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By B. T. McKenna, H. Nirschl, P. Morsch, B. Fränkle

Generally, filter media used in filter presses have a limited operational life. Besides mechanical damage, there is a growing deposition of fine particles with increasing filtration cycles, the so-called blinding, inside the filter cloth. The resulting decreasing pore diameters not only affect the efficiency of the filtration process itself by increasing the filter medium resistance, but also make it more difficult to regenerate the filter press between the individual cycles, e.g. leading to an insufficient cake discharge. Since tailings filtration requires handling of large process flows containing a significant fraction of particles in the lower micrometer range, an investigation into media rejuvenation is of interest. Keywords: Tailings filtration, filter fabric resistance, filter media regeneration, filter cleaning, intraweave contamination

Jan 1, 2020

By A. Angelov, U. Peukerd, S. Gaydardzhieve, A. Stefanov, K. Grossman, V. Stoilov

Flotation concentrate originating from the Asarel-Medet porphyry copper mining and processing complex in Bulgaria has been subjected to regrinding using a Ro-Star mill; the effects of which on the downstream metallurgical behaviour are discussed. Particularly the effect on the liberation degree was studied through an optical microscopy and MLA-SEM automated mineralogy. On the other hand, copper selective flotation of the reground bulk concentrate was realised to evaluate the anticipated metallurgical improvement. Process parameters such as involvement of prior hydrocycloning and variation of collector dosage have been evaluated. Within a two-minute residence time inside the Ro-Star mill, an improved liberation degree of the copper bearing minerals has been observed. As a consequence, enhanced copper recovery and selectivity against pyrite was noted. It has been found that in order to guarantee efficient flotation of the resulting ultrafine particles, a modified flotation regime (i.e. changing collector suite and dosages) should be followed. Keywords: RoStar Mill, liberation, flotation recovery, ultrafine particles

Jan 1, 2020

By F. Rosenblum, K. E. Water, J. A. Finch, S. Moon, Y. H. Tan

Previous work has shown that sulphide self-heating occurs in three distinct stages referred to as Stage A, Stage B and Stage C. In this paper the focus is on the transition from Stage A to Stage B, which occurs at ca. 100OC. Background literature hints that the transition corresponds to the transformation of the rhombic form of elemental sulphur to the more reactive monoclinic form that occurs at 96OC. A test apparatus is modified for adiabatic heating to track the transition. The results support this transformation of sulphur as being key to the transition, and the transition temperature is thus modified to 96OC. Variations in a sample’s response under adiabatic conditions are observed and possible reasons are discussed. Testing in adiabatic mode provides new insights into the sulphide self-heating process that complement the test designed to identify propensity to self-heat. Keywords: Self-heating; Stage A/Stage B; transition; rhombic/monoclinic elemental sulphur; adiabatic heating

Jan 1, 2020

By M. P. Brandt, T. P. Knoetze, I. I. M. Kessler

It has generally been accepted that the volatile mater in a coal is the factor that determines whether or not a specific coal dust is an explosion risk. This paper presents the results of an attempt to relate the explosibility index (Kex) of South African coals, as determined in a AD-litre explosion vessel, to the volatile mater content of the coal and the calorific value of the volatiles. A good relationship between the calorific value of the volatiles and the explosibility index was established, which makes it possible to calculate the violence of an explosion, as expressed by Kex, for South African coals. The Kex value is but one of a number of parameters that influence the explosion hazard in a specific colliery and cannot be used as the sole predictor of the propagation of an explosion underground. Other parameters include the ignitability of the coal, temperature, humidity, dispersibility of the dust, methane concentration, amount of incombustibles present, and ventilation.

