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By J. C. Ingles

"A survey of possible methods for controlling cyanide concentration indicated that the simplest method would involve the use of a potentiometric technique. Such a method was suggested by a paper from the laboratory of Mines Safety Appliances, which described a method for determining hydrogen cyanide in air. In this application, the cyanide was absorbed in caustic and a silver electrode immersed in the caustic solution provided a measure of the cyanide concentration. However, our attempts to use the silver electrode in this simple manner to measure the cyanide concentration of solutions were not very successful. A study of the mechanism by which a silver electrode responds to cyanide concentration made it evident why this simple procedure is not satisfactory.Basically, the silver electrode provides an indication of the free silver ion concentration of a solution, and generally speaking, ignores the other ions' present. It can be used to measure an anion if this anion complexes silver. This technique has been used in complexing studies to determine the activities of such anions as acetate, citrate, oxalate and chloride. To do this, the electrode has to be placed in a solution which initially contains a known concentration of free silver ions. Addition of the complexing anion causes a drop in the free silver ion concentration and hence a change in the potential of the silver electrode. The change in potential can be expressed in terms of the concentration of the complexing anion, and used to indicate its concentration in the solution being analysed. The determination of chloride-ion by a silver-silver chloride electrode is an example of an application of this technique. The solubility of the silver chloride with which the electrode is coated provides the initial free silver-ion concentration. Depression of this free silver-ion concentration by the presence of the excess chloride ion of the sample solution results in a change in the potential of the electrode which is proportional to the chloride-ion concentration."

Jan 1, 1965

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By Paul G. Dunn

Safe rapid drift development results principally in reducing exposure of underground workers to the working face. This reduction in exposure is not achieved until either the rock walls have been suitably scaled or sufficient support has been put in place. Rapid drifting enables quicker access to orebodies (increasing returns), higher production rates and a resultant lower cost of mining. The Mining Innovation, Rehabilitation And Applied Research Corporation (MIRARCO) has been developing technology and a methodology for safe rapid drift development within the underground metalliferous mining industry. In terms of rock scaling for underground metal mines, there is still considerable use of manual and mechanical impact rock scaling techniques. Two main issues result from this approach. The first is that in highly stressed or highly fractured ground, a decision has to be made as to when sufficient scaling has taken place. This is not always easy to do and hence operator judgment is a crucial element in this approach. During a baseline study of current rock scaling practices, a wide range of scaling practices were observed within five different underground mining operations; this demonstrates the difficulty inherent in the rock scaling quality decision making process. The second issue is related to the exposure of workers to freshly created rock surfaces. In manual scaling techniques this is unavoidable and despite the best scaling practices, accidents still occur. In an attempt to provide an alternative scaling technology, MIRARCO has been investigating highpressure water jet scaling for removing loose rock as part of the drift advance process. This technology not only provides a means by which scaling practices can be engineered (remove the loose material you want to in a given rock mass condition), it is also quicker and easily automated. Automating the scaling process removes workers from exposure to freshly created rock surfaces and also enhances the application of spray-on liners through improved adhesion of these support types to the rock surface. This paper describes the water jet scaling technology research and methodology for safe rapid drifting within the underground metaliferous mining industry and highlights the key issues and major drivers behind their continued development at MIRARCO.

