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As part of the Bureau of Mines subactivity in secondary resource recovery and to expand the Nation's mineral base, the Tuscaloosa Research Center made characterization and preliminary beneficiation studies of the waste residues from various coal-conversion processes: from pilot plant tests of the Synthane process for coal gasification, the Synthoil process for coal liquefaction, and the solvent-refined coal (SRC) process for sulfur removal from coal. Those coal conversion processes selected for this study were based on the availability of pilot plant samples. Physical, chemical, and mineralogical examinations of the wastes made to determine the mineral content prior to physical beneficiation tests indicated that in addition to significant quantities of carbon, some trace elements offer potential for concentration.

Jan 1, 1980

By Joseph J. Wallace

1. From the standpoint of known recoverable reserves, the following is the order of importance of the beds: Upper Kittaoning, Lower Kittanning, Upper Freeport, Lower Freeport, Middle Kittaning, Clarion, Pittsburgh, and Redstone. 2. mown measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and on 1,800 tons per acre-foot of coal in place, me estimated at 1,859 million short tons as of January 1, 1952. Of this, 1,351 million short tons me in beds 28 inches and more thick. Areas in each bed were omitted from the estimates because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1953

By Bill M. Stewart

The Bureau of Mines conducted laboratory tests to determine the effects on the physical properties of coarse coal waste of adding large amounts of fine coal waste. Maximum laboratory dry density, optimum moisture content, shear strength, and permeability tests were conducted on samples that contained 18 to 60 pct minus No.4 (U.S. Standard sieve size) coal waste. For the nonslaky materials, maximum laboratory densities were highest and permeabilities lowest when the samples contained between 30 and 40 pct minus No.4. Shear strength increased rapidly when the proportion of minus No. 4 was increased from 20 to 40 pct, but then increased only slightly or leveled off when the minus No. 4 was increased to 60 pct. Optimum moisture content and permeability were the physical properties most affected by the addition of fines. Optimum moisture content increased as much as 3 pct, and permeabilities decreased up to three orders of magnitude. Slaky coal waste material had physical property reactions to the addition of fines substantially different from those of nonslaky material.

Jan 1, 1981

By Kenneth E. Hjelmstad

In situ leach mining operations often encounter difficulty maintaining adequate leach solution flow into the are formation. Swelling and dis-persion of clay particles in the formation are often responsible for this permeability loss. Permeability and leaching tests were done in the laboratory on clayey ores to evaluate a clay-stabilizing polymer's effectiveness in preventing these problems. Test results indicate that treating the ores with the stabilizer could maintain permeabilities two to five times greater than the long-term permeabilities present in untreated ores. Both alkaline (pH 8.5) and acidic (pH 2.0) leaches were used in the permeability-leaching tests. Since in situ leaching throughput rate is directly related to permeability, these results also indicate a potentially beneficial effect on operating parameters such as capacity and injection pressure. To determine the reasons for the success of the clay stabilizers, an investigation was conducted to cieter-mine the effect of the stabilizer on clay swelling and dispersion. Clay-swelling tests indicated that the clay stabilizer reduced clay swelling. Zeta potential measurements made on fine clay particles treated with the stabilizer were compared to measurements made on untreated particles and indicated that the stabilizer was electropositive and, therefore, could reduce the degree of negative charge on the particles and their tendency to disperse or migrate.

