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By R. Sharma, I. Miskovic, S. Miskovic

Solvent extraction (SX) is a widely used method for the extraction of copper from pregnant leach solutions or other ionic solutions in hydrometallurgical applications. About 17% of total refined copper production worldwide is produced using SX followed by electrowinning (EW). Conventional SX units, such as mixer-settlers, consume a large amount of extractant, offer poor process control and yield low extraction efficiency. Extraction efficiency is poor due to low specific interface area, crud formation, emulsification, and slow phase separation stage. Micro solvent extraction (micro-SX) is a rapidly developing technology that provides an opportunity for improved process control, higher extraction efficiency, lower residence time and, as such, has a potential to reduce the environmental footprint of SX operation. In this research, extraction of copper ions in an acetate buffer media is investigated using D2EHPA with kerosene as a diluent. Chemical factors such as extractant concentration and ionic concentration of aqueous phase are varied to determine the optimum conditions. Subsequently, the extraction efficiency and reaction time of new micro-SX reactors are compared against previous bulk SX studies. Extraction in the microfluidic reactor was observed to be faster with a residence time more than an order of magnitude lesser than bulk SX. This study forms a prelude for developing new modular micro-SX units which will enable continuous, effective, and safe operation on a large scale. In future studies, numerical and analytical models validated through this work will help eliminate rigorous experimentation and enable faster design and fabrication of micro-SX units. INTRODUCTION Conventional industrial solvent extraction (SX) units such as mixer-settlers, extraction columns present various disadvantages. Low specific interfacial area, crud formation, and emulsification in industrial reactors lead to long extraction times and severely hamper extraction efficiency (Priest et al., 2011; Chen et al., 2017). Microfluidic extraction considerably improves upon the current extraction practices by (1) creating a large surface to volume ratio that enables rapid mass transfer across the interface, (2) better process control, and (3) easier separation of phases (Kashid, Renken, & Kiwi-Minsker, 2011; Ciceri, Perera, & Stevens, 2014). These factors establish micro-SX as a crucial mode for process intensification. Although, a micro SX unit has significantly low processing volume than conventional extraction methods, their throughput can be increased via massive parallelisation (‘numbering up’), which is an area of active research (Darekar, Singh, Mukhopadhyay, & Shenoy, 2016a; Kriel, Woollam, Gordon, Grant, & Priest, 2016).

Jan 1, 2019

"In 2000 the CIM Council approved the CIM Standards on Mineral Resources and Reserves – Definitions and Guidelines, developed by the CIM Standing Committee on Reserve Definitions. The Definition Standards established definitions and guidelines for the reporting of exploration information, mineral resources and mineral reserves in Canada. The Mineral Resource and Mineral Reserve definitions are incorporated, by reference, in National Instrument 43-101, Standards of Disclosure for Mineral Projects, which came into force in Canada in February 2001 and was amended in December 2005.CIM DEFINITION STANDARDS- For Mineral Resources and Mineral ReservesPrepared by the CIM Standing Committee on Reserve DefinitionsAdopted by CIM Council on December 11, 2005FOREWORDCIM Council, on August 20, 2000, approved the ""CIM Standards on Mineral Resources andReserves - Definitions and Guidelines,"" developed by the CIM Standing Committee on ReserveDefinitions. The CIM Definition Standards on Mineral Resources and Reserves (CIM DefinitionStandards) establish definitions and guidelines for the reporting of exploration information,mineral resources and mineral reserves in Canada. The Mineral Resource and Mineral Reservedefinitions were incorporated, by reference, in National Instrument 43-101 - Standards ofDisclosure for Mineral Projects (NI 43-101), which became effective February 1, 2001.At the August 20, 2000 Council meeting a new CIM Standing Committee on ReserveDefinitions was established consisting of the following: John Postle, Bernie Haystead, LarryCochrane, Normand Champigny, Mike Hoffman, Colin McKenny, Jack Mullins, Phil Olson,Fred Payne, Jody Todd and Joe Ringwald.Subsequent to the publishing of the August 20, 2000 CIM Standards on Mineral Resourcesand Reserves, various CIM committees have compiled and published more extensivedocumentation on mining industry standard practices for estimating Mineral Resources andMineral Reserves. These standard practices provide more detailed guidance than that containedin the August 20, 2000 CIM Standards on Mineral Resources and Reserves. On November 14,2004 CIM Council adopted an update to the CIM Definition Standards to reflect the moredetailed guidance available and effect certain editorial changes required to maintain consistencywith current regulations. This version of the CIM Definition Standards includes further editorialchanges required to maintain compatibility with the new version of National Instrument 43-101which is expected to become law at the end of 2005. The CIM Definition Standards can beviewed on the CIM website at www.cim.org."

