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By Kazutoshi Haga, Ariunbolor Narankhuu, Ariuntuya Battsengel, Yasushi Watanabe, Altansukh Batnasan, Akita University

"Rare earth minerals are usually concentrated by flotation, magnetic or gravity separation methods to produce concentrates that are subsequently leached with hydrochloric (HCl), sulfuric acid (H2SO4) or nitric acid (HNO3). About 75 % REEs are lost in gypsum by-product when apatite is dissolved in H2SO4, whereas more than 80% of REE can be extracted from the apatite using HCl and HNO3 leaching processes, respectively. Therefore, the main aim of this study was to find an efficient process of dissolution of rare earth elements (REEs) from apatite ore by sulfuric acid solution due to its lower cost. In order to optimize the dissolution process, effects of different parameters, namely, concentration of H2SO4 (0.05 – 6 M), solid/liquid phase ratio (1:50 – 1:100), temperature (20 – 80 ºC), agitation speed (300 – 900 rpm), and leaching time (0.5 - 6 h) on the dissolution of REEs from apatite ore were examined in various intervals. The contents of main REEs in the apatite ore used in this study were (as % wt): 3 % La, 6 % Ce, 0.6 % Pr, 2.1 % Nd, 0.2 % Sm and 0.3 % Y. X-ray diffraction (XRD) analysis identified fluorapatite and phlogopite as main minerals in the ore. The results obtained from leaching experiments showed that more than 85% of REEs were dissolved from the apatite ore under the optimized conditions, which were: 1 M H2SO4, particle size of -150 + 100 µm, S:L phase ratio of 1:50, agitation speed of 500 rpm at 20 ºC for 1h. The XRD analysis revealed that main mineral compositions of the residues from 1M and 6 M H2SO4 leaching are gypsum (CaSO42H2O) and hemigypsum (CaSO40.5H2O), respectively.INTRODUCTIONThe term rare earth elements (REEs) denote the group of 17 chemically similar metallic elements consisting of the 15 lanthanides, plus yttrium (Y) and scandium (Sc) in the periodic table. These metallic elements are generally divided into two sub-groups; (1) the cerium sub-group, which is called “light rare earth elements” (LREEs), includes the elements from lanthanum (La) to europium (Eu), and (2) the yttrium (Y) sub-group elements, which are known as “heavy rare earth elements” (HREEs), are the remaining lanthanides from gadolinium (Gd) to lutetium (Lu) plus yttrium (Gupta and Krishnamurthy, 2005). The REEs occur together in the minerals due to their chemical and physical similarities, which cause problems of separating them from one another (Abreu and Morais, 2014). Although REEs are relatively abundant in the earth’s crust, they are typically dispersed and rarely occur in concentrated forms, making them economically challenging to obtain. There are a wide variety of rare earth minerals, however economic deposits of REEs in mining are bastnasite (La, Ce) FCO3, monazite (Ce, La, Y, Th) PO4, and xenotime YPO4 (Binnemans, 2013; Xie, et al, 2014). Due to the unique physical, chemical, catalytic, electrical, magnetic and optical properties of REEs, demand of these elements has increased dramatically with the advent of new technologies in electronics, communication, construction, energy and medicine (Jordens, et al, 2013). Since 1990, China has provided about 90 % of REEs worldwide. Japan and United States are the largest consumers of China’s REEs. In 2010, China announced to reduce REEs exports to Japan, as it tended to increase prices of REEs and to reduce a stable supply of REEs in the world market (Humphries, 2013). Therefore, there has been an increase in recent exploration activities intended to reveal new commercial sources of REEs and to bring them into production (Antico, et al, 1996). Apatite is an important host mineral for REEs in igneous and metamorphic rocks and can be used as an ore for those metals (Kanazawa and Kamitani, 2006). Apatite is also the main source of phosphate fertilizers and phosphoric acid (Habashi, 2013; Emsbo, 2015)."

Jan 1, 2016

By H. Chaouki

The aim of this work is to simulate the forming process of a green anode. For this purpose, a nonlinear compressible viscoelastic constitutive law is presented. The concept of natural reference configuration is considered. Within an isothermal thermodynamic framework, a Helmholtz free energy is proposed to take into account the nonlinear compressible deformation process occurring between natural reference configuration and current configuration. A dissipation potential is introduced in order to characterize the irreversible aspect of compaction process. Thus, the constitutive law is formulated through two equations: 1) an expression of Cauchy stress tensor and 2) a differential equation characterizing the evolution of the natural reference configuration. Material parameters are assumed to be a function of the bulk density. This allows capturing the micro-mechanical phenomena within the chosen macroscopic approach. An experimental study based on compaction tests is carried out in order to characterize the mechanical behaviour of the anode paste. A user's material VUMAT subroutine for finite element dynamic explicit analysis has been developed and implemented in the ABAQUS commercial software. To evaluate the model predictive capability, numerical simulations of the compaction forming process of anode paste were performed. Simulation results show that the constitutive law predicts the experimental trends and gives interesting physical responses. This constitutes a first step toward making a benchmark with experimental results on the forming process of anode paste.

