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By Ted C. Briggs

A removable-jacket distortion apparatus was constructed and used to measure distortion coefficients for two high-pressure vessels. The measured distortion coefficients were used to compute distortion coefficients for volumes VI and (V1+V2) of a 1,000-atmosphere Burnett compressibility apparatus for the temperature range 0° to 75° C. Young?s modulus for Armco 17-4 PH stainless steel, heat treated to condition H1150-M, was computed from experimentally determined distortion coefficients. A 10-to 14-percent correction to the values obtained for Young's modulus may be required because pressure vessel end effects were neglected. The distortion coefficients of the compressibility apparatus are believed to be accurate to about 1 percent.

Jan 1, 1970

By T. Estelle Gardner

The Bureau of Mines made enthalpy measurements on sodium bromide and sodium iodide in the temperature range 400° to 1,200° K using an ice calorimeter. Equations representing enthalpy as a function of temperature were derived from the data by the method of least squares. These equations were used to calculate smooth values of heat capacity, enthalpy, and entropy at 50° K intervals from the ice point to 1,200° K. The melting point determined for sodium bromide was 1,020° K; the melting point of sodium iodide was 934° K. The heats of fusion of sodium bromide and sodium iodide were calculated to be 6,270 and 5,680 cal/mole, respectively.

Jan 1, 1967

By John S. Berber

Bureau of Mines research on the production of phthalic anhydride by vapor phase oxidation of hydrocarbons began at Morgantown, W. Va., in October 1960. For these preliminary studies, a known solution containing naphthalene and 1-methylnaphthalene was used. In another series of tests, pure naphthalene was dissolved in different solvents. A series of investigations was conducted with the neutral oil fraction (210° to 270° C) of a low-temperature tar obtained from the Texas Power and Light Company's low-temperature carbonization unit. The neutral oil fraction was first dealkylated, and then the product was distilled into 210° to 250° C and 250° to 270° C fractions. These two fractions were then subjected to catalytic vapor phase oxidation. Although a number of catalysts was tested, most of the experiments were made using 9 percent vanadium pentoxide on inert alumina. The activity of this catalyst did not decrease after 162 hours at 1,030° F. Studies were conducted over a temperature range from 610° to 1,180° F. An operating temperature of 1,030° F yielded 47.50 percent of phthalic anhydride from a synthetic mixture of naphthalene and 1-methylnaphthalene. The highest yield (84.40 percent phthalic anhydride) was obtained with naphthalene dissolved in toluene and also with naphthalene dissolved in methyl ethyl ketone. With a 210° to 250° C fraction the highest yield of phthalic anhydride obtained was 12.32 percent at a temperature of 900° F, and, with a 250° to 270° C fraction, it was 15.80 percent at a temperature of 875° F.

Jan 1, 1963

By R. V. Ramani, C. B. Manula, A. Owili-Eger

That a close analogy exists between the flow of air in mines and the flow of current in electrical networks- has been known for a long time. The laws that have been used to solve series and parallel electrical circuits have been used to solve for the equivalent resistance in mine ventilation problems. Kirchhoff's current and voltage laws have also been adopted in solving mine ventilation network problems. It will be best to define a few terms here regarding networks, and with reference to Figure 1, these definitions can be elucidated. Figure 1 can be represented by the network in Figure 2 without losing any essential details. 1. A junction is a point where two or more airways meet. 2. The segment of a roadway connecting any two junctions is known as a branch. 3. A mesh is a closed path through the network. In the above network, B, C, D and F are the junctions, CF and CD are two of the branches and CFDC is a mesh. Kirchhoff's current law states that the sum of currents entering a junction. Applying this law to the junctions in the ventilation network, one obtains for junctions C and F, the following relationships: JUNCTION C: Q1 = Q4 + Q3 (1) JUNCTION F: Q2 + Q3 = Q5 (2) Similar relationships can be drawn for other junctions. Kirchhoff's voltage law states that in any complete electric circuit, the algebraic sum of the emf's must equal the algebraic sum of the voltage drops. In mine ventilation, the square law (Atkinson's