May 1, 2004

By N. Moelans, I. Bellemans, K. Verbeken

In this work, we present a phase field model to simulate the facetted crystallization of Fe3O4 in a quaternary FeO-Fe2O3-Cu2O-SiO2 melt under different partial pressures of oxygen. An important focus in creating more realistic phase field models is the incorporation of the thermodynamic driving forces in multicomponent multiphase-field models by coupling to thermodynamic databases. The diffusion of FeO, Fe2O3 and Cu2O is considered. The ratio of FeO/Fe2O3 at the upper boundary is in equilibrium with the oxygen fugacity of the atmosphere, while conserving Fe. Two-dimensional simulations are performed with different varying oxygen fugacity in the atmosphere. For the considered composition range, the growth velocities of the spinel crystals increase with decreasing oxygen fugacity. INTRODUCTION Crystallization of silicate melts has its applications in geology, pyrometallurgy and glass making. In pyrometallurgy, the solidification of slags influences the freeze lining behaviour (Campforts et al., 2007) and the cooling of slag after tapping (Durinck, Jones, Blanpain, & Wollants, 2008). Modeling of silicate melt crystallization is frequently done on the macroscopic level, using thermodynamic equilibrium calculations to determine the fractions of all phases as a function of temperature. The Factsage software and database package (Bale et al., 2016, 2009, 2002) already proved its usefulness in pyrometallurgical applications, for example to model the phase mixture after solidification of a stainless steel slag (Durinck et al., 2008). Crystallization of phases typically results in complex morphologies on the mesoscale, e.g. dendrites or facetted growth. On this mesoscale, the phase field concept has proved to be a very powerful tool (Moelans, Blanpain, & Wollants, 2008) for modeling crystallizing microstructures, because it can treat arbitrarily complex interface shapes with minimal mathematical complexity. In contrast to macroscopic models, the diffusion profiles and crystallization kinetics can be described as well as the morphology of individual crystals. First, Kobayashi (Kobayashi, 1993) simulated a growing dendrite in a pure undercooled metallic liquid. Then, Warren and Boettinger (1995) simulated a dendrite in an isothermal system considering a binary alloy. The extension to multi-phase systems was done by Steinbach et al. (1996). This was further extended by Tiaden, Nestler, Diepers, and Steinbach (1998) to a framework with coupled diffusion and phase field equations in multi-component systems.

Jan 1, 2019

By B. A. Peppley

The current most common method of hydrogen production for fuel cell systems, including SOFC systems, is autothermal reforming. Autothermal reformers have a number of advantages including fast start up and load following and ease of control. However, there are a number of problems inherent with the addition of air into a system connected to the anode feed such as dilution of the fuel with nitrogen and the potential for oxygen to reach the anode chamber directly. Pure steam reforming, which does not involve air addition, provides a richer fuel mixture to the SOFC anode and is inherently safer than autothermal reforming. Although in theory pure steam reforming can be shown to provide these advantages, a number of technical problems need to be overcome before such a system can be practical. In particular, issues such as catalyst degradation due to poisoning and thermal sintering, coking, as well as fuel-steam mixing need to be addressed. Experimental results from a prototype reformer will be presented to illustrate a number of these points. This paper will compare differences in system efficiency, safety and complexity between autothermal/SOFC systems versus a steam reformer/SOFC system. A system simulation will be utilized that is able to account for material and energy balances for a SOFC power generator operating on diesel fuel. The requirements for improved catalysts will be discussed and an analysis of the potential benefits of sulfur tolerance and lower temperature activity will be considered.

Jan 1, 2005

By F. King, R. Sutherby, J. Been

With thousands of kilometers of buried oil and gas pipelines throughout the country, carrying flammable, high-energy hydrocarbons, the integrity and safety of this transportation and distribution network are paramount. The pipeline industry has the primary responsibility for pipeline safety and has in many ways taken the lead in dealing with safety issues. Over recent years, regulatory demands have increased, requiring operators to comprehensively evaluate their pipelines through indirect and direct inspections and to manage risk through integrity programs. Mechanistic and correlative models have been developed that assist in the prediction of pipeline integrity and the determination of reassessment intervals. These lifetime prediction models are based on decades of laboratory research as well as pipeline operating data, material data, and field monitoring data pertaining to soil conditions and CP. An overview is presented of an integrated approach towards the development of such models for the evaluation of external cracking and corrosion of transmission lines.

