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By A. V. Zimin

It is a well-known fact that usage of reverse cationic flotation in magnetite ores processing enables to improve the quality of magnetite concentrates. We designed an iron ore concentrate technology (with 70 -71 % of iron) including reverse cationic flotation in pneumo-mechanical flotators RIF (developed by RIVS Corporation, Russia) with good biodegradable etheramines as collectors for flotation of quartz. Practical application of high biodegradable flotation reagents decreases environmental impact risk of objects and enterprises of mining industrial complex. This work presents results of development of flotation technology for production of high quality ferruginous concentrates from magnetite ores of Russia and Ukraine deposits. Keywords: magnetite ores, reverse cationic flotation, ferruginous concentrates, pneumatic-mechanical flotation machines, environmental impact

Sep 1, 2012

By E. G. Ozhogina, O. B. Kotova

"The ores of black, non-ferrous, rare, noble metals are mostly distinguished by a variety of mineral types and complexity of their material composition.The article is devoted to the promotion of the concept of mineral processing in modern realitiesof the deficit of high-quality ores and increase their demand.Normative and methodical documentationsfor specific types of analysis with the definition of the field of application are shown. For example,the pyrochlore-monazite-goethite ores from one of the deposits from Eastern Siberia - Chuktukonskoe ore fieldare tested. The development of mineralogical methods, and testing of specific raw materials are shown.The method of small-angle X-ray (and also synchrotron) scattering, which was developed for solving problems associated with structural high-resolution diagnostics, was tested for bauxites of Vezhay-Vorykvinskoye field. KEYWORDS Technological mineralogy, rebellious ores, ore quality assessment, ?mineralogical-analytical methods INTRODUCTION A highly intense production of many types of mineral raw results in gradual depletion and deterioration of mining-geological and mining-technical conditions of development. Relatively easily accessible and rich deposits are getting exhausted in the first place, and it is necessary to involve poor and rebellious ores into production and processing. Traditional technologies can hardly be applied (Chanturia, 2017; Bazin et al., 2014; Ponaryadov, 2017). The urgency of development of the concept of technological mineralogy focuses on the confirmation of new methods and approaches to the development of mineral raw, creation of scientific and methodological prerequisites for solving the problem of rational development of mineral raw, maximal extraction and integrated application of all minerals (both principal and associated), expansion and strengthening of mineral and raw base. The article is aimed at updating tasks that should be addressed within the applied mineralogical researches: – the forecast of quality of ore at early stages of exploration and technological indicators for the redistribution of raw, – interactive monitoring of these indicators by mineralogical and analytical methods; – assessment of environmental consequences of mining and processing of minerals and measures that eliminate these consequences."