Jan 1, 1993

By M. Mbonami, R. Pretorius, J. Miller, P. Kyony, B. Nel, N. Mautsa

Challenges due to the formation of stable froth in acid leach systems is common at many copper and Ccbalt producers. Stable froth affects downstream process, critical equipment, and operational parameters. In severe cases the froth present safety and environmental risks and increased operational costs. Solids reports in the pregnant leach solution, accumulates, and clogs launders resulting in a potential costly safety and environmental risk. Solvent extraction is operationally affected by crud formation, organic solvent and extractant losses, reduced mass transfer due to the solids carried downstream. This article reviews the generally inadequate mechanical and hydraulic solutions of froth elimination employed over the years. The recent introduction of a chemically based solution able to eliminate froth problems that can potentially turn around the situation for those who adopt the technology.

Jan 1, 2023

By P. F. Dicks, N. J. Shackleton, E. H. W. Theron, V. Malysiak

Flotation is a complex physical chemical process in which flotation reagents play a vital role in valuable minerals recovery and concentrate grades. This study examines the performance of new generation AECI Mining Chemicals (previously named Senmin) collectors. They were developed to enhance the valuable minerals recovery and flotation selectivity by tailoring the collectors to target specific valuable mineral species present in an ore and thus create added value for concentrators treating PGM ores. The case study was conducted on a Platreef ore, where batch flotation tests were performed and the concentrates were mineralogically characterised for PGE and BMS using QEMSCAN. Further batch flotation testwork was conducted on Merensky and UG2 ores from various localities in South Africa to confirm the trends observed for Platreef ore. The results have shown that there is a strong correlation between PGE mineral type and AECI Mining Chemicals collector type - clearly demonstrating that one reagent type does not fit all flotation applications. Keywords: Batch flotation, QEMSCAN, collectors, PGE and BMS

Jan 1, 2020

By N. B. Prenn, R. H. Robinson

"The model described is a design and economic planning tool for analyzing surface mineral deposits. Mineralization, topography, costs and significant geologic features are input to the model. The results are:(i) final pit limits yielding the maximum total profit,(ii) annual cut-off grades and plant sizing yielding the maximum present value, and(iii) annual maps of the pit and annual production statistics for the mine, concentrator and smelter.Additionally, summaries are printed of the block mining sequence and cash flow. A special feature is an option to include dump-leaching operations. Stockpiling of material can also be simulated by the model. The model is built around theories of dynamic cut-off grades and a pit design algorithm. The dynamic cut-off grades maximize present value by examination of all economic and physical constraints for the optimum combination. The pit design algorithm is a set of rules formulated to find the maximum value from a special graph. The graph is different from graphs of analytical geometry, being made up of points and arrows connecting some of the points. These graph elements describe the relationship between any point in the deposit and the material which must be mined to get at that point. The model was designed to bring together the interdependent theories of economics, pit design and production scheduling."

Jan 1, 2014

By H. P. Kritzinger, T. C. Kingsley

Rotary kilns are used for a variety of mineral processing operations. Hatch makes use of a kiln model developed from first principles to evaluate designs for its clients. This tool has been applied to a variety of pyrometallurgical applications. This paper illustrates the application of numerical optimization techniques in combination with the kiln model in the interrogation of a generic iron-ore reduction process. The fundamental modelling concepts are explained, followed by a description of the optimization approach. The results show how the combination of the two methods, with modern computing power, can generate a large number of viable design and operating candidates.

Jan 1, 2014

By T. H. Yang, Q. K. Wang, T. Song, J. W. Zhou

The grinding circuit can be one of the most important mineral processing circuits in plants. Along with the application of large-scale milling machines, the design and optimisation of the operation strategy for grinding circuits is more complicated. An in-house grinding process simulation tool was developed to mass balance, model fit and simulate crushing, grinding and classification circuits. An industrial grinding and classification circuit in a copper mine was modelled, and the modelling parameters were verified by a particular group of plant survey data. To justify the prediction ability of the fitted models, the model predictions under different operation conditions were compared with another group of plant survey data. Then the model predicted the effects on the circuit of changing operating conditions. Circuit analysis of the comminution process for water feed to a SAG mill, water feed to sump, the rolling speed of a SAG mill and the percentage of ball filling in a SAG mill was put into practise, based on the simulation results. The simulation results can be used to help plant operators understand the features of the comminution process and may help to build a knowledge library for process control. Keywords: Process modelling, grinding, comminution, circuit analysis

