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By N. S. Dalal, X. Shi, V. Vallyathan

"Electron spin resonance (ESR) and cytotoxicity measurements were made on newly fractured silica to examine specifically the role of the fractured-induced, siliconbased radicals (Si· and SiO·), and silica-generated hydroxyl (·OH) radicals in the mechanism of the cell membrane damage by silica. The concentration of the Si· and SiO· radicals was controlled through decay processes, thermal annealing, and boiling, while that of the ·OH radicals was varied by using catalase, superoxide dismutase, KMnO4, Ha2seO3, ascorbic acid, and metal ions, and monitored via ESR spectroscopy. The dust's cytotozicity potential was evaluated by measuring the silica-induced hemolysis and also by determining lipid peroxidation (using linoleic acid). Prom the comparison of hemolysis and ESR results it is deduced that the radicals play little· or no role in the silica-induced hemolysis. However, the lipid peroxidation data indicate that the radicals might be involved in the initiation of an oxidative chain reaction leading to the macrophage membrane damage through lipid peroxidation. INTRODUCTIONThe biochemical mechanism of Quartz-related pneumoconiosis is still not fully understood. It is believed, nevertheless, that one event of primary importance is the perturbation of cell membranes by the dust particles (Allison et al., 1966; Allison and Harrow, 1971; Bateman et al., 1982; Parazzi, et al., 1968; Reiser and Last, 1979; Shi et al., 1989; Summerton et al., 1977). The ensuing cell-membrane damage unleashes certain lytic enzymes resulting in additional cell injury and eventual fibrosis (Nolan et al., 1981; Summerton et al., 1977). Thus considerable effort is currently being made towards the understanding of the processes by which quartz particles disrupt the membrane of a red blood cell (RBC) or a pulmonary alveolar macrophage (PAM). A simple but important method of evaluating the membrane damage potential of a dust is the hemolysis test (Harington et al., 1971). Even though this test is used routinely for screening dusts for their cytotoxicity potential, the biochemical mechanism underlying the cell lysis by many dusts, including quartz, is still controversial (Kilroe-Smith, 1974; Singh and Rahman, 1987), and this provided us the impetus for the present undertaking."

Jan 1, 1989

By Joseph A. DeCarlo

For the first time the Bureau of Mines is combining, in one report, comprehensive tabulations on both beehive and slot-type ovens. This publication presents statistical data on the number and capacity of all such coke ovens in the United States on December 31, 1957. Combining data on both types of ovens should prove helpful to those interested in keeping abreast of the latest changes in carbonizing capacity, particularly since the coke has similar properties and uses. Annual reports furnished to the Bureau of Mines by coke-oven operators shared that 78 oven-coke plants were operating in 22 States on December 31, 1957. This was a decline of one plant from December 31, 1956, as the Republic Steel Corp. took the ovens at Canton, Ohio, out of production on December 17, 1957, for dismantling and rebuilding in 1958. Total oven-coke capacity was 80,299,400 tons in 1957.

Jan 1, 1958

By A. A. Cochran

Methods of preparing small heats of steel containing radioisotopes were developed, and the techniques of stripping film autoradiography were used to detect and study the carbide and sulfide phases in titanium-bearing steels. Metallography had revealed areas of titanium sulfide and ferrite or pearlite adjacent to areas of titanium carbide and ferrite, and unidentified, irregular phases at the boundaries between these two areas. Sulfur 35 was used to deter-mine the extent of the titanium sulfide inclusions, and carbon 14 was used to delineate the titanium carbide phase. Individual radioactive areas were located with a resolution of approximately 10 microns. A general background exposure that was not correlated with microscopically visible phases was observed in the carbon 14 autoradiographs. The evidence from both sulfur 35 autoradiographs and carbon 14 autoradiographs indicated that the unidentified inclusions were sulfides rather than carbides. INTRODUCTION The use of radioisotopes to facilitate the work at the Rolla Metallurgy Research Center was expanded in fiscal year 1959 when the Bureau of Mines authorized the installation of an intermediate-level radioactivity laboratory. Before this time, sealed cobalt 60 sources had been employed for radiography, but no tracer work was done. The primary objective of the first experiments conducted in the new laboratory was to supplement physical metallurgy investigations of selected problems in steel research.