Jan 1, 1984

By J. H. Schuenemeyer

Consider a set of points, some of which are anomalous (larger than a specified cutoff value), located on a plane. Whether some or all of these points are clustered to form one anomaly or more or, alternatively whether these points are scattered at random, may be investigated by measuring perimeters of convex hulls. A convex hull is the smallest convex polygon that will encompass a group of points. (Examples of convex polygons are triangles, rectangles, and all other regular polygons.) A set of anomalous points is selected and the perimeters of the convex hulls of this set and all its subsets are measured and compared with tabulated values of perimeters for each subset size. For a given subset size consider those perimeters which are less than the tabulated perimeter. If the number of convex hulls is greater than the maximum number expected by chance, then the chance that any one of the observed-hulls-is a nonrandom cluster is the ratio of the observed number to the sum of the observed and the maximum number expected by chance. Otherwise, the points are evidently not clustered. If many sample points are anomalous, an alternate model defines various configurations of contiguous points and compares the observed number of configurations per unit area with the expected number. Applications are discussed in several fields of geology and geochemistry-including geochemical exploration surveys and heavy mineral spatial distributions--as well as in mining (dust control) and medical geography.

Jan 1, 1972

By N. S. Dalal, B. Jafari, F. H. Y. Green, M. M. Suryan, V. Vallyathan

"Freshly ground and aged anthracite and bituminous coal samples were investigated by electron spin resonance (ESR) spectroscopy to detect the presence, concentration and reactivity of free radicals. Freshly ground anthracite coal produced greater concentration of free radicals than the bituminous coal, and the radical reactivity was also greater for the anthracite. The reactivity of the newly produced free radicals in the anthracite dust correlated with the dust's toxicity. Furthermore similar coal-based free radicals were detected in the lung tissue of autopsied coal miners, suggestive of persistent reactivity by the embedded coal dust leading to the progressive disease process. Results of the studies on the severity of coal workers' pneumoconiosis (CWP) and free radical concentration m lung tissue support this hypothesis.INTRODUCTIONCOAL WORKERS' PNEUMOCONIOSIS (CWP) has been an important topic of concern to miners, mining engineers, epidemiologists and medical researchers for decades. It is well known that the prevalence and severity of CWP differ markedly between different regions and mines despite comparable exposures to respirable dust (REISNER and RoBOCK, 1977; HURLEY et al., 1979). These variations in pathogenicity of coal mine dusts can only partially be explained by differences in the mineral composition and by rank of coal (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). Cytotoxity studies on mammalian cells do not correspond well with the human disease pattern (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al.,1980; VALL YA THAN et al., 1988). For example, while epidemiological studies of coal miners (REISNER and ROBECK, 1977; HURLEY et al., 1979) indicate that the prevalence of CWP correlates roughly with the rank of coal, such correlation has not yet been established in biological studies, despite considerable effort (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). In order to help resolve this apparent paradox we have undertaken a systematic study to evaluate whether any correlation exists between the concentration of free radicals present in fresh or aged coal dusts from two well-characterized U.S. coals. This study was also prompted in part by observations reported in the literature that organic free radicals can be formed on the surface of freshly fractured coals (LEBEDEV et al., 1978; DULIBA and CLARKSON, 1984). In particular, ARTEMOV and REZNIK (1980) noted that the decay lifetimes and, hence, the reactivity of the organic free radicals formed on crushing Russian coals, .depended"

Jan 1, 1989

By J. B. Gayle

The removal of coal particles from a slurry by flotation is made possible by the formation of stable aggregates with air bubbles of suitable sizes. The formation of such aggregates is theoretically possible only for certain favorable combinations of the solid-liquid-gas interfacial tensions. Because interfacial tensions involving solid phases are not conveniently measurable, a related variable, the contact angle, frequently is used as a measure of the floatability of various materials. Zero angles indicate nonfloatable substances, and large angles indicate substances having a high degree of floatability. During a study of contact angles for coal and substances related to coal in their similarity of response to various physical and chemical treatments, particularly flotation, carbonization, and oxidation, the reproducibility of replicate determinations taken within a 4-hour period was found to be much better than that for comparable results taken over a longer period of time. Consideration of possible causes for these differences led to an investigation of the effects of temperature variations on contact angles. References to literature revealed only a small amount of information, some of it apparently conflicting. Specifically, Sutherland and Wark4/ found that temperature variations "within limits" did not appreciably influence the angles measured for galena conditioned with potassium ethyl xanthate. On the other hand, McGlashan and McLeod5/ presented preliminary data showing that for sphalerite conditioned with potassium ethyl xanthate the angle is maximum at 25° to 35° C., depending on the pH of the system.