Jan 1, 2018

By Hong Zhong, Shuai Wang, Xin Ma

"In this paper, we report a simple and effective process for producing a surfactant mixture of O-isopropyl-N-ethyl thionocarbamate (IPETC) and 4-(tert-butyl)benzyl mercaptan (BBSH). The composite collector was synthesized via one-pot reaction of sodium isopropyl xanthate, 4-tert-butylbenzylchloride and ethylamine using tert-butyl alcohol as solvent. The whole process for the synthesis of composite collector involves neither foul smelling reagents or intermediates, nor any by-products requires special treatment for disposal, and thus can be scaled up to an industrial level. The flotation response of chalcopyrite and pyrite independently with IPETC and BBSH collectors and with their mixture (the mole ratio of IPETC and BBSH is 1:1) was assessed. The microflotation results showed that the collecting ability of BBSH was slightly stronger than that of IPETC and that IPETC was more selective collector than BBSH against pyrite, and that the composite collector displayed a stronger collecting ability toward chalcopyrite than IPETC, and superior selectivity for chalcopyrite against pyrite than BBSH. The batch flotation results showed that composite collector exhibited better performance than IPETC and BBSH. It was demonstrated that the mixing of IPETC and BBSH would give rise to a synergistic effect significantly enhancing overall flotation performance. In addition, the adsorption mechanism of BBSH on the surface of chalcopyrite was conducted by adsorption test and infrared spectrum measurement, and the results showed that the interaction of BBSH on the chalcopyrite surface was dominated by the chemical adsorption, and the formation of a strong S-M bond plays a key role in the adsorption of mercaptans on minerals surfaces. The developed flotation reagents with special preparation method is the author’s original design, patented (patent of the People’s Republic of China) and have no analogues in the world of mineral processing. (Application number 201810100107.1, ""Alkyl thioether alcohol compounds, methods for their preparation and applications thereof "", China).1. INTRODUCTION Froth flotation is an essential method widely used in the mineral processing industry to selectively separate valuable minerals from gangues[1]. Worldwide, more than 109 tons of materials are treated annually by this method with the majority being metal sulfides and oxides[2]. Nowadays, the judicious utilization of complex sulfides to meet the ever-growing demand of mineral resources gains more attention, due to the gradual depletion of deposits with high grade, making imperative the development of new high-efficiency collectors and mixtures of collectors to process complex minerals. In comparison to individual collectors, the use of mixtures has several notable benefits including lower dosage requirements, improved selectivity, rates and recovery and an increase in the recovery of coarse particles[3-9]. Moreover, in terms of cost and environmental issues, using collector mixtures can reduce the total amount of agents used, thus reducing the overall effect on the environment and economic costs without affecting the flotation performance. Therefore, the search for high-efficiency mixtures of collectors is still interesting and relevant."

Jan 1, 2018

By Victor Avdokhin, Ivan Kovlekov

"Studies of the process of concentration of gold-containing sands and technogenic resources show that the main reason of gold losses is misbalance between size of gold particles and degree of roughness of mineral bed. This results in free circulation of small gold particles in pores with following washing off the particles from the bed by turbulent flows.We elaborated design of magnetic sluice, intended for improving efficiency of recovering fine gold by optimizing magnetic field of a magnetic system on the base of forming catching coat from magnetic mineralsThe magnetic sluice includes trough-shaped body from magnetic-conducting material. On the bottom of the trough, magnets are placed, and opposite poles of the magnets are oriented outwards. Thickness of the bottom is determined to be sufficient for locking magnetic lines of force of the magnets on each other. The magnets of rectangular plate shape are placed on the rough bottom, covering the whole surface or with spare areas; the magnets are placed across the trough with alteration of rows with the same pole orientation.Catching coat is formed of natural magnetic and weak-magnetic placer minerals in field of magnetic system of the sluice. Magnetic minerals, placing along magnetic lines of force, form rough coat of fluffy structure. Size of the magnetic particles is chosen taking into account expected size of gold particles, which are to be fixed on the rough coat or between the magnetic particles. Changing coarseness of particles of mineral bed allows to regulate selectivity of recovering heavy minerals.Forming artificial fleece from magnetic minerals of initial sand, increasing capacity of the bed and relative hydraulic proportionality of mineral particles of the bed provide for the most effective recovery of fine gold."

Jan 1, 2003

By M. Ghiani, R. Peretti, S. di Giovanni, G. Zonnedda, A. Serci, A. Zucca

"Beneficiation of the epithermal gold mineralizations associated with an extensive alteration zone in the Serrenti-Furtei region on the island of Sardinia, is proving a complex issue. Experimental investigations have in fact demonstrated that while the ores contained in the upper parts of the deposit are amenable to conventional cyanidation, the gold contained in the refractory ores in the lower portions needs to be recovered by means of flotation, combined with leaching where necessary.The results of commercial heap leaching, carbon-in-leach (CIL) processing and flotation, designed on the basis of the experimental findings and applied to the oxidized portions and transition zones of the deep sulphide mineralizations, confirmed the expectations emerging from the laboratory tests."