Jan 1, 1962

By B. J. Scheiner

Electrooxidation of cinnabar mercury ores (HgS) was investigated as a means of providing an effective and economical hydrometallurgical technique for extraction of mercury from its ores, particularly those too low in grade to allow economical metal recovery by retorting or furnacing techniques. Oxidation was accomplished by electrolysis of ere slurried with brine. Cinnabar was dissolved by oxidation of the insoluble sulfide to soluble mercuric salts. The mercury ion in a brine solution forms a stable tetrachloro complex. Typical laboratory experiments required I to 7 hours of electrolysis at 35-percent pulp density in a brine solution that contained 4 to 20 weight-percent sodium chloride (NaCl). Power consumption ranged from 10 to 50 kwhr/ton of dry ore. Mercury extraction values between 90 and 99 percent were obtained with all of the ores investigated. Subsequent mercury recovery from leach solutions was readily accomplished by precipitation on zinc. Pilot mill experiments in a 100- to 200-lb/hr extraction plant are in progress to quantify power and reagent requirements, and extraction and recovery data obtained to date closely parallel those obtained in the laboratory.

Jan 1, 1970

By S. H. Ash

As part of the work done at the Washington coal mines during the year 1929 , a study was made of the safety practices in and about the mines . Inasmuch as electrical blasting has made considerable headway it is interesting to note the manner in which it is done and the reasons why it was discarded at some of the mines . Blasting is done at the mines in the State by means of capped fuse , electric blasting " caps , " and in some instances by electric delay detonators . Black blasting powder with fuse is used at most of the open- light mines . The use of squibs was discontinued several years ago because the coal operators , without exception , recognized the dangers incidental to their use . Permissible explosive and dynamite are also used at some of the open- light mines . With the exception of some rock work and the driving of level work in gangways and air courses the explosive is detonated by means of capped fuse .

Apr 1, 1930

By Martin H. Rogoff

The presence of antibiotic materials extractable with polar organic solvents was demonstrated in coals of various ranks. Since these antibiotics occur in low concentrations, 200 pounds of a high-volatile C coal was extracted with acetone at room temperature to obtain sufficient material for detailed study. The biologically active materials in the extract were concentrated by extracting with aqueous sodium hydroxide. The fractions soluble in sodium hydroxide inhibited bacterial cultures when present in concentrations comparable to those at which other antibiotics are active (5 µg/ml). Steam distillation of the extracts did not yield highly active materials, contrary to the finds of other investigators. Mass spectrometry of the extract indicated, mainly, the presence of 6-ring compounds in the region of mass 324 to 392. The predominance of 3-ring aromatic systems found by ultraviolet analysis suggests compounds such as biphenanthryl or similar structures. The activity of the hydroxide- soluble material decreased markedly when the phenolic hydroxyl groups were transformed into trimethylsilyl ethers. Hydrolysis of the ethers yielded a product having the same activity as the original material, which indicates that phenolic compounds are largely responsible for the antibiotic activity observed.

Jan 1, 1963

By J. L. Eakin

The Bureau of Mines determined agents that are effective in foaming heavy brines and oil from gas wells in severe concentrations of sodium chloride, in severe concentrations of calcium chloride, or in moderate oil-brine mixtures. Dynamic foam tests were designed to select the more effective foaming agents. Numerous foaming agents were tested in concentrated simulated brines, in oilfield brines having varied concentrations of ions, in heavy natural brines, and in a commercial brine generally used as a reservoir pressure-balancing fluid. Several agents were detected that could perform efficiently in the field under the most severe saline conditions. Agents that promote foaming in oil-brine mixtures were also determined.

Jan 1, 1965

In 2005, a total of 4,490 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). Stone mines comprised 30.6% of all mining operations. ? Mines producing the primary commodity of limestone (crushed and broken) comprised the largest number of operations (n=2,039; 45.4%). ? Stone mining operations were located in all states and territories except Delaware and North Dakota. ? Of all states, Pennsylvania had the most stone mines (n=379; 8.4%).

Jan 1, 2008

By Robert H. Merrill

Measurement of the deformation of a borehole in rock subjected to a change in applied stress can be used to calculate the magnitude and direction of the applied stress, provided a satisfactory deformation-applied stress relationship exists , In this investigation by the Bureau of Mines the deformation of a bore- hole in a rock model subjected to a known applied stress was compared with the theoretical deformation of a hole in an elastic, isotropic plate and was found to be in good agreement. Hence, this relationship can be used to calculate the applied stress on a borehole from borehole deformation measurements.