Jan 1, 2003

By R. P. Viljoen, A. L. Sokolov

"The distribution of mineralized provinces is analyzed on the basis of their genetic link with specific blocks of the earth's crust including ancient platforms, mobile belts and zones of tectonicmagmatic activation. Mobile and fold belts surround the Siberian platform in Russia and the Kaapvaal craton in South Africa, with decreasing age zoning away from ancient platform margins. The main differences in the geological development of the two cratonic areas are: (1) the long period before the final stabilization of the Siberian platform (3600 Ma to 1600 Ma) and the comparatively short period of time for the stabilization of the Kaapvaal craton (3600 Ma to 3050 Ma) and (2) the intensive multiple activation of the marginal zones of the Siberian platform and the tectonicallycontrolled, magmatic sedimentary, intracratonic activity, typical of the Kaapvaal craton. Mineralization of the Siberian platform is largely characterized by marginal reactivation zones of differing ages although mineralized intracratonic Cu-bearing basins of Proterozoic age are also known. Mineralization of the Kaapvaal craton is mainly related to the formation of the intracratonic basins i.e., Witwatersrand (Au, U) and Transvaal (Au). The latter is characterized by multi-age volcanic-intrusive activity including the emplacement of Bushveld Complex (Cu, Ni, Pt, Cr, Au, V). The Siberian platform is characterized by the prolonged development of inherited mineralization from Archean until the late Mesozoic. The main period of mineralization in the Kaapvaal craton is restricted to the middle Proterozoic.The Baykal-Patomskaya and Namaqua-Natal mobile zones occupy similar positions adjacent to the Siberian and Kaapvaal cratons, respectively, and demonstrate similar modes of metallogenic development: i.e., the early formation of exhalative Pb-Zn-Cu deposits during the early stage and magmatic Cu deposits during the late stage. The more remote mobile belt near the Siberian platform, the Trans-Baykal, is characterized by intensive multi-age mineralization (Wo, Mo, Sn, fluorite), related to a period of tectonic-magmatic activation. The Saldania Belt occupies a similar position near the Kaapvaal craton but is known for its poor Au, and Cu mineralization. It does, however, have some similarities with Trans-Baykal Belt in regard to Mo-W bearing granitoids.The phenomenon of interference of geosynclinal, orogenic, platform, and tectono-magmatic activation regimes is known for the Russian section of the Pacific Ocean Volcanic Belt."

Jan 1, 1994

By H. Helmstaedt, P. Thurston, R. Harrap

"Evolution of the continental lithosphere over Earth’s 4.6 billion year history is one of the fundamental questions of geoscience. Much of the Earth’s present-day continental crust formed during the first 2 billion years, the Archean eon, of the planet’s lifetime and thus, Archean processes of lithospheric formation must be studied in order to address this question. Until recently, the processes of Archean lithospheric evolution were thought to be fundamentally different from present-day plate tectonic processes. However, subsequent evidence suggests that the growth of Archean continents may be explained in terms of modern tectonic accretionary tectonics similar to those presently operating in the southwest Pacific region. The evidence supporting this hypothesis was compiled largely by Canadian geoscientists working in the Superior Province of the Canadian Shield in northwestern Ontario, over the past 15 years. Study of Archean rocks is also economically important because the Archean rocks of the world, although comprising only a relatively small fraction of the exposed continental crust, contain much of the world’s mineral wealth, including more than half of the world’s gold, as well as significant base metal reserves. Furthermore, the vast majority of primary economic diamond deposits are derived from the lithospheric roots beneath Archean cratons.The LITHOPROBE Western Superior Transect is located within the western part of the Superior Province in northwestern Ontario (Fig. 1). The Superior Province is the largest and best exposed Archean crustal block in the world and forms the nucleus of the North American continent. The internal structure of the Superior Province records a history of the processes that formed the earliest lithospheric elements of the Earth into cratons, thus providing an ideal laboratory for investigating early crustal evolution. The Western Superior Province is characterized by a regional pattern of alternating, 100 km to 200 km wide geological belts (Fig. 2). The observed geologic relationships between and within these subprovinces have been explained in terms of a modern tectonic model of terrane accretion. Oceanic floor, volcanic island arcs, oceanic sediments and continental fragments were accreted successively from north to south against the southern margin of a cratonic nucleus (North Caribou terrane, Fig. 2) which grew steadily in size with the arrival of new terranes through geologic time. If this model is correct, it suggests that the tectonic processes operating today have been active without major variation over the past 3 billion years."

Jan 1, 1998

By Alfred W. G. Wilson

MR. F. E. LATHE: In studying any subject whatever, one should at least occasionally stand back from the canvas, as it were, and take a broad view of the picture. It is such a view of the subject of industrial minerals that Dr. Wilson has given us today, and, in consideration of our efforts to utilize Canada's resources to the utmost in the present emergency, it seems most timely. I shall confine my remarks on the subject to the resources of the atmosphere and hydrosphere. We seldom stop to realize our dependence upon the atmosphere, not merely as a source of the oxygen we breathe but also of other indispensable elements. As recently as the beginning of the present century, grave concern was felt lest the rapidly increasing population of the world should ultimately starve for lack of the nitrogen required for crop growth. I recently noticed a reference to the Scientific American for March, 1890-just fifty years ago-in which an account is given of work on the fixation of nitrogen, which, said the article, "leads to the conclusion that while cyanides and ammonia may be thus produced experimentally, there are as yet insuperable difficulties in the way of adapting those methods to industrial purposes". Y et, in the early part of the present century, the development of the arc, cyanamide, and synthetic ammonia processes of nitrogen fixation was such as to remove, for all time to come the possibility of a shortage of nitrogen. Today, the atmosphere is by far our greatest source of nitrogen, and the capacity of the nitrogen fixation plants of the world is at least 4,000,000 tons annually-much more than can at present be utilized. Pure oxygen or oxygen-enriched air offers great possibilities in metallurgy and industrial chemistry, but, so far, little application has been made. In a paper presented to the Institute in 1926, 1 pointed out the theoretical savings which could be effected by the use of oxygen in burning carbon-when the gases pass off at 2,460°F., the fuel saving is no less than 50 percent. The use of oxygen on a commercial scale is intimately tied up with the question of refractories, but we should not forget that the possible changes in metallurgical practice by the use of oxygen are truly of revolutionary character.

