Search Documents

By Larry P. Jackson

As part of the current research effort in shale-oil chemistry conducted by the Federal Bureau of Mines, reduced chlorophyllins were prepared and pyrolyzed in an effort to identify the role of plant pigments and their decomposition products in the nitrogenous compounds found in the product of oil-shale pyrolysis. The properties of the chlorophyllin pyrolysates were related to the composition of the reduced chlorophyllins with particular emphasis on the amount and types of nitrogen compounds formed. A comparison based on the types of nitrogen compounds present was made betvJeen shale oil and the chlorophyll in pyrolsates. In order to make this comparison, a sample of shale-oil light distillate was separated into polar and nonpolar fractions, and a careful examination of the polar fraction was conducted to obtain an accurate picture of the types of nitrogen compounds present. The information gathered from these studies was used to evaluate reduced chlorophyllin as a model of oil-shale kerogen insofar as the production of nitrogen compounds was concerned. The results indicate that the reduced chlorophyllin does yield nitrogen products which are directly related to the nitrogenous compounds in shale oil, and it therefore represents a good model of shale-oil kerogen.

Jan 1, 1975

By George M. Lucich

This report describes a sensitive, proportional temperature controller developed by the Bureau of Mines that is useful in the temperature range from 40 to 400° C with an accuracy of ±0.10 C. A temperature controller of this kind is potentially useful for regulating temperatures in air chambers, liquid baths, furnaces, and reaction vessels, and for other applications. This instrument was developed to control the duration and temperature of the heating cycle of a charcoal-filled adsorber that is part of a special helium analyzer used by the Bureau. The controller was made from commercially available parts, and can be easily modified to provide continuous temperature control. The circuit is solid state and employs no electromechanical devices. Over a 2-year period of use as a component of the special helium analyzer, this temperature controller performed successfully and required no maintenance.

Jan 1, 1979

By W. A. Calhoun

A method for concentration of the nickel-cobalt-bearing mineral, siegenite, from a table middling has been developed by the Bureau of Mines at Rolla, Mo. The table middling is composed of a complex series of sulfide minerals, occurring in mill operations in the southeast Missouri "lead belt." In these operations the siegenite is lost as a separate concentrate, being diverted to other products. The procedure also includes recovering commercial-grade concentrates of copper and lead. A low-grade zinc concentrate, a potential coproduct, was also made.

Jan 1, 1962

By Gregory P. Cole, Jeffrey Shawn Peterson

The Pittsburgh Research center3 conducted research to study and improve electrical fault detection on coal mine direct-current (dc) trolley systems. A suspended trolley line delivers power at voltages of 300 or 600 V dc to the haulage equipment and other loads. Roof falls or other accidents may force the trolley line down so that an electrical fault current may flow between the trolley line and rail. This fault current could result in localized heating, arcing, and perhaps fire. Such faults are not always preventable by the existing circuit protection because the current magnitude is well below typical operating levels of the trolley system. The research discussed in this report studies the applicability of computerized signal analysis techniques to solve this problem. Tests were conducted at cooperating coal mines. Measurements were taken during normal loading of the trolley system (light, intermediate, and heavy traffic), during induced fault conditions (arcing and bolted faults), and during transitions between the two. These data were then used to train and test a microprocessor-based fault detection algorithm. Later, field tests of the detection algorithm found that it correctly classified the state of the trolley system greater than 95% of the time.

Jan 1, 1997

By Rose L. Ballard

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are tables that show the principal nonfuel mineral commodities exported from and imported into the United States, and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of volume I and in the State chapters of volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1982