Jan 1, 2011

By J. R. CAMERON

Gypsum is mined in all Atlantic Provinces except Prince Edward Island. It is generally thought to have been derived from the hydration of anhydrite in areas of minimal drainage. Late Devonian downwarping and crustal oscillation east of the Appalachian fold belt allowed the Windsor Sea to advance and retreat in a depositional trough and deposit about 1,000 m of sediments in Mississippian time, much of which were evaporites. The best areas for further gypsum development are lowland basins such as the Cape Breton Lowlands, the Hillsborough area of New Brunswick and the St. George's Lowlands in Newfoundland, all of which are already sites of gypsum quarries. Nova Scotia's gypsum is mined from the Lower Windsor Group, which is divided into subzones 'A' and 'B'; 'B' provides most of the province's gypsum production. The Atlantic Provinces gypsum industry has markets from the St. Lawrence waterway to the mouth of the Mississippi River.

Jan 1, 1984

By M. Uszko

The paper presents the conditions for determining the selection of methods for methane drainage in Polish hard coal mines. Various factors for the evaluation of methane drainage performance are used, including the methane drainage effectiveness ratio. However, as will be discussed there are limitations to the methane drainage ratio approach resulting from the characteristics of the deposits extracted in Kompania Weglowa S.A. coal mines.

Aug 1, 2013

By J. Dubinski

Underground mining of copper ore in the Legnicko-Glogowski Copper District basin generates a number of seismic events, whose energy often exceeds 108 J (Butra, 2010). The number of tremors and their location shows that the area of rock mass involved in the deformation and failure processes significantly exceeds the area of mining operations. Locations of seismic foci of high energy tremors, as well as the aftershocks that accompany them, extend hundreds of metres, confirming that processes to restore the energy balance of rock mass occur in a short amount of time and over a wide area. Thus, an area of similar size should be considered in predictive analyses of the tremor?s position. It should be emphasized that a large portion of the rock mass still has a level of freedom resulting from the way the rock mass is held together and its geometric continuity. This level of freedom is dependent on the scale and duration of mining, the number and size of natural structures, and rock mass pressure, including gravitational pressure constricting individual fragments of rock mass in the area (Burtan, 2012). It can therefore be assumed that in real conditions, areas where mechanical strength of the layers has been exceeded may be located a considerable distance from each other and do not necessarily need to coincide with the working area location. In this sense, a rock mass influenced by mining exploitation is essentially a rock mass in which numerous fragments with concentrated energy exist simultaneously. Energy will be released within these rock mass areas each time rock mass strengths are exceeded by the induced stress changes related to mining operations. This paper presents a discussion on how to predict the location of seismic activity areas based on a change of position of seismic energy equivalents. This parameter is calculated for a given set of seismic tremors with defined foci coordinates. For a given set of seismic tremors, the location of seismic energy equivalents may be used for predicting the location of high-energy seismic events.

Aug 1, 2013

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

By John Hansen

This paper has been written for presentation at the 103rd Annual General Meeting of the Canadian Institute of Mining, Metallurgy, and Petroleum, April 29 to May 02, 2000. The paper addresses blast pattern fragmentation and diggability versus the blasting technique used. RESUME The author is the Vice President for Thunderbird Mining Systems. In this capacity he manages the mine site installation of surface mining mobile equipment monitoring and navigation systems. These systems are onboard instrumentation and software systems designed to: ??measure and log mobile equipments? production and health; and ??direct the equipment operators via onboard displays that show comprehensive maps and engineering instructions. The author is a mining engineering graduate from the Royal School of Mines. His work experience includes front line supervisor and mining engineer for Hudson Bay Mining & Smelting, mining engineer for Teck Corporation, and mining consultant for PriceWaterhouseCoopers.

