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By M. M. Tilman

The Bureau of Mines investigated the precipitation strengthening of lead¬-base alloys containing 0.5 through 4 weight-percent combined Cd plus Sb. The Cd and Sb were alloyed in a 1-to-1 atomic ratio which maintained compositions along the quasi-binary section Pb-CdSb. Tensile properties, creep rates, and stress-rupture values were obtained on alloys in the aged condition. The highest tensile strength was observed in an alloy of Pb-3 CdSb, After aging for 6 months at 90°±3° F, this alloy had a mean tensile strength of 8,950 psi with 15-percent elongation. An aged alloy of Pb-1 CdSb exhibited a steady state creep rate of 1.2 X 10-3 percent per day at a stress of 500 psi and a temperature of 90°±3° F. Times to rupture at stresses up to 4,000 psi and at a temperature of 90°±3° F were obtained for some compositions.

Jan 1, 1970

By Thomas F. Tomb

The penetration characteristics of a horizontal plate elutriator and of a 10-mm nylon cyclone were evaluated. The test aerosols were polydisperse coal-dust particles ranging from less than 0.3 to 15 micrometers in diameter. Particle densities ranged from 1.3 to 1.4 grams per cubic centimeter. Equivalent Stokes diameters were measured using Coulter counter analytical techniques. Experimental results indicate that the penetration characteristics of the horizontal plate elutriator closely approximate the sampling efficiency curve defining the respirable fraction of the dust cloud recommended and adopted by the Johannesburg Pneumoconiosis Conference in 1959. Penetration characteris-tics of the 10-mm cyclone were evaluated at flow rates of 1.4, 1.5, 2.0, 2.5, and 2.8 liters of air per minute. The data indicate that the penetration curve obtained at 2.0 liters per minute most closely approximates the sampling efficiency curve for respirable dust recommended at a meeting sponsored by the U.S. Atomic Energy Commission in 1961.

Jan 1, 1970

By G. W. Murrie, W. P. Diamond, C. M. McCulloch

It is estimated that more than 1 trillion cubic feet of methane is contained within the coals of the Mary Lee group in Jefferson, eastern Tuscaloosa, and southern Walker Counties, Ala. Most of this methane will be encountered by mining. Coals of the Mary Lee group are presently being mined at depths exceeding 1,000 feet and will in the near future be mined at even greater depths, where the problem of methane gas affecting the mining operations will be acute. It is calculated that approximately 90 pct of the methane is at depths greater than 1,000 feet, and over half of the gas is contained within only 12 pct of the study area which is under more than 1,500 feet of over- burden. Degasification in advance of mining will increase mine safety, reduce ventilation expenditures, increase productivity, provide an additional energy source, and make it possible to mine parts of deep coalbeds that probably could not otherwise be mined.

Jan 1, 1976

By K. O. Bennington

Enthalpies of formation of three sodium titanates were determined by hydrofluoric acid solution calorimetry, The values obtained for formation from the elements at 298.15° K are -370.9±0.5 kcal/mole for Na2TiO3, -832.1±0.9 kcal/mole for Na2Ti307, and -1,510.9±1.7 kcal/mole for Na2Ti6013. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature both from the elements and from the component oxides for Na2Ti03 and Na2Ti307.

Jan 1, 1973

By E. F. Ferrell

The Bureau of Mines, U.S. Department of the Interior, studied the use of manganese sea nodules for catalytic oxidation in air of 1 pct carbon monoxide, 1 pct propane, and 1 pct methane. Catalysts were prepared from both Pacific Ocean and Atlantic Ocean nodules and compared with a platinum catalyst using a fixed-bed, steady-state microreactor with gas chromatographic analysis. Combustion temperatures with manganese nodules were 50° to 100° C lower than those with the platinum catalyst. Ion-exchange addition of rare-earth promotors to the nodule catalyst decreased combustion temperatures an additional 5° to 45° C.

Jan 1, 1978

1. In 2001, a total of 785 nonmetal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Examples of nonmetal mining operations include the mining of clay, trona, barite, phosphate rock, gypsum, talc, gemstones, and pumice. Nonmetal mines comprised 5.4% of all mining operations.1 • Nonmetal mining operations are located in all but seven states or territories (Alaska, Delaware, Maine, New Hampshire, Rhode Island, Puerto Rico, and the Virgin Islands). • The median number of operator employees per nonmetal mine was 6.1.2 • Mines producing common clay comprised 31.2% (n = 245) of all nonmetal mining operations.