This Volume documents the Phase 111 effort on the Seismic Detection and Location of Isolated Miners on Contract H0122026 undertaken during the fall of 1972 by a task team composed of ADL staff and several seismic consultants. The team was assembled specifically to work together on complementary tasks, at an accelerated level of effort for four months, to meet the Bureau of Mines' time schedule for obtaining independent, objective, technical judgments regarding seismic methods and systems for detecting and locating isolated miners. The impetus for this work resulted from a compilation and analysis, during the first half of 1972, of new experimental data obtained from a series of in-mine field tests conducted by Westinghouse Corp .+ using the CMRSS* interim seismic location system. The Bureau of Mines took advantage of the availability of these new data to reassess the potential and limitations of various seismic methods and systems, and to direct its seismic system improvement program accordingly. ADL assisted the Bureau in this reassessment by drawing on the skills of seismic consultants from industry, universities and government, to supplement the skills of the ADL project team. The consultants were principal resources of broadly-based and detailed technical expertise in the areas of seismic signal-source and signal-propagation characteristics, natural and cultural seismic noise, seismic sensors and field instrumentation, seismic signal and data processing for detection and location, and overall seismic system utilization in the field under operational emergency conditions. Specifically, the participating consultants were: F. Crowley, Air Force Cambridge Research Laboratories ; W. Dean, Teledyne Geotech, Alexandria Laboratories; R. Greenfield, Pennsylvania State University; J. Kuo, Columbia University; D. Peters and R. Crosson, University of Washington; and F. Pilotte, U.S. VELA Seismological Center. The principal ADL participants were J. Ginty, R. Lagace, M. Roetter, and R. Spencer.

Jan 1, 1974

By Dennis R. Dolinar

Screen material in the form of welded wire mesh and geogrids are used in underground coal mines to prevent the fall of small pieces of rock from the roof between roof bolts. Further, if the screen is installed during the production cycle, roof fall injuries can be reduced significantly. Therefore, the National Institute for Occupational Safety and Health (NIOSH), because of the safety implications, conducted an evaluation of screen materials commonly used in U.S. coal mines to determine their support characteristics and identify the parameters that could affect their performance with respect to controlling the fall of rock from the roof surface. To evaluate the load and stiffness characteristics of the screen, a test frame was designed and installed in the Mine Roof Simulator (MRS) at the NIOSH Pittsburgh Research Laboratory (PRL). With this test set up, the screen is bolted at four corners of the frame and a center load is applied. The test set up allows for up to 20 in of screen deflection while the load and screen defection are continuously recorded. A series of tests were conducted to evaluate the effects of various parameters such as bolt tension, the type of load bearing surface and the size of bearing plates on welded screen performance. The most common screen material used in U. S. coal mines is an 8-gauge wire welded in a 4-by-4-in spacing or aperture. The peak screen load was normally limited by wire breakage. The conditions at the bearing plate influence the nature of the wire breakage. However, the screen stiffness was controlled by slippage at the bearing plates, and by weld and wire failure. The size of the bearing plate had a significant effect on the performance of the welded screen. Therefore, the design capacity of the 8-gauge screen is evaluated based on plate size. For a 6-by-6-in bearing plate the average peak load is 2,900 lb with a stiffness of 250 lb/in. For an 8-by-8-in bearing plate, the average peak load is 4,500 lb with a stiffness of 430 lb/in. These test results are based on a 4-by-4-ft bolt spacing. A geogrid mesh was also tested.

By Ronald S. Conti

Fire is a major concern for those who work in underground mines. A mine fire can occur at anytime and often results in a partial or total evacuation of mine personnel and could result in the loss of lives. Therefore, having a workforce that is well trained to prevent, detect, and fight a fire is important. This paper focuses on responders’ preparedness for fire. Responders in this context are considered the entire workforce and are categorized as first, second, and sustained responders and evacuating miners. Quality training enhances ones awareness of mine fire hazards and promotes self-confidence in combating fires and responding to emergencies. Early warning systems and other escapeway aids such as a through-the-earth signaling and communication system, lasers and strobe lights are also addressed. The technological advancements that have been made can improve the state-of-preparedness for responders to underground emergencies and increase the chances of survival for escaping personnel.

By Michael S. Wieland

The work-principle from thermodynamics was used to formulate a model for predicting toxic fumes from mining explosives in underground chamber tests, where rapid turbulent combustion within the surrounding air noticeably changes the resulting concentrations. Two model constants were required to help characterize the reaction zone undergoing rapid chemical transformations in conjunction with heat transfer and work output: a stoichiometry mixing fraction and a reaction-quenching temperature. Rudimentary theory with an unsteady uniform concentration gradient was taken to characterize the combustion zone, yielding 75% for the mixing fraction. Four quenching temperature trends were resolved and compared to test results of ammonium nitrate compositions with different fuel-oil percentages (ANFO). The quenching temperature 2345 K was the optimum choice for fitting the two major components of fume toxicity: carbon monoxide (CO) and total nitrogen oxides (NOx). The resulting two-constant model was used to generate comparisons for test results of ANFO compositions with additives. Though respectable fits were usually found, charge formulations which reacted weakly could not be resolved numerically. The work-principle model yields toxic concentrations for a range of charge formulations, making it a useful tool for investigating the potential hazard of released fumes and reducing the risk of unwanted incidents. Keywords: Toxicity; Fumes; Explosives