Jan 1, 1940

By E. Hinton, L. Bloomquist

"This paper describes a guidance system for autonomous underground mining vehicles, which does not require any infrastructure or inertial positioning systems to aid the guidance process.BackgroundINCO Limited mines approximately ten million tons per annum through 12 operating mines in the Sudbury, Ontario, area (Fig. 1). With challenges from operating in a cyclical marketplace as well as new technologies making alternative nickel ores more competitive to refine, the Mines Research department embarked on a strategy that pointed toward automation as a tool to help the company become even more economical in mining.The mining industry has been looking for ways and means to mine orebodies more and more inexpensively. Automation and the lessons learned from manufacturing had a great influence in the direction of research at INCO Limited over the past ten years. Guidance systems have evolved over the years but the majority of commercially available systems rely on some form of infrastructure. This, in part, has caused some resistance from operators to install and maintain automated or semi-automated systems for guidance of underground machinery.Internal industrial studies cited travel time to and from the workplace as one of the major time sinks in the shift of underground miners. Depending on the mine, it may be as much as two hours moving in and out of an area. Some work areas have accommodated this by having “hot changes” at the work place. However, at some point in time, there are two people tasked with the same job and on site at the same time to make this overlap occur.Tele-operation of underground hard rock equipment eliminated this overlap and also provided a comfortable environment in which to work. By taking advantage of the communications network installed, the miners proved that they could operate three machines with relative ease. This was accomplished by a vision-based, “painted line,” autonomous guidance system termed the light rope system.With a few years’ experience with the system, some issues have arisen, including the cost of the rope itself (Fig. 2).The vehicle’s route is limited to the paths defined by the light rope, and a system of switching power to the light rope to select different routes is required. The rope itself is subject to damage from nearby blasts. Also, the system offers no obstacle detection; the vehicle may be switched off as a means of shutting the machine down thus protecting personnel in the area."

Jan 1, 2001

By Michel Gauthier, Jacque Trottier

"ForewordA symposium on base metal deposits was held in Bathurst, New Brunswick, from June 10-13, 1990, sponsored jointly by the Geological Surveys Branch of the New Brunswick Department of Natural Resources and Energy, the New Brunswick Prospectors and Developers Association, and the Geology Division of the Canadian Institute of Mining, Metallurgy and Petroleum. Papers prepared for the symposuim are being published as a series of articles in the CIM Bulletin. This third paper (the first was by Fyffe, et al., in Vol. 83, No. 938, the second is in this issue) in the series presents an overview of the tectonic setting and geochemistry of base metal deposits in the Eastern Townships of Quebec.ABSTRACTIt is well known that the classification system of volcanogenic massive sulphides (VMS) is based upon their metal content. This metal content, the result of hydrothermal solutions circulating within strata underlying the deposits, is generally thought to be related directly to two parameters: (1) the nature of the underlying stratigraphic sequence; and (2) the physico-chemical conditions that existed at the time of the hydrothermal event. Furthermore, these two parameters are, in turn, related to the tectonic setting. One must bear in mind that these parameters are diachronous and evolve with time. These factors are considered in our analysis of the major VMS deposits of the southeastern Quebec Appalachians. This analysis will describe the time and environment of formation of these deposits and integrate them into an evolving paleotectonic model.VMS deposits in the southeastern Quebec Appalachians formed during three distinct metallogenic episodes. During the first episode, which involved early closing of the Iapetus Ocean and associated destruction of oceanic crust by subduction processes(Early Ordovician?), cupriferous VMS deposits hosted by pillowed, mafic (boninitic) lava flows were formed in immature island-arc systems (""Cyprus-type"", e.g. Huntingdon deposit).In the second episode, which also occurred during the closure of Iapetus but at a later stage (Early to Middle Ordovician), mature island-arcs formed and hosted polymetallic VMS deposits (""Kuroko-type"", e.g. Eustis deposit).Finally, during culmination of the Taconic and/or Acadian orogenies (Middle Ordovician and/or Devonian), transtensional basins, associated with tholeitic to transitional mafic volcanism began to develop. Major sedimentation occurred contemporaneous with volcanism, and within this framework polymetallic VMS deposits were formed (""Besshi-type"", e.g. the Memphremagog deposit).Although incomplete, the proposed paleotectonic model represents the sequence of the tectonic settings that prevailed during the formation of the VMS deposits of the southeastern Quebec Appalachians."