Jan 1, 1975

By A. J. Barry

[This is the third report related to fundamental retail roof-bolting research in underground mines (1, 2)3/ and describes an investigation of the torque-load relationship for 3/ -inch, expansion-type mine roof bolts. In a previous investigation the relationship between torque and bolt load was established for 1-inch slotted-type bolts (1). The two types of bolts differ in diameter and method of tightening and consequently may exhibit different torque-load behavior. The 1-inch bolt is tightened by turning the nut, the 3/4-inch bolt by rotating the beaded bolt itself. Experience indicates that roof bolts should be tightened to moors satisfactory anchorage sand to minimise nag of tie roof over the mine opening. The generally accepted means for determining the bolt load is to see a torque wrench to measure he torque applied in tightening the bolt and, from a predetermined relationship between torque and molt load, to, determine the corresponding bolt load. Because frictional effects may vary between one type of shell assembly or bolt and others, 7 types of expansion shell units and 3 types of 3/4-inch-diameter, mild steel bolts were tested.]

Jan 1, 1954

By Phyllip Worley, Frank E. Chase, Christopher Mark

The Harris No. 1 Mine, located in Boone County, WV, has been longwalling the Eagle Coalbed for over 30 years. Harris has experienced numerous interactions associated with the extensive room-and-pillar and longwall mining operations which have been conducted in the overlying No. 2 Gas Coalbed. The problems have included roof falls, excessive rib sloughage, and gateroad and bleeder entry closure. A detailed evaluation of the multiple seam experiences at Harris No. 1 Mine was conducted as part of the National Institute for Occupational Safety and Health (NIOSH) nation-wide multiple seam mining case history data base. One observation from the Harris gateroad case histories was that smaller, critically loaded, upper seam pillars seemed to cause more severe ground conditions than did wider pillars. The LaModel program was used to investigate this supposition, and the results confirmed that “critical” sized pillars do transmit the highest amounts of stress to adjacent seams. In addition, the data suggest that the probability of a major multiple seam mining interaction increases when the depth of cover is 1,000 ft or greater and when the Eagle seam pillars have a Analysis of Longwall Pillar stability factor less than 1.50.

By Harry R. Nicholls

As part of the pre- and post - shot mine examination at Project GNOME , acceleration data were recorded underground from a series of chemical explosive shots . The cube root of the charge weight was used to scale acceleration and distance because charge weight was not constant . Regression analysis of particle acceleration - distance data gave the following propagation equation : A W1 /3 = 5.10 x 105 ( R / W¹ / 3 ) −2 .43 The quantity A W1 /3 is scaled particle acceleration expressed in g's - lbs¹ / 3 , and R/W1 /3 is scaled distance expressed in ft / lbs¹ /3 Data obtained from the nuclear explosion were scaled and fall within one standard deviation of the calculated propagation law for the smaller shots . Cube root scaling laws were adequate to group acceleration data from explosive charges varying by a factor of more than 1 x 10 in charge weight and over shot - to - gage distances varying from 100 to 46,000 feet . Data obtained from a series of small tests provided sufficient data from which reliable predictions of acceleration could be made for the large nuclear explosion .

Jan 1, 1964

By O. C. Blade, E. L. Garton

Louisiana is one of the major oil-producing States of the country. Commercial production of crude oil in the State began in 1902 and has increased to an estimated output of 157,409,000 barrels in 1945, which is the maximum production up to this time and places the State fourth in the nation. The cumulative production for Louisiana through 1944 is 1,544,481,000 barrels, and, adding the output for 1945, the total to January 1, 1946, is 1,681,890,000 barrels. Data on annual production of crude oil in Louisiana and tentative statistics for 1945 are given in table 1. The large production of crude oil in Louisiana and the present trend to utilize petroleum in accordance with its general characteristics make it increasingly important to present analytical data for crude oils. This report is the fifth of a series presenting such data obtained on crude oils from Louisiana according to the procedure used by the Bureau of Mines. Individual analyses are given for 82 samples from 64 fields; many of the samples are from recently discovered fields, and some are from new producing formations.