Jan 1, 2003

By B. A. Kutlin, S. A. Ropeyko, N. A. Yurlova

"The aim of NPO RIVS research and practice activities is to minimize impact of the mineral processing plants (MPP) on environment by using new concentration methods, high-technology equipment, implementation of engineering solutions directed to reduce emission of polluting substances (PS) into atmosphere, application of low-waste technologies, decrease of water withdrawal from a surface water or groundwater source for process needs. In our studies environmental safety of mineral flotation is provided through technologies using highly selective chemicals, that leads not only to reducing reagent consumption, and production of saleable products of high content of extracted minerals, but also to reducing pollutant emissions, decreasing supply of surfactants (SAA) in natural geosystems, primarily, in ground and surface waters. Decrease of water withdrawal from a surface water or groundwater sources for process needs can be achieved by using closed circuits and waste water treatment for further use in process operations, recycled water conditioning to obtain optimum quality parameters for process operations of concentration. Concentration in water (wet processing), tailings dewatering and semidry and dry (filtration cake) stockpiling in tailing ponds, efficient dust-collecting systems contribute to pollutant emission reduction. Use of mineral wastes – concentration tailings as a source of valued components, facilitates efficient use of natural resources and reduces wastes and its impact on natural ecosystems due to smaller areas of damaged lands during waste products disposal. Process and engineering solutions of NPO RIVS that allow diminishing impact of MPP on natural environment (NE) have been implemented in mining and processing complexes of Russia, Kazakhstan, Ukraine, Kirghizia and Mongolia. Compliance with environmental safety requirements contributes to enhancement of mineral processing and sustainable mineral development.INTRODUCTION Mining and processing complexes have a significant impact on environment as a result of extraction and recovery of mineral resources, landscape changes, waste disposal and, as a consequence, pollution of soils, surface and underground water sources. Therefore, the aim of the operation of the mineral processing enterprises in its research and practical activities is to reduce impact on environment due to new beneficiation technologies, high-technology equipment, implementation of engineering solutions directed to reduce emissions of polluting substances (PS) into atmosphere, use of low-waste technologies, decrease of water withdrawal from a surface water or groundwater source for process needs. Compliance with the requirements of environmental safety encourages advancement of mineral processing technologies and sustainable mineral development. Concentration in water, tailings dewatering and semidry and dry (filtration cake) stockpiling in tailing ponds, efficient dust-collecting systems contribute to pollutant emission reduction. Use of mineral wastes – concentration tailings as a source of valued components, facilitates efficient use of natural resources and minimizes waste formation and its impact on natural ecosystems due to reduction of damaged land areas during waste disposal."

Jan 1, 2018

By Katarina Theander, Robert J. Pugh

The generation of froth with a critical degree of stability and height is an important aspect of the froth flotation. In this paper we have studied the synergism and anti-synergism in frothing behaviour in a mixed flotation collector/frother mixture (a model fatty acid; sodium oleate and a model frother; nonionic (polyethyleneoxide alkyl C14E6). Values of the collector / frother molecular interaction parameters (the ß-parameters) were determined from the surface tension data using regular solution theory. The frothing characteristics of the system were evaluated using a glass column equipped with a series of conductivity electrodes, which enabled the water content of the froth to be determined. From these measurements, the dynamic frothability and static froth stability were determined. It was concluded that the synergism/anti-synergism in frothability was depended on the molecular composition of the surfactant system, the diffusion of monomer to the thin film interface and on the breakdown of the mixed nonionic/anionic micelles.