Jan 1, 1991

By J. Peace, J. R. Fletcher

"British Steel has increased its usage of stainless steel for bunker, silo and chute linings to reduce maintenance costs and improve productivity.A generation of low cost 12% Cr steels has been specifically developed to satisfy the needs of hardness, flow promotion and through life costing which are demanded by bulk solids handling industries.The range of stainless steels include:• a very hard martensitic grade which is particularly suitable for high stress applications where impact and abrasion are predominant;• a titanium stabilized duplex steel for structural applications, as well as low friction , medium abrasion resistant wear liner plate; and• a ferritic stainless steel with rubber backing for low stress application where flow promotion of product is the predominant requirement.Industrial applications and experiences along with methods of fixin g the stainless steels will be discussed in conjunction with the relative through-life costs of the products.IntroductionBritish Steel has become one of the most efficient steel manufacturers in the world, with improvements seen in productivity, quality, delivery, performance and response to the needs of the worldwide market place.Part of this success stems from reductions in engineering downtime in the key areas of its operations, by the introduction of better engineering design and the use of enhanced materials where significant cost benefits have been identified.The nature of producing iron and steel requires the use and handling of a number of raw materials with wide ranging properties, each calling for a different approach to solving the difficulties encountered in storing and transporting these materials to their respective point of use. Figure 1 shows steel production for 1988-89 where over 30 million tonnes of raw materials were handled in making 14 million tonnes of liquid steel at British Steel's five integrated works.Typically solid raw materials include, iron ore, coal, limestone, ferro alloys and scrap. Intermediate products such as coke and sinter create their own specific handling and wear problems.Coals and ores are shipped into the United Kingdom from several sources, and have a great variety of properties. Some coals can be extremely wet and sticky, whereas others are dry and dusty . The ores handled can vary from wet concentrate and fines to heavy angular rubble and pellets. These raw materials are off-loaded, stored and conveyed through British Steel's own port facilities at Port Talbot, Immingham, Redcar and Hunterston. British Steel also produces the majority of its own coke and all its own sinter. Coke and sinter are frequently handled at elevated temperatures which cause other handling problems."

Jan 1, 1991

By E. Johansson, T. Siren, K. Kemppainen

"As part of the preparations for the design of an underground repository for radioactive waste at Posiva’s Olkiluoto site on the west coast of Finland, there has been considerable site investigation work. Except the extensive surface based investigations, Posiva started in 2004 the construction of an underground characterisation facility termed the ‘ONKALO’. The ONKALO has now been completely excavated to the anticipated repository depth i.e. -430–450 m. The research conducted in the ONKALO gives further information on the bedrock and groundwater conditions of the final disposal site, as well as on the impact of the construction. The ONKALO provides an excellent opportunity to investigate the rock at tunnel scale, to conduct in-situ testing in rock, to develop excavation and final disposal techniques in realistic conditions. The ONKALO has aided in collecting the data needed, supported by a Preliminary Safety Assessment, for the application of the construction license that was submitted in the end of 2012. The target is to begin disposal operations in 2022. According to current plans, the final disposal would end in 2112 and the repository would be sealed up by 2120. The testing in the ONKALO still continues several years. This paper presents the current characterisation and research activities in the ONKALO. INTRODUCTIONAfter the Finnish Government's favourable policy decision in 2001, Posiva Oy, which is an expert organisation responsible for the final disposal of spent nuclear fuel of the owners in Finland, has focused further investigations at the Olkiluoto site, western Finland (Figure 1) and has started in 2004 the construction of an underground facility termed the ‘ONKALO’. The ONKALO is not a nuclear waste repository, but more than just an underground research laboratory URL – it is an underground rock characterisation facility. The ONKALO has now been completely excavated to the anticipated repository depth i.e. -430–450 m. In addition to facilitating bedrock research, the ONKALO also provides an opportunity to develop excavation techniques and final disposal techniques in realistic conditions. Later, the ONKALO facilities can be put into use when building and using the repository. The construction methods and materials have been selected in order not to jeopardise the long-term safety of the repository site. The findings of the ONKALO and other investigations will provide the knowledge needed for an application, supported by a Preliminary Safety Assessment, to construct a final repository for spent nuclear fuel at the site. Posiva has submitted an application for the construction licence for a disposal facility in the end of 2012. The target is to begin disposal operations in 2022 and the repository would be sealed up by 2120."

Jan 1, 2015

By D. Kershaw

"A world-scale surface mining operation is associated with the Syncrude Oils ands Plant. Each day over 300 000tonnes of oils and are mined and transported to the process plant to produce 129 000 barrels of synthetic crude oil.Examples of research and maintenance engineering programs which have resulted in substantial gains in dragline and bucket wheel conveyor system productivities are discussed. Two central themes within these programs, which go beyond the usual technical support associated with a large surface mining operation, are pursued:1. the approach taken to determine the causes of component failures and provide Syncrude performance specifications to allow manufacturing industry to respond with more appropriate products; and2. systems and equipment studies which have led to higher productivity in the major mining equipment and the development of an auxiliary feed system.IntroductionA world-scale open pit mining operation is associated with the Syncrude Oils ands Plant located near Fort McMurray in northern Alberta. Over 300 000 tonnes per day of oils and are mined and transported to the process plant. Fifty million barrel s of synthetic crude oil were produced in 1987, which represents 10010 of Canada's crude oil requirement.following tree clearing and surface drainage, overburden is removed by mobile equipment ahead of oils and mining. Draglines excavate the 40 m depth of feed grad e oils and which is windrowed on the dragline bench. Bucketwheels reclaim the oils and from the windrows for transport by conveyor systems to the extraction plant surge pile.The Syncrude mine is operated in four essentially equal quadrants, each serviced by a dragline and a bucketwheel conveyor system. The mining face in each quadrant is approximately 2 km long and reclaimed oils and is transported by 1830 mm shift able conveyors over distances up to 6 km. Individual conveyors vary in length up to 2500 m.The Syncrude plant started operating in late 1978, and Figure I shows the mine production history through to the end o f 1987. Annual production volumes have increased from 50 million tonnes of oils and in 1979 to 105 million tonnes in 1987.The period from 1982has seen a change in operating philosophy, away from striving for very high production rates, to operating at sustained targetted levels within the measured capacity of the equipment. Higher over-all production volumes have resulted from being able to operate for more hours at these rates. This same period has also seen much greater emphasis placed on routine inspection of the equipment and planned preventive maintenance to avoid problems which could otherwise impact on production."