Dec 1, 1946

By M. B. Cooke, A. D. Bauer, E. W. Dean

The Bureau of Mines is collecting and analyzing representative samples of crude petroleum from all the producing fields in the United States , and the results are being published in a series of reports that are preliminary to the issue of a bulletin covering the entire survey . The bureau has recently completed a survey of crude oils from the Kansas district . In all 27 samples were collected and analyzed , under the direction of A. W. Ambrose , chief petroleum technologist of the Bureau. Valuable assistance was received through the cooperation of oil companies operating in the State , especially the Prairie Pipe Line Co. , and the Empire Pipe Line Co. The present report issued as Serial 2322 , on the Kansas crudes , forms the fifth of the series . Of the four previous papers , the first ( No. 2202 ) deals with crudes from the Eastern fields of the United States , the second ( No. 2235 ) with crudes from the Rocky Mountain district , the third ( No. 2290) gives additional data , cn viscosities and pour tests , for the crudes from these two fields , and the fourth ( No. 2293 ) covers the fields of northern Texas , northern Louisiana , and Arkansas . The details of the methods of collecting samples , making laboratory tests and interpreting results , have been discussed in these earlier reports . It has also been pointed out that the only adequate method of interpreting analyses of crude oils is to compare the individual reports with the analysis of some crude oil that is familiar to the operator . For this reason , no comprehensive discussion of the results of the Kansas survey is attempted, although some general statements may be made .

Feb 1, 1922

By C. M. Frost

Crude shale oil produced by gas combustion retorting of Green River oil shale was hydrocracked over a cobalt molybdate catalyst at operating pressures of 500, 1,000, 1,500, and 3,000 psig, an operating temperature of 8900 F, and a liquid hourly space velocity of 1.0. Hydrogen feed rate was maintained at 6,000 scf/bbl. The volume-percent yields of total liquid product were directly proportional to the operating pressure. Weight-percent conversion and volume-percent yields of gasoline were directly proportional to the log of the operating pressure. Catalyst deposit percentages were inversely proportional to the log of the operating pressure. Nitrogen and sulfur removal rates as well as saturation of the liquid products increased as the operating pressure was increased.

Jan 1, 1973

By BUREAU OF MINES

The Bureau of Mines in its investigations of respiratory apparatus for use in mines and allied industries, tests equipment that is voluntarily submitted by manufacturers in accordance with published schedules of tests. These tests are designed to insure that the equipment has the minimum require- ments for safety in use. Approval certificates are issued for apparatus that meets the bureau's specifications, and the memfacturer is permitted to mark his equipment with a seal showing that it has been approved as "Permissible." A complete list of permissible self-contained oxygen breathing apparatus, gas masks, and hose masks tested before July 1, 1930, was published in Bureau of Mines Information Circular 6362.1 The present list includes all equipment tested and approved up to and including April 1, 1931.

Sep 1, 1931

By Leonard Obert

This report describes an inexpensive triaxial equipment for testing 2-1 / 8- , 4- , and 5-5 / 8 - inch - diameter rock cylinders subjected to loading conditions comparable to those encountered in underground mining . Only minimal specimen preparation is required . The maximum axial load that can be applied is 250,000 lb , which corresponds to an axial stress of 70,000 psi for the 2-1 /8- inch- diameter specimen . The maximum radial pressure that can be applied is the same for each specimen diameter ; namely , 10,000 psi . The mechanical parts in this equipment are relatively easy to machine and fabricate . The cost of all parts , including the 250,000- lb hydraulic press but not including labor costs , was approximately $ 1,000 .

Jan 1, 1963

By W. A. Heitbrink, M. Schmitz, J. A. Organiscak, A. B. Cecala, E. Ahrenholtz

Operator cabs on a front-end loader and a rotary rock drill were retrofitted with ceiling mounted heating1AC units and air filtration systems. Subsequently surface coal mine field studies were conducted to evaluate the respirable dust protection these retrofitted cab systems offer to the equipment operator. A significant 10: 1 respirable dust protection factor (ratio of outside to inside cab dust levels) was measured for the front-end loader cab with positive pressurization of the cab interior. Whereas an insignificant 3: 1 respirable dust protection factor was measured for the drill cab without positive pressurization of the cab interior. These results indicate that achieving positive interior cab pressurization with retrofitted cab filtration systems is a key element to their dust control effectiveness.