Jan 1, 2003

By F. v. d. Meer, G. Kretschmar, T. Mütze, T. Leißner

"Dynamic air classifiers separate particles in a gas flow due to different particle trajectories utilizing differences in the settling velocity of particles as characteristic property for separation. The present contribution takes a close look at the separation of heterogeneous mixtures, in which valuables and gangue minerals show significant differences in density. The focus was on a moist iron ore sample, which was characterized in terms of mineralogy, grain size distribution, and particle size distribution. The material was classified at a cut size of 45 µm and at feed moistures between 0 and 6 wt.-%. Additionally to standard characterization techniques, the moisture of both products was measured as well as the yield of fines as product fraction in a corresponding processing plant. In addition, an automated mineral liberation analysis (MLA) provided information of the enrichment and segregation of individual mineral phases in the products. The MLA of the classification products reveals a selective comminution of the mineral phases and especially on overmilling of the valuables. For the first time, the separation of individual mineral phases has been assessed and compared to the classic assessment of classification processes by means of particle size analyses. KEYWORDS Dynamic classifier, segregation, MLA, selective comminution INTRODUCTION Dynamic air classifiers separate particles in a gas flow due to the different trajectories of the particles. The result of such a separation process depends on the gas throughput of the classifier, the dimensions, design and rotational speed of the deflector wheel, as well as the state of dispersion and thus the geometry of as well as the turbulence and interparticle interactions in the separation zone. Air classification of moist feed materials can be divided into several sub-process (Leschonski, 1977; Mütze et al., 2016): - dosage of the feed material, - dispersing the solid feed material into a gas stream, - feeding the dispersed material into the classification zone by pneumatic conveying, - drying of moist particles during pneumatic conveying, - separation of coarse and fine particles, and - separation of fine particles from gas."

Jan 1, 2018

By T. Inoue, K. Okaya

"Movement of mill charge in the centrifugal mill is essentially different from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. As proved e.g. in [11], this results in substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Back in 1983, Bradley et al. presented a model of the centrifugal mill based on the kinetics of the mill charge by regarding it as a lumped mass. On the other hand, numerical modeling by ‘discrete element method (DEM)’ enabled us to observe the movement of each ball in the centrifugal mill with an extremely minute time intervals (Inoue et al., XX IMPC in 1997). The former approach rendered simple, even though approximate, expression of the mill behavior, while the latter method was advantageous in describing the behavior of the mill in terms of individual events taking place in the mill body, even though the result did not reduce to a simple expression. The characteristics of the centrifugal mill described by both these approaches proved to be in a degree of agreement. Thus, the kinetic approach was capable of presenting the overall view of the mill, while the DEM model was informative of the details that could not be depicted well enough by the simple math expressions."

Jan 1, 2003

By Y. Foucaud, C. Eswaraiah, L. Filippov

Enhanced gravity separators such as Falcon concentrator which uses additional centrifugal force, are the most common gravity concentration techniques used for fine particles processing. Hence, understanding the kinetics and separation mechanisms within these separators is of paramount interest. Recent research yielded a predictive physical model for the Falcon Ultra Fine (UF) which however does not explain some results obtained with industrial ores. This study aims to identify the mechanisms involved in Falcon UF separation with the objective of confirming or rejecting the hypotheses on which the current model is built and suggesting potential points of improvement. The Falcon UF kinetics is investigated through the processing of complex low-grade and fine-grained ores from the Altenberg tin deposit (Germany), the Tabuaço tungsten deposit (Portugal) as well as a synthetic iron ore. Saturation tests are performed on the Falcon UF by controlling the separation efficiency in terms of recovery and enrichment ratio with time or feed mass. Results show an evolution of Falcon UF performance with time in contradiction with the stationary separation hypothesis on which the physical model is based. Observation of the concentrate bed suggests the presence of erosion figures in furrows which may play locally an active role in the separation. In terms of Falcon UF separation timing, three phases can be distinguished. First, upon initial feeding of the bowl, a bed quickly grows unselectively and ultra-fine particles are ejected from the bowl until the bed reaches its final profile. Next, actual separation occurs with selective concentration of dense particles. Finally, capture sites saturate and recovery drops. The evolution of partition curves over time confirms the existence of two separation mechanisms. First, differential particles settling within the flowing film responsible for the ejection of small size particles during the whole separation cycle which is already accounted for in the physical model. The second mechanism involved may be explained by the action of lift force, neglected in the physical model, which acts preferentially on coarse particles deposited at the surface of the bed resulting in coarser particles being rejected in the tailings. Hence, the addition of a lift force component to the existing model is suggested to account for this second separation mechanism.