Jan 1, 1990

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By S. D. Normani

A Deep Geologic Repository (DGR) for Low and Intermediate Level radioactive waste has been proposed by Ontario Power Generation for the Bruce Nuclear site in Ontario, Canada. The DGR is to be constructed at a depth of about 680m below ground surface within the argillaceous Ordovician limestone of the Cobourg Formation. The objective of this paper is to apply paleoclimate boundary conditions to a regional-scale groundwater flow model for the DGR site and to describe the influence of glacial loading and unloading on flow system evolution using the FRAC3DVS-OPG flow and transport model. The regional-scale domain encompasses an area of 18,775km2 extending from Lake Huron to Georgian Bay in southwestern Ontario, Canada. From a hydrogeologic perspective, the domain can be subdivided into a shallow zone, an intermediate zone, and a deep zone comprised of the low-permeability units of Ordovician and the more permeable Cambrian where present. The deep groundwater zone is characterized by units containing stagnant water having high concentrations of total dissolved solids (TDS) that can exceed 300g=L. The high TDS values at depth require density-dependent coupled flow and transport calculations within FRAC3DVS-OPG. The computational sequence involves the calculation of steady-state density independent flow that is used as the initial condition for the determination of pseudo-equilibrium for a density-dependent flow system that has an initial TDS distribution. The 1,000,000 year pseudo-equilibrium heads and brine concentrations are used as the initial condition for the paleoclimate simulations. Over the past 900,000 years, the Canadian Shield has experienced approximately nine episodes of complete glaciation. During the glaciation cycles, the entire Canadian land mass has been covered by a series of continental ice-sheets whose maximum thickness reached 4 km and whose southern extents reached, in some cases, beyond the present-day Canada-U.S. border. The glaciation phase of a single glaciation-deglaciation episode is typically 90,000 years in duration, while the deglaciation portion proceeds relatively rapidly and has an average duration of approximately 10,000 years. Output from the University of Toronto Glacial Systems Model, a continental scale North American glacial reconstruction of the most recent 120,000 year glaciation event developed by W. R. Peltier, is used to supply the paleoclimate boundary conditions used in this paper. Permeabilty reductions due to the presence of permafrost are also considered in the paleoclimate simulations. This paper will demonstrate that the choice of rock properties can significantly affect residual pore water pressures within the rock matrix, as well as the migration of glacial meltwater.

May 1, 2009

By P. I. Laforest, M. S. Moats

"Antimony in smelted copper anodes has been shown to cause problems in electrorefining including brittleness of starter sheets. In order to improve deposit properties, a study was conducted examining the effect of anode chemistry on cathode ductility and electrolyte chemistry. Two industrial anodes with different molar ratios of As/(Sb+Bi) were used in laboratory electrorefining experiments with commercial electrolyte, and the addition of commercial glue and Avitone. The ductility of 21-hr copper deposits was evaluated by a 180° bend test. X-ray diffraction (XRD) and metallography were performed on unbent specimens to characterize the deposit structure. Increasing the anode As/(Sb+Bi) molar ratio from 0.54 to 3.8 resulted in an increase, on average, from four to eight bends to failure in cathode material produced. Significantly lower concentration of antimony (V) in the electrolyte was detected when operating with the higher molar ratio anode. The presence of (111) and (200) planes was noted in cathode material produced from the higher molar ratio anode suggesting that mixed growth character could be responsible for the observed increase in bend test results. The ductility of the starter sheet materials was improved by a higher anode molar ratio.INTRODUCTIONThe presence of antimony in copper electrorefining electrolyte has been reported to cause problems in cathode production (Hiskey, 2012; Peng, Zheng & Chen, 2012; Wang, Chen, Zhou-Lan & Lian-Sheng, 2006; Wang, Chen, Zhou-Lan, Wang, Xiao & Zhang, 2010; Wang, Chen, Zhou-Lan, Wang, Xiao & Tang, 2011; Wesstrom, 2014). To better understand the impact of antimony, laboratory scale electrorefining experiments were conducted using industrial inputs (anodes, cathodes and electrolyte). The influences of anode chemistry on the valences of antimony and arsenic in the electrolyte were monitored and correlated to physical cathode characteristics, such as a bend test to failure and crystallographic orientation.Commercially, starter sheets are produced by electrorefining impure cast copper anodes onto titanium blanks. The starter sheets are then hung in an electrorefining or electrowinning cell using loops of bent starter sheet material. These loops, in the absence of sufficient ductility, fail resulting in cathodes falling into the electrolysis cells. It is thought that the reduction in ductility can be related to anode composition; in particular, the molar ratio of arsenic to antimony plus bismuth As/(Sb+Bi). It has been stated that maintaining this ratio above 2:1 results in numerous improvements to electrorefining operations (Baltazar, Claessens & Thiriar, 1987; Kamath, Mitra, Radhakrishnan & Shetty, 2003; Krusmark, Young & Faro, 1995; Noguchi, Itoh & Nakamura, 1995; Wenzl, 2008)."