Jan 1, 2005

By Al Holmes

"In a recent survey of Canadian work values, 89% of the men surveyed and 97% of the women surveyed described the work in a mine as ""not at all auraetive"", Work in a mine, in fact, was rated by both sexes as the least attractive of all of the types of work surveyed. Confronted with this prevailing attitude, Canada's mining industry starts out with two strikes against it in its bid to attract and hold on to its fair share of available work force.Behavioural scientists have, for decades, been seeking answers to the questions:• ""Why do people work?""• ""Why do people choose a particular occupation?""• ""Why do people choose a particular organization?""• ""Why do people leave one organization for another?""• ""Why do some people stay in an organization?""• ""Why do some people work harder than others?""Their answers to these questions, although tentative and often contradictory, are being used by more and more organizations to solve people problems. Few industries can afford to ignore them, least of all, perhaps, the mining industry.Consider the following developments:I. General Motors and the United Auto Workers turn around the car assembly plant in Tarrytown, New York in seven years from the plant with the poorest labour relations and production record to one of the best under a program referred to as ""improving the quality of work life.""2. Shell Canada and the Oil, Chemical and Atomic Workers have designed a new petro-chemical processing plant in Sarnia using a set of principles that seek to optimize both the social and the technical system."

Jan 1, 1980

By H. Hejny

Given the current status of political discussion in Europe about raw materials issues, the sustainable development of the extractive industry and the reduction of its environmental and societal footprint are among the key topics in this discussion. In this context, the European Commission approved the EO-MINERS project (Earth Observation for Monitoring and Observing Environmental and Societal Impacts of Mineral Resources Exploration and Exploitation). The overall aim of EO-MINERS is to bring into play EO-based methods and tools to facilitate and improve interaction between the mineral extractive industry, authorities, and the society in view of its sustainable development while improving its societal acceptability. Developing generic, standardised and reliable EO-based products to monitor the environmental and societal footprint of mining projects is the way chosen by EO-MINERS to improve this interaction, along with the organisation of tripartite meetings gathering all relevant stakeholders. The project uses existing EO knowledge and carries out new developments on three demonstration sites (Sokolov lignite mining area, Czech Republic, Witbank coal field, South Africa, Makmal gold mine, Kyrgyzstan) to further evaluate and demonstrate the capabilities of integrated EObased methods and tools in monitoring the environmental and societal footprints of the extractive industry during all phases of a mining project, from the exploration to the exploitation and closure stages. It contributes providing reliable and objective information about affected ecosystems, populations and societies, to serve as a basis for a sound ?trialogue? between corporate stakeholders, governmental organisations and societal stakeholders. The project already developed a set of consolidated indicators based upon previous knowledge about mining-related issues along with interviews of national, regional, and local stakeholders. These indicators reflect known environmental and societal issues at mining sites as well as the interest of various relevant stakeholder groups. The process described in the EO-MINERS project ? policy assessment > indicator identification > choice of suitable EO tools able to serve monitoring task > monitoring by EO tools > making available objective information for fair dialogue among stakeholders ? is generally applicable to all stages of a mining project. The key to success will be the right choice of indicators addressing the problem and subsequently the right choice of suitable EO tools and finally the willingness of all stakeholders to find a common solution. To this end, the EO-MINERS project organises site-specific ?trialogue? workshops at each demonstrations site, which aim to provide relevant information in adequate quality to the stakeholders as common ground for discussions. Local stakeholders, including mining companies, regulatory bodies, and community representatives are invited to participate in these workshops where the relevance of the developed EO-based products to environmental and societal impact assessment will be discussed. The presentation will discuss results obtained during these trialogue workshops, as well as the success and difficulties and reluctances encountered. The project will further indicate ways and means how the EO products and other project results may be used for monitoring purposes in all phases of a mine.