By Samuel A. Goldberg

The Federal Coal Mine Health and Safety Act of 1969 delegated to the Bureau of Mines a yearly program of health inspections. Respirable coal mine dust concentrations are measured by Bureau inspectors. Samples of respirable coal mine dust are weighed to determine dust concentration and then analyzed for ash and quartz content. This paper describes the laboratory procedure for determining the percent quartz in the respirable coal mine dust samples.

Jan 1, 1972

By W. H. Ode

Low-temperature distillation tests at 200°, 350°, and 500° C. were made on a subbituminous coal from Boulder County, Colo., and a subbituminous coal from Weld County, Colo., in connection with a survey of carbonizing properties of American coals4/ and. investigations of their chemical and physical properties.5/ The coal represented by the sample from weld County was reported to give off combustible volatile matter at unusually low temperatures when placed on a fuel bed. The yields of tar and oil and the composition of the gas from this coal, as obtained in the distillation tests, did not confirm this report. These yields and the gas composition of the Weld County coal differed but little from those obtained from the coal from Boulder County. Both coals yielded tar and gas in amounts considered to be normal for coals of their rank.

Jan 1, 1937

By Rose L. Ballard

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of volume I and in the State chapters of volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1984

By G. B. Atkinson

Properties of catalysts prepared from intermetallic compound precursors were investigated by the Bureau of Mines as part of its mission to decrease U.S. dependence on foreign sources for scarce catalytic materials, such as nickel, cobalt, and chromium. Methods were developed whereby catalysts with surface areas of 30 to 40 m2/g were prepared from intermetallic compounds. Activity of these catalysts for the methanation reaction and methanol synthesis was deter-mined using a fixed-bed, single-pass, flow-through reactor. Catalysts prepared from rare-earth-nickel intermetallics had specific activity for methanation that was five times greater than that of commercial catalysts and were equal to or better than commercial catalysts with regard to sulfur tolerance. Under identical reaction conditions, catalysts prepared from thorium-copper intermetallics produced more than 10 times as much methanol as a commercial low-pressure catalyst and exhibited a high degree of catalytic stability.

Jan 1, 1982

By E. D. Gardner

A custom gold and silver plant is one that treats ores for a fee. Usually such plants are located in mining districts and treat local ores. Ores of milling grade generally can stand only moderate transportation charges. These plants are scattered throughout the West. Most plants now doing a custom business originally were built by mining companies to handle ores from their own mires. As excess mill capacity became available ores from neighboring properties were treated, vainly as an accommodation. Later, as their own ore bodies became depleted, the mills were operated entirely on a custom basis. A few plants pull ore from their own mines only when the supply of custom ore is insufficient to keep the mill operating. Some of the present custom plants were built for custom work alone. Although built originally to treat the ores of the Golden Cycle mine, the Golden Cycle plant at Colorado Springs, Colo., soon became a custom mill and has been operating successfully for many years. It is the largest gold mill in the Western States and. treats Cripple Creek ores, from which most of its tonnage still comes. The plant is equipped to treat a great variety of ores and receives shipments from a wide area. It competes with smelters in Colorado, as it has a roasting plant to prepare sulphide concentrates for treatment in its cyanide plant. Most custom mills, however, are not adapted for more than one or two kinds of ore. Gold occurs in its ores both in the metallic state (free) and locked up in sulphides. It also occurs in a few places, notably at Cripple Creek and a few other Colorado districts, as tellurides. Mien the gold occurs in the native state, the ores is said to be free-milling and can be recovered by amalgamation. Usually, however, some subsidiary treatment is required to make a satisfactory extraction. Amalgamation generally was followed by tabling in the earlier mills; at present, flotation has replaced tables at many places. As depth is reached in raining and the workings extend below the oxidized zone the character of the ore usually changes, or, as the miners say, "it gets base". Since the advent of flotation, the average recovery of gold in base ores has been improved-greatly. Cyanidation is applied to some types of both gold and silver ores. The recovery by cyanidation is in general considerably higher than by other methods in vogue and in addition has the advantage of making a finished product which can be sold directly to the mist, thus obviating smelting charges on concentrate and discounts