Jan 1, 2020

By L. J. Su, J. Y. Zhang, P. W. Gu, J. F. Xu

Surface tension of mold flux is a key factor affecting optimum casting conditions. A thermodynamic model was developed to determine the surface tension of mold flux containing fluoride based on the ion and molecule coexistence theory of slag structure and Butler’s equation. The relationship between composition and surface tension was investigated by this model. Results indicated that the calculated values showed good agreement with literature data, and the average error was 8.19%. The surface tension value of the CaO–Al2O3-based mold flux was larger than that of the CaO– SiO2-based mold flux. The surface tension in a multi-component system decreased with increasing contents of SiO2, CaF2, and Na2O, which are considered surface-active components. This trend was more significant in the CaO–Al2O3-based mold flux.

Dec 11, 2024

By D. He, A. Yaacoubi, A. Baçaoui, K. Boujounoui, A. Abidi, K. El Amari

The effects of utilizing recycled tailings pond water from the flotation plant at the Mining Company of Guemassa (MCG) on galena recovery and selectivity towards chalcopyrite (RPb-Cu) , sphalerite (RPb- Zn), and pyrrhotite (RPb-Fe) were studied at bench scale. The results showed that recycling the tailings pond water in the lead circuit without addition of fresh water gave a good flotation performance in terms of lead recovery (Rpb) (75%) and selectivity towards the other metals: RPb-Cu (54%), RPb-Zn (60%) and RPb-Fe(65%). This allows the water to be recycled at least four times. However, increasing the d80 from 100 μm to 160 μm currently used at the MCG plant had a negative effect on the lead flotation performance.

Nov 30, 2022

By D. A. Cowen

Toll and custom treatment of base metal concentrates have been performed for decades as mines and concentrators are developed distant from capital and, energy-intensive smelting and refining facilities. Commercial treatment terms have been developed and refined for over a century, and are negotiated taking into account a complex array of quality and economic factors. Treatment of third-party concentrates in the South African platinum industry is a comparatively recent development, brought about by the opening up of mineral rights and operations being developed that are smaller than the critical size required to sustain capitalization of smelting or refining plant. Published commercial terms have not been demonstrated to reflect the complexities and subtleties of base metal concentrate markets. This paper outlines some key elements and parameter ranges of base metal concentrate treatment contracts, and applies similar principles to typical Merensky and UG2 platinum group element (PGE) concentrates to determine potential value distribution between the mining and treatment parties in tolling arrangements.

Jan 1, 2012

By L. Rojas Mendoza, F. J. Hrach, A. Gupta, K. P. Flynn

ST Equipment & Technology (STET)’s tribo-electrostatic belt separator technology allows for the beneficiation of fine mineral powders by means of an entirely water-free technology with high throughput and low energy consumption. The STET separator is suited for separation of very fine (<1 μm) to moderately coarse (500 μm) particles, in contrast to other electrostatic processes that are typically limited to particles >75 μm in size. STET has performed exploratory studies with several iron ores including tailings and experimental results to date have demonstrated that low-grade iron fines can be upgraded by means of STET tribo-electrostatic separator to commercial grades (58-65%Fe). Experimental results together with high-level economic evaluations indicate that scavenging processes involving low drying costs, DSO operations and tailings beneficiation offer a commercially viable processing method to recover fine iron that would otherwise be lost by traditional processing. Dry electrostatic processing of iron ore presents a clean, low-energy opportunity for iron producers to reduce costs and wet tailings generation associated with traditional gravimetric, flotation and wet magnetic separation circuits. Moreover, STET technology allows for mining waste utilisation and resource recovery from iron ore fines and tailings, therefore offering processors a novel method to recover fines that would otherwise be difficult to process to sellable grades with existing technologies. Keywords: Iron fines, industrial minerals, dry separation, calcium carbonate, talc, barite, quartz, tribo-electrostatic charging, belt separator, fly ash