Jan 1, 1961

By L. C. IlsLey

A list of permissible mine equipment, tested and approved prior to Jan 1, 1937, was published in Bureau of Mines Information Circular 6942 • .ll The present list inc ludes additional equipment approved during the calendar yea r 1937. The ma terial has been listed und er the same. headings as th ose used. in Information Circular 6942. The number that appears at the beginning of each it em represents the number o f this type of ma.chine appr.oved including the machine in questi on; for instance, the miing ma.chine numbered 70 was the seventiet h co al cutting ma chine design for which approval has been isnued. All of the equipment listed represents new designs except that covered by the first item, that is, 57 under the • heading nLoading Machines and Conveyors. 11 This item covers the approval of the 500-volt design of a machine the 250-v olt design of which was approved on January 17, 1935. The system under wich these devices were tested permits the manu-. facturer., after his equipment has passed certain tests prescribed by the 'Ui"eau of Mines, to mark his equipment with a seal showing that it has been approved by the Bureau. These tests are designed to insure t hat equipments hav,e the minimum requirements for safety in use. The only object of the :Bureau in making such tests and publishing lists of permissible equipment is to help decrease the hazards of mining.

Apr 1, 1938

By D. W. Scott

Thermodynamics is a powerful tool for investigating rotational isomerism in substituted ethanes and related molecules. Accurate calorimetric data can be interpreted to give information, not only about the energy difference between conformations, but also about the shape of the potential barrier hindering rotation from one conformation to another. However, a deterrent to this use of thermodynamics is the labor required to calculate the contributions to the thermodynamic functions for assumed potential functions. Tables of thermo-dynamic contributions for appropriate potential functions can eliminate that labor and greatly facilitate the thermodynamic study of rotational isomerism. In this research, tables of contributions to the thermodynamic functions were compiled for two potential functions typical of some commonly encountered examples of rotational isomerism. TYPES OF POTENTIAL FUNCTIONS Potential function 1, illustrated in figure 1, A, has two equal minima higher than the third. It has the general shape of the barrier to internal rotation in n-butane, for example. The trans conformation of n-butane has the lowest energy, and the two skew or gauche conformations have equal but higher energy. Potential function2, illustrated in figure 1, B, has two equal minima lower than the third. It has the general shape of the barrier in 2-methylbutane, for example. The two C1 conformations of 2-methylbutane have equal energy much lower than the assumed Cs conformation, which has not been observed spectroscopically.

Jan 1, 1962

Limestone formations in the United States can be subject to relatively high horizontal stresses due to the existence of tectonic loading of the limestone strata. Underground limestone mines use the room-and-pillar method, in which 12- to 18-m-wide rooms are typically excavated. The stability of these excavations can be compromised by the horizontal stress, resulting in a rockfall hazard. Rockfalls are the cause of 15% of all reportable injuries in underground limestone mines. Horizontal stress related damage can occur in the form of guttering along one or more sides of an excavation, roof beam buckling or oval shaped roof falls, with the long axis perpendicular to the major horizontal stress. Numerical analyses show that the pillar layout and orientation of the mine workings have an effect on the horizontal stress distribution within the roof. The effects of high horizontal stresses can be mitigated by orientating the heading development direction parallel to the maximum horizontal stress, reducing the number of cross-cuts and offsetting the cross-cuts to limit the potential lateral extent of horizontal stress related roof falls. The modeling approach described in this paper can be used as a tool to evaluate potential roof failure and optimize the stability of room and pillar layouts.

Jan 1, 2008

By Marcia L. Harris

Toxic fumes produced by detonating explosives in surface mining and construction operations pose potential hazards to workers and the public. Blasting operations produce both toxic and nontoxic gaseous products; the toxic products are mainly carbon monoxide (CO) and the oxides of nitrogen (NOx). Since 1988, there have been 17 documented incidents in the United States and Canada in which carbon monoxide (CO) is suspected to have migrated through ground strata into occupied enclosed spaces as a result of proximate trench blasting or surface mine blasting. These incidents resulted in 39 suspected or medically verified carbon monoxide poisonings as well as one fatality. At worst people may be fatally poisoned and the least to be expected is increased public objections to blasting. Local and state agencies could demand a cessation of the blasting requiring more expensive mechanical means to break the rock. This paper discusses the most feasible means of preventing CO migration, mitigating CO that has migrated, and detecting CO in an underground enclosed space and may help reduce the exposure of unsuspecting area residents to carbon monoxide and help prevent the implementation of unnecessary regulations and limitations on blasting. Single-hole shots and small-scale multiple-hole blasts were performed that indicate promising means of prevention and mitigation.