Jan 1, 2016

By H. Rafiei Renani, C. D. Martin

"The Cohesion Weakening Friction Strengthening (CWFS) is adopted in numerical analysis to capture the observed progressive failure of hard rock pillars. As a case study, pillars at the Elliot Lake mines with width to height ratios of 0.5 to 3 were analyzed in FLAC3D. Pillars with width to height ratios of 0.5 and 1 show a very similar strain softening behavior while with width to height ratios of 2 and especially 3 indicated prolonged strain hardening. The CWFS model successfully captured the mechanism of progressive failure observed in hard rock pillars including initiation of spalling at the corners, progress of spalling towards the centre and formation of hour-glass shaped pillar, and eventually shearing through the width of pillar. Both the CWFS model and site specific empirical formula successfully separated the stable and failed cases in the Elliot Lake mines. While both models are in reasonable agreement for width to height ratios of less than 2, the empirical formula gives increasingly lower strength values for wider pillars which may result in excessively conservative and uneconomical design.INTRODUCTIONPillars are the portion of in situ rock left between the adjacent openings to maintain the stability of excavations. Conditions of equilibrium require that the loads previously carried by the excavated rocks be transferred to the pillars resulting in elevated stresses within the pillar. Hence, prediction of the behavior of pillars under these loads is important for underground design. Determination of the strength of pillars is a classic subject in underground mining. In conventional mining methods such as room and pillar operations, economic incentives point towards higher excavation ratios i.e., leaving smaller pillars between the mined excavations, while safety and stability requirements favor wider stronger pillars. In some mining methods such as caving operations, the problem is even more challenging. On one hand, the whole operation is directly dependent on the proper continuous flow of caved ore between the drawpoints which requires optimizing the spacing between drawpoints and thereby often leaving narrower pillars. On the other hand, the pillars should be wide enough to ensure the safety of mining operation. Both the blockage of drawpoints as a result of wide pillars and uncontrolled failure of narrow pillars can jeopardize the investments and mining operation.Therefore, design of pillar poses a somewhat unique challenge to rock engineers where simple conservative approaches frequently used in other design methods are no longer acceptable. The behavior of pillar under elevated loads should be predicted accurately."

Jan 1, 2015

By Bhawani Singh, Mahendra Singh, N. K. C Samadhiya

"Inherently anisotropic rocks occur in abundance at many rock engineering project sites in Himalayan region. These rocks pose difficulty in analysis and design due to their direction dependent strength behaviour. Moreover the strength varies in a non-linear manner with confining pressure. Mohr- Coulomb strength criterion is widely used by geotechnical engineers for defining strength of rocks subjected to given confining pressure. However, the conventional Mohr-Coulomb (MC) criterion suffers from the limitation that the strength is treated to be linearly dependent on confining pressure. In the present article, the MC criterion has been modified by incorporating non-linear term while retaining the original parameters c and ?. The non-linearity with confining stress level has been imbibed through critical state concept (Barton, 1976). The criterion has been applied to a triaxial test data base comprising of more than 1140 triaxial tests conducted world-wide on anisotropic rocks. Statistical evaluation of the goodness of fit of the proposed criterion to the data-base has been carried out. Further the predictive capabilities have been evaluated by determining the error in estimation of triaxial strength if only few triaxial test data are available for determining the criterion parameters. The data base has also been back-analysed to assess the critical confining pressure for anisotropic rocks. Statistically the critical confining pressure, for the present criterion, may be taken nearly equal to 1.25?cmax, where ?cmax is the maximum value of the UCS out of all orientations of planes of anisotropy. It is concluded that reasonably good estimates of the anisotropic strength are possible through the proposed criterion.INTRODUCTIONMany rocks encountered in Himalayan region like shale, slate, schist and phyllite are inherently anisotropic and exhibit direction dependency in their strength behaviour. In addition, the strength of the rock also depends on the confining pressure and, the strength response is non-linear especially when the confining pressure may vary over large range. Conventionally, Mohr-Coulomb criterion is the most widely used criterion for rocks. However, the limitation of this criterion in its present form is that the strength is treated to be linearly dependent on the confining pressure. The present study attempts to address the following two main objectives: i) Include nonlinear response in the Mohr-Coulomb criterion while retaining parameters c and In their original form; and ii) consider anisotropic response of the rock for a given confining pressure. A nonlinear strength criterion, which uses shear strength parameters c and as per Mohr-Coulomb criterion, has been suggested based on critical state concept for rocks."

