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By J. S. Duval

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The compilation of the National Uranium Resource Evaluation aerial gamma-ray data to produce maps of the apparent surface concentrations of potassium, uranium and thorium for the conterminous USA has resulted in a reasonably accurate representation of the distribution of these elements in the surface rocks and soils. This claim is supported by the general agreement between the mapped geology and the patterns seen in the data

Jul 1, 1991

By P. H. Davenport, L. W. Nolan

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Geochemical mapping provides a direct approach to delineating areas of epigenetic mineralisation and for relating the regional distribution of this mineralisation to an overall tectonostratigraphic and structural framework, as well as to extensive areas of hydrothermal alteration. Organic lake sediment is a widely available and effective sampling medium for regional geochemical mapping in Newfoundland, that has proved to be valuable in Au, Sb and W exploration

Jul 1, 1991

By L. B. Clarke

The optimal maintenance and control of the air flow and pressure distribution in a mine network are achieved by the correct positioning of the mine fans and regulators within the mine ventilation circuit. The principal considerations are the location of the main and underground fans or regulators and the attendant control of mine leakage. Air flow control is achieved by either passive or active regulation. Passive regulation adds resistance, usually in the form of a regulating door. Active regulation adds pressure sources in the form of underground booster fans. Ventilation engineers are increasingly turning to analytical tools to assist them in the design and operation of ventilation systems. The application of computer methods, formal optimisation methods and numerical solution methods is outlined

Jul 1, 1996

By P Stone, J. M. Cook, P. R. Simpson, C Mcdermott

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The SW part of the Southern Uplands is a back-arc section of an accretionary thrust system, divided into structural blocks by major NE-SW shear zones and NW-SE faults forming the margins of Permian half-grabens. The highest arsenic levels in stream sediments (over 65 ppm) are associated with those blocks carrying brittle-ductile transition fabrics. Three factors combine to recomend the area as having potential for gold mineralisation: As-rich greywackes as country rock, felsic intrusions and a major shear zone. Selected stream sediments were analysed for gold using lead fire assay with ultra-pure flux and ICP-MS finish. Several localities showed over 15 ppb Au, the three most significant being within the hanging wall of the Orlock Bridge Fault and each having distinct characteristics

Aug 1, 1995

By D. C. Goldring

Many high-grade iron ores are considered to result from the supergene enrichment of banded iron formations. The secondary processes may be related to either present-day or ancient erosion cycles and may reach a considerable depth. Other high-grade ores hosted by banded iron formations are regarded as either sedimentary or metamorphic in origin although often also subjected to the secondary processes. The evidence for this multiplicity of origins is reviewed with descriptions of selected deposits: Kedia d'Idjil and M'Haoudat in Mauritania, Bomi Hills and the Nimba Range in Liberia, the Itabira district in Minas Gerais, Brazil, and El Pao in eastern Venezuela. Emphasis is placed on the recognition of textures that show that some ores are tectonites, the precursor materials having undergone pervasive deformation accompanied by metamorphism. The question whether such ores are pre- or syntectonic is difficult to resolve, the evidence being inconclusive, but a diagenetic/early deformation origin is preferred. The possible range of origins has to be taken into account in exploration, particularly as regards the depth of drilling, and in the characterisation of ores for metallurgical use

Jul 1, 1991

By F. M. Vokes, P. M. Ihlen

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Ore deposition was related to three major stages: continental rifting and separation (Vendian-Late Cambrian), convergence (Late Cambrian-Early Silurian) and collision (Early Silurian-Devonian). The first stage included deposition of volcanogenic massive sulphide Zn-Cu and stratabound or stratiform Fe and Zn-Pb(-Cu) on continental margins, as well as less economic Nb and Fe in carbonatites, U, Mo, Ni and V in Alum Shales and orthomagmatic Cr, Fe-Ti and Ni(-Cu). The numerous volcanogenic massive sulphides formed during convergence included Early Ordovician Cu-Zn, mature-arc Cu, Zn, Pb and Fe-oxide deposits, Besshi-type deposits dominated by Cu or Zn in gabbro-intruded sediments and minor Cu-Ni(-PGE), Cu-Mo and skarn deposits. The collisional stage is represented by epigenetic deposits including sandstone Pb deposits (Pb, Zn, Ba, F and Cu) and minor vein deposits with variable Au, Ag, Pb, Cu, Zn, Fe, As, Sb, W and Mo

