the Fundao tailings dam in Minas Gerais, Brazil in 2015 and the Mount Polley tailings dam in BC, Canada in 2014"

Jan 1, 2017

By T. Majcherczyk

Shaft lining reinforcing analysis of two shafts under construction has been presented in this study. The first shaft was driven from the surface, while the second was deepened. Mining and geological conditions have been studied with respect to the lining capacity. The improvement of shaft stability comprised two elements, i.e. reinforcement of the shaft lining capacity and improvement of the strength properties of the rock mass. In both tested cases, the particular hazard was connected with non uniform loadings of the lining, which could generate shearing stresses within lining structure. Thus such elements as armored concrete with high strength properties, bolting and injection sealing of the rock mass, and the use of special ring reinforcing the shaft lining have been used in order to reinforce the shaft-rock mass system. Practical conclusions related with new technological solutions, allowing the rock mass and shaft lining reinforcement, have been included for the present study. Practical conclusions related with new technological solutions, allowing for rock mass and shaft lining reinforcement, have been also included to the present study.

Aug 1, 2013

By A. D. Pittuck

Refractory minerals .containing uranium and columbium have been successfully treated at Queen's University, Kingston, to produce high-grade concentrates. Recoveries of over 90 per cent of the uranium and columbium have been obtained when treating concentrates containing euxenite, fergusonite, betafite, and pyrochlore. The processes ?consisted -of leaching the columbium with hydrofluoric acid, and the uranium with nitric acid, sulphuric acid, or sodium carbonate solutions. The leach liquors were extracted with organic solvents from which the values were stripped and precipitated, producing final products assaying 45 to 55 per cent Ob2O5 and 60 to 70 per cent U3Os.

Jan 1, 1958

By A. Rodriguez-Prado, P. Kuschk, R. L. Legge, W. C. Lennox

Using constructed wetlands to chemically reduce hexavalent chromium Cr(VI) to Cr(III) from industrial and mining wastewater has proven to be feasible and efficient. Applying first-order kinetics to describe the process is simple, but in some cases a more accurate model is required to reflect the process. This paper studies the feasibility of using non–first-order kinetics to describe the reduction process. Results indicate that half- and second-order kinetics adequately described Cr(VI) reduction in laboratory wetland mesocosms. The organic carbon content played a relevant role, whether it was built up by plant growth or spiked into the feed water.

Jan 1, 2014

By R. E. Hamilton

"The requirements for effective optimization of a mineral dressing operation are discussed, with specific reference to a flotation system . Also considered are the relation-ships between automatic control and optimization pro-grams. Variables are classified into the following groups, and the significance of the classification is discussed: (a) Directly measurable (b) Directly manipulable (c) Uncontrollable (d) Calculable from measurable variables (e) Affected by changes in manipulable or uncontrol-lable variables. New sensors for measuring variables not normally measured are described."

Jan 1, 1967

By A. Grimod

Rockfall drapery systems are commonly used as a simple, fast and cheap measure against the rock falling trajectories affecting very steep slopes. The system basically consists of a steel mesh, which is held on the top edge with a longitudinal cable fixed by means of a suitable number of anchors. The effect of this kind of intervention is to control the falls of the rocks, which are driven toward the bottom with slow velocity, or are stabilized on place. It can be used on any kind of slope to protect sensitive target in the mining industry, roads and railways, and inhabited areas. The falling blocks, typically smaller than 0.6 - 1.0 m in diameter, pile up into a trench (or into a ?pocket of mesh?) at the bottom. In comparison to other types of rockfall interventions, the simple drapery is cheaper, and its maintenance is easier, but on the other hand it cannot be considered the remedy for shallow instabilities, because it can only mitigate the effect of the falling trajectories. The design of simple draperies requires the analysis of several factors like the slope features (height, gradient, morphology), the geological and dynamic features (nature of the ground or rock, type of instability, erosion problem, blocks size), the environmental condition (presence of vegetation, aesthetical problem), the installation problem (accesses to the slope, safety for the workers, safety for the surrounding areas) and finally the performance required (temporary or permanent intervention, required maintenance, cost). Finally the most problematic design-step is the choice of the suitable mesh, the top longitudinal cable, and the top anchors type. Because of the highly variable nature of rockfall behaviour these structures cannot be standardized, but they have to be analyzed and designed for each case. Maccaferri has developed a new software application (MacRO 2) has a practical tool to define the mesh and the related supporting structure composed by up-slope cable and anchors. The software, based on the approach proposed by Muhunthan B. et al. (2005), allows designers to verify the top longitudinal cable, the anchors, and the mesh drapery, and to plan for maintenance procedures. Even if the method seems quite simple and rough, it is effective and lets the designer correctly foresee the materials and the geometrical features to be used on the interventions. This paper analyses the condition for the simple drapery installation, the main steps for the calculations, and it will present a case study in a U.S. mine. Nevertheless, even if the software allows a quick and simple calculation approach, onsite observations are always recommended in order to achieve a good design, with the ultimate goal of protecting property and human lives.

Aug 1, 2013

By D. C. Fraser, W. J. Scott

"Airborne electromagnetic surveys were flown during 1965 in the Moose River area of Ontario. The systems used were INPUT Mark II and the Canadian Aero Otter. Anomalies indicated by both systems were located on the ground with vertical-loop EM. Two such anomalies were drilled, with no explanation being found in the bedrock geology. Subsequent seismic, resistivity and gravity surveys indicated that the sources of these anomalies lay in the overburden. Current work in the similar geological environment of the Winisk River area has shown that comparable AEM anomalies can still be misleading. The lesson to be, learned from these experiences is that additional geophysical work can help to resolve doubtful cases before drilling decisions are made."

Jan 1, 1973

By K. U. Kainer

Magnesium and its alloys as the lightest available construction metal offer a wide range of opportunities for the usage in transportation industries, especially Magnesium wrought alloys with their improved mechanical properties show a high potential for structural applications, While magnesium cast components have found their application the interest is now spreading to wrought alloys due to the possibility to get even more homogeneous and better properties compared to cast parts, Therefore alloy and process development especially for extruded and sheet material is a main concern to enhance the application of Magnesium wrought alloys, Castings are still form the majority of applications of magnesium alloys, although efforts to develop adequate wrought alloys have increased, In the presentation, the alloy requirements for processing of cast and wrought alloys will be discussed, The various processing routes and alloy compositions result in specific microstructures and properties which determine the potential use of these alloys, Today, the spectrum of available alloys covers standard alloys as well as alloys for use at elevated temperatures, The trend will be to further diversify the alloy compositions and to improve the alloy properties, Areas of concern still remain the wrought processing and the high temperature (creep) and corrosion properties of magnesium alloys, Examples of recent developments in these sectors will be given, The presentation will also provide an overview of the historical and current use of magnesium and an outlook on future applications.

Jan 1, 2006

By N. J. Shackleton, N. A. Chapman, V. Malysiak, C. T. O’Connor

In this study, the effect of using conventional crushing and high-pressure grinding rolls (HPGR) in combination with dry or wet milling was investigated using a base-metal sulphide (BMS) sphalerite and a platinum group mineral (PGM) ore to determine how these processes affect the flotation performance. In sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc, whereas in PGMs, similar treatment produced the poorest results. The results were investigated further by the effect of factors such as percentage liberation and particle size on the flotation results.

Jan 1, 2012