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By J. Kronsteiner, E. Kabliman

"In the present work, we developed a Smart Process Control Toolkit (SProC) as a single simulation environment for the modelling of materials microstructure and its interaction with the local microchemistry during manufacturing of semi-finished products. This toolkit supports the data communication between sub-sequent processing steps such as casting, homogenization, pre-heating to deformation, etc. The thermo-kinetical simulation software MatCalc of MatCalc Engineering© GmbH was used for modelling of precipitation kinetics, such as formation of primary and secondary phases and their evolution. An import/export functionality of the precipitation distribution after each processing step was implemented to follow the parameter history. For the evolution of the local microstructure, a Mean Dislocation Density based Model (MD2M) was used. This model consists of two parts: (1) Flow Stress Model for calculation of the total strength during the deformation and (2) Static Recrystallization Model for account of the recrystallization and grain growth after the deformation. Validation was done by a comparison of experimental and simulated hot compression tests of a conventional AA2024 alloy.INTRODUCTION Optimization of a semi-finished products quality, elimination of typical production issues and cost savings are of a great demand for supply industries. However, it is currently not feasible to investigate the whole manufacturing process in detail at an industrial level. Concerning the processing parameters, one must understand the correlation mechanisms between macroscopic properties and microscopic material behavior. Numerical simulations, which could reproduce the real processing conditions on the one hand, and employ a physically based modelling on the other, are thus attracting a lot of attention and their power is no longer under the question. It is well known that e.g. the total strength of the material depends directly on distribution of precipitation particles and mean grain size. In order to follow their evolution during the manufacturing process beginning from casting to the final semi-finished product, and thus be able to control the process, one should use the techniques which would at the same time reproduce experimental processing conditions of real size objects (e.g. sheet, extrusions, etc.) and account for the evolution of a local microstructure and its interaction with the microchemistry. A commonly used approach is to implement a model which would describe the evolution of microstructure based on a dislocation density approach into a user defined material subroutine of some finite element solver. There is, however, also an influence of the manufacturing process by e.g. the evolution of a local microchemistry (formation, transformation and dissolution of the precipitation particles) on the microstructure and thus the macroscopic material behavior. Thus, a method is needed to follow the variable history through the simulation of the whole production chain."

Jan 1, 2018

By J. Oliver, B. Wilson, 10

"Red Dog is one of the world’s largest zinc producing mines and a significant producer of lead and silver. While some of the operational challenges relate to the mine’s location in a remote part of Alaska, there are also challenges in the mineral separation process. Recent processing upgrades have included the installation of two M5000 IsaMills to improve the zinc regrind circuit and of one Jameson Cell to improve the pre-flotation circuit. Relatively fine grinding is required to achieve efficient mineral separation at Red Dog, but while fine grinding aids in the production of high grade concentrates, it also creates challenges in the efficient recovery of fine minerals. Over half of the lead lost to the lead circuit tailings, as well as almost half of the zinc lost to the final tailings, is in the finer size fractions (<10 µm). The high pulp density experienced in the pre-flotation and lead rougher circuits also causes significant entrainment loss of lead and zinc to the pre-flotation concentrate and of zinc to the lead concentrate. To help improve fine mineral recovery, Red Dog has recently plant tested and installed magnetic conditioning technology in the flotation circuits. The equipment aggregates fine paramagnetic sulphides and selectively increases their flotation recovery. This paper outlines the testing and positive results at Red Dog.INTRODUCTIONRed Dog is the largest zinc mine in North America and represents approximately 29% of North American zinc concentrate production. The mine is located in northwest Alaska, approximately 100 miles north of the Arctic Circle and 50 miles inland from the Chukchi Sea. The remote location makes the mine accessible only by air or seasonally by ocean-going barges. Red Dog is a partnership between NANA Regional Corporation Inc, the land owner and Teck Alaska Incorporated, the operator of the mine. Red Dog Ore and Mineralogy The Red Dog deposit is a rich sedimentary exhalative (sedex) zinc-lead-silver deposit. The main minerals present in order of abundance are: quartz, sphalerite, pyrite, barite and galena. Production began in 1989 with mining of the Main deposit. Between 1989 and 2012, approximately 55.6 million tonnes of ore with an average grade of 20.5% Zn, 5.6% Pb, and 97 g/t Ag was mined from the Main deposit. Subsequent to the development of the Main pit reserve, two additional open pit deposits were discovered: Aqqaluk and Qanaiyaq. The first blast in Aqqaluk occurred on June 4, 2010. As of December 31, 2014, the Aqqaluk deposit reserve is an estimated 45.7 million tonnes of ore with an average grade of 15.1% Zn, 3.9% Pb and 71 g/t Ag."