May 1, 2001

By R. Heikkilä

A large research and development program called RYM PRE (Process Re-Engineering) has been active in Finland since 2010. As a part of the program, a work packet Infra FINBIM is focused on the development of new national process model, specifications and requirements for the whole Finnish Infra Industry. In the Infra FINBIM, total 15 companies and main owners and 3 research organisations are included. The work is further continuing. The main achieved results up today have been the first specifications and requirements of the BIM based total process for infra sector, about 30 different pilot projects for testing of the new design and construction process models producing a lot of results and observations, a new open information transfer format Inframodel3 based on LandXML standard, the achieved acceptance of the Building SMART organization for support of international development, utilization and extension of the format within the whole infra industry, processes, software and other technical equipment. An evaluation of the results and this work will be drawn.

Aug 1, 2013

By lchimura. R. .

Japan Oil, Gas and Metals National Corporation (JOGMEC) and Centro de Investigation Minera y Metalurgica (CIMM) commenced a five year project from 2001 to modify the treatment of the furnace dust from Teniente converter containing harmful elements like arsenic and lead. The project was supported by Japanese and Chilean governments, and a demonstration plant was installed and operated at Las Ventanas Smelter and Refinery (Division Ventanas CODELCO). The basic and detailed engineering was made by Mitsui Mining and Smelting Co., Ltd (MMS) based on the joint study among JOGMEC, CIMM and Division Ventanas CODELCO. Arsenic in flue dust is lixiviated by sulfuric acid and fixed as crystalline ferric arsenate, where leachability of arsenic will be lower enough than the regulation, 5mg/I by TCLP (Toxicity Charactaristic Leaching Procedure) of USEPA. On the other hand, the recovered copper from the dust will be fed to the copper production process at Las Ventanas Smelter and Refinery, while zinc will be recovered as the exportable product. As introducing the crystallization and growing stage, the stable crystalline ferric arsenate formation can be achieved under the normal pressure.

Jan 1, 2007

By L. Vinnett, T. Ledezma, F. Contreras, F. Díaz

"Mass balances in secondary grinding are subject to critical constraints mainly because of the unknown load distribution from the SAG mills, the uncertainties in the hydrocyclone split estimations and the lack of flowmeters in the key streams. In this paper, a methodology to support mass balances based on the use of radioactive tracer is presented. This approach was successfully implemented in two secondary grinding circuits of Minera Los Pelambres, which operate with ball mills of 21’ x 33.5’. The method allowed the load distribution of the SAG product (secondary grinding feed) to be determined. This load distribution was used as an input in the mass balance data reconciliation.The effective residence times of solid tracers were obtained in the secondary grinding equipment, where irradiated solid was used as a tracer. The residence times were obtained from the parametric deconvolution between the input and output tracer signals. The model fitting was performed to reconstruct the normalized output tracer concentration. Effective residence times of solid tracers in the ball mills ranged from 1.9 min to 9.5 min. The use of radioactive tracer measurement in grinding circuits is a powerful tool to consolidate mass balance results as well as to characterize grinding mills.INTRODUCTIONGrinding is the last stage of the comminution circuits. At this stage, the ore particles are reduced in size by a combination of impact and abrasion, either dry or wet (Austin & Concha, 1994). The grinding equipment mostly used in industrial operations correspond to horizontal tumbling mills (Wills & Napier- Munn, 2006). Tumbling mills employ steel balls or rods as grinding media. Ball mills, which are a type of tumbling mills, use steel grinding media with greater surface area per mass unit than SAG (semiautogenous grinding) mills or rod mills (primary grinding). Hence, the ball mills are suitable to obtain the particle size required in the next separation stages (Napier-Munn et al., 1996; Wills & Napier-Munn, 2006)."