Jan 1, 2020

By A. Chryssoulis, D. Venter, R. Dunne

An often-overlooked parameter of flotation processing is the impact of surface chemistry. Flotation processing, being a heterogenous process is largely reliant upon the chemistry occurring at the interfaces between solid-liquid phases. Development of analytical techniques such as Auger electron spectroscopy, X-Ray photoelectron spectroscopy (XPS) and low energy electron diffractions (LEEDS) has allowed for a dynamic view characterizing surface composition and structures. The advent of ‘static’ systems, capable of measuring ultra-thin layers on surfaces at low concentrations, was the next step in surface analytical developments. In general, it is the low concentrations and fragmentation patterns which limit the analysis of certain chemical species at plant concentration ranges. At present, analysis of inorganic and organic surface modifiers by time of flight mass spectrometers with a variety of ionization techniques has become a common analytical method to measure chemical species on the outermost surface of mineral particles. By studying the relationship between surface analysis results with metallurgical outcomes, the implications of the presence of surface species can be determined. The presence of flotation activators or depressants can be established using Laser Ionization Mass Spectrometry (LIMS) and Resonant Ionization Mass Spectrometry (RIMS) which are highly versatile surface sensitive analytical techniques. A case study applied to sphalerite flotation in the Neves Corvo Cu-Pb-Zn concentrator and the implication inorganic surface modifiers have is presented. By determining the relative concentrations of Cu, Pb, oxidation products, Ca and other surface species in floated and rejected mineral particles, rationale for improving recovery and selectivity is elucidated. Keywords: Cu-Pb-Zn Flotation, Process Mineralogy, Surface Chemistry, Flotation kinetics

Jan 1, 2020

By J. L. Havenga, L. J. van der Walt, J. T. Nel, H. Bissett

"SynopsisNew technologies used to manufacture high-quality components, such as direct laser sintering, require spherical powders of a narrow particle size distribution as this affects the packing density and sintering mechanism. The powder also has to be chemically pure as impurities such as H, O, C, N, and S causes brittleness, influence metal properties such as tensile strength, hardness, and ductility, and also increase surface tension during processing.Two new metal powder processes have been developed over the past few years. Necsa produces zirconium powders via a plasma process for use in the nuclear industry, and the CSIR produces titanium particles for use in the aerospace industry.Spheroidization and densification of these metal powders require remelting of irregular shaped particles at high temperature and solidifying the resulting droplets by rapid quenching. Spherical metal powders can be obtained by various energy-intensive methods such as atomization of molten metal at high temperatures or rotating electrode methods. Rapid heating and cooling, which prevents contamination of the powder by impurities, is, however, difficult when using these methods for highmelting- point metals. For this reason plasma methods should be considered.Thermal plasmas, characterized by their extremely high temperatures (3000–10 000 K) and rapid heating and cooling rates (approx. 106 K/s) under oxidizing, reducing, or inert conditions, are suitable for spheroidization of metal powders with relatively high melting points. Thermal plasmas for this purpose can be produced by direct current (DC) plasma arc torches or radio frequency (RF) inductively coupled discharges. In order to obtain chemically pure spheroidized powder, plasma gases such as N2, H2, O2, and CH4 cannot be considered, while Ar, Ne, and He are suitable. Neon is, however, expensive, while helium ionizes easily and it is therefore difficult to obtain a thermal helium plasma at temperatures higher than 3000 K. Therefore argon should be used as plasma gas. Residence times of particles in the plasma region range from 5–20 ms, but this is usually sufficient as 7–8 ms is required for heating and melting of titanium or zirconium metal particles in the 30 µm size range at 3500 K. In this study the melting and spheriodization of titanium powders was investigated by DC non-transferred arc and RF induction plasma methods. The powders were characterized before and after plasma treatment by optical microscopy and scanning electron microscopy (SEM) to observe if any melting or spheroidization had occurred."

