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By Paul W. Cleary

"Particle scale simulation of industrial particle flows using DEM (Discrete Element Method) offers the opportunity for better understanding the flow dynamics leading to improvements in equipment design and operation that can potentially lead to large increases in efficiency, throughput or product quality. DEM has been used for modelling many industrial applications, particularly milling. This includes ball and rock motions and power consumption in ball mills, AG and SAG mills, vibrational segregation, flows in rotating drums, operation of dragline excavators and hopper flows. In mineral processing, DEM has been concentrated on mills because of their critical importance. However DEM also offers the opportunity to improve many other parts of mineral processing operations. These areas often do not receive the attention that the key comminution equipment commands, but can become critical when they fail or under-perform. Importantly their assessment/improvement using DEM is often much more feasible because of smaller problem sizes and the absence of poorly understood physics such as breakage. In this paper we describe DEM simulations of four important pieces of non-comminution equipment that are commonly found in or near mineral processing plants (these are shown in Figure 1):"

Jan 1, 2003

By G. S. Hansford, G. E. Searby

"Ferrous iron oxidation kinetics was measured in continuous culture at temperatures between 65 and 75ºC, using thermophilic microbes suitable for high temperature bioleaching. The resulting specific oxidation rates were modelled as a function of the ferric/ferrous iron ratio. The results were compared to those obtained by conventional mesophilic microbes.Microbially mediated ferrous iron oxidation is a vital sub-process in the mesophilic bioleaching of sulfide minerals and is expected to be of similar importance at elevated temperatures using thermophilicmicrobes.A thermophilic archaeal culture used in chalcopyrite bioleaching was successfully grown in continuous culture on ferrous sulfate, indicating the capability of the microbes to sustain growth for long periods on the energy provided by the conversion of ferrous iron to ferric iron, the primary leaching agent in sulfide mineral bioleaching.Steady state data was obtained at residence times of between 70 and 10 hours, with washout occurring at residence times between 11 and 9 hours, corresponding to a maximum growth rate (µmax) of between 0.09 and 0.11 hr-1. The reactions were followed by measurements of the solution redox potential, soluble iron concentrations, and offgas analysis of the oxygen and carbon dioxide utilisation rates."

Jan 1, 2003

By Claudio L. Schneider, Reiner Neumann

Any serious study of stereological conversion procedures must be based on an as accurate as possible complete fractionation of a real mineralogical texture. The original work on the Dolomite- Sphalerite Magstream? separation provided excellent data for establishing a working stereological conversion procedure, which has been successfully applied to a number of ores since its implementation. The linear grade distributions measured from these fractionated particles have been published and are accessible. The procedure for stereological conversion from areal measurements is exactly equal to the procedure for linear measurements. Particle composition from the dolomite-sphalerite density-fractionated particle sets, derived from both linear and areal data (Figures 1 and 2, respectively) are redundant, after proper transformation, and match the particle’s compositional range (plotted against S.G.) expected from Magstream?; direct density measurements by Hemicropicnometry plots within the ranges. Linear data cannot be used without conversion, but areal measurements are often directly applied as liberation spectra. Our areal measurements, without stereological conversion (Figure 3), differ completely from the results after transformation, and its density range falls mostly out of the expected/measured values. Therefore non-transformed areal data cannot be directly applied as useful liberation information.

Jan 1, 2003

By S. Kelebek, A. Khan, J. Caceres, D. Beckett

"Pyrrhotite in nickel-copper sulphide ores is nickeliferrous and intimately associated with pentlandite. Due to its low nickel content, pyrrhotite rejection is an important step in processing of these ores. In our laboratory, various reagents were investigated for their effect on pyrrhotite depression. Among these, a combined use of triethylenetetramine and sodium metabisulphite was found highly promising.The work described in this paper has two parts. The firs part is a summary of results obtained on process samples from the pyrrhotite rejection circuit at Falconbridge’s Strathcona Mill. The second part involves simulation of the circuit performance based on the reagent conditions used in the experimental work and the concept of split factors.Two sets of reagent conditions were evaluated. The first one involved baseline conditions, simulating the current reagent performance. The second one simulated the impact these new reagents can have on the circuit performance.The simulation results obtained under baseline conditions indicated a good agreement with the current circuit performance (Figure 1). The simulation results suggest that at practically the same pentlandite recovery and tailing grades, the circuit concentrate nickel grade can be doubled through effective pyrrhotite rejection by these new reagents (Figure 2)."