Jan 1, 1935

By Oleg Terichow

The Bureau of Mines studied the penetration of a slender cylindrical tube into a sand bed, simulating seafloor material under the application of a static load. The factorial experimental design was based on three factors: tube diameter, geometry of penetrating bit, and seawater saturation of sand, all of which were found to be significant in influencing the depth of penetration. The geometry of the penetrating bit, or shoe, is of major significance in the mechanics of penetration and should be considered the most important factor for additional study. Linear regression analyses of the load-penetration data show that the relationship is linear.

Jan 1, 1970

By Robert P. Vinson

A sequential sampler, based on the Archimedes screw, has been developed by the Bureau of Mines. Its initial purpose was to collect air samples during tracer gas studies in underground mines. However, the basic concept can be applied to other sampling needs, including sampling of liquids. A prototype was built and successfully tested in the Bureau's Experimental Mine at Bruceton, Pa. The simple design makes the sampler inherently durable and low in cost.

Jan 1, 1976

By D. Caruso

The health and financial costs of cumulative injuries are plaguing the mining industry. Industry leaders are concentrating on reducing the risk of injury to their workers through design and redesign of work environments. While ergonomics is not a currently regulated field, many mines are realizing that the only way to tackle their most costly injuries, cumulative injuries, is to make the proactive choice to understand those injuries, their root causes and to make workplace changes to prevent them from occurring. Reduction of these injuries not only improves the health and morale of the workers but increases productivity and profit for the companies. Knowledge and reporting of ergonomic risk factors by employees and ergonomics committees is key to these changes and to the reduction of cumulative injuries. NIOSH is developing strong relationships with industry associations and equipment manufacturers to leverage their communication abilities to transfer knowledge to their customers and make a difference in the health and safety of U.S. miners. The benefits of a formalized approach to reducing these injuries along with examples will be presented.

By L. R. Burdick

The Smokescope is an instrument recently developed for determining the density of smoke by shade comparison. The instrument is designed so that the smoke is seen adjacent to two shades of gray corresponding to Nos. 2 and 3 on the Ringelmann chart. Data on smoke density are important in the smoke-abatement field. The method that is specified and accepted as standard for smoke-density determination by the majority of city smoke regulations involves comparing the smoke shade with the four shades on the Ringelmann chart as published by the Bureau of Mines.2/ This investigation was made to determine the accuracy and convenience of the Smokescope. It was conducted as a part of the Bureau I s air-pollution work, which includes the study of techniques that will promote smoke abatement. The accuracy of the Smokescope was arbitrarily defined as the difference between the Smokescope determinations and the determinations by the accepted, standard method and was expressed as Smokescope correction. Although the corrections obtained were strictly correct only for the two observers and the Smokescope of the investigation, they indicate what might be expected from any observer who uses a Smokescope with reference shades that duplicate those of the test instrument. The report is devoted largely to the data on Smokescope correction, which were taken from a single stack under controlled smoke conditions. Field work, which was done at various locations with different stacks, is mentioned briefly in connection with the comparison of the convenience of the two methods. The data for estimating Smokescope correction were taken for the three variables that were expected to affect the results, namely, the density of the smoke, the amount of light, and the color of the sky behind the smoke.

Jan 1, 1955

By Fred N. Kissell

Experimental work by the Bureau of Mines indicates that when a coalbed is degassed by boreholes, the flow of methane may actually increase with time. This phenomenon appears to be the result of a relative-permeability effect; that is, the coalbed permeability to the gas increases sharply with decreasing water saturation. This report reviews the background of experimental evidence indicating a relative-permeability effect, and presents the results of a computer simulation of two-phase flow in coal.

Jan 1, 1975

By Fred N. Kissell

Methane-flow and pressure data taken from a mine in the Pocahontas No. 3 coalbed are compared with flow rates from lump coal obtained in laboratory experiments. From this, it is concluded that the main source of gas is the intact coalbed rather than a "crushed zone" near the working face. The permeability and sorption capacity of the intact coalbed are calculated and gas emission rates are theoretically accounted for.

Jan 1, 1972