Jan 1, 2016

By Avinash Kandalam, Markus Reuter, Jörg Kleeberg, Michael Stelter

The Top Submerged Lance (TSL) technology has obtained significant importance in the pyrometallurgy industry for nearly four decades. One of the advantages of TSL furnace is its high reaction rate, which is caused by splashing and turbulence of the melt. In contradiction, this phenomenon stands as a barrier for conducting experimental investigations to validate the simulation models. The highly turbulent and splashing environment in the TSL furnace is caused due to the immersion of the lance into the slag layer and thus the effect of the flame structure is directly related to the splashing, turbulence, reaction kinetics and life-span of the lance. Moreover, the material properties such as viscosity, density and the surface tension will also influence the flame structure. As a first step to understand the flame structure, attempts are made to generate a stable flame of the lance in an open environment. INTRODUCTION Top Submerged Lance (TSL) technology was invented during the 1970s at Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia by Floyd and Denholm. This technology was later commercialised and currently, there are about 100 TSL plants around the world commissioned by various licence holders such as AUSMELT (Outotec) and ISASMELT (Xstrata- Glencore Technology). Copper is the most produced non-ferrous metal followed by lead and zinc, see Hunt (2005). Today, a wide range of primary, secondary, and complex recycling materials are used as a feed material in the TSL, Alvear et al. (2010), Kaye et al. (2008). The working principle of TSL technology lies on inserting and submerging a lance from the top of a vertical cylindrical chamber into the slag layer. The lance is considered as the heart of the furnace, where the air and fuel are transported through two concentric tubes and are mixed in a combustion chamber, which is approximately 7 cm from the tip of the lance (considering the pilot-scale TSL furnace at the Institute for Nonferrous Metallurgy and Purest Materials - INEMET). The TSL furnace is very flexible with the type of fuel, feed material and the air input. The fuel can be natural gas/heating oil/fine coal particles and the air could be enriched with oxygen (Figure 1). The general mechanism of the TSL furnace lies on feeding the material from the top of the furnace and the material is pulled into the molten bath due to the high turbulent atmosphere, which results in high reaction rates. The thermocouples installed in the furnace (i.e. in the ceramic linings) allow the operator to know the temperature of the melt. For example, in the case of copper production the tapped material (i.e. matte/metal) can be transported to a settler for further processing or directly used.

Jan 1, 2019

By D. Virely, M. Gasc-Barbier, J. Guittard

"The valleys of the Dordogne and the Vézère (France) have been inhabited since prehistoric times, as evidenced by the famous site of Lascaux. A few miles away, the village of La Roque-Gageac is also a very popular tourist destination (about 1.5 million tourists per year): The village is sandwiched between a massive limestone cliff and the Dordogne river. The collapse of a cave roof high above the village in January 2010 led us to characterize instability together for the cave and the whole cliff and propose a adapted instrumentation to monitor the fracture openings in the rock mass that are linked to climatic variations. Measurements have been going on and been recorded for nearly 4 years. They point out the role of thermal stress fatigue in the breakdown of the rock mass. In this paper we describe the site under study, the instrumentation and its main results. INTRODUCTIONThe phenomenon of thermal fatigue has been very little studied as far as rocks are concerned, whereas it is rather well characterized for other types of materials: Elsevier published a journal dedicated to fatigue (International Journal of fatigue). In the case of rocks, thermal phenomena and their impacts on mechanical behavior have been analyzed from a micro-structural point of view, and it is now well-known that an increase in temperature causes a dilatation of crystals (Arnould et al., 2004; Berest & Weber, 1998). This dilatation may lead to the development of inter-granular traction and compression stresses, and if those stresses are greater than fracture strength, inter-granular and intra-granular cracks may take place. On the other hand, the fatigue phenomenon (cyclic repetition of a temperature variation which is less extreme than the one that may lead to this inter-granular or intra-granular fracture) is a phenomenon which has not been much studied.The principal studies on thermal fatigue on rocks come mainly from the field of geomorphology, particularly in connection with the analysis of the evolutions of past climate that can explain the present shapes of those landforms: those studies remained essentially qualitative and not quantitative. Le Ber & Oter Duthoit (1987) proposed a thermal and thermodynamic approach to analyse the disaggregation of rock masses. This analysis is dedicated to the study of paleoclimates and was implemented to better understand the formation of slope deposits in order to propose transfer models permitting the reconstruction of the climactic conditions contemporary to their appearance. Since deterioration in the cliff only appears after several cycles, it means that it is a gradual and irreversible deterioration which leads to an increase of the « disorder ». Seen from a macroscopic system point of view, this irreversible evolution is quantified by the internal creation of entropy."

Jan 1, 2015

By John Lamb

"The French Mine (formerly the Oregon) is 4 miles by road south of the Nickel Plate Mine. It lies on the steep eastern slope of the Similkameen River valley at elevation 4,000 feet, between Cahill and Winters Creeks.The property was discovered in .1901 and bought 4 years later by Messrs. French and Deardorf. It was developed in a modest way by the owners and by several companies until 1947, without success. The spectacular showings of bornite and chalcopyrite in the outcrop drew attention to its possibilities for copper rather than gold. Diamond drilling by the owners in 1947 yielded several high-grade gold intersections and created new interest. In 1949 the property was purchased by Kelowna Mines Hedley Limited. Exploration drilling and geological mapping outlined sufficient ore to commence production in 1950. Except for a few months each winter the operation has been continuous, and to the end of 1954 had produced almost 30,000 tons of high grade ore. The ore is crushed at the mine and hauled 8 miles by truck to the Company mill at Hedley, where it is treated together with the ore from Nickel Plate.Regional GeologyThe country rock consists of brown tuff, flows, limestone, and cherty formations belonging to the Nicola group (Rice 1947) of Triassic age. West of and just below the mine is a large mass of granodiorite which is part of the same body that underlies Nickel Plate Mountain. Bedding attitudes in the mine area are locally complicated, but dips are generally less than 45 degrees. To the south and below the mine the beds stand almost vertical, continuing downward with this attitude for 2,000 feet to Winters Creek. The main granodiorite contact is also steep, conforming to the sedimentary formations, whereas northward towards Nickel Plate it dips gently to the northwest, slightly flattter than the thick westerly dipping pile of sediments above it. The interpretation of this structure by Billingsley (1936) is that the French mine lies near the crest of the large northeasterly trending asymmetrical anticline which contains in its gently dipping western limb the Nickel Plate orebodies. The granodiorite body conforming roughly to this shape seems to occupy the core of the anticline. Sill-like prongs of granodiorite extend upward to the east from the main mass, outcropping over wide areas at the head of Winters Creek (Figure 1). There is a possibility that overthrusting from the west, similar to that on Nickel Plate Mountain, occurs not far below the French mine.An interesting feature of the granodiorite-sediment contact is that where it dips gently westward no alteration exists in the sediments, but where it has a steep front pronounced heat effects are indicated by the presence of a thousand-foot-wide zone of reddish garnet skarn."