Jan 1, 2003

By Thomas Mütze, Anja Hirte, Ursx Peuker, Thomas Kuhn

"The comminution behavior of two ferromanganese nodules samples of the equatorial northeast Pacific has been examined as a basis for the separation of two kinds of metal-rich layers. Those layers were finely grown together during nodule formation and are one reason that the exploration of deep-sea minerals calls for the development of new mineral processing concepts. Therefore fundamental analyses of the fracture behavior have been made under compressive and impact stress. Further experiments took focus on the crushing behavior in a jaw crusher and a small scale impact crusher as well as the milling behavior in a dry vibrating mill, a wet planetary ball mill, and a wet agitated ball mill. The comminuted products were characterized by PSD, particle shape, particle density, and porosity. The experiments show a low stress resistance of the ferromanganese nodules. Compared to compressive stress, impact stress turned out to be the more effective for crushing. Both samples showed no significant difference in the comminution behaviour which makes differing mechanical treatments unnecessary. In both cases particle sizes below 1 µm were achieved by wet grinding. This particle size is necessary to separate the two kinds of metal-rich layers which is part of continuative studies."

Jan 1, 2014

By Lev O. Filippov, Inna V. Filippova

"Flotation of metal-organic precipitate in column is sensible to the hydrodynamic conditions determined by the diameter and the dispersion of rising bubbles. Thus, the dissipation energy in the system resulting of ratio between superficial fluid velocities (gas and feed) in the column is the main parameter for precipitate flotation in pilot or industrial scales. The suggested limiting factor is the aggregate stability under the turbulence created by the rising bubbles. The stability of precipitate is related to the structural organisation of aggregates, which determines the size distribution of particles during precipitation and flotation stages.Structural evolution of Mo precipitate and the destruction phenomenon were described by using of the various fractal dimensions. The fractal studies allow the detection of a structural scaled organisation of the precipitate flocs. The fractal dimension of the particle mass distribution Dm=1.94+/-0.15 suggests, for the floc structure, a cluster-cluster aggregation process either with restructuring or breakage phases.The destruction process, which occurs for the lowest values of the dissipation energy E (0.02 . 0.05 W/kg) was characterised by a fractal dimension Dg of size distribution. Besides, the destruction of floc produces very fine particles, and thus induces the difficulties of bubble-particle collision during the precipitate flotation in column."

Jan 1, 2003

By Vasily V. Lodeischikov, Adolf F. Panchenko, Olga D. Khmelnitskaya, Vladimir E. Dementyev

Pilot plant tests of underground gold leaching from Maminskoye deposit oxide ores at a grade of 0,7 g/t Au were carried out. The underground leaching flow sheet includes Au dissolution by chlorine-containing solutions, Au adsorption from solution on active carbon, carbon concentrate ashing and calcine melting to produce high grade gold concentrate. The underground leaching system throughput was 15 m3 of solution per hour. Gold concentration in pregnant solutions was 0.12-0.13 mg/l. Gold recovery from solutions into carbon was in the range of 63-84%. It was demonstrated that the low Au recovery in the adsorption cycle was due to the presence in pregnant solutions of "active" chlorine, which destroys active carbon and causes a sharp decrease of the carbon loading capacity for gold. To improve the adsorption indices, previously dechlorinated pregnant solutions using bituminous coal or Na2S2O3, is recommended. Ion exchange process was tested as an alternative for gold extraction from dechlorinated solutions. In the testwork period, 4.4 kg of gold were produced with a chlorine consumption of 3.5 kg per 1 g of gold. During the tests a program of environmental protection measures was completed to provide the necessary safety precautions of the underground leaching works.