Jan 1, 2016

By Jamal Jafari, Abbas Sam

"The concentration of the fourth production line at Golgohar includes 66% iron with Blaine number of 500 cm2/g. For pelletizing process, the feed iron grade should be greater than 68% with minimum Blaine number of 1800 cm2/g. In this study, the low intensity magnetic Separators, particularly the feed particle size distribution of LIMS were considered. The feed particle size distribution of the separators was optimized to prepare an appropriate concentrate (as mill pelletizing feed). The samples were performed from the LIMS feed and after grinding, four d80 (64, 103, 132, and 15 3µm) were prepared. Then, laboratory magnetic separation experiments were conducted on these samples. The best results obtained using d80 of 132µm. In this particle fraction, the iron grade and Blaine number were 70.3% and 1571 cm2/g, respectively. Therefore, it seems necessary to include a grinding and classification systems before LIMS stage. According to the presence of a high amount of -132 µm particles in the initial feed, an inverse closed circuit was selected. The hydrocyclone was designed in three units as the classification system with 62 cm (diameter), 22 cm (overflow outlet) and 11 cm (apex diameter). By simulation of hydrocyclone with USIMPAC software, the size distribution of underflow was determined. Based on these results, a ball mill with dimensions of 6.7 m (length) and 5 m (diameter) was designed as grinding system.INTRODUCTIONGole-Gohar iron ore concentration plant No.4 (Polycom Plant) in Gole-Gohar Industrial and Mining Complex was installed to increase production capacity as well as treating the circulating load from AG and SAG mills of the main concentration plant of the complex. The load from the mine is crushed using jaw and cone crushers. The crushed ore is then combined with the circulated load and the combination is then grounded using HPGR and ball mills respectively.After comminution, there is a magnetic separation plant which includes a medium intensity magnetic separator (MIMS) followed by three low intensity magnetic separators (LIMS). Final concentrate dewatering is done using three belt filters. After the primary magnetic separation, the ore is upgraded to 62% Fe content and final concentrate which is the product of LIMS has 66% Fe content."

Jan 1, 2016

By Thomas Genty, Pascal Marcotte, Matthew Gillman, John Baechler

Elevated concentrations of ammonia nitrogen is a common characteristic of mine impacted water and generally results from the dissolution of undetonated explosives (i.e., Ammonium Nitrate and Fuel Oil and emulsion explosives) by contact water. Several active water treatment technologies are commercially available to remove ammonia nitrogen, but reduction of active treatment demand by promoting natural attenuation is considered best industry practice. In this paper, the results of laboratory-scale and full-scale trials of a semi-passive approach (i.e., enhanced algae growth) to remove ammonia nitrogen at the Meliadine mine are presented. Phosphorus was found to be the limiting factor to algae growth at the mine site. The addition of various concentrations of phosphorus was first tested at a laboratory scale. The samples were exposed to in-situ conditions, and ammonia nitrogen removal rates ranging from 40% to 93% were achieved over a period of 24 days. This paper also presents the methodology and results of an in-pond treatment during which a 50% ammonia nitrogen removal rate was observed after 68 days. The studied mine site uses breakpoint chlorination as its primary treatment approach for ammonia nitrogen removal. The results presented in this paper show the potential of using enhanced algae growth as a pre-treatment method, subsequently reducing the quantity of chemicals required for operating the breakpoint chlorination plant. This potential requires further investigation and additional trials are currently under evaluation.

Jan 1, 2023

In the flotation of a copper ore, entrainment of fine silicate and iron sulfide gangue minerals resulted in poor copper concentrate grade. In the cleaning stage, rejection of these gangue minerals was particularly difficult due to severe mechanical entrainment when the rougher concentrate was ground to 10 µm. To reduce gangue entrainment, polymeric depressants were tested. The rationale being that with the use of such polymeric depressants that also possess flocculation power, not only minerals-to-be-depressed can be made hydrophilic, but their particle size can also be enlarged. In this manner both the "genuine" flotation and the mechanical entrainment can be reduced. An effective polymer to reduce entrainment of silicate gangue mineral in sulfide flotation was identified from bench flotation tests conducted on single minerals. It was then applied to the flotation of a copper-gold ore confirming the beneficial role of the polymeric depressant in the reduction of fine gangue entrainment.

Jan 1, 2007

By D. B. Apel

As depths to the ore bodies keep increasing around the globe, the problem how to deal with the increasing temperature of undisturbed rock mass becomes very important. In extreme cases the rock temperature at the bottom of the mine could raise up to 80 °C. In deep mines, geothermal heat is considered as the primary heat load contributor, which accounts for 50?90% of the total heat load depending on different geological conditions. Thus the geothermal heat control in underground mines is the most important and demanding issue to ensure a suitable working environment. In this study, expanded perlite aggregate (EPA) was incorporated as a lightweight substitute for sand. Five mixtures were prepared using 0, 25, 50, 75 and 100% replacement ratios of sand by EPA. These, mixtures were tested in the laboratory for both the insulating and strength properties of the developed shotcrete. The goal of this research was not only to develop shotcrete which would exhibit good insulating properties but also which would exhibit strength properties similar to the regular shotcrete. This paper not only reports the results of the laboratory tests but also discusses the output of numerical model which was performed to evaluate the benefits of using the insulating shotcrete in reducing the cooling costs at hot underground mines.