Jan 1, 1949

By M. Mahdi Aboutalebi, Roderick I. L. Guthrie, Mihaiela Isac

"A preliminary computational fluid flow model has been developed to simulate the flow field of liquid steel in the mold region of billet mold casting. This study reports the effect of different Submerged Entry Nozzles (SEN) on the fluid flow in round and square billet, curved mold, casters. In this study, ANSYS Fluent 14.5 software was used to model the 3-D turbulent flow of liquid steel. The standard k-0 model was used to simulate turbulence in the mold region. Similarly, the species transport equations were discretized to simulate the dye injection test into the mold cavity. The behavior of flow in the mold region was validated against previous experimental work. Predicted results showed that different nozzle types plus the slight curvatures in the molds can significantly influence the flow patterns generated within the mold region, and thereby affect the finished quality of the billet products.INTRODUCTIONConventional Continuous Casting (C.C) processes are presently used to solidify more than 95% of the 1.5 billion tons of steel now produced in the world annually (World Steel in Figure, 2014). This overwhelming contribution of C.C processes for steel production is the prime motivation for this study, in order to understand and optimize the casting processes and thereby reduce internal defects and minimize energy consumption. The primary objective of all C.C processes is to maintain liquid metal purity during the casting process and to create a uniform flow within the caster so as to avoid internal and external defects. In this regard, studying fluid flows in the mold region of continuous caster has attracted many research groups, in both academia and industry, in recent years. The mold region is one of the most critical parts of the C.C. process, in which the transport phenomena associated with this region can significantly affect the quality of the final products. Thus, proper control of fluid flows within this region can be expected to greatly decrease both internal and surface defects such as Oscillation Marks (OM), inclusion entrapment, and Mold Powder Entrapment (MPE). In the casting process, the fluid flow in the mold region can be affected by a number of variables, such as; the flow control system (stopper rod or slide gate), nozzle geometry, SEN (Submerged Entry Nozzle) depth, casting speed, mold dimensions, gas injection, and the application of electromagnetic fields. One of the most influential and easily-changed fluid flows are the jets of steel issuing from the SEN. Nozzle geometries are variable, consisting of a number of exit ports, different port angles, and/or port sizes, the bottom shape of the nozzle, and the SEN immersion depth (Thomas, 2001). The SEN characteristics can markedly affect meniscus surface velocities, surface level profiles, and turbulence levels that can vary in terms of the frequency and the magnitude of their fluctuations."

Jan 1, 2016

By C. Sist, J. Shannon, J. Fossenier, J. F. Adams

With the cleanest and easiest to treat copper concentrates dwindling and becoming harder to find, electrorefineries must deal with the reality of higher impurity anodes. There are well-known strategies for managing nickel, bismuth, antimony, etc. using bleeds (Ni, Bi, Sb, As) or arsenic control (Bi, Sb) or hydrometallurgical add-on circuits (IX, MRT, SX for As, Bi, Sb). However, for integrated copper producers and those producing other base metals it is often worth considering a more holistic, global approach. This paper will discuss both the well-known strategies as well as some global strategies and the role that hydrometallurgy can play in them. Examples will include atmospheric and pressure leaching, selective precipitation and impurity recycling or fixation. INTRODUCTION In the electrorefining of copper, impure copper anodes are electrically corroded, and pure copper is deposited on cathodes by passing DC current through an acidic copper sulphate solution. The anode copper impurities either settle to the cell bottom as insoluble components (anode slimes) or remain in solution with minimal deposition at the cathodes when correct operating parameters are maintained. Consideration of impurities is important in all copper electrorefineries. A typical impure anode contains 98.5–99.5% copper (Schlesinger et al., 2011). Table 1 shows the range of impurities reported for all copper anodes in the 2007 survey of operating refineries (Moats et al., 2007). Also shown is an approximate “limit” of anode compositions within which the majority of refineries operate without additional impurity removal capacity (beyond conventional liberator/bleed circuits). The column is somewhat subjective and meant to be an approximation only since there are many factors that influence impurity deportments and refinery impurity tolerances. More recent world survey data from 2013 show the averages for all impurities trending upward from 2003 to 2013 (Moats et al., 2013). With a competitive market for good concentrate and more copper recycling from electronics (which contain high levels of impurities such as nickel, lead and antimony), this trend is expected to continue through the coming years. The traditional primary method of impurity control is refinery bleed through liberator cells which are employed in the vast majority of refineries (Moats et al., 2013). These are used to control copper (primary liberators), nickel, arsenic, antimony and bismuth (secondary and tertiary liberators). Other methods of impurity control include arsenic addition (upstream in the smelter deporting to anode or directly to electrolyte) to control antimony and bismuth (Kamath et al., 2003), ion exchange or molecular recognition technology (Hur et al., 2005; Navarro et al., 2012) for antimony and bismuth. Many refineries also operate nickel evaporators to remove nickel sulphate before recycling back acid. Some use, or are contemplating using, acid purification units to recycle acid and arsenic without nickel and making nickel carbonate (Kamath et al., 2003; Sheedy et al., 2006).