Jan 1, 2003

By A. J. Lynch, L. Ergun, M. Oner

"A research program on modelling cement grinding circuits has been in operation at Hacettepe University, Ankara, for four years. It has concentrated so far on tube mill and air separator grinding circuits for cement clinker, with emphasis on plant sampling surveys, including axial sampling inside the tube mills. The data used for model development have come from 33 surveys in 9 plants.The operating conditions have been:- mill sizes - 3.2 to 4.8 metres diameter and 8.5 to 15 metres long,- mill feed rates - 46 to 158 tonnes per hour,- air flow through mills - 25000 to 125000 cubic metres per hour,- cement clinker work indexes - 10.3 to 18,- separator sizes - 2. to 3.1 metres diameter,- separator feed rates - 132 to 689 tonnes per hour,- separator speeds - 12.3 to 21 metres per second.The ball mill model is Whiten’s perfect mixing model and the separator model is the Tromp curve with a fish-hook. This paper emphasises the importance of calculating the breakage rates and the discharge functions with three case studies at five different circuits which were selected for discussion because they show how particular features of circuit operation can be included in the general models. Size distribution graphs are used to illustrate every aspect of the discussion"

Jan 1, 2003

By C. Raghu Kumar

Hydraulic or teetered bed separators (TBS) are finding new avenues for application in the field of mineral processing. Floatex Density Separator (FDS) is a hydraulic/teetered bed separator capable of operating at high tonnage due to its advanced instrumentation. FDS/TBS is being used in Indian mineral sand industry for classification and segregation of different minerals. The purpose of this paper is to provide details on the performance of the plant scale FDS in recovering the chromite from feed (below 1mm size). Historically this feed has been processed using hydrocyclones and spiral classifiers; however, there is a strong trend now to employ teetered bed separators, thus allowing significant changes to be made in the plant for improving process efficiency. In the present work, the performance of the plant scale FDS is described in terms of partition curve (yield, cut size, classification efficiency/Ep) for different combination of process variables and also in terms of metallurgical grade and recovery. It is found that, efficient classification can be achieved at a maximum cut size of 380 µm with and the imperfection is also reported as low as 0.16. The grade of the underflow product is enriched as maximum as 52.2% Cr2O3 from a feed assaying 40.4% Cr2O3.

Sep 1, 2012

By D. Kosior

Influence of frothers (a-terpineol and n-octanol) concentration on kinetics of a three phase contact (TPC) formation by a bubble colliding with a hydrophobic surface (Teflon) of different roughness was studied using a high-speed camera (1040 frames per second). It was found that the Teflon surface roughness and the frother concentration strongly affected time of the TPC formation (tTPC) and time of drainage (tD) of the liquid film separating the colliding bubble from the solid surfaces. With increasing Teflon surface roughness, from ca 1 to 80 µm, the time of the TPC formation was shortened by over the order of magnitude, from ca 100 to a few milliseconds only. At low a-terpineol and n-octanol concentrations, thetTPC values were shorter than in distilled water due to lowering the bubble velocity in the frother presence and diminished bouncing of the colliding bubble. However, at high frothers concentrations the tTPC values were prolonged, despite that the bubble velocity was similar. The prolongation of the tTPC at high frother concentrations indicates that air (micro- and/or nano-bubbles) was present at the Teflon surfaces of different roughness. The mechanism of the tTPCprolongation at high frother dosage is described.