Jan 1, 2018

By Rong Fan, Roger Smart, Ning Xu

As part of an Australian Research Council project with Newmont and Newcrest mining companies studying the influence of clay minerals on rheology, hydrodynamics and flotation response, the cryo-SEM technique has been used to capture and image the clay (low crystallinity kaolinite Q38) aggregate structures in the flotation pulp immediately after collector and before frother addition. Samples were also collected from the earliest froth phase and the froth overflow corresponding to early and later concentrates. In this technique, a copper tube is filled with the sample during operation of the cell. The tube is immediately plunged into liquid nitrogen vitrifying the water phase before it can crystallise as ice thereby retaining the structures without volume or other physical change. After sublimation of the vitrified water surface, the aggregate structures are revealed and can be compared between pulp and froth phases from clays in different feeds and flotation conditions. The images from both low-clay ore and ore with clay content reveal various levels of aggregation as predominantly edge-edge connected aggregates similar to those found in our previous studies of high-clay tailings. For the samples from the ore with clay content, more extensive edge-edge clay strings are found in the early froth phase as compared to exiting froth overflow and the pulp phase with short edge-edge connected strings. It is suggested that the strings of clay particles result from edge-edge aggregation in the Plateau borders of the bubbles before breakage during sampling and the more extensive edge-edge aggregation in early froth phase is induced by crowding in the bubble borders. The clay strings collected into the overflow concentrate are almost all broken up compared with the Froth before drop-back. The implications for entrainment and entrapment mechanisms of gangue capture in froth will be discussed.

Jan 1, 2014

By E. G. Ozhogina, O. B. Kotova

"The ores of black, non-ferrous, rare, noble metals are mostly distinguished by a variety of mineral types and complexity of their material composition. This article is devoted to the promotion of the concept of mineral processing in modern realities of the deficit of high–grade ores and increase in their demand. Normative and methodical documentation for specific types analysis with the definition of the field of application are presented in this paper. . For example, the pyrochlore-monazite-goethite ores from one of the deposits from Eastern Siberia - Chuktukonskoe ore field were tested. The development of mineralogical methods and testing of specific raw materials are shown. The method of small-angle X-ray (and also synchrotron) scattering, which was developed for solving problems associated with structural high-resolution diagnostics, was tested for bauxites of Vezhay-Vorykvinskoye field.INTRODUCTION A highly intense production of many types of mineral deposits results in gradual depletion and of mining-geological and mining-technical conditions of various ore reserves ?. Relatively easily accessible and rich deposits are getting depleted in the first place, and it is necessary to involve low grade and refractory ores into production and processing. Traditional technologies can hardly be applied (Chanturia, 2017; Bazin et al., 2014; Ponaryadov, 2017). The urgency of development of the concept of technological mineralogy focuses on the confirmation of new methods and approaches to the development of mineral deposits, creation of scientific and methodological pre-requisites for solving the problem of rational development of mineral deposits, maximum extraction and integrated application of all minerals (both principal and associated), expansion and strengthening of mineral and ores.The article is aimed at updating tasks that should be addressed within the applied mineralogical research: – forecast of quality of ore at early stages of exploration and technological indicators for the redistribution of properties ore, – interactive monitoring of these indicators by mineralogical and analytical methods;"

Jan 1, 2018

By F. Bello, J. Engels

"During 2012 and 2013, Minera Esperanza conducted a series of thickening and deposition trials to identify design and operational parameters associated with increased thickening of its tailings. These trials focused on benchmarking the current solids concentration of tailings (62 - 64%) in anticipation of an increase to 67% solids once two new 45 m diameter deep-cone paste thickeners are commissioned in 2014. These trials studied the sedimentation and rheological characteristics of the existing tailings and performed deposition modelling to assist with developing short- and long-term designs for the tailings storage facility. To verify and optimise these models, Minera Esperanza considered a series of laboratory, pilot, and industrial-scale deposition trials. This paper provides a review of the trials conducted in the laboratory and at industrial-scale and considers the results and optimisations for the short- and long-term design of Minera Esperanza’s tailings storage facility."