By D. E. Kirby

In the preparation of beryllium-copper alloys by fused-salt electrolysis, beryllium was electrowon from beryllium oxide dissolved in fluoride electrolytes and deposited on copper cathodes. At 880° to 1,030° C, deposition was on solid cathodes. Beryllium deposited on the copper, forming a liquid alloy that dripped from the cathode. Dripping alloys containing 3 to 4 weight-percent beryllium were produced with as high as 90 percent cathode current efficiency, by electrolysis at 910°.C. To prepare alloys of higher beryllium content, attempts were made at depositing beryllium on liquid copper cathodes. These efforts were generally unsuccessful, although alloys containing as much as 12 percent beryllium were prepared by this method. At temperatures of 1,100° to 1,300° C, requisite to maintaining beryllium-copper compositions as liquids, the beryllium reacted with cell structures.

Jan 1, 1972

By John W. Buch

"INTRODUCTION The Ruhr coal basin is estimated to cover an area of more than 1,000 square miles. Here, the total thickness of the coal bearing formation (Carboniferous) is 10,500 feet, and drilling-hole have revealed 92 coal beds with a total thickness of 262 feet. 6/ Beds pitch from 0 to 90 degrees and about 70 percent of the wartime production came from beds that pitched less than 30 decrees. 5/For example at the Minisiter Stein mine, there are 24 minable coal beds ranging from 80 centimeters. (2 ft., 7 1/2 in.) to 250 centimeters (8 2 1/2 in.). The vertical thickness of the measures is 1,000 meters (3,200 ft.), and at this mine the deposits are covered with 150 meters (500 ft.) of surface wash. The cross section (fig, 1) at Fritz mine; Hoesch, A.G., Essen, Ruhr, is characteristic, The mines have been developed and worked to vertical depths of 2,000 to 2,500 feet by vertical shafts; main-level intervals are 500 to 700 feet apart. Haulage roads are straight, driven in rock, and centered as nearly as practical between property boundaries. Levels are sectionalized by driving crosscuts at right angles to the main haulage road on 800- to 900-foot centers. The roads are the main transportation arteries for the use of trolley or Diesel locomotives. A plan of the sixth main level (fig. 2) at the Bruchstrasse mine; Gelsenkirchener A.G., Bochum, illustrates main-level development and,sectionalizing with crosscuts. The cross section in figure 3 is that of the fourth crosscut west at the same mine."

Oct 1, 1946

By Roy L. Wilfong

Surface area measurements were conducted on cadmium sulfide powders following thermal treatments at temperatures up to 500° C and treatment times up to 1 week. Thermal treatments at temperatures up to 300° C produced no significant changes in the surface area of the powders even after 1 week of exposure. At 500° C some decomposition of the cadmium sulfide occurred.

Jan 1, 1970

The current procedure for measuring the concentration of respirable coal mine dust is as follows. Each filter is preweighed by the filter manufacturer to ±0.1 mg. Following sampling with the Coal Mine Dust Personal Sample Unit (CPSU) at 2.0 L/min, the filter with coal mine dust is sent to MSHA for weighing. The current MSHA procedure for weighing respirable dust samples uses a Mettler Model AE163 analytical balance in conjunction with an automatic weighing system with a precision of ±0.02 mg [Tomb 19901. Each balance is calibrated twice per day. Quality control for the automatic weighing system includes the systematic weighing of one in eight filters on a second Mettler AE163 balance. Tolerance is set at ±0.1 mg between the two weighings of the same sample. Weights are truncated at the 0.1 mg level (e.g., 3.457 mg is truncated to 3.4 mg) [Bowman et al. 19851. The difference of the two truncated weights is then recorded as the weight of coal dust deposited. The respirable concentration (mg/m3) is computed by multiplying by a correction equal to 1.38 and dividing by the volume of air sampled (2.0 L/min x sampling time [min]).

Jan 1, 1997

By G. B. Atkinson

The Bureau of Mines, in cooperation with McDermitt Mine, investigated a method for recovering mercury metal from mercury sulfide flotation concentrate by a hydrometallurgical technique. This preliminary report shows the feasibility of leaching mercury with a cupric chloride solution and electrowinning mercury from the solution. Proposed chemical reactions are shown in equations 1 through 3: 2CuC12 + HgS + 2CuCl + HgC12 + S°; (1) electrolysis HgC12 ?Hg + C12; (2) 2CuC1 + C12 ? 2CuC12. (3) A bench-scale leaching-electrowinning apparatus capable of treating 2.36 kg of sulfide concentrate in 11 days was operated continuously. An acid chloride solution containing, in grams per liter, 70 Ca, 60 Cu, 30 Fe, and 80 Hg was used as both leachant and electrolyte; 99.5 pct of the mercury was solubilized from the sulfide concentrate. Electrolysis of the leaching solution recovered mercury metal at an average current efficiency of 32 pct and an average energy consumption of 1.2 kwhr/lb Hg. Results from a preliminary economic evaluation indicated that a plant producing 31,500 flasks of mercury per year would have a capital cost of $3.7 million and an operating cost of $62 per flask of mercury.