Jan 1, 2015

By Ernst-Ulrich Reuther, Alexander Donmen

Mine ventilation in the German coal mining industry is concerned mainly with problems of thermal environment arising from greater depths and with increasing emission of methane gas. The development of computer techniques over the past ten years for solving these and ancillary problems is reviewed. The emphasis from a planning and control point of view falls mainly on ventilation network calculations, temperature predictions and advance estimates of methane emission.

Jan 1, 2014

By A. E. Lewis, J. Du Plessis, J. Chivavava

Current metallurgical processes lack selective and efficient REE recovery from aqueous leach liquors. Antisolvent crystallisation is used to selectively recover pure inorganic salts from aqueous solutions without excessive chemical use in ambient conditions. Yttrium sulfate octahydrate (Y2(SO4)3.8H2O) was used as a representative rare earth salt to investigate the effect of antisolvent selection on the crystal morphology and size distribution of the final crystalline product produced through antisolvent crystallisation. The antisolvents of choice were short length alcohols that are water miscible i.e. methanol, ethanol, 2-propanol and t-butanol. All experimental parameters except the type of antisolvent were kept constant under isothermal conditions. The large reduction in solubility of the salt by the antisolvent creates high supersaturations. This leads to high product yields as observed in this study at > 91%. In general, a variety of morphologies were successfully formed in each individual alcohol including; rods, plates, prismatic cubes and starburst clusters. The powder X-ray diffraction (XRD) analysis indicated that Y2(SO4)3.8H2O was the only species present for all final products. There was a change observed from the starburst and rod structures for the shorter alcohols towards prismatic cubes for the longer alcohols due to different strengths in the solute-antisolvent interaction at the crystal growth faces. The crystal sizes increased with an increase in the alcohol chain length because of the lower supersaturation conditions due to a limit in the mass transfer induced by the bulkier alcohol structure. In conclusion, it has been shown that the particle morphology and size can be greatly affected by the selection of antisolvent even under high supersaturation conditions, contributing to understanding the effect of different antisolvents on the final particle characteristics. The engineering of favoured product characteristics can therefore be achieved by antisolvent crystallisation, presenting a viable alternative process for the recovery of REE. Keywords: Antisolvent crystallisation, rare earth elements, morphology, particle size

Jan 1, 2020

By Q. Cui, B. Z. Zhou, Z. G. Song, Y. G. Zhu, G. B. Zheng

The complex refractory Cu-Pb-Zn polymetallic ore in Xinjiang, China is a massive sulphide ore with complex mineral components. In the past two years, the ore mineralogy has changed, resulting in a decline in metallurgy, with too much zinc reporting to the lead and copper concentrates. A detailed mineralogical study indicating the presence of secondary copper minerals, which could be activating the sphalerite early in the present circuit, was used to develop a novel reagent and flotation flowsheet termed “Pb-Cu co-flotation, Cu intensified flotation, Zn flotation”. It was tested and found to significantly contribute to improving the flotation performance of the ore. In the Pb-Cu co-flotation circuit, successful depression of pyrite and sphalerite was achieved using a BK612- Na2S based depressant system. Most of the galena and some of the Cu bearing minerals with excellent floatability were collected with the use of the selective collector BK906. The rest of Cu bearing minerals were floated in a copper Z200 circuit using a BK537-lime-zinc sulphate based depressant scheme. Zinc flotation from the copper tailing was performed in a SIBX circuit using lime as a pyrite depressant. Using the proposed flowsheet, overall Pb, Cu, and Zn recovery increased significantly to 88%, 87%, and 90% respectively. Keywords: Complex polymetallic ore, Cu-Pb-Zn, Pb-Cu co-flotation, particle size