Jan 1, 2014

By Bianca Foggiatto, Marko Hilden, Malcolm Powell

"Since the introduction of the concept of flexible circuits (Powell and Bye, 2009), it has been further developed and refined to the definition of ‚FlexiCircuits leverage ore variability to maximise resource utilisation?. The focus of flexible circuits is to investigate processing options that provide extra capacity through sophistication rather than scale. This requires a combination of smart ore characterisation, economic modelling and innovative processing plant design. Flexible circuit design can reduce energy requirements through gangue rejection or progressive ore upgrade; and increased robustness and controllability by leveraging off ore variation. Each rock type, as characterised through Geometallurgical ore modelling, may be processed more efficiently by individually optimising processing paths. The objective of FlexiCircuits is to transform the processing capability of comminution and concentrator plants - targeting step change in performance through integrating a range of interrelated improvement opportunities. Considerable effort has been applied to developing the modelling and simulations tools required to develop and demonstrate the potential of this concept. This paper presents a practical application as a test case. A realistic application of flexible circuits is provided through a conceptual circuit design of an iron ore processing plant. It is simulated as a multi-component feed with a range of new models in the researcher’s Model Developers’ Kit (MDK) to trial the ability of different circuit designs to respond to variable ore and quantifying the potential of these circuits to transform processing capability of variable ore feed. The outcomes of the simulations are presented and discussed, providing a practical demonstration of the level of modelling and simulation required and the potential of flexible circuit design."

Jan 1, 2014

By Silvia Serranti, Giuseppe Bonifazi, Roberta Palmieri

The possibility to develop an efficient recovery and reuse of concrete materials from Demolition Waste (DW) represents one of the main targets applied to end-of-life constructions dismantling/recycling. The need to recycle end-of life concrete materials is strongly increasing in these last years for several reasons: i) the decrease of steady supplies of good quality natural aggregates, ii) the need to secure ample supplies of concrete aggregates to the construction industry and, finally, iii) the environmental constraints limiting the DW wastes disposal. The fulfilment of these goals produces several benefits, that is: i) a reduction of new resources consumption, ii) a strong reduction of the costs linked to transport and energy production, iii) the possibility to utilize materials, otherwise lost (e.g. land filled), iv) land preservation and, finally, v) the reduction of the environmental impact of new exploitation activities. A lot of efforts have been addressed to develop, set-up and apply innovative technologies to maximize DW conversion into useful secondary raw materials. The possibility to utilize efficient, reliable and low cost analytical tools to perform detection/control actions: i) to assess concrete characteristics, before demolition, and ii) to detect the presence of contaminants in coarse aggregates (e.g. bricks, gypsum, steel, glass, plastics, wood, etc.) represent the key issues to fulfil in order to develop innovative process/control actions/procedures inside the DW sector. In this paper a new technology, based on HyperSpectral Imaging (HSI) sensors is investigated to develop suitable and low cost strategies finalised to define and implement innovative smart detection engines for sorting and/or DW flow stream quality control, addressed to perform recovered materials and/or products certification. The proposed sensing architecture is fast, accurate, affordable and it can strongly contribute to bring down the economic threshold above which recycling is cost efficient.