Jan 1, 2019

By É. Poulin, J. Bouchard, E. M. Pérez-García

Process control and optimization have always been crucial aspects in the mineral processing industry, and expectations constantly increase to cope with more stringent security, quality, efficiency, and environmental performances. The main challenges to reduce variability of key process variables, and steer profits to higher values while maintaining sustainability indexes within acceptable ranges come from nonlinear responses and circulating loads. The most commonly implemented control strategies rely on simple PID controllers for practical implementation and maintenance considerations. If arguably good performances are accomplished when these are adequately set up, there is also room for further gains by using more advanced methods such as model-based techniques. There is thus a need for more realistic process and equipment models. Based on advances of the past few decades, this paper introduces an autogenous/semi-autogenous mill (AG/SAG) model to be included in a modular comminution circuit simulation toolbox comprising ball/rod mills, material handling, and classification devices. The proposed mill model incorporates a modified version of the classic comminution equation that makes grinding rates proportional to the energy input. It requires the determination of a selection function (fragmentation rates) and a breaking function (fragments distribution). The former is modelled with an S-shaped curve characteristic of AG/SAG processes and the latter is a size-relative distribution of the produced fragments. The power draw is predicted employing the empirical equation of Austin. The paper also develops a case study to illustrate how the proposed simulation framework can capture the behaviour of an actual plant. Model calibration consists in an optimization problem that search the global minimum of the difference between predicted and measured/estimated size distributions, power draw, solid fractions, etc. Results demonstrate that the mill simulator can mimic an actual process in its operation conditions. INTRODUCTION Comminution is a key stage in the mineral processing industry, obviously because the phases of interest must be liberated to be able to recover them. In general terms, the global performance of a plant depends largely on the efficiency of the grinding circuit and on the material properties such as its grindability, density, and mineral grades. The subject has vastly been studied since as early as the 19th century, when Rittinger (1867) and Kick (1883) developed some of the first empirical models to relate grinding and energy input. The great interest in the subject comes from the fact that this operation is costly and, probably most concerning, highly inefficient. Buckingham et al. (2011) estimated that ore comminution can represent up to 60% of the overall plant power draw. Moreover, only a modest fraction of the power draw effectively translates into rock fragmentation. For grinding, estimates range between 1% and 25%, depending on the reference used, while the rest is mainly lost as heath (Fuerstenau & Abouzeid, 2002; Tromans & Meech, 2002; Bouchard et al., 2017).

Jan 1, 2019

By W. Schubert, N. Radoncic

"The term “squeezing” is frequently used, although it is ill defined. Definitions like “large and long lasting displacements” raise the questions about the threshold values for the magnitude and duration of displacements. Large displacements during tunnelling frequently are observed in fault zones with high overburden. Whether this causes problems very much depends on the design approach used. On the one hand, the magnitude of expected displacements has to be predicted prior to excavation to provide for enough allowance for the displacements without violating the clearance profile. On the other hand, the support characteristics must be compatible with the expected imposed strains. As the magnitude of the displacements and thus the strains in the support depend on the support capacity and its characteristic (yielding potential), only well engineered systems will be successful.Experience in Alpine tunnels over the last decades has shown that closed shotcrete linings can sustain a strain of approximately 0.8% to 1% without failure. Any strain above this value inevitably leads to failure of the lining, and thus a loss of resistance, causing additional displacements. Based on a large number of simulations, a criterion for a critical overburden depth up to which closed linings can be used has been developed. Traditionally open gaps in the shotcrete linings have been used to allow for larger strains. To enhance the efficiency of the linings, yielding elements have been developed, which are integrated in the shotcrete lining, allowing large strains and controlled development of support resistance (Figure 2). When designing such yielding support systems, the development of the displacements, as well as the rheological behaviour of the supports must be considered. As the development of displacements to a large extent depends on the face advance, also the advance rate has to be considered, to be able to compare the time-dependent strength of the lining to the stresses developing as a result of the imposed strains. Another issue is the compatibility of the rock bolts with the large strains. With standard grouted bolts, there is a potential that the “fresh” grout is sheared due to the initially large strain rates. Special rib designs of the bolts allow for a higher strain tolerance.For successful tunnelling through fault zones quality monitoring and up-to-date data evaluation is of crucial importance. With advanced evaluation tools, changes in the ground conditions ahead of the face can be reliably predicted. With the help of empirical relations, the development of the displacements for different advance rates and supports can be predicted, allowing for the determination of the required overexcavation.The paper presents a review of the development of ductile elements, methods of analysis, and monitoring data interpretation."

Jan 1, 2015

By N. P. Hristov, L. V. Kuzev

"A simulation study of the fill factor of a drum mill was conducted using two types of grinding media: balls and tetraballpebs. Each medium was composed of equal number of grinding bodies having equal weight but different shape. The difference was in the density of the two grinding media.Standard spherical grinding bodies (balls), which were used in practice, and equivalent (by weight) grinding bodies in the shape of spheroidal tetrahedrons (tetraballpebs) were studied. The simulation was conducted in a module of a 1.2 m diameter drum mill, whose length exceeded twice the diameter of the corresponding grinding body. The grinding balls had a few percent (3 to 6) higher fill factor than the grinding tetraballpebs in the same shell.Vertical sections of the grinding medium were taken across the studied shell module along its axis. They showed the location of each grinding body in the fill volume. Defects in the packing of the grinding bodies and the contacts between them and with the inner surface of the shell were also show. Differences in the contact points of the balls and the tetraballpebs were noted. For the tetraballpebs, we observed contacts both between the spherical surfaces and with the edges and vertices of the grinding bodies.The topography of the grinding media is shown visually.INTRODUCTIONThe grinding balls have been studied extensively. It is the traditional grinding medium in ore processing industry. The parameter characterising the grinding medium is its density. It is the mass of the grinding medium per unit of volume. The parameter may have a range of values. It depends on:• The physical properties of the material they are made of;• The shape of the grinding body;• The dimensions of the body;• Size distribution of the grinding bodies in the grinding media.In comminution, the fill factor of the mill shell is the process parameter that is representative of the grinding medium. Some publications have indicated the disadvantages of ball grinding. For example, Wu, Xiang, Glen, and Duan (2008) note in the analysis of the mechanism of grinding that the balls are not the best grinding media and disadvantages include among others:• Easy over-grinding resulting from the point contact between the balls;• Attrition surface is the smallest in the grinding media;• Poor selective exposure of minerals resulting from the accidental and often significantly more powerful impact on the feed;• The grinding efficiency drops as the fineness of grind is increased;In the Handbook of mineral processing, Polkin (1950) noted that the shape of the grinding bodies determines the volume of the void spaces therein and therefore the shape affects the grinding efficiency per unit of volume of the grinding medium."