Jul 1, 2003

By C. M. Frost

Crude shale oil prepared by gas-combustion retorting of Colorado oil shale was hydrogenated over a cobalt molybdate catalyst at an operating pressure of 1,000 psig, temperatures of 781° and 761° F, and liquid hourly space velocities of 0.10 and 0.05 Vo/Vo/hr, respectively. The yields of total liquid products and the amounts of nitrogen and sulfur removed were comparable with those obtained at an operating pressure of 3,000 psig and a liquid hourly space velocity of 1.0 Vo/Vo/hr. Approximately 1.5 times as much gasoline was produced at the lower pressure and space velocities.

Jan 1, 1973

By Fred Garcia, William P. Diamond

As part of its mine safety and health research program, the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, has been investigating the geologic and mining factors influencing methane gas emissions associated with longwall mining. A primary focus of this research has been the consequences of increasing longwall panel dimensions, particularly face width, in gassy coalbeds. Continuous longwall face emission monitoring studies were conducted at two adjacent mines operating in the Pocahontas No. 3 Coalbed, where longwall faces were to be extended from 229 to 305 m (750 to 1,000 ft). Average longwall pass methane emission rates for 229-m (750-ft) wide faces were 61 % (0.072 m31sec (153 cfm)) higher at the VP-3 Mine than at the VP-1 Mine. It was predicted by regression analysis of methane emissions data from 229-m (750-ft) wide faces that extending faces to 305 m (1,000 ft) would increase methane emission rates by only 7%, or 0.009 m3/sec (20 cfm), to 0.144 mysec (304 cfm) at the VP-1 Mine. In contrast, it was predicted that extending faces to 305 m (1,000 ft) at the VP-3 Mine would increase methane emissions by as much as 13%, or 0.029 mysec (65 cfm), to 0.268 dlsec (567 cfm).

Jan 10, 1999

By James H. Russell

Several solid sorbents were compared for their effectiveness in removing sulfur dioxide from flue gases. The materials were tested for the rate of sorption and capacity at about 300° C, and rate of regeneration around 700° C in thin beds and in 4-inch-diameter fluidized beds. Rates of material loss were also estimated. The sorbents tested included three samples of alkalized alumina, two samples of sodium carbonate-impregnated alumina, and one proprietary sample of porous silica impregnated with copper and iron compounds. The results showed that all the alkalized aluminas had good sorption capacities and rates, required high temperature regeneration, and suffered excessive material loss; the sodium carbonate-impregnated aluminas (1) had high sorption rates but barely adequate capacities, (2) required high temperature regeneration, and (3) suffered excessive material losses; and the copper-iron impregnated silica suffered only slight material loss and could be regenerated at a relatively low temperature, but the sorption rate and capacity were too small. None of the sorbents met all the arbitrary performance criteria that follow: sorption rate constant of 1 min-1, sorption capacity of 0.1 g sulfur per g sorbent, regeneration rate constant of about 0.075 min-1 at a reasonable temperature, less than 0.07 pct per hour material loss during operation, and a chemical life of 500 cycles.

Jan 1, 1971

By Charles E. Munroe

On March 14, 1921, an explosion occurred at about 6:15 A.~. on the premises of an iron-mining concern throug:1 which two magazines, one containing upwards of 9,000 pounds ot a high explosive of the dynamite class, and a second, 60 feet distant, containing upwards of 10,000 No. 6 detonators, were completely destroyed, and a ncratertt,? f3et deep by 30 feet in diameter, was excavated in the gro~ at ~he place whare the mag~iine containing the high explosive had been lo~ated. As a rule any eye wit~esses to the circumstances im.~ediataly preceding and d(irectly concurrent with a.c.ci.:lental ex;losions ar.e victims of s11ch explosions, and, therefore, the conclusions reached as to the cauoa. of such explosions must, perf'orce, be based aln:ost completely on circumstantial evidetJ.ce. In this iii.stance, b:ecause both the explosive and detonators were of -orov{:;d: character; because of the time of the day and the state of operations iit the·· time of the e:.q,losion; because the rerroteness of the location of the n:-1agazi::1es 1 0::1 the side of a ravine, easily admittfi of unobserved approach; beca:iise differencas existed, and because no obvious cause was at once apparent, there arose suspicfon that the explosion was not accidental.