Aug 1, 2013

By K. A. Natarajan, M. N. Chandraprabha

Selective separation of minerals from complex sulphide ores is a challenging task and it is often difficult to get commercially acceptable individual concentrates by conventional selective flotation using inorganic collector reagents. Microbially-induced mineral beneficiation has proved to be more effective, economically viable and an environmentally benign process for the effective separation of various minerals. Applications of microbially-induced mineral beneficiation are demonstrated in this paper with respect to beneficiation of complex multimetal sulfides. The role of adapted microorganisms and bioreagents in the beneficiation of complex sulphide minerals are also illustrated.

Jan 1, 2009

By A. Azizi, P. Blatter, A. Bouajila

ABSTRACT In-situ monitoring of gold dissolution by means of a rotating electrochemical quartzcrystal microbalance unveiled dramatic decreases in gold leaching from sulphide-rich ore after 360 minutes in an actual cyanidation circuit. Pre-oxidation was effective in enhancing gold extraction by preventing a passive film from forming on gold surfaces. This work aims to highlight efforts undertaken to determine (1) how gold cyanidation is limited by passivation, (2) what reactions and mechanisms are involved during sulphide-rich ore cyanidation, and (3) how peroxidation efficiency of an industrial sulphide ore is controlled by galvanic associations between its sulphide constituents.

Jan 1, 2013

By M. Kamyab

The Deep Exploration Technology project, as part of the Australian Cooperative Research Centre, is developing technologies to drill deep boreholes for mineral exploration purposes. The aim of the initiative is to transfer drilling technologies from oil and gas into mining applications. Several modifications have to be pondered due to this technology exchange: smaller cuttings sizes because of using impregnated diamond bits; narrower annulus space; higher drilling fluid velocity and likelihood of turbulent flow regime in the annulus; and higher pressure loss. In particular the results of our lab experiments have shown that the increase in concentration of small size cuttings can significantly change the rheology of the mud when drilling in hard rocks. This, in return, could have a noticeable increase in the pressure loss encountered along the annulus space. As a continuation of the above study, numerical simulations were conducted to investigate the cuttings transport behaviour in small size annulus space. Fluid velocity, annulus size, cuttings concentration, cuttings density, and cuttings size were some of the parameters that were varied to see their effects on cuttings transportation and the pressure loss along the annulus space. The results indicate that, due to the differences between oil and gas and mining drilling, conventional oil well planning is not applicable for mineral exploration drilling and numerical simulation would help in this matter.

Aug 1, 2013

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By Jessica E. Heuchan

An industry survey has been conducted by the Queen's University Mining Engineering Department of 30 Canadian mining organizations to determine how effectively newly graduated mining engineers meet the needs of the industry. The principal objectives of the survey were to evaluate, and thus provide focus on change for, curricula being taught at Canadian mining engineering schools in service of the industry's needs; to provide feedback on current industry expectations; and to reinforce contacts with the industry as a means of providing future collaboration. A strong focus of the survey was placed upon industry's perception of the special attributes of engineering hires and applicability of student academic training to meet their industrial requirements. In providing this detailed summary of corporate responses, a clearer understanding of the mining industry's expectations of engineering training at Canadian colleges and universities has been gained.

May 1, 2003

By S. V. Ulianov, A. Y. Senchenko, A. A. Shvets, A. V. Aksenov

Development of an efficient technology to process complex ores containing gold and antimony as well as silver is described in the paper. The results from the testwork aimed at the valuables recovery by means of flotation are presented. A process sample of antimonite gold-bearing ore was studied in TOMS institute aiming at development of a technology to process such an ore with generation of antimony concentrate and sulphide gold-containing concentrate. Material composition study indicated that the ore included 5.3% of sulphides: arsenopyrite – 2.4%, pyrite -2.4%, and antimonite – 0.5%. Gold is present as an isomorphic dissemination in arsenopyrite. At sighter testing stage a direct selective flotation flowsheet was chosen to process the ore. Antimonite flotation was activated due to addition of lead nitrate. A single cleaning of a rougher flotation concentrate resulted in antinomy concentrate with 30% Sb content and 71% recovery. Au recovery into antimony concentrate did not exceed 1%. Sb flotation tailings were used to float the remaining sulphides and gold. The resulted sulphide concentrate was characterized by Au content of 20 g/t at about 80% recovery, arsenic content - 10% at ~80% recovery, and sulphur content - 18% at ~81% recovery. The sulphide concentrate can be forwarded to further processing aiming at gold recovery. Given that the concentrate is highly refractory it should be pretreated (bacterial or pressure oxidation, Albion process) prior to cyanidation in order to liberate gold from sulphides. The proposed technology allows one to solve the problem of precious metals recovery from antimonite ores.

Jan 1, 2016