Jan 1, 2016

By Jiahao Xu, Namsoo P. Kim, Guikuan Yue

Iron (ferrous ions and ferric ions) plays an important role in the heap leaching of copper sulfide minerals and copper electrowinning. In our previous study, a novel oxidation-reduction potential (ORP) equation only based on the variables of temperature and nominal ferric/ferrous ratio was developed to predict the redox potential of the quaternary H2SO4-Fe2(SO4)3-FeSO4-H2O system, and its applicability was also extended to more complex acidic iron sulfate solutions, especially those generated during the acidic leaching and bioleaching of Printed Circuit Boards (PCBs) to recover copper. In this work, the broader range of applicability of this equation to other complicated acidic iron solutions containing copper ions has been extended and determined. Specifically, synthetic iron-containing solutions with copper ions according to the conditions of industrial electrolyte during copper electrowinning and heap leaching have been used to measure the ORP and test the developed equation. It seems that this equation can still be employed to predict the redox potential of the Fe3+/Fe2+ couple for the simulated solutions under conditions related to copper electrowinning and pregnant leaching solution generated during heap leaching over a wide range of solution concentration, nominal Fe3+/Fe2+ ratio and temperature. It has shown that the prediction and measurement of redox potential is highly useful to estimate and understand the iron chemistry of industrial leaching and electrowinning processes. INTRODUCTION It is well-known that iron (ferric or ferrous) ions are widely involved in the hydrometallurgical production of non-ferrous metals such as Cu, Au and Zn, mainly in the form of acidic iron sulfate solutions. As far as Cu is concerned, in a typical leaching-solvent extraction-electrowinning process, ferric ion plays a central role in the heap leaching process and is reduced to ferrous ions in the pregnant leaching solution. Ferric ion is the most important surrogate oxidant and the dissolved ferric/ferrous couple plays an important catalytic role in accelerating the leaching rate with oxygen as an oxidant (Peters et al., 1986; Schlesinger, King, Sole, & Davenport, 2011). In addition, during the traditional electro-winning process, oxygen is evolved at the anode, and copper is reduced at the cathode. A common idea is that iron in the electrolyte in copper electrowinning cell (with total iron of 1–4.4 g/L) plays an important role in reducing the current efficiency. According to the published results (Winand et al., 1975; Dew et al., 1985; Moats et al., 2009; Khouraibchia et al., 2010), thecurrent efficiency decreases linearly with increasing ferric ion concentration and the energy consumption increase was mainly caused by the decrease in current efficiency.

Jan 1, 2019

By Xuanxue Mo, Zengqian Hou

"Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcanogenic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and backarc spreading during its evolution and formed a complete trench-are-basin system, i.e., the Ganzilitang suture zone, forearc basin, outer are, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate faultbound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.All VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is twofold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. All deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asymmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe.The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerals (Groups I and informed during intensifying stages of hydrothermal activity, and the majority of semi-yellow-ore minerals (Group III) formed during a thermal maximum. There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kurokotype VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By T. I. . I. Sibbald, D. E. Jiricka

The Goldfields area on the north shore of Lake Athabasca , was active in the thirties and early fortie . In 1934, Tom Box discovered gold mineralization in quartz veins in pyritized 'granite' at the ite of what wa to become the Box Mine of the Consolidated Mining and Smelting Company of Canada Ltd . In the rush of activity that followed numerou other gold occurrences were found. the most significant of the e being the Athona and Frontier prospects which underwent underground development bur did not reach production. Probable reserve identified to date in the Box and Athona deposits amount to some 3.5 million ton grading an average 0.ITT oz gold/ton . Some 10 to 15 million tons of lower grade, po ible reserve are also reported at the Box. From 1939 to 1942, the mine produced, from underground , 64,066 ounces of gold from ore grading 0.0452 oz gold/ton at a cost of between $1.5 and $2.0 a ton. The Goldfield area is underlain by upracrustal rock intruded by mafic bodies and invaded by ·granite'. The upracru tal . thought to be of Lower Proterozoic age are characterized by a helf-type ucce ion metamorpho ed under lowermiddle amphibolire facie conditions into quartzites, quartz-mica chi ts. dolomitic marbles, diop idic calc-silicates and cordierite-anthophyllite-biotite schi t . Amphibolites of presumed igneou origin form concordant to subconcordant units up to a few ten of metre thick in the upracrustals and occur as le regular masses in the 'g ranite·. Compositionally they vary from gabbroic to granodioritic. with the more mafic varieties being most common. Granitic rocks exhibiting a variety of textural , structural and compositional characteristics underlie most of the area. Four main units are recognized: foliated (older) 'granite', 'leucogranite', feldspar augen 'granite· and pyritic mine 'granite', however, in geological mapping the e are somewhat arbitrarily differentiated due to transitional relationships and admixture of types. Although there is no unambiguous age data available for the e 'granite ' adjacent northshore 'granite' of geologically similar age yield Rb-Sr isochron dates around 2000 Ma. The area is characterized by two major deformation events of which the earliest gave rise to the dominant regional foliation and to rare minor and outcrop scale folds. This foliation which in general parallels compositional layering is folded into the major Goldfields syncline, whose axis plunges weakly to moderately outh. Related open minor folds have subvertical axial surfaces which are locally paralleled by a weakly defined schistosity. Most rock display a pronounced rodding fabric, coaxial with second fold axes and apparently the product of this deformation event. However, a note of caution is introduced into this interpretation, as the rodding fabric is also parallel to first fold axe .