Sep 1, 2012

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"INTRODUCTIONThe objective of this work was to deport silver into a residue suitable for subsequent extraction without compromising the high base metal extraction during the pressure oxidation.RESULTS AND DISCUSSIONThe complex sulphide from the tailing pond of Cannington mine, Australia, was re-grounded and a bulk concentrate was recovered by flotation. The major economic sulphides are galena and sphalerite. The chemical analyses revealed 17.22% Fe; 4.88% Zn; 8.22% Pb; 9.49% S2- and 422 g/t Ag. The baseline cyanidation yielded 36.60% of silver at high cyanide consumption (24.17 kg/t NaCN). Pressure oxidation at 150°C (in the absence of iodide), followed by cyanidation of the residue yielded 8% silver extraction. Pressure oxidation was carried out at 110-150°C in sulphate media with additions of potassium iodide and the resulting residue was subjected to cyanidation. High recovery of silver was achieved because its incorporation into lead-hydronium jarosite during the pressure oxidation was minimised, while its deportment into the cyanide-soluble silver iodide was favoured (Figure 1). Silver recovery decreased slightly at high temperatures (140° and 150°C) because of the enhanced stability and kinetics of leadhydronium jarosite, but this could be overcome by increasing acidity and iodide concentration of the slurry."

Jan 1, 2003

By Marco Le Roux, Martha Van Rensburg, Quentin Campbell

Fluidised bed drying is currently receiving much attention as a dewatering option during the beneficiation of fine (defined here as between 1 mm and 2 mm particles) coal. Apart from concerns about safety and combustion, the operating costs can be high if very high gas or air temperatures are used. The aim of this study was to investigate the removal of moisture from fine coal by using air at a lower temperature (25 - 55°C) within a controlled environment by lowering of the relative humidity of the air. It was firstly proven that fluidization has a major advantage over non-fluidized beds, with regards to drying rate and final moisture content. Hereafter several parameters that influence the dewatering rate and final moisture content were tested, from which it was concluded that the relative humidity of air acts as the largest driving force for dewatering. Parameters tested included relative humidity, temperature and coal composition. Energy balances showed a positive nett energy increase in the dried coal during combustion when related to the energy input during drying. In comparison with thermal drying technologies, fluidized bed drying was proven to be less energy intensive. It was therefore shown that this is a viable technology for the dewatering of fine coal.

Jan 1, 2014

By S. K. Pan, M. P. Srivastava, N. Prasad

"Dalli mines of Bhilai Steel Plant, India is fully mechanized iron ore mine having wet processing system. It has a capacity to treat 5 Mt of ROM. In processing circuit of Dalli mines, scrubbing, wet screening and classification operation is being carried out. Average slime generation for the last five years is about 14% of ROM. As the mining has reached to the lower benches, fines generation is more. As a result, very fine and heavy particles, which settle fast, are being discarded with the slime to tailing pond. These heavy and faster settling particles were causing jamming in the thickeners.Laboratory investigations were carried out at Research and Development Centre for Iron and Steel (RDCIS) to suggest a suitable scheme to recover high quality fines so that the availability of thickener can improve. The slime samples were first treated in a floatex density separator. The concentrate obtained from the floatex density separator was treated in hydrocyclone. Laboratory investigations indicated that the slime with 49% Fe, 12.7% silica and 10.7% alumina can be upgraded to 62.1% Fe, 3.3% silica and 2% alumina with 36% material recovery. Based on the laboratory studies ,a system was installed at Dalli minesThe general arrangement of the system is shown in Fig. below."

Jan 1, 2003

By V. Avzian Belozersky reg 453524, Vasily V. Lodeischikov, Adolf F. Panchenko, Til E. Vidusov, Olga D. Khmelnitskaya, Vladimir E. Dementyev