Jan 1, 2008

By J. B. Gayle

Although heated circuits frequently have been employed in the conditioning stases of certain flotation processes, particularly the flotation of fluorite, the control of temperature is not generally considered economically feasible for the flotation of coal. This viewpoint, although widely held, can neither be substantiated nor refuted by reference to published data. Some evidence is available, however, that temperature is an important variable in the floatability of coal as well as other minerals. For example, Gayle and Swelley4 found that contact angles for coal and related substances were definitely dependent on temperature. Bailey and Whalan5 showed that changes in pulp temperature may exert a pronounced influence on recoveries of coal in batch flotation tests. The present laboratory-scale investigation was undertaken to obtain information about the effects of changes in pulp temperature on coal flotation recovery and also on the selectivity of separation possible using different reagents. The results indicated that flotation recoveries were markedly affected by temperature variations when certain reagents, particularly simple aliphatic alcohols, were used. For other reagents, particularly kerosine, flotation recoveries were substantially independent of variations in pulp temperature. Release-analysis results indicated that temperature variations did not greatly affect the selectivity of separation possible with the reagents tested.

Jan 1, 1961

By J. A. Stampe

In connection with its investigations of strategic minerals in the United States, the Bureau of Mines ran magnetic surveys totaling more than 533,000 linear feet at 30 deposits of magnetite in northern New Jersey. These deposits occur in a belt of granitic gneiss and in limited areas of limestone. The ore consists of magnetite accompanied by score of the following minerals: Hornblende, augite, apatite, feldspar, biotite, calcite, garnet and pyrolusite. Results of these investigations are being presented in two reports of which this is the second. The first paper, Certain. Magnetite Deposits in New Jersey, by A. L. Neumann and McHenry Mosier, was issued in April 1948 as Report of Investigations 4225.

Jan 1, 1949

By P. H. Floyd

This report presents the results of laboratory beneficiation tests on a sample of scheelite ore and a sample of low-grade scheelite flotation concentrate from the Sangdong mine, Korea. Sangdong was the foremost producer of tungsten concentrates on two occasions - during part of World War II and in 1953. It was also a significant producer of bismuth concentrates. Resources are very extensive and could support a 5,000-ton annual output of tungsten concentrates for many years. Located in the eastern part of South Korea near the 37° latitude, Sangdong has been a vital source of dollar income for the Republic of Korea in recent years. Its shutdown in March 1954 came about as a result of the great decline of tungsten prices and the fact that a sales contract with the United States Government had been terminated, In addition to establishing new markets, the problem of reopening Sangdong will be related to cost reductions and improving mill recoveries. Large quantities of offgrade scheelite concentrates were produced in the past and shipped to the United States for further beneficiation. Other low-grade concentrates and middlings have been stockpiled or discarded at the mine plant.

Jan 1, 1954

By C. J. Chindgren

Two air classification systems were built and tested as separatory devices for recovering the nonferrous metal values from shredded automotive nonmagnetic reject scrap. A horizontal air system with a capacity up to 16 tons per hour was used to obtain preliminary separations, and a smaller capacity vertical system was used as a cleaning device. Shredded automobile reject material containing aluminum, copper, and zinc values of about $55 per ton were air-classified in the horizontal elutriator. Ninety-six percent of the metal was recovered in a 74-percent metal concentrate. Tandem operation of both classifiers recovered 92 percent of the metal in an 80-percent concentrate while rejecting 87 percent of the nonmetallics. Heavy media separation of the air-classified concentrate produced an overall recovery of 91 percent of the metal in the form of a 99-percent metal concentrate.

Jan 1, 1971

By Robert C. Hickman

In its search for strategic minerals, the Bureau of Mines investigated the Rutherford Mine property in Amelia County, Va. The property was visited by F. W. Horton, mining engineer, and Margaret Fuller Boos, mineral technologist, of the Bureau of Mines, in company with Eugene Dawson, of the War Production Board, on July 16-11, 1943. An exploration program by the Bureau was recommended, and work was started on July 28, 1943, and continued until September 16, 1943. A total of 1,250 feet was diamond drilled in 5 holes on the property.