Jan 1, 1986

"Industry Guide 7 contains the Securities and Exchange Commission’s basic mining disclosure policy. It provides guidance for Registrants on various matters including the definition and disclosure of proven and probable reserves and the definitions of exploration, development and production stages. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures. As NI 43-101 is law in Canada, the SEC allows mineral resources and mineral reserves prepared under CIM Definition Standards for issuers that are reporting in Canada but are also registered with the SEC. The SEC places conditions on the disclosure of these estimates. US shareholders are cautioned that the requirements under NI 43-101 and the CIM Definition Standards differ significantly from those of Industry Guide 7.Note: this Guide contains the Commission's basic mining disclosure policy. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures pursuant to the rules of Regulation S-K. Questions regarding the application of these definitions and rules to specific situations should be asked of the Commission's mining engineers or geologists at either the Office of Engineering, Division of Corporation Finance, 202-272-3252, or the Branch of Geology, Central Regional Office, 303-844-1000.(a) Definitions. The following definitions apply to registrants engaged or to be engaged in significant mining operations:(1) Reserve. That part of a mineral deposit which could be economically and legally extracted or produced at the time of the reserve determination.Note: Reserves are customarily stated in terms of DoreD when dealing with metalliferous minerals; when other materials such as coal, oil shale, tar, sands, limestone, etc. are involved, an appropriate term such as Drecoverable coalD may be substituted.(2) Proven (Measured) Reserves. Reserves for which (a) quantity is computed from dimensions revealed in outcrops, trenches, workings or drill holes, grade and/or quality are computed from the results of detailed sampling and (b) the sites for inspection, sampling and measurement are spaced so closely and the geologic character is so well defined that size, shape, depth and mineral content of reserves are well- established.(3) Probable (Indicated) Reserves. Reserves for which quantity and grade and/or quality are computed from information similar to that used for proven (measured) reserves, but the sites for inspection, sampling, and measurement are farther apart or are otherwise less adequately spaced. The degree of assurance, although lower than that for proven (measured) reserves, is high enough to assume continuity between points of observation.(4)(i) Exploration StageDincludes all issuers engaged in the search for mineral deposit (reserves) which are not in either the development or production stage."

Jan 1, 2003

By P. Taskinen, A. Jokilaakso

The Flash Smelting Process for copper and nickel production has been one of the most successful new metallurgical process developments in the 20th century. The experimental data from laboratory scale investigations of studies has produced information and insight into the reaction mechanisms and kinetics of the flash reactions of copper concentrates. Advanced computer models coupling chemical reactions with a Computational Fluid Dynamics (CFD) software became possible with the development of commercial CFD software together with increased computing power. Currently, there are both experimental and CFD modelling, including also CFD–DEM coupling (Discrete Element Method), studies ongoing for investigating the kinetics of matte – slag reactions in the flash smelting furnace (FSF) settler. The ultimate goal of the modelling work is to develop a comprehensive FSF model for studying the behavior of changing raw materials, both primary and secondary, and distribution of their elements between the matte, slag, and gas phases. The use of User-Defined-Functions (UDF) is one way to digitalize metallurgical knowledge and experimental information to be used for supporting process experts and development of artificial intelligence applications in metallurgy. In this paper, a review of the development of the FSF reaction shaft modelling and experimental investigations, and the current work for the settler reactions’ experiments and modelling are presented. INTRODUCTION The Outotec Flash Smelting process (Bryk, Ryselin, Honkasalo, & Malmström 1958) has been used in the copper and nickel industry for 70 years with continuous support from experimental investigations by many research groups in academia, among others Jorgensen and Segnit (1977); Jokilaakso, Suominen, Taskinen and Lilius (1991), Chaubal and Sohn (1986), Kim and Themelis (1986), and in industry Mäkinen and Jåfs (1982); Kojo, Lahtinen and Miettinen (2009); Tuominen, Pienimäki and Fagerlund (2016). It has been developed also for pyrite and lead smelting (Asteljoki, Sulanto & Talonen, 1984). A schematic illustration of the FSF and other main parts of the process is depicted in Figure 1. Also, two and three dimensional physical water or gas models have extensively been used in product and process development (Lilja & Rajainmäki 1995). During the recent decades, computer based models have increasingly been adopted in the FSF research and development (Ahokainen & Jokilaakso, 1998); Ahokainen, Jokilaakso, Taskinen & Kytö, 2006; Hahn & Sohn, 1990; Jorgensen & Elliot, 1992; Zhou, Zhou, Chen & Mao, 2014; White, Haywood, Ranasinghe & Chen, 2015) to name a few, but also in supporting engineering and sales of the technology (Miettinen 2017). Even though the reactions of the sulfidic concentrate particles have been included in the reaction shaft modelling, the complete FSF model with both gas-solid/drop and molten slag/matte drop has so far been and still is too demanding for today’s computer hardware.

Jan 1, 2019

By P. Au, R. Kearsey, D. Y. Seo, Patnaik. P. C.