Aug 1, 2013

By A. F. Banks

"IntroductionThe typical potash processing plant recovers and/ or upgrades from 10% to 20% of its production through the recrystallization process. The feed to the recrystallization section consists of preconcentrated slurries of fine crystal size that cannot be raised to the required product grade by flotation and fine dusts also of low grade and too fine for compaction feed. It produces high grade white potash crystals that can be marketed as a high grade product or blended into the flotation products to raise their grade. In this chapter, a typical leaching (dissolving) and recrystallization operation will be discussed.The crystallization process makes use of the three phase system chemistry of NaCl, KCl, and H,O. The normal potash process operates on a temperature range of 75°F to 95 °F. A three phase slurry feed to the dissolving circuits will be within that range. The potash (KCl) is dissolved by heating the slurry in the presence of sufficient brine to a temperature of 190°F to 200°F. As the slurry is heated, the potash (KCI) dissolves and the salt (NaCI) precipitates. The potash rich brine is then clarified and the salt and other undissolved solids removed by thickening. Clarified brine becomes the crystallizer feed.The hot brine is cooled in evaporative cooling crystallizers. In cooling, the potash precipitates as a high grade white crystal. Crystallization is done in multiple effects to permit energy recovery and control of the process. In a four effect crystallizer the cooling is done by recycling mother liquor counter currently through the first two effect condensors and using brine pond brine for the cooling of the last two.The crystallizer product is removed from the last effect as a slurry at normal process temperature and is fed either to its own centrifuging and drying circuit or blended with the flotation product for centrifuging and drying."

Jan 1, 1989

WHAT IF? ?Mine closure and reclamation liabilities were fully funded -at all times from current mine revenues ?Unexpected & catastrophic events were insured ?Remediation costs could be capped ?Risk management was improved ?best practice and independent oversight ?Host communities?concerns were adequately addressed If this could be achieved within a cost-effective financial structure, this may be a solution to a complex issue for the mining industry

May 1, 2006

By David Green

"This paper describes Outokumpu's Tank Cell concept using the unit reactor principle and operating experience gained in various applications. Presently the tank cells used range in size from 35 t pilot size to 100 m' (3500 cuft). The paper discusses operating experience and results from commercial installations in copper and zinc rougher and cleaner services.The key feature of the Tank Cell described is the effective control of the froth phase and resulting possibility to operate on an improved grade recovery curve by manipulating the control variables."

Jan 1, 1995

By Jennifer Young

Presentation Outline ? Introduction ? Aboriginal Inclusiveness ? Common interpretations, practices ? Aboriginal Community Expectations ? Lessons Learned ? Native Code of Conduct Introduction Jennifer Young ? Nestu'et (Mi'kmaq) means: becoming wiser, becoming more knowledgeable Aboriginal Inclusiveness ? Internal hiring strategies (affirmative action) ? Incorporating cultural awareness programs ? Approaches in governmental/organizational policy development Practices in negotiating economic development and fiscal sharing strategies

May 1, 2010

By Sergio Fuentes

During the past fifteen years, mines utilizing the block caving method have improved performance and systematically reduced total mining costs. This paper describes improvements in mine design, mine planning and mine management, including methods enabling the Chilean and International mining industry to ensure cost savings and productivity growth while using the block caving method. These improvements have encouraged the re-evaluation of underground operations at operating and closed open pits, and challenge surface mining applications as the only low cost mining method. This paper describes a strategy to estimate the optimum open pit to underground transition time during the life of a mine.

May 1, 2003

By H. Dundar

The first application of High Pressure Grinding Rolls was in 1985 at a cement plant, for the purpose of capacity improvement. Then various circuit configurations were derived to achieve a reduction in overall specific energy consumption, by transferring more of the grinding required to the HPGR. In most circuit configurations, the recycle of fines is required for effective breakage between the rollers. By increasing the fines amount in the feed material to a specific level within the recycling load, a uniform material bed is created and a higher pressure gradient along the roller width is obtained, resulting in compact flakes, including more fines. The fines recycle results in enhancement of the interparticle breakage. This paper will discuss the effect of the feed size distribution on HPGR performance.

Jan 1, 2012

By Lee Barbour

Waste-rock piles from metal mining operations are comprised of large surface deposits of unsaturated, coarse-grained soil and rock. The unsaturated condition and heterogeneous, coarsegrained nature of these deposits make them difficult to monitor or characterize. Key parameters that must be evaluated include; volume-mass relationships (e.g. water content, air content, porosity, density, degree of saturation, grain-size), transport properties (e.g. air-permeability, gas diffusion, hydraulic conductivity), geochemistry (e.g. solids, gas, and fluid phases) and soilatmospheric fluxes (water and gas). This paper describes some of the techniques that have been developed to characterize waste rock piles for uranium mines in Northern Saskatchewan. For each technique, the method of measurement is described, and preliminary field data are presented and discussed.