Jan 1, 2020

By C. Chingwaru, W. Chingwaru, J. Vidmar

"Zimbabwe is endowed with rich deposits of minerals such as diamonds, platinum, coal, uranium, lithium, gold, antimony, iron, and chrome. Bioleaching has been implemented as an efficient and low-cost method to extract metals such as copper, cobalt, and gold from sulphide and/or ironcontaining ores and mineral concentrates in a number of countries around the globe. Zimbabwe, despite being a world leader in mineral wealth, has gone through years of economic stagnation which have brought with them energy shortages. Bioleaching is an innovative way to recover minerals from ores using relatively low-capital-cost and non-polluting technology. Principally, iron- and sulphur-oxidizing bacteria can be used to oxidize iron and sulphide to ferric iron and sulphuric acid, respectively, and the ferric iron oxidizes the insoluble metal sulphides to soluble metal sulphates that can be readily recovered from solution. Although some minerals such as gold are inert to biological reactions, they can be liberated using bacteria that act on certain types of ores and other minerals that co-occur with these minerals. The geology of the mineralized areas in Zimbabwe, rich in chalcopyrite / pyrite, allows a number of microorganisms to be used for the extraction of minerals by bio-oxidation. This paper reviews the potential of bioleaching in the country. IntroductionZimbabwe has rich deposits of minerals including diamonds, platinum, coal, uranium, lithium, gold, antimony, iron, and chrome. Bioleaching is defined as the use of microorganisms to facilitate the extraction of metals from sulphide or iron-containing ores or concentrates (Rawlings, 2004, 1997). Bioleaching has been shown to be an efficient (Blowes, Ptacek, and Jurjovec, 2003; Nordstrom and Southam, 1997; Schippers, 2004) and low-cost (Schippers et al., 2010) method to extract minerals in many countries around the globe. For example, aerobic Fe(II)- and sulphur-oxidizing bacteria have been shown to be up to two orders of magnitude more efficient in the oxidation of pyrite than the chemical processes (Blowes, Ptacek, and Jurjovec, 2003; Nordstrom and Southam, 1997; Schippers, 2004). Additionally, bioleaching can be used to extract minerals from low-grade ores, sulphidic waste rock dumps, and tailings efficiently (Schippers et al., 2010)."

Jan 1, 2017

By D. Kumar, B. Rai, S. G. Srinivasan, V. Jain

Chalcopyrite and pyrite are among the major gold bearing minerals in the world. The gold content in chalcopyrite and pyrite varies from 0.02 to 200 ppm and 0.01 to 20 ppm, respectively. Apart from gold, chalcopyrite is also the primary source of copper. Thus, the recovery of gold and copper are often associated with the recovery of chalcopyrite and pyrite. Flotation is one of the most successful methods applied to beneficiate chalcopyrite and pyrite. The success of a flotation process depends on an appropriate choice of the flotation collector used to achieve the desired selectivity. A thorough understanding of the atomic structure of the predominantly exposed mineral surfaces can immensely aid in developing highly selective collectors that can exploit both the physical and chemical characteristics of these surfaces. In the present study, density functional theory calculations within the plane wave framework are used to understand the surface structure and reconstruction of the most stable chalcopyrite (001), (100), (110) and (112) and most stable pyrite (100) surfaces. The chalcopyrite (001) and (100) metal-terminated surfaces undergo significant reconstruction and result in metal-metal bond formation in the sub-surface layer while the surface layer is replaced by S-atoms. On the other hand, the (001) and (100) S-terminated surfaces show S—S disulfide bond formation upon relaxation, which are consistent with literature reports. The chalcopyrite (110), (112) surfaces and pyrite (100) surface undergo rearrangement, but no reconstructions in terms of metal-metal or disulfide bond formation are observed on these surfaces. Keywords: DFT, surface reconstruction, pyrite, chalcopyrite, adsorption

Jan 1, 2020