Three nickel based superalloys (7.5%Cr+5%Co+2%Mo+1%Ti+5%Al and Ni balance (wt%)) containing different amounts of W and Re were produced in the single crystal (SX) condition utilizing the Bridgman casting process. First, the effect of different levels of Re, and W on chemical microsegregation were investigated by EPMA quantitative analysis, and eutectic phase fraction analysis. Second, in order to investigate the effect of these refractory elements addition on oxidation behaviour, isothermal oxidation testing of the SX nickel based superalloys was conducted at 1000°C for 277 hours under 3 ppm moisture content of air in a thermogravimetric analyzer (TGA). All three SX nickel based superalloys revealed an excellent SX solidification structure with a common primary dendrite arm spacing of -250 µm and a large fraction of ?/?&apos; eutectic located between the secondary dendrite arms. From the average EPMA compositional results, with the exception of Ni, elements such as Cr, Co, Re, Mo, and W all tended to segregate towards the dendrite core during solidification, while Al, Ti, and Ta were present in greater quantity in the last liquid phase to solidify, which resulted in large eutectic ?/? &apos; phases to form within the interdendritic regions. As the nominal level of Re increased, microsegreagation of Re, W, Cr and Mo increased, indicating that Re had a much greater influence on partitioning behavior compared to W. Figure la shows the specific mass gain as a function of exposure time for each alloy. An alloy with 2wt% of W and Re (Alloy B) exhibited less weight gain compared to two other alloys with either higher content of W or Re (Alloy A and C). Microstructural and compositional analyses of oxidized samples were conducted using SEM and EDS. Figure lb shows the typical surface morphologies of the oxidized Alloys A and B. It is evident that more oxide nodules (indicated by arrows in the figure) were presented in Alloy A. It is speculated that the amount of these nodules was responsible for more mass gain in Alloy A compared to the two other alloys. From the examination of the longitudinal section of the oxidized samples as shown in Figure 2, for Alloy A, nodules actually penetrated deep into the material. For Alloy B, however, a relatively uniform and continuous oxide layer was developed and deeply attacked areas were not observed. It was also found that preferential oxidized regions were located at the area between the ?/?&apos; eutectic phase and the dendrite arms where the concentration of refractory elements was relatively high. Therefore, it is plausible that the oxidation kinetics of these alloys is related to the extent of microsegregation.

Jan 1, 2004

By Jeremy D. Glennon

A number of exciting challenges, opportunities and unanswered questions remain concerning the chemistry, geochemistry, medical, industrial and analytical applications of gold and its compounds.1 Among the challenges presented is the need for extraction methods for gold, at process and indeed analytical scales, that avoid the use of organic solvents or hazardous reagents. Extensive environmental contamination has occurred in the Brazilian Amazon from the mercury-gold amalgamation process. Major problems with the cyanidation process are the relatively slow dissolution kinetics and the health and environmental problems associated with it. With innovation and technical changes, a cleaner way for solubilising and extracting this versatile precious metal can be found. This cleaner future may lie in supercritical fluid science. Interestingly, geochemical studies of gold solubility and speciation in hydrothermal solutions have highlighted the importance of supercritical conditions and sulphur species in the deposition of gold in natural environments. Gold solubility in supercritical brines is far higher than previously supposed while interest in the high content of carbon dioxide in the mineralizing fluids is growing. 2,3 In recent years, also, there has been a tremendous amount of attention paid in analytical chemistry and in industry, to the area of supercritical fluid extraction (SFE) of organic and metallic species. 4 This interest has been fuelled by the introduction of more stringent environmental control and the subsequent need for cleaner solvents and processes to replace established ones. Carbon dioxide is the substance of choice for SFE because of its moderate critical parameters (Tc = 31oC, Pc = 73atm), inertness and availability in pure form. It is an excellent extraction medium for non-polar and moderately polar species, and with careful ligand design, it can be used for analytical and process scale metal extraction from solution and solid phases. In general, the dissolution of a metal in supercritical CO2 (sc-CO2) requires that the charge on the metal ion be neutralised on complexation by the ligand or through a form of ion pairing (analogous to the situation where metal ions are extracted into organic solvents, such as methyl isobutyl ketone or toluene). In this way, then, many chelating agents such as dithiocarbamates and hydroxamic acids have been utilised to extract metal ions such as Cu and Fe into sc- CO2, the process greatly enhanced by the use of fluorinated ligand derivatives. 5-7 In this review paper, we show that supercritical conditions and complexation with sulphur donor atoms, important in the natural deposition of gold, can form the basis of a clean, eco-friendly chemistry for gold extraction. Analytical scale extractions of gold from a variety of matrices can be conveniently used to assess the efficiency of any new proposed ligand.

Oct 1, 2003

By S. C. Tadolini

"Roof bolts are the primary means of roof support in underground mines in the United States. Presently, post installation loads are measured on about 10% of the expansion anchor and combination bolts by using standard torque wrenches that Unit the accuracy of the measurements to about ±30%. No system has been available for measuring the loads generated on full-column resin grouted bolts. Mine roof bolts are long, slender, non-uniformly sized, roughly forged, and placed in a corrosive environment, creating obstacles for researchers trying to utilize ultrasonic reflection techniques to measure strain. A complete measurement system has now been developed by the U.S. Bureau of Mines, Denver Research Center. This system is being used successfully in determining loads measured on expansion anchor and combination bolting systems, examining the transfer mechanics of full-column, resin-grouted bolts, and measuring loads generated on bolts in an underground roadway support system.IntroductionMillions of roof bolts are used each year to provide structural support in underground U.S. metal, non-metal, and coal mines. Approximately 45% of the bolts used are expansion anchor, 45% are resin-assisted combination or full-column resin-grouted, and 10% are friction anchored. The effectiveness of these bolting types is dependent on a number of factors including rock density, bolt length, in situ stresses, rock properties, bolt pattern, installation tension, etc. When implementing expansion anchor and resin assisted combination bolts , installation and post-installation tension, or load, is a major determinant of support quality and subsequent behaviour of the reinforced roof. The method by which these systems carry roof loads is well understood and documented(1,2).The importance of these installation and long-term bolt tension measurements is well recognized and are required in the federal government regulations(3). A statistical sample of the bolts, lout of 4 during installation and lout of 10 inby the last open crosscut, is required to be measured using current torque wrench technology. The disadvantages of this system are the disturbance and weakening of the anchorage and limitations of accuracy to approximately ± 30%. The method by which resin-grouted bolting systems carry roof loads is much less understood, mainly because testing procedures used to evaluate point-anchor systems are not effective on resin-grouted bolts.Due to these problems, the U.S. Bureau of Mines designed a measurement technique that provided a highly accurate, low cost-per- bolt system that led to the development of ultrasonic pulse echo instrumentation. The original system was designed to measure the tension only on expansion anchor bolts. Recent developments and system modifications have permitted measurements on resin-assisted and full-column resin-grouted bolts. The use of these types of support systems has been increasing steadily in underground coal mines.The development of this instrumentation has provided laboratory and field results that help to explain the mechanics and relationships between the applied loads and the interaction between the grouted bolt system consisting of the bolt tendon, grout, and rock."