Jan 1, 1950

By Jr. Watts, B. K. Cantrell, D. H. Carlson, K. L. Rubow

"Abstract — The use of diesel equipment in underground coal mines is controversial because the National Institute for Occupational Safety and Health (NIOSH ) regards ""wholediesel exhaust"" as ""a potential occupational carcinogen."" Threshold limit values (TLVs ) are recommended for the gaseous pollutants CO, CO2, NO, NO2, SO2 and some hydrocarbons emitted in diesel exhaust. There is, however, no TLV recommended for diesel exhaust aerosols (DEA) nor is there a standard method for sample these aerosols.The University of Minnesota and the USBM have collaborated to develop a personal diesel exhaust aerosol sampler (PDEAS) that utilizes size selective, partial impaction and gravimetric analysis. During the field tests of this sampler, numerous air quality measurements were conducted in underground coal mines that used diesel equipment. The objective of this report is to present these data and to assess the impact of diesel face haulage equipment on mine a quality.Air quality data were collected in four underground coal mines. The mines used continuous miners and diesel haulage equipment. Daily samples were collected at the section intake, haulage way and on haulage vehicles. Both full- and partial-shift samples were collected using a variety of aerosol instruments. These included the PDEAS and the micro-orifice uniform deposit impactor (MOUDI) that sample the mine aerosol diesel exhaust fraction. Two of the mines were also monitored for the major gaseous constituents found in diesel exhaust CO,CO2, NO, NC, and SO2. These measurements were made by either collecting bag samples for subsequent gas analysis or by Palmes dosimeters.Concentrations of CO, CO2, NO, NO2 and SO2 were well below regulated levels. The mine average DEA concentration determined by the PDEAS in the haulageway for the three mines surveyed was 0.79 mg/m4, with a standard deviation of 0.19 mg/m3 DEA contributed 65% of the respirable aerosol, at this location. These results were the same as the mean DEA concentrations calculated from size distribution measurements obtained using the MOUDI. This was 0.78 mg/m3, with a standard deviation of 022 mg/m3."

Mar 1, 1992

By Michael P. Moore, Christopher J. Rise

"Over the past twenty years, there have been numerous studies which have attempted to correlate the prevalence of Coal Workers' Pneumoconiosis (CWP) with different characteristics of the coal seam. Some investigators have tried to find a relationship, or the lack of a relationship, between the rank of coal seams and the incidence of CWP. Others have attempted to show that there is a positive correlation between the mean mass of respirable dust in the mine atmosphere and the prevalence of CWP. Still others have tried to determine the influence of the quartz content of respirable dust on the incidence of CWP. Unfortunately, many of these different investigations have conflicting conclusions.One area of research with conflicting conclusions deals with the relationship between the rank of the coal and the incidence of CWP. For example, an inves¬tigation conducted in Pennsylvania and West Virginia coal mines concluded that the prevalence of CWP increases with an increase in coal rank (1). A study in Great Britain also observed a close relationship between the rank of coal and the prevalence of CWP (2). However, another study involving 312 Appalachian coal miners concluded that the association between coal rank and CWP might be fortuitous and that other factors may be more important (3). In addition, an investigation involving 2,600 miners during a period of twenty years in Great Britain established that there is only a weak correlation between the prevalence of CWP and the rank of the coal (4). Consequently, it appears that there is still uncertainty as to whether or not the rank of the coal seam has an influence on the development of CWP.Another area of investigation concerns the relationship between the mean mass of respirable dust present in the mine atmosphere and the prevalence of CWP. A study involving 4,122 miners over a period of ten years in Great Britain noted a high correlation between the mean mass of respirable dust and the incidence of CWP (5). Another investigation involving 3,154 British face workers con¬cluded that the overall mass of respirable dust is the factor most closely related to the ten-year attack rate of CWP (6). However, a study conducted in thirty-one mines in the United States concluded that it is doubtful that the quantity of respirable dust alone is responsible for the difference in the prevalence of CWP (7). Even though there are conflicting conclusions, there are many more investigators who confirm, rather than deny, the relationship between the mean mass of respirable dust and the development of CWP.The third subject of investigation is the role of quartz in the incidence of CWP. For example, two studies in Great Britain concluded that the quartz content in coal mine dust has no relationship to the prevalence of CWP (8,9). But a study involving 312 Appalachian coal miners revealed that the level of exposure to free silica plays an important role in the development of CWP (10). Once again, the conclusions reached by different researchers are conflicting.Probably the most important factor in the discrepancy among the studies is the variability among different coal mines. A mine operating in an inherently ""dusty"" seam may have a low concentration of respirable dust while a mine operating in a less dusty seam may have a high concentration of respirable dust. This discrepancy is a result of variables such as the effectiveness of ventilation or the efficiency of the water sprays. Consequently, it is very difficult to compare the dustiness of different coal seams by in-mine measurements of the respirable dust concentration. A laboratory test would more accurately characterize a coal seam according to its respirable dust production."

Jan 1, 1988