Sep 1, 1921

By D. S. Colby, E. M. SEELEY

The total production capacity of the natural-gasoline industry increased to 27,212,000 gallons (647,905 barrels) daily on January 1, 1950, from 21,322,000 gallons (507,670 barrels) daily on January 1, 1948. The rate of growth during these 2 years averaged 13 percent per year, compared with 9 percent per year from 1946 to 1948 and 6 percent from 1944 to 1946. The total number of operable plants on January 1, 1950, was 554, 5 more than at the beginning of 1948. The number of absorption plants increased by 12, the number of cycling plants by 7, and the number of combination plants by 4. The number of compression plants and charcoal plants continued to decrease. Absorption plants accounted for 67 percent of the total capacity on January 1, 1950, compared with 62 percent 2 years previous. Eighty-two per- cent of the expansion in these 2 years was in absorption-plant capacity. Cycle plants accounted for 24 percent of the total industry capacity at the beginning of 1950, compared with 27 percent on January 1, 1948. The average daily capacity of absorption plants increased from 38,400 gallons at the beginning of 1948 to 50,600 gallons at the beginning of 1950. During the same period, the average daily capacity of cycle plants decreased from 150,200 gallons to 144,100 gallons. Texas showed the largest gain in number of plants 13 absorption, 4 compression, and 4 cycling plants. The State accounted for 67 percent of the gain in capacity and on January 1, 1950 had 50 percent total national capacity. Louisiana followed with 7 additional plants. Pennsylvania reported 14 and West Virginia reported 13 fewer plants than in 1948. Most of these reductions were in the number of compression plants.

Jul 1, 1950

By Ronald D. Hill, Elmore C. Grim

The United States is richly endowed with mineral resources. However, mineral recovery by its very nature, involves a destructive process, Figures 1 and 2. In the past, mining practices were all too often conducted with the purpose of removing minerals by the simplest and cheapest method possible, without plans for the preservation of land, water, and air, and with too little consideration for the rights of others. A mining company is in business to make a profit, but every company, regardless of the nature of its business, has moral obligations to reduce its undesirable effects on the environment and to safeguard the rights of others. The problem of environmental degradation caused by surface mining is widespread and serious. Minerals in some form occur in each of the 50 States and several States are extensively mined. Data on the acreage disturbed in the United States, by commodity and State are presented in Table 1. Thirty-one States have laws regulating surface mining, (Table 2). Briefly reviewed in Appendix A-1 are the basic provisions of State laws governing surface mining. It can be seen that these laws vary considerably from State to State owing largely to the mining conditions within that State. Of the 24 coal-producing States, only three (Alaska, Arizona, and Utah) do not regulate strip mining. Even the states that are often cited as models of comprehensive regulations still have problems minimizing environmental damages. Uncontrolled surface mining presents a situation as critical to the well-being of the society as any it has ever faced. Many mining activities have imposed huge social costs on the public at large. These costs are long-range and are in the form of stream pollution, floods, landslides, loss of fish and wildlife habitats, unreclaimed land, erosion, and the impairment of natural beauty. In a 1965 Department of Interior study,(1)it was estimated that of the 25,000 miles (1+0,225 kilometers) of contour bench in Appalachia, approximately 1,700 miles (2735 kilometers) are affected by massive landslides. Additionally, 1+800 miles (7723 kilometers) of streams and 29,000 surface acres (11,716 hectares) of impoundments and reservoirs have been seriously affected by coal strip mining operations in the United States.