"Presently, there is a number of gold deposits which cannot be developed using the conventional technologies with acceptable economic indices due to low gold content, high depth of ore occurence and other conditions. For such ores, an innovation technology of underground gold leaching in the place of their occurrence is of special interest. The technology excludes ore mining and hoisting to the surface. This enables the production cost of 1 g of gold to be considerably reduced in comparison with conventional methods of gold recovery.The Maminskoye deposit oxidized ores were chosen as the subject of underground leaching because they are ideally suited for this purpose due to their composition and hydrological parameters. The ore reserves within the underground leaching block are 90, 000 t with 0.7 g/t average gold grade.An experimental system for underground leaching with a throughput of 15 cubic m solutions per hour was developed. A combined filtration-and-infiltration system of the ore massif development by holedrillingwhere pregnant solutions are air-lifted was worked out.The underground leaching flowsheet includes Au dissolution by chlorine-containing solutions, Au adsorption from solution onto active carbon, carbon concentrate ashing and calcine melting to produce Dore metal."

Jan 1, 2003

By Z. Kwela, A. Manhique, W. W. Focke, W. van der Merwe

"The main features of the de Wet improved alkali fusion process for the manufacture of AZST are: Fewer process are steps necessary; radioactivity is removed by leaching rather than by precipitation; fewer waste streams are generated; there is less waste to discard and alkali reagent is recovered in the form of a sodium silicate solution that is essentially free of radioactivity.Here we report on our efforts maximize the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated. The fusion products were characterized by infrared spectroscopy, X-ray diffraction and by wet chemical analysis.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since these compounds do not hydrolyze in water they limit the recovery of alkali in the sodium silicate product stream. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed."

Jan 1, 2003

By N. Kgabi, F. B. Waanders, E. Vinken, A. Mans

"Mössbauer and SEM identification of the iron mineral phases present in South African coal fractions from the Free State, Gauteng, Mmpumalanga, Natal and Waterberg coal fields, as well as from ash samples from coal used in the Lethabo power plant, containing a large amount of inorganic matter, was conducted. The iron is mainly associated with sulphur in the mineral but the amounts of these and other minerals vary considerably in coals from diverse origins. By means of Mössbauer analyses the iron bearing minerals were identified as pyrite, jarosite, illite and ankerite. In the SEM analyses quartz, associated with various clay minerals was identified with differences in abundance found between the coals from the different locations.The fly ash, produced at the high combustion temperatures in the power plant, gave rise to a spectrum, typical of a glass. SEM analyses showed that agglo- meration of the fly ash was due to the presence of Ca in the coal. The lab. produced fly ash was combusted at temperatures ranging from 200-1 200°C and the pyrite changed partially to hematite and partly into the glass due to the presence of the quarts and the clay minerals. A similar spectrum as the power plant fly ash spectrum was obtained.In the weathering experiments the pyrite changed to a sulphate component in a very short time during air drying."

Jan 1, 2003

By Takashi Furuyama, Sukeyuki Mori, Tetsuo Ikejiri, Abel Bissombolo, Yoshitsugu Koga, Masamichi Hata

In Japan, the increasing number of automobiles newly put into circulation is followed by a larger amount of end-of-life vehicles from which valuable metals are being recovered in shredder and related plants. Nevertheless, the processing of these scrapped automobiles which has reach a recycling rate of about 75%, generates a huge volume of waste, locally known as .shredder dust., which is commonly dumped on landfills. The saturation and depletion of valuable disposal sites in the near future, as well as the social and environmental problems related to the accumulation of these residues disposals are a major challenge for the automobile shredding industry. To promote an alternative way for the management of these disposals, the authors have initiated and developed a system for their processing, on the basis that more than 90% of these residues are combustible materials that could be used as refuses derived fuel. The developed processing system points out the mechanical/physical separation of shredded automobiles residues into two streams by means of an ascending airflow passing through a vertical zigzag separator and, the compaction of the light-density fraction of materials (that is about 60% of auto shredder residue recovered as float products and mainly composed of cotton, sponges and light plastics) to form a refuse derived fuel (RDF), the density, calorific value and ignition loss of which are 1.19 g/cm3, 4470 kcal/kg and 60.7%, respectively.