Jan 1, 2015

By P. Garritsen, J .. A. Blanco, M. C. Bell

"By 1994, Inco Limited will lower sulphur dioxide emissions from the Copper Cliffsmelter by 60% to 265 000 tonnes/year, primarily through implementing two key process changes. First, new milling technology will permit economic rejection of additonal pyrrhotite prior to smelting. Second, a bulk coppernickel concentrate will be oxygen flash-smelted, thereby eliminating the existing multi-hearth roasters and reverberatory furnaces . All copper will be recovered in the matte separation plant as a nickeliferous chalcocite, and will be oxygen flash-smelted for blister production. This paper outlines the development of the project and describes the process, including the flash furnaces, new sulphuric acid plant and additional oxygen plant.IntroductionInco 's SO2 Abatement Program will lower sulphur dioxide emissions at Sudbury from the current levels of 685 000 tonnes per year to 265 000 tonnes per year by 1994 as required by Ontario' s countdown on acid rain regulations.It is the high tonnage of sulphur mined that creates the magnitude of the SO2 emission problem at Sudbury. At a production rate of 240 million pounds of nickel per year, Inco mines 12 million tonnes of ore. At 10% sulphur it mines 1.2 million tonnes per year of sulphur. If Inco did not fix any of this sulphur it would be emitting 2.4 million tonnes per year of sulphur dioxide-about as much as all other Canadian emissions. Today, however, Inco is already fixing 70% of the SO2 in ore, in several ways : mostly as sulphur in pyrrhotite rejected to tailings in the milling operations; as acid from the roasting of pyrrhotite and some nickel concentrate at the Iron Ore Recovery Plant (lORP) and some as liquid S02 from the copper flash smelting furnace. By fixing 70% of the sulphur the current allowable SO2 emission levels of 685 000 tonnes per year is met. Total sulphuric acid production is currently 450 000 tonnes per year and in fact, the 10RP operation is being continued only to maintain established acid markets.Historically emissions have been reduced from the 2 000 000 tonne per year level to the current level of 685 000 tonnes per year by rejecting pyrrhotite from the smelter feed, and 70% of the SO2 containment problem at Sudbury has already been addressed.While Inco's profits are large at current nickel prices, most people have forgotten that back in 1982 Inco was losing a million dollars a day. Inco did make a dramatic response to this economic stimulus. The Ontario Division increased productivity by 65% and lowered costs to become the lowest cost nickel producer."

Jan 1, 1990

By A. Mcdonald

"An X-Met Analyzer was purchased from Outokumpu in late 1983for use in the Hudson Bay Mining and Smelting smelter. Its first use was in the fuming plant to give zinc assays of each charge of slag tapped from the fuming furnaces. This quickly told the operators exactly when each charge had reached its economic tap-out point, and gave supervision a fool-proof method of identifying good operation. These and other factors led to major improvements in coal utilization in the fumers and to major increases in zinc oxide production. A second unit was later purchased for the reverberatory furnace to give silica and iron assays of the slag, and these were used to make adjustments in the feed composition to maintain the desired SiO2:Fe ratio in the slag. Since purchasing the units for the furnace, the oil consumption and copper content of the slag have dropped significantly. IntroductionSmelters have lagged far behind concentrators in process control by mean s of rapid product analysis. The on-stream X-ray analyzer was developed about seventeen years ago, and soon concentrators around the world were getting assays of the incoming ore, .concentrates and tailings every fifteen minutes, and using these to control reagent additions and other process variables. Almost always, the concentrate grade and recovery improved.In smelters, product streams are solids or molten materials, not the more easily handled slurries, and until seven years ago no inexpensive equipment was available to provide rapid analysis of this type of material. In approximately 1980, several companies developed instruments based on irradiating solid samples with low-intensity gamma rays from radio-isotope sources, and measuring the secondary X-rays emitted from different elements in the sample to provide an analysis of the elements desired.The smelter staff had a close look at what was needed and listed the following points as being critical:1. ability to provide Zn assays of a sample of slag within 15 minutes of taking it, in order to achieve optimum fuming times (zinc fuming , being a batch process, had the greatest potential benefit from rapid slag analysis);2. ability to give Cu and Fe assays on the slag, and on other smelter products, such as matte and converter slag;3. ability to give Si02 assays since the SiO2 content of the slag has a strong effect on fuming rate; and4. ability to stand up to an industrial atmosphere such as exists in the fuming plant."

Jan 1, 1987

By C. Chongo, L. Little, Q. Mclennan

Since commissioning in 2005, First Quantum Minerals’ Kansanshi Mine in Zambia has produced over three million tons of copper and 1.8 million ounces of gold from a deposit with highly varied copper mineralization. The processing plant is complex with three independent flotation circuits, gold gravity concentration, atmospheric and high pressure leaching, solvent extraction, and electro-winning. For the first ten years of operating the plant, copper mineralogy was inferred from total copper and acid soluble copper assays, and various misconceptions developed about the mineralogy which impacted operational strategy and project decisions. In 2015, an on-site mineralogy section was set up with an Automated Scanning Electron Microscope, the Zeiss MinScan. This instrument has provided detailed mineralogical data that have debunked some of the mineralogy myths that had developed, highlighting the key underlying issues affecting processing performance. This has enabled the development of projects targeting losses of specific copper minerals in defined size classes, unlocking significant value. This paper describes some of the early misconceptions around mineralogy at Kansanshi processing plant, outlining projects that have benefitted from understanding copper mineral distribution. Learnings from Kansanshi are to be applied at other FQM sites, with a similar mineralogy program being set up at the Cobre Panama project. INTRODUCTION The deposit Kansanshi Mine is located in the North Western Province of Zambia, and it has been the largest copper producer in Africa for over a decade. The deposit occurs within a broad northwest trending antiform that can be traced for 12 km, hosted in a zone of complicated faulting, abundant vein injection, breccia development and down-dropped rock units that lies within Kansanshi’s mining license. The copper mineralization within the deposit is predominantly vein-hosted, although some is strata-bound, occurring in thin bands and veinlets parallel to foliation, and some is disseminated associated with albite-carbonate alteration (Gray, 2015). Supergene enrichment has led to significant variety in the copper mineral speciation. This alteration is complex, and has not followed the text-book principles with a neat layer of supergene mineralization overlying fresh hypogene ore. Rather, the occurrence and extent of oxidation and supergene enrichment is highly irregular throughout the deposit, sometimes occurring at significant depth in localized pockets and along fault lines. Gold mineralization tends to follow the copper within the deposit, but it is dominated by coarse-grained, free-milling native gold. The extent of copper oxidation – measured as the fraction of total copper that assays as acid soluble – is used to classify ore into three main ore types, named Sulphide, Mixed, and Oxide, which are then fed to three different primary crushers for processing in independent circuits.