Jan 1, 1974

By John W. Adams

The present status of the National Bureau of Standards program is that many magnetic tapes of analog data have been recorded in four major mines. Each mine uses different types of equipment. In addition, some surface measurements of noise have been made at two additional mines. Two types of recordings have been made: (1) broadband measurements for spectral plots and (2) narrowband measurements for amplitude probability density (APD) plots. Only data from one mine (Robena #4) has been processed and was, presented at this workshop. The short-term goals are: (1) finish processing data from the other mines, (2) establish or reduce measurement system uncertainties, (3) put Robella report into final form for distribution, and (4) hold a review to determine what has been done, to distribute and to interpret the preliminary data, and to determine what still needs to be done. Long-term goals are: (1) complete final reports on each of the mine trips, (2) establish techniques for predicting noise in mines already visited and establish uncertainty bounds for these predictions, and (3) establish techniques for predicting noise in mines that have not been visited (but that use similar equipment to those visited) and also establish uncertainty bounds for these predictions. Specific factors or formats to be presented include: (A) For underground broadband measurements: 1. 300 Hz to 100 kHz spectral plots 2. 300 Hz to 384 kHz spectral plots 3. 300 Hz to 192 kHz spectral plots 4. 300 Hz to 6kHz (subject to change to 3 or 12 kHz) spectral plots (B) For surface broadband measurements: 1. 300 Hz to 6 kHz (or 12 kHz) spectral plots 2. 300 Hz to 3 kHz spectral plots (C) For underground narrowband measurements : 1. APD plots at 12 frequencies from 10 kHz to 32 mHz of magnetic field strength 2. R. M.S. and average values will be calculated based on time averaging for these plots (D) Sample spectral measurements of: 1. Roof-bolt voltages 2. Trolley wire-to-rail voltages 3. Phone line currents

Jan 1, 1973

By Anthony T. Lannacchione, Donald G. Puglio

The Bureau of Mines developed data on the methane content of the Hartshorne coalbed, Haskell and Le Flore Counties, Okla. The methane content is calculated to be between 1.1 and 1.5 trillion cubic feet, based on an estimate of total coal in place of 2.4 to 3.2 billion short tons. Methane increases with depth, but the rate of increase decreases with greater depths. Degasification in advance of mining is recommended for all mines operating at depths greater than 500 feet to reduce hazards and methane explosions, decrease mine ventilation costs, and conserve the natural gas that would be otherwise wasted.

Jan 1, 1979

By D. S. Colby

The productive capacity of natural gasoline and cycling plants in the United States or. January 1, 1954, was 926 thousand barrels per day, according to the Bureau of Mines biennial survey. This represented an increase of 114 thousand barrels per day during the 2-year period since the last survey. In the previous 2-year period, capacity had increased 164 thousand barrels per day. The total number of plants increased from 521 on January 1, 1952, to 535 on January 1, 1954. The number of operating plants increased from 506 to 521. The major increases in capacity took place in Texas, Illinois, Oklahoma, Louisiana, and New Mexico, with the absorption-type plant continuing to account for most of the new construction. In 1954, however, 6 plants reported using a refrigeration process whereas only 1 plant reported this in 1952. The number of operating compression-type plants continued to decline and combination plants showed a decline this year because a number of these plants were reclassified as absorption-type.

Jan 1, 1954

By A. Dale Marcy, Pamela L. Drake

Workers who perform routine welding tasks are potentially exposed to fume that may contain manganese. Manganese may cause respiratory problems and is implicated in causing the occurrence of Parkinson-like symptoms. In this study, a field colorimetric method for extracting and measuring manganese in welding fume was developed. The method uses ultrasonic extraction with an acidic hydrogen peroxide solution to extract welding fume collected on polyvinyl chloride filters. Commercially available pre-packaged reagents are used to produce a colored solution, created by a reaction of manganese(II) with 1-(2-pyridylazo)-2-naphthol. Absorbance measurements are then made using a portable spectrophotometer. The method detection limit and limit of quantification (LOQ) were 5.2 mg filter-1 and 17 mg filter-1, respectively, with a dynamic range up to 400 mg filter-1. When the results are above the LOQ for the colorimetric method, the manganese masses are equivalent to those measured by the International Organization for Standardization Method 15202-2, which employs a strong acid digestion and analysis using inductively coupled plasma-optical emission spectrometry.