Jan 1, 2003

By Michael Young, Rodrigo Araya, Cesar Gomez, Le Huynh, James Finch

The performance of flotation machines is closely related to the gas dispersion characteristics achieved in their operation. It is known that frothers play a major role not only in the size distribution of the generated bubble population, but also on the swarm rise velocity. A program to characterize frother effects on two-phase hydrodynamics (air-water) of Jameson cells was undertaken in a fully instrumented pilot unit installed at McGill University. Gas dispersion parameters (gas velocity, gas holdup and bubble size distributions) of the gas-liquid mixture generated in the downcomer were measured after its release into the separation chamber. The unit was operated under different conditions including gas velocity, liquid jet velocity and frother concentration (MIBC). Bubble size distributions for concentrations above the critical coalescence concentration (CCC) were narrow with Sauter mean diameter between 0.6 to 1.3 mm. The bubble size followed the general trend as encountered in other types of flotation machines, i.e., rapid decrease with increasing frother concentrations below 10 µL/L, and almost no change in size for concentrations above 30 µL/L. The CCC was between 10 and 15 µL/L. Strong correlations were found between bubble size and air-to-liquid flow ratio (APR), and between the bulk density of the aerated solution in the separation tank and the vacuum inside the downcomer. An equation is proposed to estimate gas holdup in the separation tank from vacuum and bulk density readings.

Jan 1, 2014

By Hajime Miki, Mutia Dewi Yuniati, Tsuyoshi Hirajima, Keiko Sasaki

Acid mine drainage is mainly due to pyrite/arsenopyrite oxidation processes, and suppressing such processes is important issue. As a promising process it is reported that silicate ion can complex with catechol (1,2-dihydroxybenzene) and this complex is oxidized to a solid silica layer on the surface of those sulphide minerals. Detailed behavior was investigated from the result of electrochemical experiments. Results of polarization potential showed that oxidation peak can be seen only in the presence of both silicate ion and catechol addition at this peak potential and this peak can be identified as silicate-catechol complex oxidation to silica. Potentiostatic experiments indicated the dissolution kinetics of pyrite. Untreated pyrite dissolution rates were higher than pyrite treated with catechol and silica solution. To enhance the silica layer reaction on pyrite, the pyrite potential was held at 550 mV vs. SHE in catechol silica solution. This pyrite dissolution kinetics was almost the same as untreated pyrite. Potential hold followed by drying for 30 min process resulted in much lower pyrite dissolution rates. Drying is important for development of the silica layer. Analysis of this potentiostatic curve provided a way to estimate the thickness of the produced silica layer and kinetic information of treated/untreated pyrite. Untreated pyrite showed thinner initial layer thickness on the surface of pyrite (oxidized passive layer, not silica) and higher oxidative kinetics of pyrite compared with silica-coated pyrite.

Jan 1, 2014

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

Although the cyanidation process for gold leaching has been applied for more than a hundred years, some aspects of it, such as the passivation of the gold and the depassivating action of heavy metals, are still not well understood. In this work the anodic behaviour and surface composition of gold in alkaline aqueous cyanide with lead additions were investigated using polarization experiments and XPS. It was found that lead in the solution activated the gold at low concentrations, somewhat more positive than the reversible potential for gold, but that the activity again decreased at higher concentrations of lead. The potential range for the activation of the gold coincides with that where underpotential deposition of lead occurs, i.e. –200 to –600 mV(SCE), as indicated by the surface composition of the gold, shown in figure 1. Note that the concentration of lead on the surface of the gold only increased with time in the bulk plating potential range for lead, where gold is not activated by the presence of lead. It is also shown that up to 20 mg/L of lead added to the solution will activate the gold, provided that bulk plating of the lead is avoided. It is also important to avoid reducing conditions during leaching, where bulk plating of lead may occur, if the gold is to be activated by lead to achieve a high leaching rate, as the bulk plated lead screens the surface rather than activating it.

Jan 1, 2003