Jun 19, 1905

By W. D. Maier, H. V. Eales

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. A lithological and geochemical study revealed significant lateral variation of the interval over 170 km of strike, from about 30 m at the Union Section to 220 m near Brits. The cumulates also become more evolved and leucocratic with distance from the Union Section both towards the NE (Amandelbult) and SE (Impala, Rustenburg and Brits). It is inferred that the persistent heat flux from a putative major feeder zone near the Union Section impaired deposition of felsic cumulates in the vicinity, delaying crystallisation of successive phases in parts of the chamber near the feeder. New influxes were therefore deposited on a footwall of varying thickness and lithology in response to different degrees of crystallisation and accumulation along strike. The development of cyclic units of chromitite, harzburgite, pyroxenite, norite and anorthosite was interrupted at different stages in different parts of the chamber

Apr 1, 1994

By J. K. Whyatt, W. P. Blake, T. J. Williams

A study at the Idaho mine revealed that, despite the apparent randomness of seismic events, common characteristics defined five recurring types. These characteristics included the geological structure that slipped, the first-motion pattern and the location and intensity of damage. Many large events caused little or no damage, and where it did occur it was concentrated at intersections between slipping structures and mine openings. Of 39 events between 1989 and 1994 with local magnitudes of 2.5 or more, 10 were caused by slip on bedding planes in the southern limb of the mine, 6 occurred near the vein along a set of near-vertical faults that form the central shear zone, 8 were strike-slip events on the Southern Control Fault, 4 were by slip on the vein itself and 10 involved strike-slip and/or dip-slip movement along the North Control Fault. Strategies for control of mining-induced seismicity need to consider all five types of event, lest a strategy to reduce one type increases others

Jun 19, 1905

By S Durucan, A Korre

The application of simple methods of statistical analysis, coupled with geostatistical analysis and geographic information systems, can only summarise and give an outline of the spatial distribution of the parameters measured. Spatial analysis of the components or factors calculated, through principal component analysis or factor analysis, allows assessment of the geographical distribution of the dominant processes contributing to soil composition and/or contamination. Neither of these tools, however, distinguishes between the different sources of pollution. The application of canonical correlation to the data, driven by expert appraisal of the potential pollution sources, allows their quantitative and spatial assessment while GIS provides the environment in which to organise and present the results. The methodology is illustrated by its application to soil-contamination data from the Lavrio area in Greece, where silver-bearing orebodies have been mined for more than 25 centuries

Jun 21, 1905

By W. R. Paterson, W. Morton, D. B. Cameron

The Massbal II computer simulation program has been used to develop a general framework for the building of thermochemical models of metallurgical processes. The framework allows the rapid, simple construction of complex models of process equipment for use in flowsheet design, planning and plant operation. Application of the program to model the iron-making blast furnace and a flash smelting process is described

Apr 1, 1991

By S. Kelebek, J. A. Finch, Zhenghe Xu, S. R. (Ram) Rao

To improve SO2 emission compliance, pyrrhotite from Sudbury copper-nickel ores is being depressed with DETA. To understand the mechanism of depression, the role of complexing in controlling metal-ion activation of pyrrhotite was investigated. DETA was found to remove Cu and Ni ions but leave hydrophilic ferric species on the pyrrhotite surface. The metal:DETA ratio appeared to be 1:2. Cu was more readily removed than Ni, but the combination of DETA with sulphur dioxide was equally effective for both metal ions. Certain combinations of DETA, Ni ions, xanthate and dithionite (S2O4) or dithionate (S2O6), as representative derivatives of SO2 in water, produced hydrophilic precipitates. These may enhance pyrrhotite depression