Jan 1, 2014

By S. Banisi, A. Ghasemi, S. Zare, F. Ghorbani, E. Nematollahi

"Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Working at the maximum operating capacity of comminution equipment plays a significant role in the efficiency of the circuit. Appropriate design of cone crusher feed box could result in the choked crushing which is known as a vital factor in achieving target performance. In this research, the non-uniform cone crusher feeding at the Sarcheshmeh copper complex was studied and appropriate measures were taken to solve the problem. The problem resulted in non-uniform and high wear rate of crusher liners and high fluctuations of power draw. In recent decades, the discrete element method (DEM) has been applied successfully to study the effect of different factors on the behavior of particles flow. In this work, various designs for feed box were tested using an in-house developed DEM software called KMPCDEM©. The best feed box design obtained from the simulations was selected, constructed and installed in of the cone crushers. The new feed box design resulted in more uniform feed distribution on the distributor plate of crusher indicated by a reduction of the standard deviation of power draw measurements from 13 to 3 kWh. The better control of the crusher, 49% increase in the crusher throughput and finer and narrower product size distribution were the main outcomes of the installation of the new feed box. Furthermore, the wear rate on mantle and liners of crusher not only decreased but it also became uniform.INTRODUCTION Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Reaching the maximum operating capacity in comminution equipment is a key sign of approaching the nominal productivity of the process. Due to the effect of crusher efficiency on the downstream circuit performance, optimization of the crushing circuits has received considerable attention (Herbst, & Potapov, 2004; Quist, & Evertsson, 2010; Li, Huiqi, McDowell, Glenn R, Lowndes and Ian, 2014; Cleary, Sinnott, Morrison, Cummins, & Delaney, 2017). Improving the performance of crushing circuits not only decreases the capital and operating costs but also increases the efficiency of downstream grinding circuits (Jacobson, Janssen, & Urbinatti, 2010). In cone crushers particles can be subjected to two different modes of compressive breakage; single particle breakage (free feeding) and inter-particle breakage (choked feeding). The maximum efficiency of the cone crusher directly depends on the type of feeding arrangement (Operation Manual, 1977). An appropriate feeding must lead to choked feeding the cone crusher. If the rate and method of feeding the crushers are correctly be executed, the maximum efficiency of the crushers could be available (Jacobson et al., 2010)."

Jan 1, 2018

By A. Akcil, O. Celep, C. Erust, E. Y. Yazici1, H. Deveci1

"Recycling of WEEE has already gain prime importance from both environmental and economic point of view. For the recovery of metals from e-waste, many conventional physical, bio/hydrometallurgical and pyrometallurgical processes are proposed. Economic potential of e-waste is mainly driven by its precious metal content. Physical separation methods (e.g. electrostatic, magnetic, eddy current and gravity separation) exploit the differences in the physical properties of metals and non-metals. Physical separation methods are simple and economically sound but they suffer from metal losses and ineffectiveness at fine sizes. Hydrometallurgical processes are promising owing to their relatively low cost, reduced environmental impact, potential for high metal recoveries and suitability for small scale applications. Hydrometallurgical processes can be developed for selective extraction of base/precious metals using suitable reagent systems. Sulphate-based leaching with a suitable oxidant (e.g. H2O2, O2, Fe3+) is effective for copper and other base metals. After removal/recovery of base metals, precious metals can be easily extracted using various lixiviants including thiosulphate, thiourea, cyanide and chloride. However, further research is required to develop new, cost effective and environmentally friendly processes and/or refine existing ones for leaching and, in particular, downstream processes. INTRODUCTION Electrical and electronic equipments are indispensable to modern societies with numerous applications in the field of medicine, transport, communication, education, security and environmental protection. With technological developments and innovations, the replacement of old equipment leads to ever fast accumulation of waste materials such as waste electrical and electronic equipment (WEEE or e-waste). People are upgrading their mobile phones, computers, televisions, audio equipment and printers more frequently than ever before (Babu et al., 2007; Lee et al., 2007). With the rapid growth in technology today, the life span and utilisation period of most electronic and electrical equipment has been reduced considerably with concomitant generation of huge amounts of WEEE over the past several decades. According to statistics presented by Balde et al. (2015), total WEEE produced around the world was 41.8 million tonnes in 2014 and expected to rise to approximately 50 million tonnes by 2018. Kumar et al. (2017) estimated that annual growth rate for the WEEE stream is 3–5% (Singh et al., 2016). The aim of this paper is to provide an overview of physical separation and hydrometallurgical methods available for the treatment of WEEE."