Jan 1, 1983

By Steven J. Page

Overexposure to airborne respirable crystalline silica dust can cause disabling or fatal respiratory disease, and mine worker exposure to silica dust continues to be an ongoing occupational health concern. Exposures of surface coal mine rock drillers to respirable crystalline silica are of particular concern. On surface coal mine drills, bailing air flushes the cuttings out of the drill hole. Conveyor belting material is typically used to fabricate a shroud around the drill deck in an effort to contain the drill dust so that it can be captured by a collector. Dust leakage from the drill shroud is usually the worst dust source problem on most drills. The focus of this work is drill shroud dust leakage and the relationships of various drill parameters on this leakage. Experimental data were obtained and used in combination with dimensional analysis to establish these relationships. In general, it is found that airborne respirable dust (ARD) concentrations vary in a direct relationship with shroud leakage area and in an inverse relationship with drill deck cross sectional area and shroud height. This work expands the testing and dimensional analysis previously reported for collector/bailing air flow ratios ranging from 2:1 to 4:1 to include ratios approaching 1:1. A semi empirical mathematical model has been developed and expanded to describe ARD generation on surface coal mine drills. Geometric parameters included are drill deck height and cross sectional area, shroud leakage associated with the deck shroud, and the operational parameters of bailing airflow and dust collector airflow. The relationships can be described by logarithmic functions and yield predictive ARD values, which fall in the range measured on operating drills for collector/bailing air flow ratios greater than 2. However, at values of collector/bailing air flow ratios of approximately 1.1, the amount of ARD shows minimal response, if any, to drill deck shroud improvements that do not result in near perfect seals. This is a condition that can occur in actual operation and is a substantially different result than previously expected and reported. Application of these results should provide mine operators with sufficient information to determine (1) the relative magnitude of their dust emissions, (2) where they should focus their efforts to reduce ARD emissions and (3) the improvement they could reasonably expect to achieve. Given that exposures of surface coal mine rock drillers to respirable crystalline silica are of particular concern, substantial reductions of airborne silica dust during drilling may be estimated and achieved through use of the analysis presented. Keywords: drill; dust; model; dimensional analysis

Jan 1, 2008

By Edward P. Barrett

[Iron oxides, when reduced at temperatures below 900° form a dark gray substance, very porous bait otherwise in almost the same form as the original particles. In the temperature ire range of 1,000 to 1,100° the product is pertly sintered but still shows the outlines of the original particles. Those products are known as "sponge iron." At temperatures of 1,100 to 1,2000 the metallic iron begins to flow together and to a semifused, pasty, porous mass called a "bloom," which can he worked under a hammer to form a product similar to wrought iron; it contains slag inclusions and is too low in carbon to make steel. If the temperature is 1,300 to 1,300°, part of the iron will fuse enough to absorb more carbon. The dissolved carbon lowers the melting point and still more carbon is absorbed. The melted portion acts a flux for the unmelted metallic particles until the entire mass becomes a high-carbon fluid known as "cast iron." Sponge iron was probably the form in which the first iron was recovered from the ores. As early as the eighth century the Catlan forge3 developed into a low-shaft furnace known as the "high bloomary," in which iron eras produced in the form of a pasty mass. In 1340 the first blast furnace was built in Belgium. The greater part of the iron was made into wrought-iron blooms by crude puddling processes. Charcoal was used as the fuel until tie latter part of the 17th century when coke was used in England. In 1865 Bessemer built his first converter in. England, and within a few years the Siemen's regenerative open-hearth furnace was developed, also in England. Enormous expansion in the metallurgy of iron followed. The idea of "direct processes" for the production of iron arid steel has persisted throughout all this time. The production of steel from sponge iron has theoretical advantages over the present-day standard methods, and handreds of so--called "direct processes" have been proposed or tried during the past century.4]

Jan 1, 1929