Jun 19, 1905

By L. J. Cabri

Although no complete mineralogical balances have been published, the background knowledge and proven, highly sensitive analytical techniques to produce them already exist. For PGE-Cu-Ni sulphide ores a combination of ore microscopy, image analysis and electron microprobe analysis with proton microprobe analysis of sulphides for Pd, Rh and Ru and ion microprobe analysis for Pt, Ir and Rh (in some minerals) should provide the necessary data when combined with reliable assays. Other sulphide ores, such as the Cu-Ni-(PGE) ores of Sudbury, Ontario, require a similar approach except that the ion microprobe would be more suitable for the analysis of Pd, Pt and Rh because of its greater sensitivity. Oxide-silicate ores may be harder to deal with quantitatively, although the potential to confirm the presence of trace PGE within silicates and oxides may be greater than in PGE sulphide and Cu-Ni-(PGE) sulphide ores. However, solid solution of PGE in oxides and silicates still requires thorough documentation and evaluation in terms of their significance for the overall metallurgical balance

Apr 1, 1994

By J. E. Misiewicz, A Rozendaal

Paper presented at Geofluids '93, held in Torquay, UK, 4-7 May 1993. The tin field consists of a fragment of Lower Proterozoic volcanosedimentary rocks surrounded by granitoids. Almost all the significant deposits are hosted by arkoses and are classified as replacement and space-filling types, with particular styles of mineralisation dominating at different mines. Petrological and geochemical investigation of borehole cores from four centres indicated the presence of a stratified zone 500-600 m thick and continuous over at least 20 km along strike, consisting of pervasively altered clastic arenitic sediments. The alteration is zoned into a grey-green sodic albitised footwall, an 80 m thick sericitised-tourmalinised sulphidic tin zone and a red haematitic potassic hanging-wall. The zoning and the localisation of three cassiterite phases are consistent with the tectonic history and with multiple pulses of stanniferous hydrothermal fluids derived from late differentiates of the granites over a prolonged period. Areas of high fracture density acted as conduits for the fluids, whose initially rapid ascent was retarded by decreasing pressure contrast, limited development of fracturing and/or impermeable shaly arkose to cause lateral spreading and pervasive alteration over a broad, stratified front. Lateral overlapping of local fronts at the various centres suggests a continuous zone, while the many petrological and geochemical similarities point to a shared fluid composition

Aug 1, 1995

By E. Niehuis, J. Y. Kim, H. G. Cramer, S. L. Chryssoulis, K. G. Stowe, C. Bendel

TOF-SIMS was used to detect, identify from parent molecular ions and determine the relative concentrations of collectors sorbed on the surface of mineral particles in concentrate and tailings samples from three Canadian concentrators. In the Kidd Creek Zn circuit, sphalerite lost to tailings carried on average a quarter of the amount of isobutyl xanthate present on that recovered to Zn concentrate; amyl xanthate, which is not reported as added to the circuit, was also detected on floated sphalerite and pyrite. At Brunswick, sphalerite particles lost to the scavenger tailings had ten times less amyl xanthate and isobutyl xanthate than those recovered to the Zn final concentrate, while both xanthates were detected on sphalerite floated to the Cu-Pb cleaner circuit. At Matagami, significantly more isopropyl xanthate and isopropyl dithiophosphate were detected on sphalerite recovered to the final Zn concentrate than on that lost to the Zn rougher tailings

Dec 1, 1995

By O. R. Eckstrand, M. Asif, P. L. Schwann, A. J. Naldrett, R. J. F. Scoates

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. PGE-bearing sulphide mineralisation is contained in the lower 600 m of the Upper Central Layered Zone of the intrusion. There are four regimes with distinctive crystallisation characteristics. PGE content is low, both in bulk rock and in terms of metal in 100% sulphides, in the sulphide-rich cumulates but increases sharply in the sulphide-poor cumulates at the base of regime 1. Increases in regime 2 have no such clear relationship with incoming cumulus sulphides. PGE contents are low throughout regime 3, but regime 4 has sulphides with high PGE content, decreasing rapidly upwards, at the base of many of its cyclic units. The observations are interpreted as indicating that sulphide saturation occurred in the middle of a cyclic unit in regime 1, after which fractional segregation of sulphide caused a systematic decrease in PGE content. The resulting contrast between 40 000 ppb PGE in sulphides below the mineralised zone and less than 1 000 ppb above is of practical importance in exploration for such zones. In regime 2 the magma chamber was open to fresh influxes and PGE content was not so sensitive to sulphide saturation. In many regime 4 units influxes of new magma caused immediate sulphide saturation and PGE depletion, so that PGE-rich cumulates do not underlie PGE-bearing sulphide zones. Theoretical analysis indicates that regime 1-type behaviour is likely to characterise intrusions below the level at which plagioclase has entered as a cumulus phase and regime 4-type behaviour above