Nov 1, 2002

By Joseph J. Poveromo

The blast furnace today continues as the primary production method of hot metal in large-scale steel production. The blast furnace process has been the target of repeated attempts to replace it with various process options, including direct reduction and coke-free smelting reduction. While these new technologies are being adopted in appropriate niches, the blast furnace has responded to the challenge by being amenable to continuous improvement. I will review the role of the blast furnace, major developmental and improvement trends, and then list the current important issues in ironmaking. I will outline the challenges to be faced by the blast furnace to maintain its position as the primary hot metal production process. The material presented here is an update of earlier presentations made in Stockholm, Sweden, 1996, Duluth, 1998 and Chicago, 2000.

May 1, 2003

By J. Paraszczak

Application of teleoperated and automated (or ?autonomous?) mobile equipment in underground metal mines represents a promising avenue for overcoming some of the challenges facing the industry. This paper addresses the overall effectiveness of autonomous loading and haulage equipment compared with conventional human-operated machines. Factors affecting availability, utilization, and production rate are explored, and an emphasis is placed on some problems and risks not present in conventional human-operated systems, as well as on the character and criticality of autonomous equipment. The need for a more in-depth analysis of factors affecting overall autonomous equipment effectiveness is stressed; these factors should be taken into consideration at the stage of feasibility studies. The paper concludes with recommendations and directions for future research.

Aug 1, 2010

By R. S. Rogers

Abstract - Forensic geology in a mineral exploration context is concerned with geology and related technical matters as they pertain to legal cases involving exploration and evaluation of mineral properties. Such cases involve the possibility of outright scams that include falsification of data and information, as well as inappropriate application of various technical procedures. Experience in forensic geology in such cases emphasizes the need for systematic quality control procedures during routine exploration/appraisal and indicates the need for more attention to ‘target hardening’ (improving security in the chain of custody of samples and assay results). A number of ‘early warning signs’ that might suggest some form of tampering or falsification of information are listed. These measures will support the work of the "Qualified Persons" (geologists and engineers) entrusted with the scientific and technical aspects of mineral exploration, and facilitate the increased attention to regulatory oversight and enforcement of securities laws recommended in the report "Setting New Standards."

Jan 1, 1998

By J. Paraszczak

ABSTRACT: Application of teleoperated and automated (or “autonomous”) mobile equipment in under-ground metal mines represents a promising avenue for overcoming some of the challenges facing the industry. This paper addresses the overall effectiveness of autonomous loading and haulage equipment compared with conventional human-operated machines. Factors affecting availability, utilization, and production rate are explored, and an emphasis is placed on some problems and risks not present in conventional human-operated systems, as well as on the character and criticality of autonomous equipment. The need for a more in-depth analysis of factors affecting overall autonomous equipment effectiveness is stressed; these factors should be taken into consideration at the stage of feasibility studies. The paper concludes with recommendations and directions for future research.

Jan 1, 2010

By Apoorva Bajaj

Iron ore mines of Steel Authority of India Limited (SAIL) have to comply with strict chemical composition norms laid down for iron ore lumps supplied to its steel plants. This requires a careful planning of the overall ore excavation operation. In general terms, the problem can be stated as: Given the chemical composition of ore for all excavation sites, excavation capacity of each shovel, distance of each excavation site from the crushing plant and the number of dumpers available for transport of the ore, find out the percentage of ore to be excavated from each excavation site such that the production rate is maximized and the chemical composition norm is satisfied to the best possible extent. This paper presents an approach to solve this problem using Branch and Bound method. The specification for r.o.m. quality has been modified by incorporating a new parameter, ?Al2O3 / SiO2? ratio, which has a significant effect on the performance of iron blast furnace.

Oct 1, 2009