Jan 1, 1960

By R. R. Nothdurft

The internal friction of eight single crystals of magnesium with orienta-tion ranging from 10° to 84° was measured at 33.5 kc and 272° C, and the results were interpreted in terms of the pinned-dislocation model proposed by Granato and Lucke. Results show that the strain-amplitude-dependent decrement varies with orientation in a manner predictable by the G-L model. Different values of strain-amplitude-independent decrement were observed at different orientation angles, but correlation with the theory was not conclusive. Problems and steps for further study are discussed.

Jan 1, 1965

By S. M. Shelton, W. A. Calhoun, M. M. Fine, T. L. Johnston

"This report is () expansive test program by the Bureau of Mines to determine methods from various and ferrous manganese-grade product () widespread () and manfniferrous iron ores. Among the samples received for testing was one from the pits of the Barytes Mining Co., 1-1/ 2 miles northeast of Cartersville, Ga.. The property is approximately in the center of the Cartersville manganese district and shares a common corner with properties of the New Riverside Ochre Co. and the Etowah Development Co., both producers of manganifereus ores. The deposit is typical of the district and occurs in residual clays resulting from weathering of the Shady limestone and Weisner quartzite. 7/The property is developed by a number of open pits ranging to 60 feet in depth. In 1918 several carloads of manganiferous iron ore was mined from an alit on the property. Since then mining operations have been negligible. The ore is known locally as calico ore.A 4-ton sample representing -re as it occurs in the -pen pits vas furnished for testing. The sample consisted of a mixture of red iron oxides, wad, and clay, with small pebbles of manganese oxides and siliceous fragments scattered throughout."

Mar 1, 1943

By Joan Weinberg

The real gross national product (GNP) advanced at a annual rate of 3.1 % during the second quarter, following a revised 3.4% increase in the first quarter (see table 1). Export growth continues to play an important role in the rising output. Combined with the decline in imports, it resulted in a noticeably improved trade position. Imports of consumer goods, including automobiles and food, fell while exports rose. Imported cars have been losing ground to domestic cars. The foreign car share of the U.S. market fell from 36% in October 1987, to 29% in May 1988. Business spending for new plant and equipment contributed strongly to the GNP increase. Equipment purchases, particularly of computers, rose at a 14.8% annual rate, following a large first-quarter gain. Purchases of structures rose 11.8%. The other key component of business spending, change in business inventories, declined from the first quarter. Inventory buildup in late 1987 had been considered excessive.

Jan 1, 1988

By George R. Schottler

The Bureau of Mines investigated the distribution of uranium and various methods of ore sampling in a uranium deposit typical of those in the Morrison Formation sandstone of the Ambrosia Lake area, Grants mining district, north-western New Mexico. Chemical and radiometric assays of diamond-drill core samples are compared in detail by statistical techniques, and the assay data are correlated with the stratigraphy of the deposit. Conclusions applicable to ore-reserve estimation in geologically similar uranium deposits are drawn.

Jan 1, 1971

By Douglas A. Donato

This Information Circular presents the MULSIM/PC system of numerical modeling computer programs developed by the U.S. Bureau of Mines. This system consists of four programs: PREMUL, the preprocessor or mesh generator; MULSIM/PC, the actual numerical modeling program (number cruncher); MUL3D, a three-dimensional postprocessor; and MUL2D, a two-dimensional postprocessor. These programs were specifically designed to operate on IBM-compatible (MS-DOS-based) personal computers for easy transfer of this technology to the mining industry and academia. MULSIM/PC uses a subvariation of the boundary-element method, namely, the displacement-discontinuity technique, for linear-elastic geomechanical analysis of mine plans in one or two parallel underground tabular deposits. Results calculated by this technique include stresses and displacements as they relate to changing mine geometries and materials. In addition to describing the MULSIM/PC program and its features, and providing a detailed example model, this report also documents the associated preprocessing and postprocessing programs that are part of the MULSIM/PC system. User's guides for all the programs are contained in the appendixes following the main report.