Jan 1, 2018

By A. A. Lavrinenko

There are discussed the possibilities of using of flotation tailings of platinum-copper-nickel sulfide ores of the Norilsk region for the preparation of backfill mixture instead of a specially produced rock and binder materials to reduce the cost of stowing operations and impact on the environment. It is shown that due to the presence in the tailings of flotation up to 10% of sulfide sulphur, which reduces the strength of the fill materials, and more than 1 g/t PGM it is necessary the preliminary extraction of the sulfides in the product for further processing that give an opportunity to reduce the losses of valuable components. It is shown that by the flotation of the current tailings it is possible to extract 91% of sulfide sulphur, 60% of palladium and 30% platinum in 17% sulfide concentrate containing 2.1 g/t palladium, and to reduce the sulphur content in the tailings up to 0.7%. Due to the easy oxidation of pyrrhotite, there is recommended fractional delivery of the collector with a total consumption 200 g/t. There are discussed results of the flotation study with an additional collector of PGM (sodium diizobutyditiophosfinate), which one show the possibility to increase extraction of platinum on 45%, as well as extraction of sulphur and palladium. For the flotation of sulfides and PGM from the current tailings there is recommended a combination of collectors for primary flotation and only butyl xanthate using in control operations. The possibility of using sludge fraction of the current tailings as a component for the preparation of the combined cementing materials after exposure of sulfides is analyzed. It is shown that the efficiency of the flotation of sulfides from this fraction can be enhanced using selective flocculants. There are discussed the advantages of implementation of completely hydrophobic butadiene-styrene copolymer in comparison with partially hydrophobic polymers. There is discussed an efficiency of the mechanochemical treatment of old tailings in turbo mill and sulphuric acid to remove oxide films from the surface of pyrrhotite before its flotation. Due to the pretreatment operation there is achieved increasing of sulphur extraction and after the introduction to the flotation circuit three control operations there is produced the fill material with sulphur content 2.5%. Keywords: tailings, copper-nickel ore, pyrrhotite, butyl xanthate, sodium diisobutyl dithiophosphinate, selective flocculation, butadiene-styrene copolymer, mechanochemical treatment

Sep 1, 2012

By L. K. Smith

Flotation work conducted by CSIRO on both single minerals and high-arsenic copper ores from a number of sources, has shown it is possible to produce separate low-arsenic copper concentrates and high-arsenic copper concentrates from high-arsenic copper ores. The procedure involves controlled separations at high or low pulp potential regions exploiting subtle differences in the flotation behavior of the arsenic-bearing and non-arsenic-bearing copper minerals. An overview of several case studies investigating the applicability of the controlled potential flotation approach to the separation of copper and arsenic from sulfide copper ores is presented. It highlights the variables which influence the efficiency of the separation which include mineralogy, liberation and reagent selection. The procedure can produce a saleable low-arsenic copper concentrate, which can be directly smelted without penalty, and a high-arsenic low copper concentrate, which will require further processing. Keywords: flotation, copper, arsenic, controlled-potential flotation

Sep 1, 2012

There are some problems in the beneficiation of fine-grained oxidized iron mineral such as high cost, severe sliming, poor results and low recovery due to the fine disseminated size of the mineral. Taking several representative types of finely-disseminated oxidized iron minerals as examples, the author analyzed the main difficulties in the beneficiation of such kind of ores and discussed the existing problems in grinding-classification, technological process, flotation reagents and separation equipments and the resolvents of these problems.

Jan 1, 2014