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

APPENDIX G TABLE IX MINE A 1 General Total Employees 3000 Maximum No, of Men Underground/Shift 800 Shifts/Day 3 Type of Ore Copper Daily Production (TPD) 25,000 Mining Method Room and Pillar Vein Dip/Thickness l0°/l5 ft Number of Levels/Max Depth 1/0 to 1800 ft 2 Haulage, Conveyances and Travelway Main Haulage Rubber Tire/10 miles belts Man-Ways - Typical Route of Travel to most Remote Sites Rubber Tired Vehicles Hoists - Capacity/Speed/Depth Depth under construction 3 Ventilation 2,500,000 cfm - 5 surface fans 4 Compressed Air N/A cfm 10" and 12" lines 5 Incendiary Storage 2 day powder 1000 gal fuel oil 6 Communications 1 complete system - all shops, dinner areas, and feeder/breaker stations 2 partial systems 7 Escapeway- Systems Man Check System Section boss log and punch cards Alarm System Mine phones with paging system Posting of Escape Route Maps No Escape Signs Every intersection, fluorescent paint Evacuation Drills 2/yr/shift Refuge Chambers - 1 cinder block - No longer required

Jan 1, 1976

By Richard J. Mainiero

The Bureau of Mines has developed a prototype nonincendive explosive rock-breaker charge that can be fired unconfined in underground bituminous coal mines without the danger of igniting a flammable atmosphere that might be present. At present, unconfined shooting in underground coal mines is prohibited, but there are situations where the use of such shots would yield an overall improvement in safety. The charge consists of 1-1/2 lb of permissible water gel explosive in the form of a short cylinder 7 inches in diameter and 7/8 inches high, surrounded by a 1 1/2-inch-thick layer of damp salt, and encased in latex rubber reinforced with cheese cloth. The latex rubber housing provides a charge package that is strong enough to resist rough handling yet is pliable enough to conform to an irregular stone surface. A charge of this shape was found to be more effective at breaking rock than charges with lined or unlined cavities. Incendivity tests in a gallery have shown that the prototype charge will not ignite a flammable methane-air atmosphere when fired. Rock- breaking tests made with limestone boulders indicate that the charge will satisfactorily break stone slabs weighing 1 to 2 tons, and that two or more charges might be effective for slabs weighing up to 10 tons. In cooperation with the Mine Safety and Health Administration (MSHA), a test protocol for the certification of these charges as "permissible" for use in flammable atmospheres is being developed.

Jan 1, 1982

By J. E. Tiffany, Z. C. Gaugler

This supplement has been prepared to furnish information on amendments to the regulations that were approved by acting secretary of the Interior on June 24, 1946, while this report was in the press. Page 14, item 2, and page 20, item 4, have been amended by the addition of the following footnote: "Pending the development of a satisfactory multiple-shot permissible blasting unit, a blasting unit of Type II, Class A, covered by Federal Specification WB 411, December 31, 1941 (with or without Amendment 2, June 16, 1945), may be used until Decem- ber 31, 1947. Should a satisfactory multiple-shot permissible unit be made available prior to that date, this interim approval may be terminated." Page 14, footnote / has been amended to read as follows: "The use of charges over 1-1/2 pounds and not exceeding 3 pounds is approved pending further investigation. The approval, which may be withdrawn at any time, expires December 31, 1947, unless renewed. For charges over 1-1/2 pounds, the following additional requirements must be observed: (1) Shot holes must be 6 feet or greater in length. (2) Explosives must be charged in a continuous train with no cartridges deliberately deformed or crushed, with all car- tridges in contact with each other, and with the end cartridges touching the rear of the hole and the stemming, respectively. (3) The permissible explosive must be one showing toxic gas omission that will place it in either Class A or Class B."

Jan 1, 1947

By Robert Blickensderfer

Equipment and procedure for the continuous roll bonding of metal strips are described. The reels, mill rolls, and furnace were located within a vacuum chamber capable of operation at a residual gas pressure of 1 x 10-4 to 1 x 10-5 torr. Several metals were successfully clad at rolling temperatures of 930° to 1,050° C in lengths up to 120 ft. The bimetals that were clad included stainless steel to carbon steel, molybdenum and nickel to stainless steel and carbon steel, and titanium to carbon steel. Bend tests of bond integrity are described, and microstructures of the interfaces are presented. The amounts of brittle intermetallic phases formed at the interface are minimized by this cladding method.

Jan 1, 1980