Jan 1, 1992

By R. Karl Zipf

A fatal explosion in a sealed area at the Sago Mine in 2006 prompted researchers and regulators in the United States to re-examine the requirements for explosion-resistant mine seals. Seals are used in underground coal mines to isolate abandoned mining areas from active workings. Prior to the Sago disaster, mining regulations required seals to withstand a 140 kPa explosion pressure. Recent research at the National Institute for Occupational Safety and Health (NIOSH)Pittsburgh Research Laboratory showed that pressures from explosions can far exceed this pressure. U.S. mining regulations now require much stronger seals. Current research focuses on understanding the science, engineering and management of sealed areas of coal mines. Scientific efforts seek understanding of how explosive methane-air mixtures accumulate using measurements and models of the sealed area atmosphere. Additional scientific efforts aim to understand the explosion pressures that can develop using a combination of numerical modeling and experiments. Engineering efforts aim to produce design guidelines for seals that can resist the new higher pressure design criteria. NIOSH researchers are also developing guidance for monitoring of sealed area atmospheres and inertization of potentially explosive gas mixtures within sealed areas. This paper seeks to encourage scientific discussion among international peers since preventing explosions within sealed areas is of interest to underground coal operators and regulators.

Jan 1, 2009

By R. V. Ramani, V. T. Burgos, J. A. McClay

General The underground mining environment has traditionally been hostile and as early mines were developed, coal seams with particularly difficult natural conditions were bypassed in favor of those more easily exploited. Barring the discovery of new and novel sources of energy, the depletion of petroleum and natural gas reserves will eventually force the United States back to the use of coal as its primary energy source. Figure 1 illustrates the trend away from coal which has taken place over the past half century. Today, the demand for coal requires a re-evaluation of all coal seams to meet the needs of the energy market. Difficult mining conditions may result in an increase in the consumption of roof control materials, require greater investment in pumping and ventilation systems, and increase the need for in-depth engineering of far greater safety in production plans. They may also cause delays in mine development and curtail production, all of which combine to drive up the unit production cost. It is reasonable to expect that conditions will continue to deteriorate as current reserves are depleted, thus bringing this factor into greater prominence in the future. For several years now, it has become apparent that in addition to economic objectives, coal companies must set and achieve several concomitant objectives to accomodate society's interest in the conservation of natural resources. Government action to meet this interest has taken the form of two categories of Federal legislation, environmental protection and employee health and safety. The effects of both of these have not been fully evaluated with respect to the total economic picture, although preliminary evidence indicates that an immediate increase in

Jan 1, 1975

By J. K. Whyatt

The Bureau of Mines, under a cooperative agreement with Callahan Mining Corp., measured rock displacement at the 4,7S0-ft level of the 5,100-ft-deep rectangular, timbered Caladay Shaft in northern Idaho. Displacements were measured with multiple-position borehole exten-someters (MPBX) installed 4 ft above the face and timber extensometers (TE) installed with the timber sets. This report presents the displacement data along with preliminary, qualitative observations of rock behavior. The measured displacements showed an instantaneous response to shaft sinking and significant time dependency. The relative magnitudes of displacement measured at the shaft walls were heavily influenced by local geologic structure and distance from the shaft bottom.