Jan 1, 2019

By Nawshad Haque, Leanne Smith, Hal Aral, Joseph Cho, Warren Bruckard

"Water availability is one of the principal parameters in determining the feasibility of mining projects in arid and semi-arid regions. The volumetric water footprint (VWF) of a conceptual model of a copper flotation plant was found to be 2.45 kL/t Cu ore, compared with an actual measurement reported in the literature of 2.72 kL/t Cu ore. The flowsheet considered included mineral processing stages such as crushing, screening, grinding, classification, separation, flotation, thickening and filtration. The effect of a number of variables on the VWF was evaluated, including solid/liquid ratio, feed mass flowrate, ore loss, water loss, moisture content of ore, ore grade and water recycling. The use of seawater with recycling provided the most environmental and economic advantage among several scenarios evaluated. The study assumed a price of $1/kL freshwater, $4/kL for transport over a 200 km distance at 2,000 m altitude and $4/kL for water treatment. The water related cost of the desalinated seawater use scenario was A$493/t Cu concentrate, while the water related costs of fresh water and blended water scenarios were A$308/t and A$268/t Cu concentrate, respectively. The water related cost (fresh water scenario) accounted for 44% to 49% of the entire mining and processing costs that included drilling, blasting, loading, hauling, crushing, grinding and concentrating. The total overall cost was A$435/t Cu concentrate for the seawater with recycling, compared to A$451/t Cu concentrate for the fresh water with recycling case.INTRODUCTIONReducing the water footprint (WFP) by utilising alternative water sources has been a focus of mining projects due to increasing concerns about water scarcity and growing energy costs. The global mining industry can expect to experience fresh water shortages in the future, and saline or hyper-saline water may be the only available water source to process minerals in arid regions. Extensive studies on alternative water sources (e.g. seawater, desalinated seawater, blended water) and the reuse of process water have recently been conducted (Moreno, Aral, Cuevas, Monardes, Adaro, Norgate & Bruckard, 2011; Aral, Mead, Cuevas, Davey & Bruckard, 2010). Such studies provide sustainable and economic strategies for mines and concentrators in the arid or semi-arid regions of the world such as in Chile, Peru, Indonesia, and Portugal. More work, however, is needed to confirm water consumption data for different base metal flowsheets and use this data to develop water models that can lead to reduced WFPs and more sustainable water usage in the mining industry."

Jan 1, 2016

By P. E. Mather, M. J. M. Krane

Uncertainty quantification is a means of articulating the reliability of model estimations. Models of copper pyrometallurgical processes have been published for decades but discussion of their reliability has typically been terse and qualitative, mitigating understanding of their exact applicability to industrial situations. This presentation shows basic uncertainty propagation and Bayesian model calibration, two powerful uncertainty quantification tools, applied to a reduced order model of copper fire/anode refining. The implications of the uncertainty quantification analyses on the applicability of the model results to industrial practice are then discussed. Finally, other possible applications of uncertainty quantification to copper extractive metallurgy are explored. INTRODUCTION Modern copper production operations, including mining operations through wire drawing factories, are ubiquitously heavily instrumented. Most mine-sites and smelters have large repositories of historical data. That said, much of this data is not exploited to its maximum effect. This proceeding provides examples of using uncertainty quantification (UQ) to maximize the informational yield of the data collected from a fire-refining operation. Anode/Fire Refining is the final pyrometallurgical step in the production of copper anodes; it is an essential and universally employed processing step at smelters (Schlesinger, King, Sole, & Davenport, 2011). Much like the smelting and converting furnaces further up the process stream, anode furnaces are difficult to instrument due to their high temperature and the corrosive and/or caking quality of their offgas. This makes continuous and accurate measurement of the streams leaving the unit operation, e.g. liquid copper, slag, and offgas very difficult. As an example, offgas flowmeters, while providing continuous draft values, could miss the actual draft value by tens of percent due to caking or corrosion. UQ methods account for the uncertainty in process measurements and parameter values; they use a process model with measurements of performance indices to provide better and better estimations of process performance. This proceeding will first introduce a surrogate model for copper fire refining, made from a 1D, transient, reacting flow model of the process presented elsewhere in these proceedings (Mather & Krane, 2019). Discussion of the data used to make the surrogate model, as well as the creation of the surrogate model, will be included. Then, a Monte Carlo simulation will be performed, showing the expected soot production rate based on the surrogate model and assumptions about the uncertainty in the model’s parameters. Finally, the surrogate model parameters will be calibrated in a Bayesian way; this will tell what the actual uncertainty in the parameters are, given a set of observed industrial data and prior assumptions of the observations’ and parameters’ uncertainty.

Jan 1, 2019