Jan 1, 1990

By D. E. M. Plaumann

"The wet grinding of asbestos has attracted the attention of engineers for many years as a means of improving fibre liberation from the ore. Today, added impetus for wet grinding has resulted from a need to minimize worker exposure to asbestos dust in conventional dry mills using air, as well as a need to provide a cleaner, technically superior fibre for use by product manufacturers. However, high viscosities of asbestos slurries create transport and grinding difficulties which have been a factor impeding use of a wet grinding process.Laboratory evaluation of reagents to reduce viscosities of asbestos slurries found that one reagent, XFS-4272.00, reduced the viscosity of a 35% (by weight) slurry by 75%. The impact of XFS-4272.00 on actual grinding parameters were evaluated using a pilot plant rod mill. Slurries containing 78% solids and XFS-4272.00 were successfully milled and asbestos fibres from that milling compared favourably in liberation and relative surface area to asbestos fibres obtained from milling a 4% slurry without additives. IntroductionAlthough the use of asbestos has been declining over the last few years, the large deposits of chrysotile in eastern Canada (Quebec in particular) remain very important. Asbestos production in Canada stands ninth in volume for mineral production with over 740 000 tonnes produced in 1985. Of this quantity, 722000 tonnes were exported with a value of $446 million. Canada is second in world production of asbestos behind the U.S.S.R. The milling of asbestos ore has been done primarily by a series of steps involving crushing, dry-grinding and aspiration using large quantities of air to release the fibres. Contrast this process to those practiced in the purification of virtually every other mineral. Ores other than asbestos are crushed and milled using an aqueous slurry in rod, ball or pebble mills. The finely ground mineral, still as a slurry, undergoes beneficiation by froth flotation, heavy media separation, hydrocyclones or any of the other aqueous techniques currently employed in mineral processing.One of the driving forces behind the use of air instead of water as a means of separating asbestos is the nature of the aqueous asbestos slurry. While most slurries of minerals contain as much as 80070 solids and can still be pumped and transported, asbestos slurries become highly viscous with as little as 10070 solids. These high viscosities reduce the pumpability of the slurry and create severe handling problems. Mills become prohibitively large and uneconomical due to having to handle slurries containing only 10% rock and 90% water.Health-related issues have affected the use of asbestos in many countries. In Canada, the asbestos-producing provinces have introduced stricter occupational legislation to improve safety in the workplace. This primarily means strict control minimizing release of air-borne asbestos fibres . Quebec and Ontario have set limitations of airborne asbestos at 2 (2) and 1(3) fibre per cubic centimetre of air. With present milling technology, maintaining these low levels in the workplace requires constant vigilance."

Jan 1, 1988

By Javier Ramirez

"Recent R&D pilot plant testing was done to validate a full industrial scale system for recovering residual magnetite from the tails of an iron ore concentration plant. The recovery system is based on an autogenous heavy media separator treating a tailings slurry at 0.45% solids by weight. A 3,100 m3/h capacity concentrator was installed based on the testing findings. Excellent metallurgical results have been observed in two years of continuous operation. This experience is the basis for the proposal of a novel process consisting of the preconcentration of base metals ores; the idea being to obtain a heavy bulk concentrate of the polymetallic minerals and discarding in one step the light gangue mineral components. The bulk concentrate then proceeds to conventional froth flotation. The reduced volumetric flow of the bulk concentrate allows a reduction in the size of the subsequent flotation circuit. A prerequisite for the heavy media separation is a fine size grinding of the ore and a correspondingly high degree of liberation of the mineral species to be recovered. A process scheme is also presented in which the gravity concentrator works in conjunction with a companion tailings thickener for process water recovery. The underflow from this thickener, having paste consistency, can be sent to a tailings dam or mixed with Portland cement for mine backfill. The process water in the system is managed at an estimated recovery in excess of 98%. Additional R&D work using this novel approach is being considered by a large iron ore concentrator for removal of liberated silica from the final concentrate; and for upgrading 3.5 million tons of a marginal hematite reserve owned by the mining company.INTRODUCTIONGravity preconcentration (static and dynamic) of sulphides prior to froth flotation has been and is being practiced at various concentrator plants (Asarco´s Young Mill: heavy media cone; Mount Isa: DSM cyclone; Afton Mines: Denver jigs; Tsumeb Mine: Reichert cone) (Burt, 1984). The idea behind installing preconcentration equipment is to reduce the volume of feed processed on flotation, thus requiring smaller flotation plants although other advantages may be of importance, such as obtaining richer concentrates due to higher grade feed, better process water and energy management, and reduced flotation reagent consumption.The SedconTM solid/liquid separator is a versatile process unit patented in Mexico (MX/u/2007/000305). As a gravity device, it may be classified as an autogenous heavy media dynamic concentrator. Figure 1 depicts the Sedcon (Sedimentador de conos) separator. The four main components are as follows: the feedwell for efficient mixing of the pulp with dilution water and flocculant (and coagulant for water clarification); the inner cones (passive elements for solid/liquid separation); the discharge underflow cone; and the scraper mechanism. The standard discharge cone is a 60° inclined cone for general applications. For paste tailings thickening applications, a deep cone with a 69° inclined cone is used."

Jan 1, 2016