Jan 1, 1987

By J. C. Edwards

The Bureau of Mines developed a mathematical model that decribes the interaction of an automated breathing and metabolic simulator, or lung, with a self-contained· self-rescuer that is supplied compressed oxygen. The model can be used to predict the gas partial volumes of 0z, Nz, and COz in the lung and in the self-rescuer breathing bag for a prescribed metabolic state that characterizes the lung. Nonlinear rate equations are used to describe the temporal evolution of the gas partial volumes. A numerical procedure was established with a FORTRAN computer program to solve these equations, which correspond to a given metabolic state. Examples are presented of applications of the model to predict bag volume and bag oxygen concentration changes with time when the bag is controlled by an automated breathing simulator. Under certain restrictive conditions, the model equations can also be used to analytically pre-dict the time required for the bag to reach a maximum or minimum volume. The model equation in this latter case was extended to transi-tions between metabolic states, with transitions described as exponential growth or decay processes.

Jan 1, 1985

By George E. Blandford

A deterministic model to assess the hydrologic impact of small watersheds subjected to unsteady storm events is presented. The overland flow model is based on the kinematic wave approximation coupled with a Green-Ampt infiltration equation. The Green-Ampt infiltration parameters are estimated using the USDA-ARS parameter estimation technique which is based on soil moisture-tension data. A Galerkin finite element formulation of the kinematic wave approximation is presented for the deterministic analysis of overland flow on small watersheds. The finite element formulation includes linear, quadratic and cubic Lagrangian one-dimensional spatial elements. A linear time variation is assumed which includes both explicit and implicit time marching algorithms, depending on the choice of the time weighting parameter. The implicit time algorithms result in a system of nonlinear equations which are evaluated using a modified Newton-Raphson iteration scheme. Initial solution estimates are generated using a linear finite difference procedure. The coupled infiltration overland flow model is tested using storm data for impervious surfaces, a laboratory soil flume, and two natural, USDA-ARS experimental watersheds.

Jan 1, 1983

By Harry W. Campbell

During 1983, the U.S. Bureau of Mines conducted a mineral survey of 19,700 acres that included the Fish Creek Mountains WSA (Wilderness Study Area), 15 miles southwest of the Salton Sea. Two United States Gypsum Co. claim groups in the WSA have more than .20 million tons of inferred gypsum reserves. These high-grade, surface and near-surface gypsum deposits are an extension of a gypsum bed that has been mined continuously since 1922. The Waters prospect in the central part of the WSA has large quantities of limestone suitable for many commercial uses. Sand and gravel is plentiful in the WSA in alluvial fan and ancient shore-line deposits. Limestone and alluvial deposits are not economic because similar material is closer to potential markets. No evidence of energy minerals or geothermal resources was identified in the WSA. A portion of the eastern Fish Creek Mountains WSA is leased for oil and gas exploration. United States Gypsum Co. holds eighteen unpatented placer claims in the northwestern part of the WSA. No other mining claims or mineral leases were identified in the study area. No mineral production is known from within the WSA.

Jan 1, 1986

One of the major unknowns in the use of iron and copper is the quantity of various low level impurities, particularly hydrogen, that may be introduced during the deoxidizing process prior to casting. Introduction of hydrogen results in the embrittlement of components made from these metals. In addition, hydrogen bubbles in castings of copper result in the formation of blisters and swelling of the casting. During the last year, a significant effort has been made at the University of Missouri-Rolla to understand the permeation of hydrogen in galvanized automotive steel components and the hydrogen absorption during the electrodeposition of copper. The galvanized steel components consisted of automotive upholstery clips, seat belt holders and brake clips. Although the process of galvanization protects the steel from corrosion the process invariably causes the steel to pick up enough hydrogen to make it susceptible to brittle fracture.

Jan 1, 1992

By S. L. May

Tantalum and columbium can be extracted from several of their ores or concentrates by chlorination procedures. Direct chlorination of high-grade minerals in the presence of carbon at temperatures between 500° and 800° C will extract up to 99 percent of the tantalum and columbium. Metallurgical beneficiation of low-grade source materials by carbothermic reduction produces a ferroalloy that is amenable to chlorination at a temperature of 500° C. Over 90 percent of the tantalum and columbium can be recovered.

Jan 1, 1965