Apr 1, 1994

By F. C. Gennari, D. M. Pasquevich

With the gradual exhaustion of natural rutile, there has been extensive research into its synthesising from lower-grade titanium minerals. The removal of Fe from pseudobrookite (Fe2TiO5) by chlorination was studied, using both isothermal and non-isothermal thermogravimetric measurements. Correlation of the results obtained from element distribution maps, scanning electron microscopy, energy-dispersive X-ray analysis and phases detected by X-ray diffraction in the chlorinated samples showed clearly two associated processes. First, the pseudobrookite particles reacted with chlorine and iron was removed selectively as FeCl3(g), leaving a solid residue rich in the TiO2 phases anatile and rutile, separated from an inner layer of unreacted pseudobrookite by a distinct interphase boundary. Second, chlorine allowed TiCl4(g) to form in the reaction bed, where it removed iron from the Fe2O3 crystals as FeCl3(g) and substituted Ti through a pseudomorphic reaction

Jun 21, 1905

By G. X. Wang, R. E. Siemens, M. C. Fuerstenau, D. Chandra

Soda roasting of concentrates from Mouat, Montana, was performed in a temperature range of 450 to 650 degrees C and chromium was solubilised by water leaching at room temperature. It was found that high extraction yields of chromium were primarily dependent on the conversion of Cr3+ to Cr6+ during the roasting step, and this was enhanced significantly by simple attrition of chromite particles during this step. Gangue impurities (mainly Si) were more detrimental to Cr extraction than lattice impurities such as Al or Mg. It appears that oxidation proceeds into grains along a preferred crystallographic plane in the cubic lattice of the chromite. The effects of roasting time, temperature, soda to chromite ratio and particle size on the extraction of chromium are presented

Jun 18, 1905

By D. R. Wardrop, G. Walton

Paper presented at the UK minerals industry conference held in Leeds, UK, 3-5 April 1995. A description is given of the approach that has been taken to the design of the 550 000 000 t superquarry with a planned life of 60 years that is proposed for development. The quarry has been designed to replicate a corrie and a sea loch and will include excavated slopes more than 570 m high. The main geological and physical controls on the layout and the choice of development method are outlined. The operation phasing is presented and the geotechnical constraints on slope design and the feasibility of alternative quarry limits are discussed. Environmental considerations have been dominant in planning and the quarry has been specifically designed for closure

Jul 1, 1996

By J Parnell, B Manson

Bitumen occurs in the basins in reservoir sandstones, in veinlets close to hydrocarbon source rocks, in veins through lava beds and in sulphide-mineralised veins where it is closely associated with, but predates, the sulphides. The role of organic matter was probably in enhancing metal reduction by creating a low-Eh environment rather than in metal transport. Coeval euhedral quartz crystals or albite in sulphide-bearing carbonate veins provide evidence of an aqueous component to the hydrocarbon fluid

Aug 1, 1995

By P. E. J. Pitfield, S. D. G. Campbell

The regional structure of shear and deformation zones in the belt, which is recognisable in plan view on Landsat TM images, is interpreted in terms of a conjugate-shear model. Gold mineralisation is related to this framework at a variety of scales. The principal recurrent structural geometries hosting deposits at mines such as Motapa, Durban, Charliesona, Cecil, Sunace, Turk group, Queens district, How, Peter Pat, Matabele Sheba, Goodenough, Old Nic and Bushtick are associated with shear zones and folds and include conjugate systems (shears, shear intersections, kink sets), side-step systems (en echelon segmentation, duplexes, monoclinal inflections, antiform-synform couplets) and interactions of the two. Linear sections of shear zones are generally poorly mineralised. The same geometries are identifiable on all scales from local to regional, so sections of regional structural lineaments or areas within mines should be prioritised for further investigation or development on the basis of the gold-bearing geometries observed to be dominant locally

Apr 1, 1996